Patents by Inventor Makhlouf Laleg

Makhlouf Laleg has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11834785
    Abstract: The present invention is directed to a method of transforming a pulp fibrous into a pre-dispersed semi-dry or dry fibrous material and to the material produced. The method opens, de-entangles and fibrillates the fibrous material of the input pulp. The method mixes the input fibrous with chemicals while evaporating moisture in an updated mechanical disc refiner process. The refiner operates to set three process variables: 1) applied refining specific energy; 2) refiner gap opening and 3) refiner output consistency. Depending on the feed pulp type and consistency, the refiner's output is a pre-dispersed semi-dry fibrous material of 30 to 99% solids with 70 to 100% of separated fibers that depending on chemical treatment are loosely entangled fibrous that disperse in water using common techniques. The pre-dispersed semi-dry output may be further processed inline or by batch process air agitation at velocities sufficient to further separate fibers and loosen fibrous entanglements.
    Type: Grant
    Filed: September 14, 2017
    Date of Patent: December 5, 2023
    Assignee: FPInnovations
    Inventors: Makhlouf Laleg, Lahoucine Ettaleb, Michael Stacey
  • Publication number: 20210285156
    Abstract: The present invention is directed to a method of transforming a pulp fibrous into a pre-dispersed semi-dry or dry fibrous material and to the material produced. The method opens, de-entangles and fibrillates the fibrous material of the input pulp. The method mixes the input fibrous with chemicals while evaporating moisture in an updated mechanical disc refiner process. The refiner operates to set three process variables: 1) applied refining specific energy; 2) refiner gap opening and 3) refiner output consistency. Depending on the feed pulp type and consistency, the refiner's output is a pre-dispersed semi-dry fibrous material of 30 to 99% solids with 70 to 100% of separated fibers that depending on chemical treatment are loosely entangled fibrous that disperse in water using common techniques. The pre-dispersed semi-dry output may be further processed inline or by batch process air agitation at velocities sufficient to further separate fibers and loosen fibrous entanglements.
    Type: Application
    Filed: September 14, 2017
    Publication date: September 16, 2021
    Applicant: FPInnovations
    Inventors: Makhlouf LALEG, Lahoucine ETTALEB, Michael STACEY
  • Publication number: 20210040273
    Abstract: Novel meltable lignin compositions having tailored compatibilities, moisture/water-resistant adhesion characteristics, and low to medium glass transition temperatures (30 to 120° C.) desirable for applications in the manufacturing of various products and the integration in the formulations of adhesives, coatings, plastics, composites and masterbatches, are obtained by blending at low temperatures (0-120° C.) dry lignins (0 to 10% moisture), in their hydrogen or protonated forms—hereby referred to as H-forms (pH=2.3-6.5 for a 10% aqueous suspension), with a reactive and/or interactive molecule or combination of molecules.
    Type: Application
    Filed: February 7, 2019
    Publication date: February 11, 2021
    Inventors: Makhlouf LALEG, Naceur JEMAA, Waleed WAFA AL DAJANI, Yaolin ZHANG, Michael PALEOLOGOU
  • Publication number: 20190224929
    Abstract: The present disclosure relates to wood pulp fiber- or cellulose filament-reinforced bulk molding compounds, composites, compositions and methods for preparation thereof. The composition comprises a resin; about 0.5 to about 15 wt. % of a 5 cellulosic reinforcement wherein the cellulosic reinforcement is chosen from wood-pulp fibers, cellulose filaments (CF) and a mixture thereof; and about 30 to about 65 wt. % of a filler.
    Type: Application
    Filed: June 21, 2017
    Publication date: July 25, 2019
    Inventors: Otman OULANTI, Makhlouf LALEG, Danielle GAGNÉ, Norayr GURNAGUL, Josée DESMEULES
  • Patent number: 10195888
    Abstract: The present invention relates to the use of cellulose nanocrystals (CNC) blended with a polymeric material selected from a polyvinyl alcohol) (PVOH), an ethylene acrylic acid copolymer (EAA), other carboxylated polymer latexes, or other polymer blends, and applied as a thin coating layer on plastic films for printing with digital processes such as inkjet and laser printing, as well as with more conventional printing processes such as flexography and offset lithography, to the control of ink adhesion to the plastic film, and to the reduction in the oxygen transmission rate (OTR) of the plastic film.
    Type: Grant
    Filed: May 5, 2015
    Date of Patent: February 5, 2019
    Assignee: FPInnovations
    Inventors: Joseph Stephen Aspler, Xuejun Zou, Makhlouf Laleg, Tony Manfred, Joelle Grenon
  • Patent number: 9856607
    Abstract: Cellulose nanofilaments from cellulose fibers, a method and a device to produce them are disclosed. The nanofilaments are fine filaments with widths in the sub-micron range and lengths up to a couple of millimeters. These nanofilaments are made from natural fibers from wood and other plants. The surface of the nanofilaments can be modified to carry anionic, cationic, polar, hydrophobic or other functional groups. Addition of these nanofilaments to papermaking furnishes substantially improves the wet-web strength and dry sheet strength much better than existing natural and synthetic polymers. The cellulose nanofilaments produced by the present invention are excellent additives for reinforcement of paper and paperboard products and composite materials, and can be used to produce superabsorbent materials.
    Type: Grant
    Filed: May 11, 2011
    Date of Patent: January 2, 2018
    Assignee: FPINNOVATIONS
    Inventors: Xujun Hua, Makhlouf Laleg, Thomas Owston
  • Publication number: 20170267009
    Abstract: The present invention relates to the use of cellulose nanocrystals (CNC) blended with a polymeric material selected from a polyvinyl alcohol) (PVOH), an ethylene acrylic acid copolymer (EAA), other carboxylated polymer latexes, or other polymer blends, and applied as a thin coating layer on plastic films for printing with digital processes such as ink jet and laser printing, as well as with more conventional printing processes such as flexography and offset lithography, to the control of ink adhesion to the plastic film, and to the reduction in the oxygen transmission rate (OTR) of the plastic film.
    Type: Application
    Filed: May 5, 2015
    Publication date: September 21, 2017
    Inventors: Joseph Stephen ASPLER, Xuejun ZOU, Makhlouf LALEG, Tony MANFRED, Joelle GRENON
  • Patent number: 9051684
    Abstract: A method to produce on a commercial scale, high aspect ratio cellulose nanofilaments (CNF) from natural lignocellulosic fibers comprises a multi-pass high consistency refining (HCR) of chemical or mechanical fibers using combinations of refining intensity and specific energy. The CNF produced represents a mixture of fine filaments with widths in the submicron and lengths from tens of micrometers to few millimeters. The product has a population of free filaments and filaments bound to the fiber core from which they were produced. The proportion of free and bound filaments is governed in large part by total specific energy applied to the pulp in the refiner, and differs from other cellulose fibrillar materials by their higher aspect ratio and the preserved degree of polymerization (DP) of cellulose, and are excellent additives for the reinforcement of paper, tissue, paperboard and the like. They display exceptional strengthening power for never-dried paper webs.
    Type: Grant
    Filed: January 19, 2012
    Date of Patent: June 9, 2015
    Assignee: FPINNOVATIONS
    Inventors: Xujun Hua, Makhlouf Laleg, Keith Miles, Reza Amiri, Lahoucine Ettaleb, Gilles Dorris
  • Patent number: 8608906
    Abstract: A method to prepare aqueous furnishes useful as feedstock in the manufacture of very high-mineral content products, particularly paper sheets having mineral filler content up to 90% that display the required physical properties for the intended applications; the furnishes comprise fibrillated long fibers/mineral fillers mixed with anionic acrylic binders and co-additives, in presence or absence of cellulose fibrils; the fibrillated long fibers and cellulose fibrils provide high surface area for greater filler fixation and the reinforcement backbone network that ties all of the product components together; the anionic binders allow rapid and strong fixation of filler particles onto the surfaces of fibrils when mixing is conducted at temperatures higher than the glass transition temperature (Tg) of the binder. The aqueous furnish provides excellent filler retention and drainage during product fabrication.
    Type: Grant
    Filed: September 29, 2011
    Date of Patent: December 17, 2013
    Assignee: FPInnovations
    Inventors: Makhlouf Laleg, Xujun Hua
  • Patent number: 8404084
    Abstract: A filler treatment process enhances the fixation of anionic latex on filler in a short time. Anionic polymer dispersions (latex) are added to papermaking filler slurries at ambient temperature and then mixed with water of temperature higher than the glass transition temperature (Tg) of the latex used. The anionic latexes applied by this process are totally and irreversibly fixed or bound onto the filler particles and the treated filler particle agglomerate to form an aggregated filler slurry which is stable over time. The latex-treated filler slurry can be added to papermaking furnishes at any point prior to the headbox of the paper machine or stored for later use. The latex-treated filler slurry improves filler retention, only slightly reduces sheet strength and improves sizing performance.
    Type: Grant
    Filed: August 30, 2011
    Date of Patent: March 26, 2013
    Assignee: FPInnovations
    Inventors: Makhlouf Laleg, Roderick Collins, Danielle Gagne, Steven Middleton
  • Publication number: 20130017394
    Abstract: A method to produce on a commercial scale, high aspect ratio cellulose nanofilaments (CNF) from natural lignocellulosic fibers comprises a multi-pass high consistency refining (HCR) of chemical or mechanical fibers using combinations of refining intensity and specific energy. The CNF produced represents a mixture of fine filaments with widths in the submicron and lengths from tens of micrometers to few millimeters. The product has a population of free filaments and filaments bound to the fiber core from which they were produced. The proportion of free and bound filaments is governed in large part by total specific energy applied to the pulp in the refiner, and differs from other cellulose fibrillar materials by their higher aspect ratio and the preserved degree of polymerization (DP) of cellulose, and are excellent additives for the reinforcement of paper, tissue, paperboard and the like. They display exceptional strengthening power for never-dried paper webs.
    Type: Application
    Filed: January 19, 2012
    Publication date: January 17, 2013
    Applicant: FPINNOVATIONS
    Inventors: Xujun Hua, Makhlouf Laleg, Keith Miles, Reza Amiri, Lahoucine Ettaleb, Gilles Dorris
  • Patent number: 8354004
    Abstract: A novel filler treatment comprising the preparation of swollen starch compositions, prepared in the presence or absence of co-additives, and the addition of the said composition to a filler suspension, has been developed. Use of the treated filler during papermaking improves filler retention and produces filled papers where addition of the filler has only a minimal negative effect on strength properties. The swollen starch compositions can be prepared in a batch or jet cooker, or by mixing with hot water under controlled conditions (i.e., temperature, pH, mixing, mixing time) in order to make the starch granules swell sufficiently to improve their properties as a filler additive but avoiding excess swelling leading to their rupture. The swollen starch composition is then rapidly mixed with the filler slurry, preferably in a static mixer, and added to the papermaking furnish at a point prior to the headbox of the paper machine.
    Type: Grant
    Filed: October 21, 2009
    Date of Patent: January 15, 2013
    Assignee: FPInnovations
    Inventor: Makhlouf Laleg
  • Publication number: 20120080156
    Abstract: A method to prepare aqueous furnishes useful as feedstock in the manufacture of very high-mineral content products, particularly paper sheets having mineral filler content up to 90% that display the required physical properties for the intended applications; the furnishes comprise fibrillated long fibres/mineral fillers mixed with anionic acrylic binders and co-additives, in presence or absence of cellulose fibrils; the fibrillated long fibres and cellulose fibrils provide high surface area for greater filler fixation and the reinforcement backbone network that ties all of the product components together; the anionic binders allow rapid and strong fixation of filler particles onto the surfaces of fibrils when mixing is conducted at temperatures higher than the glass transition temperature (Tg) of the binder. The aqueous furnish provides excellent filler retention and drainage during product fabrication.
    Type: Application
    Filed: September 29, 2011
    Publication date: April 5, 2012
    Applicant: FPINNOVATIONS
    Inventors: Makhlouf LALEG, Xujun HUA
  • Publication number: 20110308753
    Abstract: A continuous filler treatment process has been developed to enhance the fixation of anionic latex on filler in a short time. In this process anionic polymer dispersions (latex) are added to common papermaking filler slurries at ambient temperature and then mixed with water of temperature higher than the glass transition temperature (Tg) of the latex used. To efficiently fix the latex the temperature of the filler/latex mixture must be 30-60° C. higher than the Tg of the latex used. The chemical composition of the resin and the type of surfactant used during the emulsion polymerisation process of the polymer latex dispersions are important factors for efficiently fixing the latex onto the filler by adding hot water and improving the properties of paper made with the treated filler. The enhanced fixation of anionic latex onto filler using hot water is done in mixing vessels that can control shear and mixing time.
    Type: Application
    Filed: August 30, 2011
    Publication date: December 22, 2011
    Inventors: Makhlouf Laleg, Roderick Collins, Danielle Gagne, Steven Middleton
  • Publication number: 20110277947
    Abstract: Cellulose nanofilaments from cellulose fibers, a method and a device to produce them are disclosed. The nanofilaments are fine filaments with widths in the sub-micron range and lengths up to a couple of millimeters. These nanofilaments are made from natural fibers from wood and other plants. The surface of the nanofilaments can be modified to carry anionic, cationic, polar, hydrophobic or other functional groups. Addition of these nanofilaments to papermaking furnishes substantially improves the wet-web strength and dry sheet strength much better than existing natural and synthetic polymers. The cellulose nanofilaments produced by the present invention are excellent additives for reinforcement of paper and paperboard products and composite materials, and can be used to produce superabsorbent materials.
    Type: Application
    Filed: May 11, 2011
    Publication date: November 17, 2011
    Applicant: FPINNOVATIONS
    Inventors: Xujun HUA, Makhlouf LALEG, Thomas OWSTON
  • Patent number: 8025768
    Abstract: A continuous fiIter treatment process in which anionic polymer dispersions (latex) are added to common papermaking filler slurries ai ambient temperature and then mixed with water of temperature higher than the glass transition temperature (Tg) of the latex used. To efficiently fix the latex the temperature of the filler/latex mixture must be 30-60° C. higher than ihe Tg of the latex used. The chemical composition of the resin and the type of surfactant used during the emulsion polymerization process of the polymer latex dispersions are important factors for efficiently fixing the latex onto the filler by adding hot water and improving the properties of paper made with the treated filler. Enhanced fixation of anionic latex onto filler using hot water is done in mixing vessels that can control shear and mixing time. The anionic latexes are totally and irreversibly fixed or bound onto the filler particles and the aggregated filler slurry is stable over time.
    Type: Grant
    Filed: June 5, 2008
    Date of Patent: September 27, 2011
    Assignee: Fpinnovations
    Inventors: Makhlouf Laleg, Roderick Collins, Danielle Gagne, Steven Middleton
  • Patent number: 7875150
    Abstract: A new class of polymeric additives for papermaking is disclosed as well as a process for their manufacture, a method for their use and a paper sheet containing the addition. The additives can be used in paper manufacture as agents for improving retention, paper machine operation and the strength properties of the product. The additives are manufactured from a microbial biomass. The biomass that contains acetyl amino groups or other amides is chemically modified by hydrolysis of the amides to form primary amino groups. Under neutral or acidic conditions these primary amines become cationic, which assures a good absorption of the additive onto fibres and fines of pulp that is generally of anionic nature.
    Type: Grant
    Filed: May 19, 2005
    Date of Patent: January 25, 2011
    Assignee: FPInnovations
    Inventors: Miroslav Antal, Peter Volf, Ivan I. Pikulik, Makhlouf Laleg, Jan Martin Strmen, Jarka Matous
  • Publication number: 20100078138
    Abstract: A novel filler treatment comprising the preparation of swollen starch-latex compositions, prepared in the presence or absence of co-additives, and the addition of the said composition to a filler suspension, has been developed. Use of the treated filler during papermaking improves filler retention and produces filled papers where addition of the filler has only a minimal negative effect on strength properties. The swollen starch-latex compositions can be prepared in a batch or jet cooker, or by mixing with hot water under controlled conditions (i.e., temperature, pH, mixing, mixing time) in order to make the starch granules swell sufficiently to improve their properties as a filler additive but avoiding excess swelling leading to their rupture. The swollen starch-latex composition is then rapidly mixed with the filler slurry, preferably in a static mixer, and added to the papermaking furnish at a point prior to the headbox of the paper machine.
    Type: Application
    Filed: October 21, 2009
    Publication date: April 1, 2010
    Inventor: Makhlouf Laleg
  • Patent number: 7625962
    Abstract: A novel filler treatment comprising the preparation of swollen starch-latex compositions, prepared in the presence or absence of co-additives, and the addition of the said composition to a filler suspension, has been developed. Use of the treated filler during papermaking improves filler retention and produces filled papers where addition of the filler has only a minimal negative effect on strength properties. The swollen starch-latex compositions can be prepared in a batch or jet cooker, or by mixing with hot water under controlled conditions (i.e., temperature, pH, mixing, mixing time) in order to make the starch granules swell sufficiently to improve their properties as a filler additive but avoiding excess swelling leading to their rupture. The swollen starch-latex composition is then rapidly mixed with the filler slurry, preferably in a static mixer, and added to the papermaking furnish at a point prior to the headbox of the paper machine.
    Type: Grant
    Filed: July 25, 2005
    Date of Patent: December 1, 2009
    Assignee: FI Fpinnovations
    Inventor: Makhlouf Laleg
  • Publication number: 20080302496
    Abstract: A continuous filler treatment process has been developed to enhance the fixation of anionic latex on filler in a short time. In this process anionic polymer dispersions (latex) are added to common papermaking filler slurries at ambient temperature and then mixed with water of temperature higher than the glass transition temperature (Tg) of the latex used. To efficiently fix the latex the temperature of the filler/latex mixture must be 30-60° C. higher than the Tg of the latex used. The chemical composition of the resin and the type of surfactant used during the emulsion polymerisation process of the polymer latex dispersions are important factors for efficiently fixing the latex onto the filler by adding hot water and improving the properties of paper made with the treated filler. The enhanced fixation of anionic latex onto filler using hot water is done in mixing vessels that can control shear and mixing time.
    Type: Application
    Filed: June 5, 2008
    Publication date: December 11, 2008
    Inventors: Makhlouf Laleg, Roderick Collins, Danielle Gagne, Steven Middleton