Abstract: This invention relates to methods and apparatus for detecting, quantifying, and/or identifying trace quantities of an anion in the presence of an excess of another anion. One apparatus comprises a sample loop having a first end adapted to be connected to a sample-injection device and a second end adapted to be connected to an inlet of a first separator. An outlet of the first separator has connections to a first waste port and to an inlet of a first anion suppressor. An outlet of the first anion suppressor is connected to a first end of a concentrator and alternatively to waste, the concentrator connected at a second end to a second waste port and alternatively to a pump. The first end of the concentrator is alternatively connected to a second separator inlet, and the second separator is connected at an outlet thereof to an inlet of a second anion suppressor; and an outlet of the second anion suppressor is connected to a mass spectrometer.

Abstract: A method of preparing a liquid sample is provided. The method involves steps of: providing a pressurizable vessel that contains a liquid sample in a container, and a sample tube extending from beneath the surface of the liquid sample to a point outside of the vessel; introducing a purge gas into the vessel through a purge-gas inlet conduit, and simultaneously removing the gas atmosphere in the vessel through a purge-gas outlet conduit, thereby displacing the atmosphere in the pressurizable vessel; and pressurizing the vessel with the purge gas to transfer a portion of the liquid sample from the container through the sample tube. Also provided are apparatuses for preparing a liquid sample, as well as methods and apparatuses for performing an analytical measurement.

Abstract: A method of preparing a liquid sample is provided. The method involves steps of: providing a pressurizable vessel that contains a liquid sample in a container, and a sample tube extending from beneath the surface of the liquid sample to a point outside of the vessel; introducing a purge gas into the vessel through a purge-gas inlet conduit, and simultaneously removing the gas atmosphere in the vessel through a purge-gas outlet conduit, thereby displacing the atmosphere in the pressurizable vessel; and pressurizing the vessel with the purge gas to transfer a portion of the liquid sample from the container through the sample tube. Also provided are apparatuses for preparing a liquid sample, as well as methods and apparatuses for performing an analytical measurement.

Abstract: This invention relates to methods and apparatus for detecting, quantifying, and/or identifying trace quantities of an anion in the presence of an excess of another anion. One apparatus comprises a sample loop having a first end adapted to be connected to a sample-injection device and a second end adapted to be connected to an inlet of a first separator. An outlet of the first separator has connections to a first waste port and to an inlet of a first anion suppressor. An outlet of the first anion suppressor is connected to a first end of a concentrator and alternatively to waste, the concentrator connected at a second end to a second waste port and alternatively to a pump. The first end of the concentrator is alternatively connected to a second separator inlet, and the second separator is connected at an outlet thereof to an inlet of a second anion suppressor; and an outlet of the second anion suppressor is connected to a mass spectrometer.