Patents by Inventor Makoto Ashiura

Makoto Ashiura has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11807738
    Abstract: The invention provides a silane compound for obtaining a cross-linked product which hardly generates poor dispersion or adhesion between an organic polymer material and an inorganic material and exhibits excellent viscoelastic properties or adhesive properties, or a composition comprising the silane compound. In particular, the invention provides a silane compound represented by formula (1): wherein R1, R2, and R3 each independently represents a hydrocarbon group optionally containing an oxygen atom or a nitrogen atom, or a hydrogen atom; L represents a hydrocarbon group optionally containing at least one heteroatom selected from the group consisting of nitrogen, oxygen, and sulfur; and the other variables are as defined herein.
    Type: Grant
    Filed: December 24, 2019
    Date of Patent: November 7, 2023
    Assignee: ENEOS Corporation
    Inventors: Keisuke Chino, Yusuke Matsuo, Makoto Ashiura
  • Publication number: 20230340230
    Abstract: Provided is a silane coupling agent composition with which it is possible to obtain a rubber composition having excellent scorch resistance and a crosslinked product of a rubber composition having excellent viscoelastic properties.
    Type: Application
    Filed: June 4, 2021
    Publication date: October 26, 2023
    Applicant: ENEOS Corporation
    Inventors: Makoto ASHIURA, Keisuke CHINO, Yusuke MATSUO, Toshiyuki TSUTSUMI, Keitaro IWASAKI
  • Publication number: 20230340231
    Abstract: Provided are: a silane coupling agent composition with which it is possible to obtain a rubber composition having excellent scorch resistance and uncrosslinked compound viscosity; and a crosslinked product of a rubber composition having excellent viscoelastic properties, and a tire using the same which has an excellent balance of wet grip performance and low-fuel consumption.
    Type: Application
    Filed: June 4, 2021
    Publication date: October 26, 2023
    Applicant: ENEOS Corporation
    Inventors: Makoto ASHIURA, Keisuke CHINO, Yusuke MATSUO, Toshiyuki TSUTSUMI
  • Patent number: 11787923
    Abstract: A rubber composition of the present technology contains: diene rubber (A) containing a predetermined amount of specific conjugated diene rubber represented by a predetermined formula; silica having a CTAB adsorption specific surface area in a predetermined range; and a silane coupling agent represented by a predetermined formula.
    Type: Grant
    Filed: February 8, 2017
    Date of Patent: October 17, 2023
    Assignee: The Yokohama Rubber Co., LTD.
    Inventors: Hiroki Sugimoto, Shuichi Nakano, Makoto Ashiura
  • Publication number: 20230312879
    Abstract: Provided is a silane coupling agent composition with which it is possible to obtain a crosslinked product of a rubber composition having excellent scorch resistance and a rubber composition crosslinked product having excellent hardness and viscoelastic properties.
    Type: Application
    Filed: June 4, 2021
    Publication date: October 5, 2023
    Applicant: ENEOS Corporation
    Inventors: Makoto ASHIURA, Keisuke CHINO, Yusuke MATSUO, Toshiyuki TSUTSUMI
  • Publication number: 20230174747
    Abstract: Provided is a silane coupling agent composition with which it is possible to obtain a rubber composition having excellent workability and a crosslinked product of a rubber composition having an excellent hardness, viscoelastic properties, and tensile strength.
    Type: Application
    Filed: June 4, 2021
    Publication date: June 8, 2023
    Applicant: ENEOS Corporation
    Inventors: Makoto ASHIURA, Keisuke CHINO
  • Publication number: 20230167290
    Abstract: A rubber composition, comprising: an uncross-linked rubber having no hydrogen-bond cross-linkable moiety; and at least one polymer component selected from the group consisting of polymers (A) each of which has a side chain (a) containing a hydrogen-bond cross-linkable moiety having a carbonyl-containing group and/or a nitrogen-containing heterocycle and has a glass-transition point of 25° C. or below and polymers (B) each of which contains a hydrogen-bond cross-linkable moiety and a covalent-bond cross-linking moiety in a side chain and has a glass-transition point of 25° C. or below; wherein an amount of the polymer component contained is 0.01 to 200 parts by mass relative to 100 parts by mass of the uncross-linked rubber, and the polymers (A) and the polymers (B) are each a reaction product of a maleic anhydride graft-modified thermoplastic polymer having a maleation ratio of 0.1 to 10% by mass and a cross-linkable compound.
    Type: Application
    Filed: June 18, 2021
    Publication date: June 1, 2023
    Applicant: ENEOS CORPORATION
    Inventors: Keisuke CHINO, Keitaro IWASAKI, Makoto ASHIURA
  • Patent number: 11608425
    Abstract: A rubber composition for a tire contains a diene rubber, silica, and a specific modified butadiene polymer, wherein the diene rubber contains an aromatic vinyl-conjugated diene rubber A and at least one rubber component B selected from an aromatic vinyl-conjugated diene rubber b1 other than the rubber A and a butadiene rubber b2 having a weight average molecular weight of ?15000. A content of the aromatic vinyl-conjugated diene rubber A is from 30 to 90% by mass, and a content of the rubber component B is from 10 to 70% by mass, an average TG of the diene rubber is lower than ?20° C., a content of the silica is from 80 to 200 parts by mass per 100 parts by mass of the diene rubber, and a content of the modified butadiene polymer is from 1.0 to 25.0% by mass with respect to content of the silica.
    Type: Grant
    Filed: October 4, 2018
    Date of Patent: March 21, 2023
    Assignee: The Yokohama Rubber Co., Ltd.
    Inventors: Ayaki Kazariya, Makoto Ashiura, Satoshi Mihara, Kazuya Uenishi, Yu Shinke
  • Publication number: 20220380575
    Abstract: Disclosed is a rubber composition which suppresses poor mixing or poor dispersion from occurring between an organic polymer material derived from natural rubber and an inorganic material such as silica and exhibits excellent viscoelastic properties, and a silane coupling agent composition used in the same. Also disclosed is a silane coupling agent composition comprising a protein modifying agent and a silane compound represented by Formula (1): wherein each of the variables is as defined herein.
    Type: Application
    Filed: June 5, 2020
    Publication date: December 1, 2022
    Applicant: ENEOS Corporation
    Inventors: Keisuke CHINO, Makoto ASHIURA
  • Publication number: 20220363873
    Abstract: Disclosed is a rubber composition which suppresses poor mixing or poor dispersion from occurring between an organic polymer material derived from natural rubber and an inorganic material such as silica and exhibits excellent viscoelastic properties, and a silane coupling agent composition used in the same. Also disclosed is a silane coupling agent composition comprising a silane compound represented by Formula (1): wherein each variable is as defined herein.
    Type: Application
    Filed: June 5, 2020
    Publication date: November 17, 2022
    Applicant: ENEOS Corporation
    Inventors: Keisuke CHINO, Makoto ASHIURA
  • Publication number: 20220298275
    Abstract: Provided is a sulfur-containing unsaturated hydrocarbon polymer which can improve wet grip performance and fuel efficiency of a tire in a well-balanced manner by being blended into a rubber composition for a tire. A sulfur-containing unsaturated hydrocarbon polymer of the present invention is a reaction product obtained by reacting sulfur with an unsaturated bond in a polymer of an unsaturated hydrocarbon.
    Type: Application
    Filed: August 20, 2020
    Publication date: September 22, 2022
    Applicant: ENEOS Corporation
    Inventors: Keisuke CHINO, Yusuke MATSUO, Makoto ASHIURA
  • Publication number: 20220073703
    Abstract: The invention provides a silane compound for obtaining a cross-linked product which hardly generates poor dispersion or adhesion between an organic polymer material and an inorganic material and exhibits excellent viscoelastic properties or adhesive properties, or a composition comprising the silane compound. In particular, the invention provides a silane compound represented by formula (1): wherein R1, R2, and R3 each independently represents a hydrocarbon group optionally containing an oxygen atom or a nitrogen atom, or a hydrogen atom; L represents a hydrocarbon group optionally containing at least one heteroatom selected from the group consisting of nitrogen, oxygen, and sulfur; and the other variables are as defined herein.
    Type: Application
    Filed: December 24, 2019
    Publication date: March 10, 2022
    Applicant: ENEOS Corporation
    Inventors: Keisuke CHINO, Yusuke MATSUO, Makoto ASHIURA
  • Patent number: 11180634
    Abstract: The present invention provides a rubber composition for a tire, the rubber composition containing: a diene rubber; silica; and a heterocyclic compound (where, the heterocyclic compound does not have a silicon atom) having a hydrocarbon group having from 3 to 30 carbons and at least one type of heterocycle selected from the group consisting of a piperazine ring, a morpholine ring, and a thiomorpholine ring; an average glass transition temperature of the diene rubber being ?50° C. or higher; a content of the silica being from 80 to 200 parts by mass per 100 parts by mass of the diene rubber; and a content of the heterocyclic compound being from 0.5 to 20% by mass with respect to the content of the silica. Such rubber composition has excellent processability, exhibits excellent wet grip performance and has low rolling resistance when the rubber composition is formed into a tire.
    Type: Grant
    Filed: September 10, 2018
    Date of Patent: November 23, 2021
    Assignee: The Yokohama Rubber Co., Ltd.
    Inventors: Ayaki Kazariya, Makoto Ashiura, Satoshi Mihara, Kazushi Kimura, Hirokazu Kageyama
  • Patent number: 11084326
    Abstract: Provided is a rubber composition which contains a diene rubber and a reinforcing filler. The diene rubber contains a styrene-butadiene copolymer component including at least one type of styrene-butadiene copolymer and satisfying: (1) the bonded styrene content is from 5 to 50 wt. %; (2) among components obtained by ozone decomposition, the content of a decomposed component V1 containing one 1,2-bonded butadiene-derived unit out of the total of 100 mol % of decomposed components containing styrene-derived units and/or 1,2-bonded butadiene-derived units is not less than 20 mol %; (3) among components obtained by ozone decomposition, the content of a decomposed component S2V1 containing two styrene-derived units and one 1,2-bonded butadiene-derived unit out of the total of 100 mol % of decomposed components containing styrene-derived units and/or 1,2-bonded butadiene-derived units is not less than 4 mol %; and (4) the vinyl content of a butadiene moiety is not less than 20% and less than 50%.
    Type: Grant
    Filed: April 28, 2017
    Date of Patent: August 10, 2021
    Assignee: The Yokohama Rubber Co., LTD.
    Inventors: Yuko Sekine, Makoto Ashiura, Fumito Yatsuyanagi
  • Publication number: 20210171746
    Abstract: A rubber composition of the present technology contains: diene rubber (A) containing a predetermined amount of specific conjugated diene rubber represented by a predetermined formula; silica having a CTAB adsorption specific surface area in a predetermined range; and a silane coupling agent represented by a predetermined formula.
    Type: Application
    Filed: February 8, 2017
    Publication date: June 10, 2021
    Inventors: Hiroki Sugimoto, Shuichi Nakano, Makoto Ashiura
  • Patent number: 11008445
    Abstract: The present invention is to provide an aromatic vinyl-diene copolymer which exhibits excellent mechanical properties and wear resistance when being formed into a tire, a method for producing the aromatic vinyl-diene copolymer, and a rubber composition containing the aromatic vinyl-diene copolymer. The aromatic vinyl-diene copolymer of an embodiment of the present invention is an aromatic vinyl-diene copolymer which is a copolymer of an aromatic vinyl and a diene, wherein the content of a repeating unit derived from an aromatic vinyl is 18 mass % or greater, among repeating units derived from a diene, a proportion of a vinyl structure is 8 mol % or less, a proportion of a 1,4-trans structure is 75 mol % or less, and a proportion of a 1,4-cis structure is from 17 to 90 mol %, and a glass transition temperature is ?60° C. or lower.
    Type: Grant
    Filed: February 10, 2017
    Date of Patent: May 18, 2021
    Assignee: The Yokohama Rubber Co., Ltd.
    Inventors: Kazuya Uenishi, Makoto Ashiura, Motoji Fujita, Naoya Amino, Satoshi Mihara, Yu Shinke
  • Patent number: 11001654
    Abstract: The present invention is to provide a diene polymer that exhibits excellent low rolling resistance when used in a tire, a method for producing the diene polymer, and a rubber composition containing the diene polymer. The diene polymer of an embodiment of the present invention is produced by polymerizing a monomer containing at least a diene monomer by using an initiator prepared from an organolithium compound, an alkyl aluminum, and a metal alcoholate, and then terminating the polymerization by using an electrophile selected from the group consisting of titanium halides, tin halides, cyclic silazanes, alkoxysilanes, epoxides, amines, ketones, and compounds represented by Formula (N) below.
    Type: Grant
    Filed: September 8, 2016
    Date of Patent: May 11, 2021
    Assignee: The Yokohama Rubber Co., Ltd.
    Inventors: Kazuya Uenishi, Naoya Amino, Makoto Ashiura, Motoji Fujita, Satoshi Mihara, Yu Shinke
  • Patent number: 10934427
    Abstract: A rubber composition contains a diene rubber component and a reinforcing filler, the diene rubber component containing a styrene-butadiene copolymer component including at least one type of styrene-butadiene copolymer and satisfying: the bonded styrene content is from 5 to 50 wt. %; of components obtained by ozone decomposition, a content of a decomposed component V1 containing one 1,2-bonded butadiene-derived unit out of a total of 100 mol % of decomposed components containing styrene-derived unit(s) and/or the 1,2-bonded butadiene-derived unit(s) is not less than 25 mol %; of the components obtained by ozone decomposition, a content of a decomposed component S2V1 containing two of the styrene-derived units and one of the 1,2-bonded butadiene-derived unit out of a total of 100 mol % of the decomposed components containing the styrene-derived unit(s) and/or the 1,2-bonded butadiene-derived unit(s) is not less than 5 mol %; and a vinyl content of a butadiene moiety is not less than 50%.
    Type: Grant
    Filed: April 28, 2017
    Date of Patent: March 2, 2021
    Inventors: Yuko Sekine, Makoto Ashiura, Fumito Yatsuyanagi
  • Patent number: 10919341
    Abstract: A rubber composition contains a diene rubber and a reinforcing filler, and the diene rubber contains a styrene-butadiene copolymer component including at least one type of styrene-butadiene copolymer and satisfying the following: (1) the bonded styrene content is from 5 to 50 wt. %; (2) among components obtained by ozone decomposition, a content of a decomposed component V1 containing one 1,2-bonded butadiene-derived unit out of a total of 100 mol % of decomposed components containing styrene-derived units and/or 1,2-bonded butadiene-derived units is less than 20 mol %; (3) among components obtained by ozone decomposition, a content of a decomposed component S2V1 containing two styrene-derived units and one 1,2-bonded butadiene-derived unit out of a total of 100 mol % of decomposed components containing styrene-derived units and/or 1,2-bonded butadiene-derived units is less than 4 mol %; and (4) a vinyl content of a butadiene moiety is not less than 20% and less than 50%.
    Type: Grant
    Filed: April 28, 2017
    Date of Patent: February 16, 2021
    Inventors: Yuko Sekine, Makoto Ashiura, Fumito Yatsuyanagi
  • Publication number: 20200325310
    Abstract: A rubber composition for a tire contains a diene rubber, silica, and a specific modified butadiene polymer, wherein the diene rubber contains an aromatic vinyl-conjugated diene rubber A and at least one rubber component B selected from an aromatic vinyl-conjugated diene rubber b1 other than the rubber A and a butadiene rubber b2 having a weight average molecular weight of ?15000. A content of the aromatic vinyl-conjugated diene rubber A is from 30 to 90% by mass, and a content of the rubber component B is from 10 to 70% by mass, an average TG of the diene rubber is lower than ?20° C., a content of the silica is from 80 to 200 parts by mass per 100 parts by mass of the diene rubber, and a content of the modified butadiene polymer is from 1.0 to 25.0% by mass with respect to content of the silica.
    Type: Application
    Filed: October 4, 2018
    Publication date: October 15, 2020
    Inventors: Ayaki KAZARIYA, Makoto ASHIURA, Satoshi MIHARA, Kazuya UENISHI, Yu SHINKE