Abstract: Branched block copolymers, derived from alkenyl aromatic hydrocarbon-1,3-diene monomer system, and branched polyisoprene homopolymers, derived from isoprene, are obtained by polymerization in the presence of an anionic initiator; at a temperature from 0° C. to 100° C.; followed by coupling with a multifunctional coupling agent of formula (R1O)3Si—Y—Si(OR2)3, wherein R1 and R2 are independently C1-C6 alkyl groups; and Y is a C2-C8 alkylene group. The polymers thus obtained can be used in many applications, including rubber cements having high solids content and low zero shear viscosities, and for producing aqueous latices therefrom.

Abstract: Branched block copolymers, derived from alkenyl aromatic hydrocarbon-1,3-diene monomer system, and branched polyisoprene homopolymers, derived from isoprene, are obtained by polymerization in the presence of an anionic initiator; at a temperature from 0° C. to 100° C.; followed by coupling with a multifunctional coupling agent of formula (R1O)3Si—Y—Si(OR2)3, wherein R1 and R2 are independently C1-C6 alkyl groups; and Y is a C2-C8 alkylene group. The polymers thus obtained can be used in many applications, including rubber cements having high solids content and low zero shear viscosities, and for producing aqueous latices therefrom.

Abstract: The disclosure relates to rubber latex formed from any of: branched block copolymers derived from alkenyl aromatic hydrocarbon—1,3-diene monomer system, and branched polyisoprene homopolymers derived from isoprene. The polymers in embodiments are obtained by polymerization in the presence of an anionic initiator; at a temperature from 0° C. to 100° C.; followed by coupling with a multifunctional coupling agent of formula (R1O)3Si—Y—Si(OR2)3, wherein R1 and R2 are independently C1-C6 alkyl groups; and Y is a C2-C8 alkylene group. The polymers are obtained as rubber cements having high solids content and low zero shear viscosities. The rubber cements are valuable for making latices for further applications.

Abstract: Dipped formed latex articles with improved properties are formed from branched block copolymers, derived from alkenyl aromatic hydrocarbon—1,3-diene monomer system, and branched polyisoprene homopolymers, derived from isoprene. The polymers are obtained by polymerization in the presence of an anionic initiator; at a temperature from 0° C. to 100° C.; followed by coupling with a multifunctional coupling agent of formula (R1O)3Si—Y—Si(OR2)3, wherein R1 and R2 are independently C1-C6 alkyl groups; and Y is a C2-C8 alkylene group. The polymers are obtained as rubber cements having high solids content and low zero shear viscosities. The rubber cements are valuable for making latices and latex articles such as dipped goods, e.g., condoms, gloves, etc., with improved properties.

Abstract: The invention concerns an olefinically unsaturated radial styrenic block copolymer having the general formula A-B—Y—(B-A)n wherein each A is independently a polymer block composed of at least 90 mol. % of an alkenyl aromatic hydrocarbon, each B is independently a polymer block composed of at least 90 mol. % of one or more conjugated dienes, Y is the remnant of a coupling agent, and n is an integer from 2 to 5. The invention is also an improved vulcanizer-free latex comprising water and the olefinically unsaturated radial styrenic block copolymer. Moreover, the invention concerns a process for preparing articles by coagulation dipping from the improved latex and dipped goods made from such latex.

Abstract: The invention concerns an olefinically unsaturated radial styrenic block copolymer having the general formula A-B—Y—(B-A)n wherein each A is independently a polymer block composed of at least 90 mol. % of an alkenyl aromatic hydrocarbon, each B is independently a polymer block composed of at least 90 mol. % of one or more conjugated dienes, Y is the remnant of a coupling agent, and n is an integer from 2 to 5. The invention is also an improved vulcanizer-free latex comprising water and the olefinically unsaturated radial styrenic block copolymer. Moreover, the invention concerns a process for preparing articles by coagulation dipping from the improved latex and dipped goods made from such latex.