Abstract: Described herein are a novel concept of thermally stimulated delayed phosphorescence (TSDP) to harvest light emission from the higher energy triplet excited state via the up-conversion from the lowest-energy triplet excited state by efficient spin-allowed reverse internal conversion as well as the development of TSDP emitters, as exemplified by a novel class of gold(III) compounds with TSDP properties and methods of making and using said compounds. The gold(III) compound includes a triazine-containing cyclometalating tridentate ligand and one auxiliary ligand, both coordinated to a gold(III) metal center. The gold(III) compounds disclosed herein can be used as light-emitting material for fabrication of OLEDs.

Abstract: A series of thermally stable and highly luminescent cyclometalated tetradentate ligand-containing gold(III) compounds was designed and synthesized. The cyclometalated tetradentate ligand-containing gold(III) compounds can be used as light-emitting material for fabrication of light-emitting devices. The cyclometalated tetradentate ligand-containing gold(III) compounds can be deposited as a layer or a component of a layer using a solution-processing technique or a vacuum deposition process. The cyclometalated tetradentate ligand-containing gold(III) compounds are robust and can provide electroluminescence with high efficiency and brightness. More importantly, the vacuum-deposited OLEDs demonstrate long operational stabilities with half-lifetime of over 29,700 hours at 100 cd m?2.

Abstract: A series of thermally stable and highly luminescent cyclometalated tetradentate ligand-containing gold(III) compounds was designed and synthesized. The cyclometalated tetradentate ligand-containing gold(III) compounds can be used as light-emitting material for fabrication of light-emitting devices. The cyclometalated tetradentate ligand-containing gold(III) compounds can be deposited as a layer or a component of a layer using a solution-processing technique or a vacuum deposition process. The cyclometalated tetradentate ligand-containing gold(III) compounds are robust and can provide electroluminescence with high efficiency and brightness. More importantly, the vacuum-deposited OLEDs demonstrate long operational stabilities with half-lifetime of over 29,700 hours at 100 cd m?2.

Abstract: A series of thermally stable and highly luminescent cyclometalated tetradentate ligand-containing gold(III) compounds was designed and synthesized. The cyclometalated tetradentate ligand-containing gold(III) compounds can be used as light-emitting material for fabrication of light-emitting devices. The cyclometalated tetradentate ligand-containing gold(III) compounds can be deposited as a layer or a component of a layer using a solution-processing technique or a vacuum deposition process. The cyclometalated tetradentate ligand-containing gold(III) compounds are robust and can provide electroluminescence with high efficiency and brightness. More importantly, the vacuum-deposited OLEDs demonstrate long operational stabilities with half-lifetime of over 29,700 hours at 100 cd m?2.

Abstract: A novel class of gold(III) compounds containing cyclometalated tridentate ligand and one aryl auxiliary ligand, both coordinated to a gold(III) metal center. (a) X is nitrogen or carbon; (b) Y and Z are independently nitrogen or carbon; (c) A is cyclic structure (derivative) of pyridine, quinoline, isoquinoline or phenyl group; (d) B and C are independently cyclic structures (derivatives) of pyridine, quinoline, isoquinoline or phenyl groups; (e) B and C can be identical or non-identical, with the proviso that both B and C are not 4-tert-butylbenzene; (f) R? is a substituted carbon, nitrogen, oxygen or sulfur donor ligand attached to the gold atom; (g) n is zero, a positive integer or a negative integer. wherein R? is selected from, but not limited to, aryl, substituted aryl, heteroaryl, substituted heteroaryl, heterocyclic aryl and substituted heterocyclic aryl, alkoxy, aryloxy, amide, thiolate, sulfonate, phosphide, fluoride, chloride, bromide, iodide, cyanate, thiocyanate or cyanide.

Abstract: Described herein are gold (III) compounds according to formula (I) for use as emitters in organic light-emitting devices (OLEDs) and methods of making and using said compounds. The gold (III) compound includes a group 15 element containing tridentate ligand and one aryl auxiliary ligand that are both coordinated to the gold (III) metal center to form a series of thermally stable and highly luminescent gold (III) complexes. The gold (III) compounds disclosed herein can be used as light-emitting material for fabrication of OLEDs. The gold (III) compounds can be deposited as a layer or a component of a layer using a solution processing technique or a vacuum deposition process. The gold (III) compounds are robust and can provide electroluminescence with high efficiency and brightness.

Abstract: A novel class of gold (III) compounds with thermally stimulated delayed phosphorescence (TSDP) properties, methods of making and use thereof are disclosed. The gold (III) compound includes a triazine-containing cyclometalating tridentate ligand and one auxiliary ligand, both coordinated to a gold (III) metal center. The gold (III) compounds can be used as light-emitting material for fabrication of OLEDs. A novel concept of TSDP to harvest light emission from the higher energy triplet excited state via the up-conversion from the lowest-energy triplet excited state by efficient spin-allowed reverse internal conversion is also disclosed.

Abstract: Described herein are gold (III) compounds according to formula (I) for use as emitters in organic light-emitting devices (OLEDs) and methods of making and using said compounds. The gold (III) compound includes a group 15 element containing tridentate ligand and one aryl auxiliary ligand that are both coordinated to the gold (III) metal center to form a series of thermally stable and highly luminescent gold (III) complexes. The gold (III) compounds disclosed herein can be used as light-emitting material for fabrication of OLEDs. The gold (III) compounds can be deposited as a layer or a component of a layer using a solution processing technique or a vacuum deposition process. The gold (III) compounds are robust and can provide electroluminescence with high efficiency and brightness.

Abstract: A series of thermally stable and highly luminescent cyclometalated tetradentate ligand-containing gold(III) compounds was designed and synthesized. The cyclometalated tetradentate ligand-containing gold(III) compounds can be used as light-emitting material for fabrication of light-emitting devices. The cyclometalated tetradentate ligand-containing gold(III) compounds can be deposited as a layer or a component of a layer using a solution-processing technique or a vacuum deposition process. The cyclometalated tetradentate ligand-containing gold(III) compounds are robust and can provide electroluminescence with high efficiency and brightness. More importantly, the vacuum-deposited OLEDs demonstrate long operational stabilities with half-lifetime of over 29,700 hours at 100 cd m?2.

Abstract: Described herein are transition metal complexes containing nickel(II), as the central metal atom, and tridentate and tetradentate ligands. The transition metal complexes also include an ancillary ligand with strong ?-donating properties. The ancillary ligand enhances the luminescence by increasing the chances of populating the emissive state. The transition metal complexes are emissive at room temperature and/or low temperature in various media, rendering them useful as light-emitting materials for OLEDs.

Abstract: Described herein are transition metal complexes containing nickel(II), as the central metal atom, and tridentate and tetradentate ligands. The transition metal complexes also include an ancillary ligand with strong ?-donating properties. The ancillary ligand enhances the luminescence by increasing the chances of populating the emissive state. The transition metal complexes are emissive at room temperature and/or low temperature in various media, rendering them useful as light-emitting materials for OLEDs.

Abstract: Disclosed is a class of dendrimers containing cyclometalated tridentate platinum(II) compounds with one monoanionic auxiliary ligand, both coordinated to a platinum (II) metal center and having the chemical structure shown in generic formula (I), wherein at least one of R1, R2 and R3 being a dendrimeric moiety of general formula (II), each being optionally substituted.

Abstract: A novel class of gold(III) compounds containing cyclometalated tridentate ligand and one aryl auxiliary ligand, both coordinated to a gold(III) metal center. (a) X is nitrogen or carbon; (b) Y and Z are independently nitrogen or carbon; (c) A is cyclic structure (derivative) of pyridine, quinoline, isoquinoline or phenyl group; (d) B and C are independently cyclic structures (derivatives) of pyridine, quinoline, isoquinoline or phenyl groups; (e) B and C can be identical or non-identical, with the proviso that both B and C are not 4-tert-butylbenzene; (f) R? is a substituted carbon, nitrogen, oxygen or sulfur donor ligand attached to the gold atom; (g) n is zero, a positive integer or a negative integer. wherein R? is selected from, but not limited to, aryl, substituted aryl, heteroaryl, substituted heteroaryl, heterocyclic aryl and substituted heterocyclic aryl, alkoxy, aryloxy, amide, thiolate, sulfonate, phosphide, fluoride, chloride, bromide, iodide, cyanate, thiocyanate or cyanide.

Abstract: A novel class of saturated or conjugated dendrimers containing at least one strong ?-donating group coordinated to cyclometalated tridentate gold(III) compounds having the chemical structure depicted by generic formula: wherein: (a) [Au] is a cyclometalated tridentate gold(III) group; (b) Unit A is a ?-donating chemical group; (c) Unit B is a central part of the dendrons comprising a branch point of component dendrimers; (d) Unit C is optional surface groups or dendrons of the dendrimers; (e) n=0 or 1.

Abstract: A novel class of saturated or conjugated dendrimers containing at least one strong ?-donating group coordinated to cyclometalated tridentate gold(III) compounds having the chemical structure depicted by generic formula: wherein: (a) [Au] is a cyclometalated tridentate gold(III) group; (b) Unit A is a ?-donating chemical group; (c) Unit B is a central part of the dendrons comprising a branch point of component dendrimers; (d) Unit C is optional surface groups or dendrons of the dendrimers; (e) n=0 or 1.

Abstract: An air inflated bubble roof, such as for a stadium, arena or the like, includes a compression ring extending around the perimeter of the roof. An upper and a lower cable net each spans and is attached to the compression ring. An inflatable membrane member is located between the two cable nets and bows the cable nets apart when it is inflated. A bladder is located within the inflatable membrane member and, in combination with the upper and lower parts of the membrane member, forms a seal around its perimeter.

Abstract: An elongated elevated box girder and roadway structure is constructed in a number of individual elongated sections with the support structure and formwork being reused, in turn, for each section. Each section is constructed in a number of stages. Initially, a support structure is built up from grade or is mounted on permanent upright members of the structure being formed, such as piers or abutments. Formwork for the bottom slab and the upright outside webs of the box girders are placed upon the support structure. Concrete is poured into the formwork for the bottom slab and webs and, after being allowed to set for a given period, and posttensioned, if necessary, the formwork is stripped and the support structure is removed. The support structure and formwork are then moved and set up for the next section to be constructed. The roadway slab includes the top slab of the box girder and cantilever sections extending laterally outwardly from each side of the top slab.