Abstract: A nickel-metal hydride battery of the present disclosure comprises: a positive electrode active material layer, a negative electrode active material layer, and an aqueous electrolyte, wherein a negative electrode active material contained in the negative electrode active material layer is a hydrogen storage alloy having an AB2 main phase, the A site includes Ti, Zr, or a combination thereof, and the B site includes Mn, Cr, Ni, Fe, or a combination thereof.

Abstract: A hydrogen storage alloy suitable for a negative electrode of an on-board alkaline storage battery, and an alkaline storage battery using the alloy, which has an AB3-type crystal structure as a main phase, represented by: (SmxLayRz)1-a-bMgaTbNicCodMe. (R is selected from Pr, Nd; T is selected from Ti, Zr, Hf; M is selected from V, Nb, Ta, Cr, Mo, W, Mn, Fe, Cu, Al, Si, P, B; the following conditions are met: 0<x<1.0, 0<y<1.0, 0.8?x+y?1.0, x+y+z=1.0; 0.93?(x?y)·(1?a?b)+4.5(a+b)?1.62, 0<a?0.45, 0?b?0.05, 0?d?0.7, 0?e?0.15, 2.85?c+d+e?3.15 and 0.01?d+e).

Abstract: A secondary battery comprising a metallic lithium negative electrode and having a coulombic efficiency. The secondary battery of the present disclosure comprises a positive electrode active material layer, a solid electrolyte layer, and a negative electrode active material layer, wherein the negative electrode active material layer comprises a first substance and a second substance, wherein the first substance is at least one of an alloy of Li and an element X and a compound of Li and the element X; the second substance is at least one of a simple substance of a metal element M, an alloy of Li and the metal element M, and a compound of Li and the metal element M; and a formation energy ELiX of the first substance is lower than a formation energy EMX of the compound of the metal element M and the element X.

Abstract: Provided is a method for producing a composite alloy for use in an electrode for an alkaline storage battery, including a powder preparation step of preparing a hydrogen storage alloy powder containing Ti and Cr and having a BCC structure, an etching step of applying an acid to the hydrogen storage alloy powder prepared in the powder preparation step, a Pd film forming step of coating the surface of the hydrogen storage alloy powder subjected to the etching step with Pd using a substitution plating method, and a heat treatment step of heating the hydrogen storage alloy powder having a Pd film formed, at said heating being a temperature of 500° C. or less, wherein in the Pd coating forming step, the hydrogen storage alloy powder is coated with Pd under the condition that the Pd element weight ratio of the composite alloy to be produced is 0.47% or more.

Abstract: A main object of the present disclosure is to provide an anode active material with excellent capacity properties. The present disclosure achieves the object by providing an anode active material to be used in an alkaline storage battery, the anode active material including: a base material containing Ti and Cr, and including a BCC structure as a metastable phase; and a coating layer that coats the base material, and contains a catalyst metal and a metal with oxygen affinity that is more than oxygen affinity of Ti; wherein an oxide film is present in an interface between the coating layer and the base material; and when a first thickness TA (nm) and a second thickness TB(nm) of the oxide film are determined by Auger electron spectroscopy, a rate of the TA with respect to the TB, which is TA/TB is, for example, 1.50 or more.

Abstract: Provided is a method for producing a composite alloy for use in an electrode for an alkaline storage battery, including a powder preparation step of preparing a hydrogen storage alloy powder containing Ti and Cr and having a BCC structure, an etching step of applying an acid to the hydrogen storage alloy powder prepared in the powder preparation step, a Pd film forming step of coating the surface of the hydrogen storage alloy powder subjected to the etching step with Pd using a substitution plating method, and a heat treatment step of heating the hydrogen storage alloy powder having a Pd film formed, at said heating being a temperature of 500° C. or less, wherein in the Pd coating forming step, the hydrogen storage alloy powder is coated with Pd under the condition that the Pd element weight ratio of the composite alloy to be produced is 0.47% or more.

Abstract: A hydrogen storage alloy suitable for a negative electrode of an on-board alkaline storage battery, and an alkaline storage battery using the alloy, which has an AB3-type crystal structure as a main phase, represented by: (SmxLayRz)1?a?bMgaTbNicCodMe. (R is selected from Pr, Nd; T is selected from Ti, Zr, Hf; M is selected from V, Nb, Ta, Cr, Mo, W, Mn, Fe, Cu, Al, Si, P, B; the following conditions are met: 0<x<1.0, 0<y<1.0, 0.8?x+y?1.0, x+y+z=1.0; 0.93?(x?y)·(1?a?b)+4.5(a+b)?1.62, 0<a?0.45, 0?b?0.05, 0?d?0.7, 0?e?0.15, 2.85?c+d+e?3.15 and 0.01?d+e).

Abstract: An objective of the present invention is to provide a positive electrode active material that can inhibit the capacity changes associated with temperature variations, and an alkaline battery that contains this positive electrode active material. Aluminum and ytterbium are at least partially solid-dissolved in nickel hydroxide in the nickel composite hydroxide present in the positive electrode active material of the present invention.

Abstract: The present disclosure provides a positive electrode active material for sodium ion secondary batteries which has an excellent charge/discharge capacity and can reduce production costs The positive electrode active material for sodium ion secondary batteries comprises an oxyhydroxide containing: Ni or Ni and at least one transition metal element selected from the group consisting of Mg, Mn, Zn, Co and Al; Na; and S.

Abstract: An objective of the present invention is to provide a positive electrode active material that can inhibit the capacity changes associated with temperature variations, and an alkaline battery that contains this positive electrode active material. Aluminum and ytterbium are at least partially solid-dissolved in nickel hydroxide in the nickel composite hydroxide present in the positive electrode active material of the present invention.

Abstract: An object of the present disclosure is to provide an anode material with a high capacity maintenance rate. To achieve the above object, the present disclosure provides an anode material to be used for a battery that contains an aqueous liquid electrolyte, the anode material comprising: a hydrogen storing alloy that reversibly stores and releases hydrogen; wherein the hydrogen storing alloy contains Ti, Cr, and V as main components, and is an alloy that contains a BCC phase as a main phase; a lattice constant of the BCC phase is 3.01 ? or more and 3.10 ? or less; and the Cr content in the hydrogen storing alloy is 20 at % or more.

Abstract: The present invention provides a negative electrode for a secondary battery having a higher capacity than conventional batteries and the secondary battery having the negative electrode incorporated therein. The negative electrode for the secondary battery includes a silicate having a pyroxene structure and represented by a general formula ApM2-pX2O6, wherein “A” represents at least one species selected from among a group of Na, Ca, Fe, Zn, Mn and Mg, “M” represents at least one species selected from among a group of transition metal elements, Al and Mg, where one of the transition metal elements being an indispensable element of “M”, “A” and “M” represent same elements or different elements, “p” represents a number satisfying 0<p<2, “X2” represents Si2 or AlqSi2-q, and “q” represents a number satisfying 0<q<2.

Abstract: A main object of the present invention is to provide a method for producing an anode material which enhances the reversibility of the conversion reaction and the cycle characteristics of lithium secondary batteries. The object is attained by providing a method for producing an anode material that is used in a lithium secondary battery, comprising a mechanical milling step of micronizing a raw material composition containing MgH2 by mechanical milling.

Abstract: An anode material for use in a metal secondary battery contains MgH2, and a metal catalyst which is in contact with the MgH2 and improves the reversibility of a conversion reaction. The metal secondary battery includes a cathode active material layer, an anode active material layer, and an electrolyte layer that is formed between the cathode active material layer and the anode active material layer, and the anode active material layer contains the anode material. A method for the production of an anode material for use in a metal secondary battery includes a contacting step of contacting MgH2 with a metal catalyst which improves the reversibility of a conversion reaction.