Patents by Inventor Makoto Takagawa
Makoto Takagawa has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 5453852Abstract: A paper feed roller (5) is divided into a first roller (5a) and a second roller (5b); a slit (58) through which about 10 to 20 sheets of documents can pass is formed between the first roller and a gate plate (57) opposite to this; and the paper fed out therefrom is fed out to a space between the second roller (5b) and a separation pad (7) in contact with this.Also, there is adopted a construction in which the pressing force of a paper conveyance spring is transformed by a slide cam sliding in a direction parallel to the paper feed roller; and the paper width detection sensor is assembled by a fitting construction.Type: GrantFiled: March 7, 1994Date of Patent: September 26, 1995Assignees: PFU Limited, Fujitsu LimitedInventors: Shuichi Morikawa, Masahiko Futatsuka, Satoshi Ishida, Yasunori Miyauchi, Minoru Masuda, Makoto Takagawa
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Patent number: 5446226Abstract: A process for efficiently producing dimethylnaphthalene by a single-step reaction which comprises cyclizing dehydrogenating 5-tolyl-penta-2-ene in the presence of a catalyst comprising in combination (a) a solid acid such as crystalline aluminosilicate, silica-alumina or alumina; (b) a noble metal such as palladium and platinum; and a carrier such as carbon, silicon oxide, titanium oxide and zirconium oxide. The process results in simplification of production, effective utilization of reaction heat and rationalization of the heat balance.Type: GrantFiled: November 19, 1993Date of Patent: August 29, 1995Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Shinji Ozawa, Makoto Takagawa, Takayasu Fujimori
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Patent number: 5444172Abstract: There is disclosed a process for producing a monoalkenylbenzene which comprises alkenylating a side chain of an aromatic hydrocarbon compound having at least one hydrogen atom bonded at .alpha.-position of the side chain (such as xylene) with a conjugated diene having 4 or 5 carbon atoms (such as butadiene) in the presence of a catalyst produced by calcining the mixture of a basic potassium compound and alumina and then heat treating the calcined product together with metallic sodium in an atmosphere of an inert gas. According to the aforesaid process, an industrially useful monoalkenylbenzene can be produced in high yield at a low cost with enhanced safety.Type: GrantFiled: December 20, 1993Date of Patent: August 22, 1995Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Makoto Takagawa, Kenji Inamasa, Norio Fushimi, Akio Hashimoto, Takayo Sasaki
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Patent number: 5436381Abstract: There is disclosed a process for producing a monoalkenylbenzene which comprises alkenylating a side chain of an aromatic hydrocarbon compound having at least one hydrogen atom bonded at .alpha.-position of the side chain (such as xylene) with a conjugated diene having 4 or 5 carbon atoms (such as butadiene) in the presence of a catalyst produced by calcining the mixture of potassium hydroxide and aluminum hydroxide and then heat treating the calcined product together with metallic sodium in an atmosphere of an inert gas. According to the aforesaid process, an industrially useful monoalkenylbenzene can be produced in high yield at a low cost with enhanced safety.Type: GrantFiled: December 20, 1993Date of Patent: July 25, 1995Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Makoto Takagawa, Kinji Kato, Norio Fushimi, Ko Kedo
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Patent number: 5396008Abstract: There is disclosed a process for producing dimethyltetralin consisting of 1,5-, 1,6- and 2,6-dimethyltetralin which comprises cyclizing 5-tolyl-penta-2-ene in gaseous state in the presence of diluent by the use of a catalyst comprising a crystalline aluminosilicate and a carrier and optionally a molding assistant. The abovementioned process is capable of producing industrially useful dimethyltetralin as the starting raw material for dimethylnaphthalene with high yield and high selectivity with minimized side reactions over a long stabilized period.Type: GrantFiled: July 9, 1993Date of Patent: March 7, 1995Assignee: Mitsubishi Gas Chemical Co., Inc.Inventors: Shinji Ozawa, Makoto Takagawa, Kenji Dnamasa
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Patent number: 5396007Abstract: A process for producing dimethylnaphthalene by the dehydrogenation of dimethyl-tetrahydronaphthalene which comprises carrying out the dehydrogenation reaction in a gaseous state at a temperature of 200.degree. to 350.degree. C. in the presence of a diluting medium and by the use of a platinum and/or palladium catalyst supported on an activated carbon carrier. The process is capable of producing industrially useful dimethylnaphthalene with a high yield and a high selectivity and minimized side reactions, over a long stabilized period.Type: GrantFiled: July 1, 1993Date of Patent: March 7, 1995Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Yoichi Kyuko, Shinji Ozawa, Makoto Takagawa, Kenji Inamasa
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Patent number: 5371293Abstract: Bisaminomethylcyclohexane is produced in high yield by one-stage process from an aromatic dinitrile by hydrogenating the aromatic dinitrile in the presence of a ruthenium catalyst containing 1 to 10% by weight of ruthenium, in terms of metallic ruthenium, supported on a carrier, and in the presence of 0.5 parts by weight or more of liquid ammonia per part by weight of the aromatic nitrile at a temperature of 70.degree. to 150.degree. C. and a hydrogen partial pressure of 50 to 150 atm.Type: GrantFiled: March 28, 1994Date of Patent: December 6, 1994Assignee: Mitsubishi Gas Chemical Company, Inc.Inventor: Makoto Takagawa
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Patent number: 5367098Abstract: A process for producing a monoalkenyl aromatic hydrocarbon compound which comprises alkenylating a side chain of an aromatic hydrocarbon compound having at least one hydrogen atom bonded at an .alpha.-position of the side chain (such as xylene) with a conjugated diene having 4 or 5 carbon atoms (such as butadiene) in the presence of a catalyst comprising a mixture obtained by heat treating metallic sodium together with a mixture of an aluminum oxide and a potassium compound in an inert gas atmosphere. The process produces a commercially useful monoalkenyl aromatic hydrocarbon compounds in a high yields and at a low cost with enhanced safety.Type: GrantFiled: April 15, 1993Date of Patent: November 22, 1994Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Norio Fushimi, Ko Kedo, Kenji Inamasa, Makoto Takagawa
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Patent number: 5344806Abstract: There is disclosed a process for producing a monoalkenyl aromatic hydrocarbon compound which comprises alkenylating a side chain of an aromatic hydrocarbon compound having at least one hydrogen atom bonded at .alpha.-position of the side chain (such as xylene) with a conjugated diene having 4 or 5 carbon atoms (such as butadiene) in the presence of a catalyst comprising the mixture obtained by heat treating metallic sodium together with an alkaline earth metal oxide containing a potassium compound in the atmosphere of an inert gas. According to the aforesaid process, a monoalkenyl aromatic hydrocarbon compound such as industrially useful monoalkenylbenzene can be produced in high yield at a low cost with enhanced safety from a specific aromatic hydrocarbon compound and a specific conjugated diene compound.Type: GrantFiled: January 29, 1993Date of Patent: September 6, 1994Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Norio Fushimi, Kenji Inamasa, Makoto Takagawa
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Patent number: 5334794Abstract: A process for producing a monoalkenyl aromatic hydrocarbon compound which comprises alkenylating a side chain of an aromatic hydrocarbon compound having at least one hydrogen atom bonded at an .alpha.-position of the side chain (such as xylene) with a conjugated diene having 4 or 5 carbon atoms (such as butadiene) in the presence of a catalyst comprising a mixture obtained by heat treating metallic sodium together with a mixture of a zirconium oxide and a potassium compound in an inert gas atmosphere. An industrially useful monoalkenyl aromatic hydrocarbon compound is produced in a high yield at a low cost with enhanced safety from a specific aromatic hydrocarbon compound and a specific conjugated diene compound.Type: GrantFiled: April 15, 1993Date of Patent: August 2, 1994Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Norio Fushimi, Ko Kedo, Kenji Inamasa, Makoto Takagawa
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Patent number: 5321178Abstract: A process for efficiently producing 2,6-dimethylnaphthalene which comprises subjecting 2-methyl-1-(p-tolyl)butene and/or 2-methyl-1-(p-tolyl)butane as the starting raw material to a cyclization dehydrogenation reaction in the presence of a catalyst comprising (a) a palladium component, (b) an alkali or alkaline earth metal compound and (c) aluminum oxide. The process enables the production of highly pure 2,6-dimethylnaphthalene in a high yield at a low cost. The catalyst used in the process affords high safety and stability.Type: GrantFiled: January 21, 1993Date of Patent: June 14, 1994Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Kenji Inamasa, Norio Fushimi, Makoto Takagawa
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Patent number: 5276230Abstract: There is disclosed a process for efficiently producing 2,6-dimethylnaphthalene used for the production of polyethylene naphthalate which comprises subjecting 2-methyl-1-(p-tolyl)butene and/or 2-methyl-1-(p-tolyl)butane as a starting raw material to cyclization dehydrogenation reaction by the use of a catalyst comprising a platinum component and at least one component selected from the group consisting of alkali metals and alkaline earth metals each being supported on aluminum oxide. The above process enables the production of the objective compound in a high yield at a low cost by using the catalyst having high safety and stability from the widely available starting material, thereby enhancing the industrial significance of the process.Type: GrantFiled: September 14, 1992Date of Patent: January 4, 1994Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Kenji Inamasa, Norio Fushimi, Makoto Takagawa
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Patent number: 5254769Abstract: Dimethylnaphthalenes are isomerized into 2,6-dimethylnaphthalene by utilizing hydrogen fluoride as a catalyst and straight chain saturated aliphatic hydrocarbons having carbon atoms in the range from 5 to 12 as the solvent. Isomerization to other undesirable isomers such as 2,7-dimethylnaphthalene and side reactions such as disproportionation are suppressed and a very high degree of the isomerization to 2,6-DMN can be attained.Type: GrantFiled: March 16, 1992Date of Patent: October 19, 1993Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Makoto Takagawa, Ken Yamagishi, Kazuo Nagagata
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Patent number: 5068480Abstract: A process for producing 2,6-dimethylnaphthalene, which comprises subjecting 2-methyl-1-(p-tolyl)-butene, 2-methyl-1-(p-tolyl)-butane or a mixture of these to cyclization and dehydrogenation in the presence of a catalyst comprising lead oxide and/or indium oxide and aluminum oxide.Type: GrantFiled: December 3, 1990Date of Patent: November 26, 1991Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Makoto Takagawa, Ken Yamagishi, Jyun Yoshihara, Kenji Inamasa, Kumiko Watabe
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Patent number: 4916104Abstract: A catalyst composition for decomposition of methanol comprising a substantially aluminum-free precipitate composed of a copper compound and a nickel compound, a phosphate salt of aluminum and an alkali metal compound, the content of the alkali metal being 1 to 100 atoms per 100 atoms in total of copper and nickel in the precipitate.Type: GrantFiled: January 10, 1989Date of Patent: April 10, 1990Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Nobuo Isogai, Makoto Takagawa, Kumiko Watabe, Mikio Yoneoka, Ken Yamagishi
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Patent number: 4894188Abstract: Fatty acid and their derivatives are simply produced by reacting an olefin, carbon monoxide and water or reacting an alcohol or its derivative and carbon monoxide in the presence of a hydrogen fluoride catalyst and thermally decomposing the resulting reaction product in the presence of a lower hydrocarbon or a lower halogenated hydrocarbon.Type: GrantFiled: February 13, 1985Date of Patent: January 16, 1990Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Takehiko Takahashi, Makoto Takagawa, Tomiyoshi Furuta, Toshio Hidaka, Kazuo Takada
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Patent number: 4666945Abstract: A catalyst composition comprising copper oxide, zinc oxide and zirconium oxide, the content of zirconium oxide being 30 to 70% by weight. This catalyst composition is useful for synthesis of methanol from carbon monoxide and/or carbon dioxide and hydrogen by a gas-liquid-solid phase fluidized bed method or a gas-solid phase fluidized bed method.Type: GrantFiled: September 11, 1985Date of Patent: May 19, 1987Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Minoru Osugi, Makoto Takagawa, Tadasi Nakamura, Takashi Kojima, Kinya Tsuji
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Patent number: 4311867Abstract: Unbranched or less branched paraffins having 6 carbon atoms as essential components are isomerized without side reaction in high yield in the presence of hydrogen fluoride and boron trifluoride as a catalyst while keeping percent isomerization of paraffins having 6 carbon atoms lower than the equilibrium percent isomerization of the paraffins having 6 carbon atoms at a given reaction temperature, or by conducting isomerization at a plurality of stages while keeping a reaction temperature at a given stage lower than that at the preceding stage and keeping percent isomerization of paraffins having 6 carbon atoms at a given stage lower than the equilibrium percent isomerization thereof at the reaction temperature at the stage.Type: GrantFiled: April 21, 1980Date of Patent: January 19, 1982Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Makoto Takagawa, Tamotsu Ueno, Takehiko Takahashi
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Patent number: 4311868Abstract: Hydrocarbon is catalytically converted by using a fluorine compound represented by the general formula Z.sup.+ MF.sub.6.sup.-, wherein Z is a hydrogen atom or a hydrogen group, and M is a niobium atom, an antimony atom or a tantalum atom as a catalyst, wherein a catalytically inactive component is settled as a heavy liquid phase or deposited as a solid in a reaction product solution from the conversion of hydrocarbon, the heavy liquid phase or the solid is removed from the reaction product solution, thereby removing substantially the catalytically inactive component therefrom, and the remaining catalytically active component is reused in the conversion of hydrocarbon. An amount of a fresh catalyst solution to be supplemented is considerably reduced by effectively reusing the catalytically active component.Type: GrantFiled: November 20, 1979Date of Patent: January 19, 1982Assignee: Mitsubishi Gas Chemical Company, Inc.Inventors: Tamotsu Ueno, Takehiko Takahashi, Kazuo Takada, Toshio Hidaka, Makoto Takagawa