Abstract: Methods and apparatuses for measuring mechanical properties of electrodes during electrochemical reactions. Such an apparatus includes a fixture having a fluid reservoir that is open to a surrounding atmosphere, first and second electrodes located within the fluid reservoir, and a contact for coupling with a sample material located in the fluid reservoir to define a third electrode. The apparatus further includes a nanoindenter configured for applying a load to a surface of the sample material to form an indentation therein and measuring the load and the size of the indentation over time, a housing enclosing the fixture and the nanoindenter within an inert atmosphere, and a potentiostat configured to charge and discharge an electrochemical cell that is defined by the first, second, and third electrodes and an electrolyte solution in the fluid reservoir while the nanoindenter is applying the load.

Abstract: Methods and apparatuses for measuring mechanical properties of electrodes during electrochemical reactions. Such an apparatus includes a fixture having a fluid reservoir that is open to a surrounding atmosphere, first and second electrodes located within the fluid reservoir, and a contact for coupling with a sample material located in the fluid reservoir to define a third electrode. The apparatus further includes a nanoindenter configured for applying a load to a surface of the sample material to form an indentation therein and measuring the load and the size of the indentation over time, a housing enclosing the fixture and the nanoindenter within an inert atmosphere, and a potentiostat configured to charge and discharge an electrochemical cell that is defined by the first, second, and third electrodes and an electrolyte solution in the fluid reservoir while the nanoindenter is applying the load.