Patents by Inventor Luqiang Yu

Luqiang Yu has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 10544242
    Abstract: The invention discloses a process for preparing high-performance propylene polymers, the process utilizing a high activity, highly stereoselective Ziegler-Natta catalyst and two or more stages of polymerization carried out under different hydrogen concentrations to prepare propylene polymers having broad molecular weight distribution, wherein non-uniformness of isotacticity of molecular chains of the final propylene polymers is improved by adjusting or controlling stereoselectivity of catalytic active sites under different hydrogen concentrations, namely, making the low molecular weight fraction of the polymers having a higher isotacticity and making the high molecular weight fraction of the polymers having a lower isotacticity, thereby overcoming the drawbacks of the propylene polymers having broad molecular weight distribution known in the art. The resulting final polymers have excellent combined properties, in particular, remarkably improved mechanical properties.
    Type: Grant
    Filed: May 12, 2015
    Date of Patent: January 28, 2020
    Assignees: China Petroleum & Chemical Corporation and Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation
    Inventors: Wenbo Song, Meifang Guo, Jinliang Qiao, Zhichao Yang, Shijun Zhang, Luqiang Yu
  • Patent number: 10301405
    Abstract: Disclosed herein are a polypropylene with narrow molecular weight distribution and a process for preparing the same in a reactor using a Ziegler-Natta catalyst.
    Type: Grant
    Filed: October 30, 2013
    Date of Patent: May 28, 2019
    Assignees: Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corp, China Petroleum & Chemical Corporation
    Inventors: Liangshi Wang, Luqiang Yu, Shijun Zhang, Jinliang Qiao, Meifang Guo, Zhichao Yang, Jianjun Yin, Honghong Huang, Liping Hou, Jianfang Sheng
  • Patent number: 9988505
    Abstract: A polyethylene composition comprising an ethylene/?-olefin copolymerized linear low density polyethylene, wherein the polyethylene composition has a Mw of from 100,000 g/mol to 200,000 g/mol, a Mw/Mn of from 4.0 to 9.0, a Mz/Mw of from 4.0 to 7.0, and a Mz+1/Mw of from 4.5 to 13.5, is provided. A film formed of the polyethylene composition is also provided.
    Type: Grant
    Filed: October 27, 2015
    Date of Patent: June 5, 2018
    Assignees: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry, China Petroleum and Chemical Corporation
    Inventors: Dali Gao, Hongwei Shi, Shijun Zhang, Meifang Guo, Luqiang Yu, Jinliang Qiao, Ruxian Li, Yujing Tang, Jianjun Yin, Liangshi Wang, Honghong Huang, Qingquan Yang, Hao Zou, Jie Li, Liying Zhang, Hua Yin, Jianye Liu, Jingbo Shao, Mingfu Lyu, Liqiu Chu, Meng Xu, Hui Quan, Kai Xu, Mu Dong, Yun Lyu, Yihui Xu, Yaohui Xu, Peng Guo, Yiqing Bai
  • Patent number: 9751965
    Abstract: Disclosed herein is a polymerization method of propylene, which can prepare a propylene homopolymer with both high fluidity and high rigidity as well as a propylene/?-define copolymer having both high fluidity and a good rigidity-toughness balance by, for example, control of polymerization steps and elevation of polymerization temperature, while the catalyst still maintains a relatively high polymerization activity.
    Type: Grant
    Filed: October 30, 2013
    Date of Patent: September 5, 2017
    Assignees: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation
    Inventors: Luqiang Yu, Zhichao Yang, Jiangbo Chen, Jianxin Zhang, Yafeng Du, Qinyu Tong, Kang Sun, Yang Liu, Jie Zou, Lusheng Wang, Zengyue Dai, Zhong Tan
  • Publication number: 20160115285
    Abstract: A polyethylene composition comprising an ethylene/?-olefin copolymerized linear low density polyethylene, wherein the polyethylene composition has a Mw of from 100,000 g/mol to 200,000 g/mol, a Mw/Mn of from 4.0 to 9.0, a Mz/Mw of from 4.0 to 7.0, and a Mz+1/Mw of from 4.5 to 13.5, is provided. A film formed of the polyethylene composition is also provided.
    Type: Application
    Filed: October 27, 2015
    Publication date: April 28, 2016
    Inventors: Dali GAO, Hongwei SHI, Shijun ZHANG, Meifang GUO, Luqiang YU, Jinliang QIAO, Ruxian LI, Yujing TANG, Jianjun YIN, Liangshi WANG, Honghong HUANG, Qingquan YANG, Hao ZOU, Jie LI, Liying ZHANG, Hua YIN, Jianye LIU, Jingbo SHAO, Mingfu LYU, Liqiu CHU, Meng XU, Hui QUAN, Kai XU, Mu DONG, Yun LYU, Yihui XU, Yaohui XU, Peng GUO, Yiqing BAI
  • Publication number: 20150246986
    Abstract: The invention discloses a process for preparing high-performance propylene polymers, the process utilizing a high activity, highly stereoselective Ziegler-Natta catalyst and two or more stages of polymerization carried out under different hydrogen concentrations to prepare propylene polymers having broad molecular weight distribution, wherein non-uniformness of isotacticity of molecular chains of the final propylene polymers is improved by adjusting or controlling stereoselectivity of catalytic active sites under different hydrogen concentrations, namely, making the low molecular weight fraction of the polymers having a higher isotacticity and making the high molecular weight fraction of the polymers having a lower isotacticity, thereby overcoming the drawbacks of the propylene polymers having broad molecular weight distribution known in the art. The resulting final polymers have excellent combined properties, in particular, remarkably improved mechanical properties.
    Type: Application
    Filed: May 12, 2015
    Publication date: September 3, 2015
    Inventors: Wenbo Song, Meifang Guo, Jinliang Qiao, Zhichao Yang, Shijun Zhang, Luqiang Yu
  • Patent number: 9068030
    Abstract: The present invention provides a process for preparing high melt strength propylene polymer by direct polymerization, comprising that a propylene polymer with wide molecular weight distribution and containing “very high molecular weight fraction” can be prepared by controlling the species and ratios of the external electron donors in the Ziegler-Natta catalyst system at different reaction stages according to the requirement for different molecular weight fractions in the different propylene polymerization stage of the series operation, and said polymer has excellent mechanical properties, especially with very high melt strength. The present invention also provides a propylene homopolymer with high melt strength, comprising the following features: (1) the MFR is 0.2-10 g/10 min at 230° C. with a load of 2.16 kg; (2) the molecular weight distribution Mw/Mn is 6-20; (3) the content of the fraction with a molecular weight higher than 5,000,000 is higher than or equal to 0.
    Type: Grant
    Filed: January 21, 2011
    Date of Patent: June 30, 2015
    Assignees: China Petroleum & Chemical Corporation, Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation
    Inventors: Wenbo Song, Meifang Guo, Shijun Zhang, Wenjun Wei, Honghong Huang, Luqiang Yu, Tao Liu, Huijie Hu, Huan Xu, Peiqian Yu, Xiaomeng Zhang
  • Publication number: 20140121337
    Abstract: Disclosed herein is a polymerization method of propylene, which can prepare a propylene homopolymer with both high fluidity and high rigidity as well as a propylene/?-define copolymer having both high fluidity and a good rigidity-toughness balance by, for example, control of polymerization steps and elevation of polymerization temperature, while the catalyst still maintains a relatively high polymerization activity.
    Type: Application
    Filed: October 30, 2013
    Publication date: May 1, 2014
    Applicants: BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHINA PETROLEUM & CHEMICAL CORP, CNINA PETROLEUM & CHEMICAL CORPORATION
    Inventors: Luqiang YU, Zhichao Yang, Jiangbo Chen, Jianxin Zhang, Yafeng Du, Qinyu Tong, Kang Sun, Yang Liu, Jie Zou, Lusheng Wang, Zengyue Dai, Zhong Tan
  • Publication number: 20140121339
    Abstract: Disclosed herein are a polypropylene with narrow molecular weight distribution and a process for preparing the same in a reactor using a Ziegler-Natta catalyst.
    Type: Application
    Filed: October 30, 2013
    Publication date: May 1, 2014
    Applicants: BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY, CHNA PETROLEUM & CHEMICAL CORP, CHINA PETROLEUM & CHEMICAL CORPORATION
    Inventors: Liangshi WANG, Luqiang YU, Shijun ZHANG, Jinliang QIAO, Meifang GUO, Zhichao YANG, Jianjun YIN, Honghong HUANG, Liping HOU, Jianfang SHENG
  • Publication number: 20130023598
    Abstract: The present invention provides a process for preparing high melt strength propylene polymer by direct polymerization, comprising that a propylene polymer with wide molecular weight distribution and containing “very high molecular weight fraction” can be prepared by controlling the species and ratios of the external electron donors in the Ziegler-Natta catalyst system at different reaction stages according to the requirment for different molecular weight fractions in the different propylene polymerization stage of the series operation, and said polymer has excellent mechnical properties, especially with very high melt strength. The present invention also provides a propylene homopolymer with high melt strength, comprising the following features: (1) the MFR is 0.2-10 g/10 min at 230° C. with a load of 2.16 kg; (2) the molecular weight distribution Mw/Mn is 6-20; (3) the content of the fraction with a molecular weight higher than 5,000,000 is higher than or equal to 0.
    Type: Application
    Filed: January 21, 2011
    Publication date: January 24, 2013
    Inventors: Wenbo Song, Meifang Guo, Shijun Zhang, Wenjun Wei, Honghong Huang, Luqiang Yu, Tao Liu, Huijie Hu, Huan Xu, Peiqian Yu, Xiaomeng Zhang
  • Publication number: 20090326171
    Abstract: The invention discloses a process for preparing high-performance propylene polymers, the process utilizing a high activity, highly stereoselective Ziegler-Natta catalyst and two or more stages of polymerization carried out under different hydrogen concentrations to prepare propylene polymers having broad molecular weight distribution, wherein non-unifomess of isotacticity of molecular chains of the final propylene polymers is improved by adjusting or controlling stereoselectivity of catalytic active sites under different hydrogen concentrations, namely, making the low molecular weight fraction of the polymers having a higher isotacticity and making the high molecular weight fraction of the polymers having a lower isotacticity, thereby overcoming the drawbacks of the propylene polymers having broad molecular weight distribution known in the art. The resulting final polymers have excellent combined properties, in particular, remarkably improved mechanical properties.
    Type: Application
    Filed: April 20, 2007
    Publication date: December 31, 2009
    Inventors: Wenbo Song, Meifang Guo, Jinliang Qiao, Zhichao Yang, Shijun Zhang, Luqiang Yu
  • Patent number: 7611776
    Abstract: The present invention provides a propylene polymer composition for producing a biaxially oriented film, comprising propylene random copolymer and propylene homopolymer; wherein the propylene random copolymer is a copolymer of propylene and ethylene, optionally comprising one or more alpha-olefins of C4-C10; the propylene polymer composition has an overall isotacticity index, as determined by nuclear magnetic resonance method, of greater than or equal to 96.5%, and an ethylene content of greater than 0.3 wt %; and wherein, the melt flow rate of the propylene random copolymer is lower than that of the propylene homopolymer. The biaxially oriented polypropylene film produced by the propylene polymer composition of the present invention exhibits excellent physical properties, and has, in the absence of any stiffening agent, relatively higher modulus and stiffness.
    Type: Grant
    Filed: January 24, 2006
    Date of Patent: November 3, 2009
    Assignees: China Petrochemical & Chemical Corporation, Beijing Research Institute of Chemical Industry, China Petroleum & Chemical Corporation
    Inventors: Luqiang Yu, Meifang Guo, Shijun Zhang, Jinliang Qiao, Wenbo Song, Qingshan Ma, Wei Zhang, Liangshi Wang, Xi Wang, Hao Tang, Rongmei Liu
  • Publication number: 20060182987
    Abstract: The present invention provides a propylene polymer composition for producing a biaxially oriented film, comprising propylene random copolymer and propylene homopolymer; wherein the propylene random copolymer is a copolymer of propylene and ethylene, optionally comprising one or more alpha-olefins of C4-C10; the propylene polymer composition has an overall isotacticity index, as determined by nuclear magnetic resonance method, of greater than or equal to 96.5%, and an ethylene content of greater than 0.3 wt %; and wherein, the melt flow rate of the propylene random copolymer is lower than that of the propylene homopolymer. The biaxially oriented polypropylene film produced by the propylene polymer composition of the present invention exhibits excellent physical properties, and has, in the absence of any stiffening agent, relatively higher modulus and stiffness.
    Type: Application
    Filed: January 24, 2006
    Publication date: August 17, 2006
    Inventors: Luqiang Yu, Meifang Guo, Shijun Zhang, Jinliang Qiao, Wenbo Song, Qingshan Ma, Wei Zhang, Liangshi Wang, Xi Wang, Hao Tang, Rongmei Liu
  • Publication number: 20060154806
    Abstract: The present invention is to provide a composite carrier, which is spheric particles obtainable by contacting magnesium halide with one or more electron donor compounds to form a solution, then mixing the solution with silica material having an average particle size of less than 10 microns to form a mixture, and drying the mixture through spray drying process. The present invention is also to provide a catalyst component comprising said composite carrier. When the catalyst component is used together with a cocatalyst component in propylene polymerization, it exhibits higher polymerization activity and stereospecificity, and can be used to prepare high impact resistent ethylene-propylene copolymer having high ethylene content.
    Type: Application
    Filed: March 7, 2006
    Publication date: July 13, 2006
    Inventors: Wei Chen, Tianyi Zhang, Hongbin Du, Xianzhi Xia, Tongxuan Zhang, Lixin Yan, Yisen Wang, Xinsheng Wang, Jiyu Li, Ping Gao, Maoping Yin, Luqiang Yu, Qingshan Ma, Xiaodong Wang
  • Publication number: 20040229748
    Abstract: The present invention is to provide a composite carrier, which is spheric particles obtainable by contacting magnesium halide with one or more electron donor compounds to form a solution, then mixing the solution with silica material having an average particle size of less than 10 microns to form a mixture, and drying the mixture through spray drying process. The present invention is also to provide a catalyst component comprising said composite carrier. When the catalyst component is used together with a cocatalyst component in propylene polymerization, it exhibits higher polymerization activity and stereospecificity, and can be used to prepare high impact resistant ethylene-propylene copolymer having high ethylene content.
    Type: Application
    Filed: February 19, 2004
    Publication date: November 18, 2004
    Applicants: CHINA PETROLEUM & CHEMICAL CORPORATION, BEIJING RESEARCH INSTITUTE OF CHEMICAL INDUSTRY
    Inventors: Wei Chen, Tianyi Zhang, Hongbin Du, Xianzhi Xia, Tongxuan Zhang, Lixin Yan, Yisen Wang, Xinsheng Wang, Jiyu Li, Ping Gao, Maoping Yin, Luqiang Yu, Qingshan Ma, Xiaodong Wang