Patents by Inventor Manfred Hecker
Manfred Hecker has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20120065335Abstract: A polyethylene composition, in particular suitable for the preparation of films, and a process for preparing the same are described. The polyethylene composition of the invention comprises from 50 to 89% by weight of a first polyethylene component comprising at least one multimodal polyethylene including a plurality of ethylene polymer fractions having distinct molecular weights and comonomer contents, at least one of said plurality of ethylene polymer fractions being prepared by the use of a single site catalyst, and from 50 to 11% by weight of a second polyethylene component comprising a low or medium density polyethylene.Type: ApplicationFiled: November 21, 2011Publication date: March 15, 2012Applicant: BASELL POLYOLEFINE GMBHInventors: Jennifer Kipke, Shahram Mihan, Rainer Karer, Jörg Auffermann, Manfred Hecker, Paulus De Lange, Harald Schmitz
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Patent number: 8084557Abstract: A continuous gas-phase process for the polymerization of alpha-olefins, in particular ethylene, comprising passing an alpha-olefin monomer stream through an oil filter in order to reduce the amount of oil to less than 8 ppm, and polymerizing the thus purified monomer feed in gas-phase reactor; the reduction of the amount of oil improves the operability of the plant over time.Type: GrantFiled: December 18, 2008Date of Patent: December 27, 2011Assignee: Basell Polyolefine GmbHInventors: Manfred Hecker, Markus Schopf, Axel Hamann, Paulus-Petrus Maria de Lange
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Publication number: 20110230629Abstract: Method of polymerizing ethylene with C3-C20-olefine-comonomer, comprising the step of carrying out the olymerization in a single gas phase reactor with a mixed catalyst system herein the catalyst system has a catalyst mileage of higher than 6000 g polymer product/g catalyst.Type: ApplicationFiled: September 25, 2009Publication date: September 22, 2011Applicant: BASELL POLYOLEFINE GMBHInventors: Shahram Mihan, Rainer Karer, Fabiana Fantinel, Manfred Hecker, Gerhardus Meier, Maclovio Herrera Salinas
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Patent number: 8022124Abstract: Process for preparation of ethylene homopolymers or copolymers, comprising the steps of a) polymerization of ethylene or of ethylene with one or more other 1-olefins in the presence of a chromium catalyst at temperatures of from 20 to 200° C. and at pressures of from 0.1 to 20 MPa, where the chromium catalyst can be prepared via application of one or more chromium compounds to a silicate support and subsequent thermal activation under oxidative conditions at temperatures of from 620 to 900° C.; b) mixing of the polyethylene in the melt in the presence of from 1000 to 2000 ppm of an antioxidant comprising at least one sterically hindered phenol and comprising at least one phosphite in a mixing ratio of from 1:5 to 5:1, with specific energy input of at least 0.17 kWh/kg.Type: GrantFiled: January 24, 2007Date of Patent: September 20, 2011Assignee: Basell Polyolefine GmbHInventors: Wolfgang Rohde, Lutz-Gerd Heinicke, Rainer Karer, Manfred Hecker
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Publication number: 20110217499Abstract: A polyethylene for IM having excellent processing properties in terms of spiral flow testing is devised.Type: ApplicationFiled: August 27, 2009Publication date: September 8, 2011Applicant: Basell Polyolefine GmbHInventors: Gerd Mannebach, Harald Schmitz, Shahram Mihan, Rainer Karer, Manfred Hecker, Guido Funk, Adrian Popa
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Publication number: 20110045295Abstract: A novel adhesive composition suitable for composing multilayered coatings onto large, industrial equipment such as pipeline tubes is devised. The composition is a blend based on a polyethylene which determines the blend's favorable properties, which polyethylene itself can be used further in coating cables and for producing mouldings, especially rotomoulded articles.Type: ApplicationFiled: February 18, 2009Publication date: February 24, 2011Applicant: Basell Polyolefine GmbHInventors: Heinz Vogt, Shahram Mihan, Gerd Mannebach, Gerhardus Meier, Joachim Berthold, Manfred Hecker
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Publication number: 20100331502Abstract: A continuous gas-phase process for the polymerization of alpha-olefins, in particular ethylene, comprising passing an alpha-olefin monomer stream through an oil filter in order to reduce the amount of oil to less than 8 ppm, and polymerizing the thus purified monomer feed in gas-phase reactor; the reduction of the amount of oil improves the operability of the plant over time.Type: ApplicationFiled: December 18, 2008Publication date: December 30, 2010Applicant: Basell Polyolefine GmbHInventors: Manfred Hecker, Markus Schopf, Axel Hamann, Paulus-Petrus Maria De Lange
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Publication number: 20100317755Abstract: Process for preparation of ethylene homopolymers or copolymers, comprising the steps of a) polymerization of ethylene or of ethylene with one or more other 1-olefins in the presence of a chromium catalyst at temperatures of from 20 to 200° C. and at pressures of from 0.1 to 20 MPa, where the chromium catalyst can be prepared via application of one or more chromium compounds to a silicate support and subsequent thermal activation under oxidative conditions at temperatures of from 620 to 900° C.; b) mixing of the polyethylene in the melt in the presence of from 1000 to 2000 ppm of an antioxidant comprising at least one sterically hindered phenol and comprising at least one phosphite in a mixing ratio of from 1:5 to 5:1, with specific energy input of at least 0.17 kWh/kg.Type: ApplicationFiled: January 24, 2007Publication date: December 16, 2010Applicant: Basell Polyolefine GmbHInventors: Wolfgang Rohde, Lutz-Gerd Heinicke, Rainer Karer, Manfred Hecker
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Patent number: 7781544Abstract: An apparatus for the polymerization of olefins, in particular ethylene, comprising a gas-phase fluidized-bed reactor (1), a recycle gas line (2) connected to the reactor for discharging and recirculating the recycle gas stream comprising the unpolymerized olefin and a cyclone (3) located in the recycle gas line for the reduction and precipitation of the solid particles entrained in the recycle gas from the reactor, with the cyclone comprising an upper section (3a) which has an essentially vertical central axis, whose wall extends along a rotationally symmetric body and which is provided with a cyclone inlet (4) arranged eccentrically relative to the central axis, a middle section (3b) which adjoins the upper section (3a) and whose wall extends along a rotationally symmetric body which tapers in a downward direction, a lower section (3c) for discharging the solid particles precipitated from the recycle gas which adjoins the middle section (3b) and whose wall extends along a rotationally symmetric body and a tuType: GrantFiled: November 9, 2005Date of Patent: August 24, 2010Assignee: Basell Polyolefine GmbHInventors: Eberhard Herrmann, Axel Sperber, Manfred Hecker, Rainer Karer, Klaus Berhalter, Paulus De Lange, Jörg Halpap, Cyrus Ahmadzade-Youssefi
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Patent number: 7776278Abstract: Apparatus for the polymerization of olefins, in particular ethylene, comprising a gas-phase fluidized-bed reactor (1), a product offtake line (15) for taking polymer particles either continuously or discontinuously from the reactor (1), which line (15) is connected to a depressurization vessel (2) for separating polymer particles and gas, a recycle gas filter (3) for freeing the gas of entrained fine particles connected to the depressurization vessel (2), a compressor which compresses the gas which has been freed of fine particles and recirculates it into the reactor (1), with the recycle gas filter (3) having an inlet chamber (4) provided with a gas inlet (6), an outlet chamber (5) provided with a gas outlet (7), an essentially vertical sheet-like filter medium (9) for retaining the fine particles which separates the inlet chamber (4) from the outlet chamber (5) and a particle outlet (8).Type: GrantFiled: November 8, 2005Date of Patent: August 17, 2010Assignee: Basell Polyolefine GmbHInventors: Eberhard Herrmann, Manfred Hecker, Rainer Karer, Klaus Berhalter, Paulus De Lange, Jörg Halpap, Cyrus Ahmadzade-Youssefi
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Publication number: 20100144988Abstract: Monomodal copolymers of ethylene and molding compositions comprising such copolymers, wherein the copolymers have a density determined according to DIN EN ISO 1183-1, variant A in the range from 0.938 to 0.944 g/cm3, a melt index MFR21 determined according to ISO 1133 at 190° C. under a load of 21.6 kg in the range from 12 to 17 g/10 min, a weight average molar mass Mw, in the range from 140 000 g/mol to 330 000 g/mol, a polydispersity Mw/Mn in the range from 9 to 17, and a content of comonomer side chains per 1000 carbon atoms C x equal to or above a value defined via equation (I) Cx=128.7?134.62×d?, wherein d? is the numerical value of the density of the copolymer in g/cm3, the use of the copolymers for producing injection-molded articles, as well as injection-molded articles comprising the copolymers, and process for the preparation of such monomodal copolymers.Type: ApplicationFiled: January 15, 2008Publication date: June 10, 2010Applicant: Basell Polyolefine GmbHInventors: Klaus Foettinger, Manfred Hecker, Lothar Berger, Rainer Karer, Dieter Lilge
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Publication number: 20090105414Abstract: Method for metering polar, antistatically acting process auxiliaries into a polymerization reactor in which the process auxiliaries are present in solution in a nonpolar solvent, wherein the electrical conductivity of the solution is measured and the amount of the process auxiliary metered in is determined from the electrical conductivity.Type: ApplicationFiled: May 4, 2007Publication date: April 23, 2009Applicant: Basell Polyolefine GmbHInventors: Shahram Mihan, Rainer Karer, Manfred Hecker
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Publication number: 20090099315Abstract: A polyethylene composition, in particular suitable for the preparation of films, and a process for preparing the same are described. The polyethylene composition of the invention comprises from 50 to 89% by weight of a first polyethylene component comprising at least one multimodal polyethylene including a plurality of ethylene polymer fractions having distinct molecular weights and comonomer contents, at least one of said plurality of ethylene polymer fractions being prepared by the use of a single site catalyst, and from 50 to 11% by weight of a second polyethylene component comprising a low or medium density polyethylene.Type: ApplicationFiled: November 14, 2006Publication date: April 16, 2009Applicant: BASELL POLYOLEFINE GMBHInventors: Jennifer Kipke, Shahram Mihan, Rainer Karer, Jorg Auffermann, Manfred Hecker, Paulus De Lange, Harald Schmitz
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Publication number: 20080014128Abstract: Apparatus for the polymerization of olefins, in particular ethylene, comprising a gas-phase fluidized-bed reactor (1), a product offtake line (15) for taking polymer particles either continuously or discontinuously from the reactor (1), which line (15) is connected to a depressurization vessel (2) for separating polymer particles and gas, a recycle gas filter (3) for freeing the gas of entrained fine particles connected to the depressurization vessel (2), a compressor which compresses the gas which has been freed of fine particles and recirculates it into the reactor (1), with the recycle gas filter (3) having an inlet chamber (4) provided with a gas inlet (6), an outlet chamber (5) provided with a gas outlet (7), an essentially vertical sheet-like filter medium (9) for retaining the fine particles which separates the inlet chamber (4) from the outlet chamber (5) and a particle outlet (8).Type: ApplicationFiled: November 8, 2005Publication date: January 17, 2008Applicant: Basell Polyolefine GmbHInventors: Eberhard Herrmann, Manfred Hecker, Rainer Karer, Klaus Berhalter, Paulus de Lange, Jorg Halpap, Cyrus Ahmadzade-Youssefi
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Publication number: 20070264171Abstract: An apparatus for the polymerization of olefins, in particular ethylene, comprising a gas-phase fluidized-bed reactor (1), a recycle gas line (2) connected to the reactor for discharging and recirculating the recycle gas stream comprising the unpolymerized olefin and a cyclone (3) located in the recycle gas line for the reduction and precipitation of the solid particles entrained in the recycle gas from the reactor, with the cyclone comprising an upper section (3a) which has an essentially vertical central axis, whose wall extends along a rotationally symmetric body and which is provided with a cyclone inlet (4) arranged eccentrically relative to the central axis, a middle section (3b) which adjoins the upper section (3a) and whose wall extends along a rotationally symmetric body which tapers in a downward direction, a lower section (3c) for discharging the solid particles precipitated from the recycle gas which adjoins the middle section (3b) and whose wall extends along a rotationally symmetric body and a tuType: ApplicationFiled: November 9, 2005Publication date: November 15, 2007Applicant: Basell Polyolefine GmbHInventors: Eberhard Herrmann, Axel Sperber, Manfred Hecker, Rainer Karer, Klaus Berhalter, Paulus de Lange, Jorg Halpap, Cyrus Ahmadzade-Youssefi
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Patent number: 6936666Abstract: Continuous gas-phase polymerization process for preparing ethylene and propene homopolymers and copolymers, in which ethylene, propene or mixtures comprising ethylene or propene and C3-C8-?-monoolefins are polymerized in the polymerization zone of a gas-phase polymerization reactor at from 30 to 125° C. and pressures of from 1 to 100 bar in the gas phase in a bed comprising finely divided polymer in the presence of a catalyst. To remove the heat of polymerization, the reactor gas is circulated and firstly passes through a cyclone after leaving the reactor. To prevent polymer deposits in the circulating gas system, a catalyst poison having a boiling point above the maximum temperature within the circulating gas system is fed into this circulating gas system at a position between the reactor and the cyclone.Type: GrantFiled: October 29, 2002Date of Patent: August 30, 2005Assignee: Babell Polyolfine GmbHInventors: Shahram Mihan, Rainer Karer, Manfred Hecker, Philipp Rosendorfer, Kasper Evertz, Armin Lange
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Patent number: 6849699Abstract: A continuous vapor-phase fluidized-bed process for the preparation of ethylene homopolymers and copolymers having a density of from 0.87 to 0.97 g/cm3 in which ethylene or mixtures of ethylene and C3-C8 a-monoolefins are (co)polymerized in the presence of a supported chromium catalyst in the polymerization zone of a vapor-phase fluidized-bed reactor under pressures ranging from 1 to 100 bar and at temperatures ranging from 30° to 125° C. in the vapor phase in an agitated bed of bulk material comprising particulate polymer, the resultant heat of polymerization is removed by cooling the recirculated reactor gas and the resulting (co)polymer is removed from the vapor-phase fluidized-bed reactor, wherein, for the preparation of a (co)polymer of a specific density d, the (co)polymerization is carried out at a temperature which is in a range restricted by an upper envelope defined by equation I T H = 171 + 6 ? ? ? d ? 0.Type: GrantFiled: September 11, 2003Date of Patent: February 1, 2005Assignee: Basell Polyolefine GmbHInventors: Peter Bauer, Armin Lange, Rainer Karer, Philipp Rosendorfer, Manfred Hecker, Günther Schweier, Wolfgang Micklitz, Kaspar Evertz, Hans-Jacob Feindt
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Publication number: 20040236040Abstract: Continuous gas-phase polymerization process for preparing ethylene and propene homopolymers and copolymers, in which ethylene, propene or mixtures comprising ethylene or propene and C3-C8-&agr;-monoolefins are polymerized in the polymerization zone of a gas-phase polymerization reactor at from 30 to 125° C. and pressures of from 1 to 100 bar in the gas phase in a bed comprising finely divided polymer in the presence of a catalyst. To remove the heat of polymerization, the reactor gas is circulated and firstly passes through a cyclone after leaving the reactor. To prevent polymer deposits in the circulating gas system, a catalyst poison having a boiling point above the maximum temperature within the circulating gas system is fed into this circulating gas system at a position between the reactor and the cyclone.Type: ApplicationFiled: February 11, 2004Publication date: November 25, 2004Inventors: Shahram Mihan, Rainer Karer, Manfred Hecker, Philipp Rosendorfer, Kaspar Evertz, Armin Lange
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Publication number: 20040063872Abstract: A continuous vapor-phase fluidized-bed process for the preparation of ethylene homopolymers and copolymers having a density of from 0.87 to 0.97 g/cm3 in which ethylene or mixtures of ethylene and C3-C8 a-monoolefins are (co)polymerized in the presence of a supported chromium catalyst in the polymerization zone of a vapor-phase fluidized-bed reactor under pressures ranging from 1 to 100 bar and at temperatures ranging from 30° to 125° C. in the vapor phase in an agitated bed of bulk material comprising particulate polymer, the resultant heat of polymerization is removed by cooling the recirculated reactor gas and the resulting (co)polymer is removed from the vapor-phase fluidized-bed reactor, wherein, for the preparation of a (co)polymer of a specific density d, the (co)polymerization is carried out at a temperature which is in a range restricted by an upper envelope defined by equation I 1 T H = 171 + 6 ⁢ ⁢ d ′ 0.Type: ApplicationFiled: September 11, 2003Publication date: April 1, 2004Inventors: Peter Bauer, Armin Lange, Rainer Karer, Philipp Rosendorfer, Manfred Hecker, Gunther Schweier, Wolfgang Micklitz, Kaspar Evertz, Hans-Jacob Feindt
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Patent number: 6649709Abstract: A continuous vapor-phase fluidized-bed process for the preparation of ethylene homopolymers and copolymers having a density of from 0.87 to 0.97 g/cm3 in which ethylene or mixtures of ethylene and C3-C8 a-monoolefins are (co)polymerized in the presence of a supported chromium catalyst in the polymerization zone of a vapor-phase fluidized-bed reactor under pressures ranging from 1 to 100 bar and at temperatures ranging from 30° to 125° C.Type: GrantFiled: May 31, 2000Date of Patent: November 18, 2003Assignee: Basell Polyolefine GmbHInventors: Peter Bauer, Armin Lange, Rainer Karer, Philipp Rosendorfer, Manfred Hecker, Günther Schweier, Wolfgang Micklitz, Kaspar Evertz, Hans-Jacob Feindt