Abstract: The present invention relates to a process for the reduction dechlorination of ClCF.sub.2 CFClCF.sub.2 Cl to HCF.sub.2 CHFCF.sub.2 H comprising the step of contacting 1,2,3-trichloropentafluoroethane and H.sub.2 over a catalyst selected from the group consisting of palladium, platinum, ruthinium, rhodium, iridium and mixtures thereof under reaction conditions sufficent to produce a product stream containing 1,1,2,3,3-pentafluoropropane. The present invention further relates to a three step process wherein the ClCF.sub.2 CFClCF.sub.2 Cl to be reduced is synthesized by:(a) reacting HF with a compound of formula I: XCH.dbd.CYCH.sub.2 X, where X is H, Cl, or F, Y is H or Cl;to give a compound of formula II: CH.sub.2 XCFYCH.sub.2 X, where X and Y are the same as in the compound of formula I:(b) chlorinating the compound of formula II to give a compound of formula III: CCl.sub.3-m F.sub.m CFClCCl.sub.3-m F.sub.m where m is zero or 1, and(c) fluorinating the compound of formula III to give CClF.sub.2 CFClCF.sub.