Patents by Inventor Makhlouf Laleg
Makhlouf Laleg has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 11834785Abstract: The present invention is directed to a method of transforming a pulp fibrous into a pre-dispersed semi-dry or dry fibrous material and to the material produced. The method opens, de-entangles and fibrillates the fibrous material of the input pulp. The method mixes the input fibrous with chemicals while evaporating moisture in an updated mechanical disc refiner process. The refiner operates to set three process variables: 1) applied refining specific energy; 2) refiner gap opening and 3) refiner output consistency. Depending on the feed pulp type and consistency, the refiner's output is a pre-dispersed semi-dry fibrous material of 30 to 99% solids with 70 to 100% of separated fibers that depending on chemical treatment are loosely entangled fibrous that disperse in water using common techniques. The pre-dispersed semi-dry output may be further processed inline or by batch process air agitation at velocities sufficient to further separate fibers and loosen fibrous entanglements.Type: GrantFiled: September 14, 2017Date of Patent: December 5, 2023Assignee: FPInnovationsInventors: Makhlouf Laleg, Lahoucine Ettaleb, Michael Stacey
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Publication number: 20210285156Abstract: The present invention is directed to a method of transforming a pulp fibrous into a pre-dispersed semi-dry or dry fibrous material and to the material produced. The method opens, de-entangles and fibrillates the fibrous material of the input pulp. The method mixes the input fibrous with chemicals while evaporating moisture in an updated mechanical disc refiner process. The refiner operates to set three process variables: 1) applied refining specific energy; 2) refiner gap opening and 3) refiner output consistency. Depending on the feed pulp type and consistency, the refiner's output is a pre-dispersed semi-dry fibrous material of 30 to 99% solids with 70 to 100% of separated fibers that depending on chemical treatment are loosely entangled fibrous that disperse in water using common techniques. The pre-dispersed semi-dry output may be further processed inline or by batch process air agitation at velocities sufficient to further separate fibers and loosen fibrous entanglements.Type: ApplicationFiled: September 14, 2017Publication date: September 16, 2021Applicant: FPInnovationsInventors: Makhlouf LALEG, Lahoucine ETTALEB, Michael STACEY
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Publication number: 20210040273Abstract: Novel meltable lignin compositions having tailored compatibilities, moisture/water-resistant adhesion characteristics, and low to medium glass transition temperatures (30 to 120° C.) desirable for applications in the manufacturing of various products and the integration in the formulations of adhesives, coatings, plastics, composites and masterbatches, are obtained by blending at low temperatures (0-120° C.) dry lignins (0 to 10% moisture), in their hydrogen or protonated forms—hereby referred to as H-forms (pH=2.3-6.5 for a 10% aqueous suspension), with a reactive and/or interactive molecule or combination of molecules.Type: ApplicationFiled: February 7, 2019Publication date: February 11, 2021Inventors: Makhlouf LALEG, Naceur JEMAA, Waleed WAFA AL DAJANI, Yaolin ZHANG, Michael PALEOLOGOU
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Publication number: 20190224929Abstract: The present disclosure relates to wood pulp fiber- or cellulose filament-reinforced bulk molding compounds, composites, compositions and methods for preparation thereof. The composition comprises a resin; about 0.5 to about 15 wt. % of a 5 cellulosic reinforcement wherein the cellulosic reinforcement is chosen from wood-pulp fibers, cellulose filaments (CF) and a mixture thereof; and about 30 to about 65 wt. % of a filler.Type: ApplicationFiled: June 21, 2017Publication date: July 25, 2019Inventors: Otman OULANTI, Makhlouf LALEG, Danielle GAGNÉ, Norayr GURNAGUL, Josée DESMEULES
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Patent number: 10195888Abstract: The present invention relates to the use of cellulose nanocrystals (CNC) blended with a polymeric material selected from a polyvinyl alcohol) (PVOH), an ethylene acrylic acid copolymer (EAA), other carboxylated polymer latexes, or other polymer blends, and applied as a thin coating layer on plastic films for printing with digital processes such as inkjet and laser printing, as well as with more conventional printing processes such as flexography and offset lithography, to the control of ink adhesion to the plastic film, and to the reduction in the oxygen transmission rate (OTR) of the plastic film.Type: GrantFiled: May 5, 2015Date of Patent: February 5, 2019Assignee: FPInnovationsInventors: Joseph Stephen Aspler, Xuejun Zou, Makhlouf Laleg, Tony Manfred, Joelle Grenon
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Patent number: 9856607Abstract: Cellulose nanofilaments from cellulose fibers, a method and a device to produce them are disclosed. The nanofilaments are fine filaments with widths in the sub-micron range and lengths up to a couple of millimeters. These nanofilaments are made from natural fibers from wood and other plants. The surface of the nanofilaments can be modified to carry anionic, cationic, polar, hydrophobic or other functional groups. Addition of these nanofilaments to papermaking furnishes substantially improves the wet-web strength and dry sheet strength much better than existing natural and synthetic polymers. The cellulose nanofilaments produced by the present invention are excellent additives for reinforcement of paper and paperboard products and composite materials, and can be used to produce superabsorbent materials.Type: GrantFiled: May 11, 2011Date of Patent: January 2, 2018Assignee: FPINNOVATIONSInventors: Xujun Hua, Makhlouf Laleg, Thomas Owston
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Publication number: 20170267009Abstract: The present invention relates to the use of cellulose nanocrystals (CNC) blended with a polymeric material selected from a polyvinyl alcohol) (PVOH), an ethylene acrylic acid copolymer (EAA), other carboxylated polymer latexes, or other polymer blends, and applied as a thin coating layer on plastic films for printing with digital processes such as ink jet and laser printing, as well as with more conventional printing processes such as flexography and offset lithography, to the control of ink adhesion to the plastic film, and to the reduction in the oxygen transmission rate (OTR) of the plastic film.Type: ApplicationFiled: May 5, 2015Publication date: September 21, 2017Inventors: Joseph Stephen ASPLER, Xuejun ZOU, Makhlouf LALEG, Tony MANFRED, Joelle GRENON
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Patent number: 9051684Abstract: A method to produce on a commercial scale, high aspect ratio cellulose nanofilaments (CNF) from natural lignocellulosic fibers comprises a multi-pass high consistency refining (HCR) of chemical or mechanical fibers using combinations of refining intensity and specific energy. The CNF produced represents a mixture of fine filaments with widths in the submicron and lengths from tens of micrometers to few millimeters. The product has a population of free filaments and filaments bound to the fiber core from which they were produced. The proportion of free and bound filaments is governed in large part by total specific energy applied to the pulp in the refiner, and differs from other cellulose fibrillar materials by their higher aspect ratio and the preserved degree of polymerization (DP) of cellulose, and are excellent additives for the reinforcement of paper, tissue, paperboard and the like. They display exceptional strengthening power for never-dried paper webs.Type: GrantFiled: January 19, 2012Date of Patent: June 9, 2015Assignee: FPINNOVATIONSInventors: Xujun Hua, Makhlouf Laleg, Keith Miles, Reza Amiri, Lahoucine Ettaleb, Gilles Dorris
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Patent number: 8608906Abstract: A method to prepare aqueous furnishes useful as feedstock in the manufacture of very high-mineral content products, particularly paper sheets having mineral filler content up to 90% that display the required physical properties for the intended applications; the furnishes comprise fibrillated long fibers/mineral fillers mixed with anionic acrylic binders and co-additives, in presence or absence of cellulose fibrils; the fibrillated long fibers and cellulose fibrils provide high surface area for greater filler fixation and the reinforcement backbone network that ties all of the product components together; the anionic binders allow rapid and strong fixation of filler particles onto the surfaces of fibrils when mixing is conducted at temperatures higher than the glass transition temperature (Tg) of the binder. The aqueous furnish provides excellent filler retention and drainage during product fabrication.Type: GrantFiled: September 29, 2011Date of Patent: December 17, 2013Assignee: FPInnovationsInventors: Makhlouf Laleg, Xujun Hua
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Patent number: 8404084Abstract: A filler treatment process enhances the fixation of anionic latex on filler in a short time. Anionic polymer dispersions (latex) are added to papermaking filler slurries at ambient temperature and then mixed with water of temperature higher than the glass transition temperature (Tg) of the latex used. The anionic latexes applied by this process are totally and irreversibly fixed or bound onto the filler particles and the treated filler particle agglomerate to form an aggregated filler slurry which is stable over time. The latex-treated filler slurry can be added to papermaking furnishes at any point prior to the headbox of the paper machine or stored for later use. The latex-treated filler slurry improves filler retention, only slightly reduces sheet strength and improves sizing performance.Type: GrantFiled: August 30, 2011Date of Patent: March 26, 2013Assignee: FPInnovationsInventors: Makhlouf Laleg, Roderick Collins, Danielle Gagne, Steven Middleton
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Publication number: 20130017394Abstract: A method to produce on a commercial scale, high aspect ratio cellulose nanofilaments (CNF) from natural lignocellulosic fibers comprises a multi-pass high consistency refining (HCR) of chemical or mechanical fibers using combinations of refining intensity and specific energy. The CNF produced represents a mixture of fine filaments with widths in the submicron and lengths from tens of micrometers to few millimeters. The product has a population of free filaments and filaments bound to the fiber core from which they were produced. The proportion of free and bound filaments is governed in large part by total specific energy applied to the pulp in the refiner, and differs from other cellulose fibrillar materials by their higher aspect ratio and the preserved degree of polymerization (DP) of cellulose, and are excellent additives for the reinforcement of paper, tissue, paperboard and the like. They display exceptional strengthening power for never-dried paper webs.Type: ApplicationFiled: January 19, 2012Publication date: January 17, 2013Applicant: FPINNOVATIONSInventors: Xujun Hua, Makhlouf Laleg, Keith Miles, Reza Amiri, Lahoucine Ettaleb, Gilles Dorris
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Patent number: 8354004Abstract: A novel filler treatment comprising the preparation of swollen starch compositions, prepared in the presence or absence of co-additives, and the addition of the said composition to a filler suspension, has been developed. Use of the treated filler during papermaking improves filler retention and produces filled papers where addition of the filler has only a minimal negative effect on strength properties. The swollen starch compositions can be prepared in a batch or jet cooker, or by mixing with hot water under controlled conditions (i.e., temperature, pH, mixing, mixing time) in order to make the starch granules swell sufficiently to improve their properties as a filler additive but avoiding excess swelling leading to their rupture. The swollen starch composition is then rapidly mixed with the filler slurry, preferably in a static mixer, and added to the papermaking furnish at a point prior to the headbox of the paper machine.Type: GrantFiled: October 21, 2009Date of Patent: January 15, 2013Assignee: FPInnovationsInventor: Makhlouf Laleg
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Publication number: 20120080156Abstract: A method to prepare aqueous furnishes useful as feedstock in the manufacture of very high-mineral content products, particularly paper sheets having mineral filler content up to 90% that display the required physical properties for the intended applications; the furnishes comprise fibrillated long fibres/mineral fillers mixed with anionic acrylic binders and co-additives, in presence or absence of cellulose fibrils; the fibrillated long fibres and cellulose fibrils provide high surface area for greater filler fixation and the reinforcement backbone network that ties all of the product components together; the anionic binders allow rapid and strong fixation of filler particles onto the surfaces of fibrils when mixing is conducted at temperatures higher than the glass transition temperature (Tg) of the binder. The aqueous furnish provides excellent filler retention and drainage during product fabrication.Type: ApplicationFiled: September 29, 2011Publication date: April 5, 2012Applicant: FPINNOVATIONSInventors: Makhlouf LALEG, Xujun HUA
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Publication number: 20110308753Abstract: A continuous filler treatment process has been developed to enhance the fixation of anionic latex on filler in a short time. In this process anionic polymer dispersions (latex) are added to common papermaking filler slurries at ambient temperature and then mixed with water of temperature higher than the glass transition temperature (Tg) of the latex used. To efficiently fix the latex the temperature of the filler/latex mixture must be 30-60° C. higher than the Tg of the latex used. The chemical composition of the resin and the type of surfactant used during the emulsion polymerisation process of the polymer latex dispersions are important factors for efficiently fixing the latex onto the filler by adding hot water and improving the properties of paper made with the treated filler. The enhanced fixation of anionic latex onto filler using hot water is done in mixing vessels that can control shear and mixing time.Type: ApplicationFiled: August 30, 2011Publication date: December 22, 2011Inventors: Makhlouf Laleg, Roderick Collins, Danielle Gagne, Steven Middleton
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Publication number: 20110277947Abstract: Cellulose nanofilaments from cellulose fibers, a method and a device to produce them are disclosed. The nanofilaments are fine filaments with widths in the sub-micron range and lengths up to a couple of millimeters. These nanofilaments are made from natural fibers from wood and other plants. The surface of the nanofilaments can be modified to carry anionic, cationic, polar, hydrophobic or other functional groups. Addition of these nanofilaments to papermaking furnishes substantially improves the wet-web strength and dry sheet strength much better than existing natural and synthetic polymers. The cellulose nanofilaments produced by the present invention are excellent additives for reinforcement of paper and paperboard products and composite materials, and can be used to produce superabsorbent materials.Type: ApplicationFiled: May 11, 2011Publication date: November 17, 2011Applicant: FPINNOVATIONSInventors: Xujun HUA, Makhlouf LALEG, Thomas OWSTON
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Patent number: 8025768Abstract: A continuous fiIter treatment process in which anionic polymer dispersions (latex) are added to common papermaking filler slurries ai ambient temperature and then mixed with water of temperature higher than the glass transition temperature (Tg) of the latex used. To efficiently fix the latex the temperature of the filler/latex mixture must be 30-60° C. higher than ihe Tg of the latex used. The chemical composition of the resin and the type of surfactant used during the emulsion polymerization process of the polymer latex dispersions are important factors for efficiently fixing the latex onto the filler by adding hot water and improving the properties of paper made with the treated filler. Enhanced fixation of anionic latex onto filler using hot water is done in mixing vessels that can control shear and mixing time. The anionic latexes are totally and irreversibly fixed or bound onto the filler particles and the aggregated filler slurry is stable over time.Type: GrantFiled: June 5, 2008Date of Patent: September 27, 2011Assignee: FpinnovationsInventors: Makhlouf Laleg, Roderick Collins, Danielle Gagne, Steven Middleton
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Patent number: 7875150Abstract: A new class of polymeric additives for papermaking is disclosed as well as a process for their manufacture, a method for their use and a paper sheet containing the addition. The additives can be used in paper manufacture as agents for improving retention, paper machine operation and the strength properties of the product. The additives are manufactured from a microbial biomass. The biomass that contains acetyl amino groups or other amides is chemically modified by hydrolysis of the amides to form primary amino groups. Under neutral or acidic conditions these primary amines become cationic, which assures a good absorption of the additive onto fibres and fines of pulp that is generally of anionic nature.Type: GrantFiled: May 19, 2005Date of Patent: January 25, 2011Assignee: FPInnovationsInventors: Miroslav Antal, Peter Volf, Ivan I. Pikulik, Makhlouf Laleg, Jan Martin Strmen, Jarka Matous
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Publication number: 20100078138Abstract: A novel filler treatment comprising the preparation of swollen starch-latex compositions, prepared in the presence or absence of co-additives, and the addition of the said composition to a filler suspension, has been developed. Use of the treated filler during papermaking improves filler retention and produces filled papers where addition of the filler has only a minimal negative effect on strength properties. The swollen starch-latex compositions can be prepared in a batch or jet cooker, or by mixing with hot water under controlled conditions (i.e., temperature, pH, mixing, mixing time) in order to make the starch granules swell sufficiently to improve their properties as a filler additive but avoiding excess swelling leading to their rupture. The swollen starch-latex composition is then rapidly mixed with the filler slurry, preferably in a static mixer, and added to the papermaking furnish at a point prior to the headbox of the paper machine.Type: ApplicationFiled: October 21, 2009Publication date: April 1, 2010Inventor: Makhlouf Laleg
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Patent number: 7625962Abstract: A novel filler treatment comprising the preparation of swollen starch-latex compositions, prepared in the presence or absence of co-additives, and the addition of the said composition to a filler suspension, has been developed. Use of the treated filler during papermaking improves filler retention and produces filled papers where addition of the filler has only a minimal negative effect on strength properties. The swollen starch-latex compositions can be prepared in a batch or jet cooker, or by mixing with hot water under controlled conditions (i.e., temperature, pH, mixing, mixing time) in order to make the starch granules swell sufficiently to improve their properties as a filler additive but avoiding excess swelling leading to their rupture. The swollen starch-latex composition is then rapidly mixed with the filler slurry, preferably in a static mixer, and added to the papermaking furnish at a point prior to the headbox of the paper machine.Type: GrantFiled: July 25, 2005Date of Patent: December 1, 2009Assignee: FI FpinnovationsInventor: Makhlouf Laleg
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Publication number: 20080302496Abstract: A continuous filler treatment process has been developed to enhance the fixation of anionic latex on filler in a short time. In this process anionic polymer dispersions (latex) are added to common papermaking filler slurries at ambient temperature and then mixed with water of temperature higher than the glass transition temperature (Tg) of the latex used. To efficiently fix the latex the temperature of the filler/latex mixture must be 30-60° C. higher than the Tg of the latex used. The chemical composition of the resin and the type of surfactant used during the emulsion polymerisation process of the polymer latex dispersions are important factors for efficiently fixing the latex onto the filler by adding hot water and improving the properties of paper made with the treated filler. The enhanced fixation of anionic latex onto filler using hot water is done in mixing vessels that can control shear and mixing time.Type: ApplicationFiled: June 5, 2008Publication date: December 11, 2008Inventors: Makhlouf Laleg, Roderick Collins, Danielle Gagne, Steven Middleton