Abstract: Apparatus and a method for controlling gas flow into a combustion engine exhaust gas filter e.g., to control filter temperatures during filter regeneration, comprising providing a fluidic exhaust stream diverter proximate to and centrally of the inlet face of the filter and activating the fluidic diverter to divert exhaust gas flow away from central filter portions toward peripheral filter portions.

Abstract: An engine exhaust system is disclosed which in operation is capable of substantially reducing the quantities of hydrocarbons emitted to the atmosphere during engine start-up. The system utilizes molecular sieve means, such as a high-silica zeolite, which function to adsorb hydrocarbons emitted during engine start-up, before the catalytic converter has attained its effective operating temperature. The system is designed so that, once the catalytic converter has attained an effective operating temperature, the hydrocarbons can be desorbed from the molecular sieve means and conveyed to the converter for conversion to non-toxic by-products.

Abstract: A modified in-line adsorber system capable of meeting the California ultra-low emission vehicle (ULEV) standard using a combination of burn-off catalyst and a modified adsorber constructed with an open flow region of substantially unobstructed flow having a hole or a region of larger cell openings to increase the amount and rate of contact between the exhaust gas and the burn-off catalyst, and thereby reduce the light-off time of the burn-off catalyst. For best effect, the open flow region of the adsorber is positioned along the exhaust stream between the engine and the burn-off catalyst as defined by the exhaust flow path of least resistance.

Abstract: An improved system for the control of combustion engine exhaust from a motor vehicle includes an adsorber for the adsorption of hydrocarbons concentrated in the exhaust stream at engine startup, the adsorber being of honeycomb shape which includes a peripheral channeled portion and a central channeled portion, the latter including an exhaust gas by-pass port parallel with the channels, with the through-channels in the central portion of the honeycomb having a relatively high resistance to exhaust gas flow compared to the channels traversing the peripheral portion. Systems with reduced secondary air requirements and providing more efficient burn-off of the adsorbed hydrocarbons are also disclosed.

Abstract: The invention is directed at an exhaust system exhibiting an increased flow uniformity under diversion conditions comprising: (1) a honeycomb structure having an inlet and outlet end disposed in a housing located in an exhaust gas stream and downstream from an engine, and having a first substantially unobstructed flow region, and a second more obstructed flow region adjacent the first region, both providing a flow path for the exhaust gases in the exhaust gas stream; and, (2) a fluidics apparatus disposed in the exhaust stream comprising a diverter body located proximate to the first region, a diversion fluid source, a conduit for directing the diversion fluid toward the diverter body and an exhaust flow divergent device.

Abstract: A modified in-line adsorber system capable of meeting the California ultra-low emission vehicle (REV) standard using a combination of burn-off catalyst and a modified adsorber constructed with an open flow region of substantially unobstructed flow having a hole or a region of larger cell openings to increase the amount and rate of contact between the exhaust gas and the burn-off catalyst, and thereby reduce the light-off time of the burn-off catalyst. For best effect, the open flow region of the adsorber is positioned along the exhaust stream between the engine and the burn-off catalyst as defined by the exhaust flow path of least resistance.

Abstract: Flow diverter methods and apparatus useful, for example, in adsorber systems capable of meeting the California ultra-low emission vehicle (ULEV) standard, are described, the adsorber systems incorporating a combination of a burn-off catalyst and a modified adsorber constructed with an open flow region of substantially unobstructed flow having a hole or a region of larger cell openings, the flow diverter acting to control exhaust flow through the adsorber to both increase adsorption and reduce the light-off time of the burn-off catalyst.

Abstract: The present invention is directed to an in-line engine exhaust system. In general, the exhaust system is comprised of the following: (1) a honeycomb structure having an inlet and outlet end disposed in a housing and located in an exhaust gas stream downstream from an engine and possessing a first substantially unobstructed flow region, a second more obstructed flow region adjacent the first region; and, (2) a fluidics apparatus disposed in the exhaust stream proximate to the first region for creating a negative flow zone within the first region, which in turn results in diverting a portion of the exhaust gases away from the first region. More specifically, the fluidics apparatus includes a source diversion fluid, typically air, a conduit for delivering the diversion fluid and a diverter body for diverting the diversion fluid.

Abstract: The invention relates to an extruded honeycomb structure in which every cross-section is rotationally displaced from other cross-sections. The cells are twisted and as a result, are not parallel with the axis of extrusion. The twisted cells are formed by passing plastically deformable material through a die and twisting or rotationally displacing the extrudate around its central axis to obtain a twisted honeycomb structure.

Abstract: A engine exhaust system is disclosed for reducing the amount of hydrocarbons emitted during engine start-up (cold-start), before the catalytic converter has attained its effective operating temperature. The system includes a flow control device, in particular a bi-metallic flap, occupying a first position at the first temperature to direct substantially all of the engine exhaust through a molecular sieve structure to adsorb the hydrocarbons, and a second position at the second temperature, to direct the engine exhaust stream directly from the light-off catalyst to the burnoff catalyst, bypassing the molecular sieve structure.

Abstract: A method for making an activated carbon supported catalyst, the method comprising combining a carbon precursor and a catalyst precursor, curing the carbon precursor if necessary, carbonizing the carbon precursor, and activating the carbon to produce the activated carbon supported catalyst. The activated carbon supported catalyst can take the form of a coating on a substrate, a powder, or a monolithic body.

Abstract: Thin-walled honeycomb structures of activated carbon, useful for the adsorption of hydrocarbon vapors are prepared without the need for firing or sintering at elevated temperatures. The structures are prepared by forming a substantially homogeneous batch from an admixture of thermally gellable cellulose ether and/or derivative thereof such as methylcellulose, an additional organic binder such as a polyvinyl alcohol resin, and particles of activated carbon; plasticizing the batch with liquid, extruding the batch into a honeycomb shape; and drying the extruded shape at a temperature up to about 225.degree. C.

Abstract: A method for producing a thermally shock resistant washcoated substrate involves introducing a buffer solution into the microcracks, and optionally the micropores of a porous sintered body, the pH of the buffer solution being at a predetermined value to result in the formation of a gel on contact of the buffer solution with the slurry which is to be subsequently applied, contacting the body with a washcoating slurry to form a gel at the interface of the buffer solution and slurry. Formation of the gel prevents the slurry from entering the microcracks. The body is then calcined at a temperature and for a time sufficient to form the washcoated substrate.

Abstract: A porous catalyst support which may be used in a catalytic converter for treating automotive exhaust gases. The support comprises a substrate having a multichannel structure of generally thin walls and washcoat particles of colloidal particle size mainly or wholly within the pores of the walls so as to increase open frontal area and reduce back pressure. Substrate is either ceramic or metal. In a ceramic substrate with microcracks in the walls, the washcoat colloidal dispersion is free of soluble inorganic constituents and the particles do not fill the microcracks so as to prevent undesirable increase in thermal expansion and corresponding decrease in thermal shock resistance.

Abstract: A process of using a catalyst system for the oxidation of hydrocarbons, carbon monoxide, and the reduction of nitrogen oxides is provided. The unique synergy of the catalyst system, a combination of molecular sieves and noble metals, provides a system that partially or entirely replaces the need for rhodium as a catalyst in three way catalyst systems.

Abstract: A system and method are disclosed for removing hydrocarbons from a gaseous mixture, which comprises selecting a plurality of agents which are effective for adsorbing hydrocarbons at predetermined temperatures, wherein for at least two of the adsorbing agents, the temperatures at which the maximum adsorption rates for the hydrocarbons occur, are different from one another, and contacting the adsorbing agents with the gaseous mixture at the predetermined temperatures to cause adsorption of the hydrocarbons. A multistage catalyst system for converting NO.sub.x, CO, and hydrocarbons from a gaseous mixture to innocuous products is disclosed, which comprises the above described system for removing hydrocarbons as one stage, and a main body catalyst stage for converting NO.sub.x, CO, and hydrocarbons to innocuous products, wherein the gaseous mixture passes from one stage to the other.

Abstract: A phosphate-Al.sub.2 O.sub.3 material is disclosed wherein the phosphate is homogeneously dispersed throughout, the specific surface area as measured by N.sub.2 BET method is at least about 50 m.sup.2 /g, and the average pore radius is no greater than about 200.ANG.. A method is disclosed for producing the material which comprises forming a precursor material by wet-mixing a phosphate yielding species and an aluminum oxide yielding species which can be aluminum oxide, aluminum hydroxylated oxides, aluminum hydroxide, aluminum alkoxides, and combinations thereof, in amounts sufficient to result in an AlPO.sub.4 content of about 3 to 12 percent by weight in the phosphate-Al.sub.2 O.sub.3, drying and heat-treating the precursor material at a temperature and for a time sufficient to form the phosphate- Al.sub.2 O.sub.3. The material is used as a support for catalyst metals.

Abstract: An apparatus, system and method are disclosed for modifying a gaseous mixture. The apparatus comprises a unitary body having an inlet end, an outlet end, and a multiplicity of cells extending from inlet end to outlet end, the cells being separated from one another by porous walls, and filler material comprising electrically non-conducting active powder material, loaded into at least part of the volume of the cells, with some of the cells being unloaded and open, wherein a gaseous mixture enters the body at the inlet end through the open cells, and at least some of the gaseous mixture passes through the porous walls and is compositionally modified by the active material, and thereafter the resultant modified mixture passes through the open cells and exits the body at the outlet end. The apparatus can be used in conjunction with other apparatuses which are catalyzed to form a gas modifying system. The apparatus and system are especially suited for conversion of hydrocarbons, NO.sub.

Abstract: A catalyst system for the oxidation of hydrocarbons, carbon monoxide, and the reduction of nitrogen oxides is provided. The unique synergy of the catalyst system, a combination of molecular sieves and noble metals, provides a system that partially or entirely replaces the need for rhodium as a catalyst in three way catalyst systems.

Abstract: A washcoated substrate and method for producing the washcoat on the substrate are disclosed which comprises forming a slurry comprising at least one ionizable compound of A, where A is selected from barium, strontium, and combinations thereof, and A is in an amount sufficient to yield AO in an amount of about 0.2-20% by weight of the washcoat, an aluminum oxide yielding species, and a medium wherein at least a portion of the ionizable compound ionizes to form ions of A, contacting the slurry with a substrate to form a green coating containing A and the aluminum oxide yielding species thereon, and heat treating the resulting green-coated substrate at a temperature and for a time sufficient to form a washcoat consisting essentially of AO-Al.sub.2 O.sub.3 on the substrate, wherein A is homogeneously distributed throughout the Al.sub.2 O.sub.3, the washcoat having a specific surface area, as measured by the N.sub.2 BET method, of at least about 50 m.sup.