Patents by Inventor Manfred Hugo Vock

Manfred Hugo Vock has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 4122122
    Abstract: Described are the compounds 1-(2-propenyl-3-(4-methyl-3-pentenyl)-.DELTA..sup.3 -cyclohexene-1-carboxaldehyde and 1-(2-propenyl)-4-(4-methyl-3-pentenyl)-.DELTA..sup.3 -cyclohexene-1-carboxaldehyde; and a process for preparing same by means of reacting an allylic halide with a mixture of 3 and 4-(4-methyl-3-pentenyl)-.DELTA..sup.3 -cyclohexene-1-carboxaldehyde using a phase transfer agent in a two phase system according to the reaction: ##STR1## wherein the carboxaldehyde moiety is bonded to the alpha-carbon atom or the beta-carbon atom, X is chloro or bromo and M is alkali metal, processes for adding such 1-(2-propenyl)-(4-methyl-3-pentenyl)-.DELTA..sup.
    Type: Grant
    Filed: August 24, 1977
    Date of Patent: October 24, 1978
    Assignee: International Flavors & Fragrances Inc.
    Inventors: John B. Hall, Mark A. Sprecker, Manfred Hugo Vock, Edward J. Shuster, Joaquin Vinals, Robert M. Novak
  • Patent number: 4122120
    Abstract: Described is a mixture of 1-(3,3-dimethylcyclohexyl)-4-methyl-cis-2-pentene-1-one, 1-(3,3-dimethylcyclohexyl)-4-methyl-trans-2-pentene-1-one, and 1-(3,3-dimethylcyclohexyl)-4-methyl-3-pentene-1-one and a mixture of 1-(3,3-dimethylcyclohexyl)-cis-2-pentene-1-one, 1-(3,3-dimethylcyclohexyl) -trans-2-pentene-1-one and 1-(3,3-dimethylcyclohexyl)-3-pentene-1-one, useful in augmenting or enhancing flavors and perfume and perfumed article aromas.
    Type: Grant
    Filed: July 28, 1977
    Date of Patent: October 24, 1978
    Assignee: International Flavors & Fragrances Inc.
    Inventors: Mark A. Sprecker, Manfred Hugo Vock, Frederick Louis Schmitt, John B. Hall, James Milton Sanders
  • Patent number: 4120308
    Abstract: The use of substituted norbornane derivatives used in the process of flavoring tobacco and the product thereof.
    Type: Grant
    Filed: December 13, 1977
    Date of Patent: October 17, 1978
    Assignee: International Flavors & Fragrances Inc.
    Inventors: Kenneth K. Light, James Milton Sanders, Manfred Hugo Vock, Edward J. Shuster, Joaquin Vinals, William L. Schreiber, John B. Hall, Denis E. Hruza, Sr., Venkatesh Kamath, Braja Dulal Mookherjee, Ching Y. Tseng, Mark A. Sprecker
  • Patent number: 4119577
    Abstract: Substituted-norbornane derivatives are described for use as perfumes, colognes and in perfume aroma augmenting, modifying, enhancing, and imparting compositions. The substituted norbornane derivatives having the following structure: ##STR1## wherein R is C.sub.3 or C.sub.4 alkenyl.
    Type: Grant
    Filed: December 13, 1977
    Date of Patent: October 10, 1978
    Assignee: International Flavors & Fragrances Inc.
    Inventors: Kenneth K. Light, James Milton Sanders, Manfred Hugo Vock, Edward J. Shuster, Joaquin Vinals, William L. Schreiber, John B. Hall, Denis E. Hruza, Sr., Venkatesh Kamath, Braja Dulal Mookherjee, Ching Y. Tseng, Mark A. Sprecker
  • Patent number: 4119576
    Abstract: Processes and compositions are described for the use in perfume and perfumed article aroma augmenting, enhancing and imparting compositions and as perfume and perfumed article aroma imparting materials of 1-butanoyl-3,3-dimethylcyclohexane having the formula: ##STR1## Addition of the 1-butanoyl-3,3-dimethylcyclohexane (also referred to herein as 1-(3,3-dimethylcyclohexyl)-butan-1-one) to perfumes, colognes and perfumed articles produces fruity, berry and herbaceous aromas with green and tobacco nuances.
    Type: Grant
    Filed: November 15, 1977
    Date of Patent: October 10, 1978
    Assignee: International Flavors & Fragrances Inc.
    Inventors: Mark A. Sprecker, Manfred Hugo Vock, Frederick Louis Schmitt, John B. Hall, James Milton Sanders
  • Patent number: 4119574
    Abstract: Processes and compositions are described for the use in perfume and perfumed article aroma augmenting, enhancing and imparting compositions and as perfume and perfumed article aroma imparting materials of hydroxy cyclohexenone derivatives having the generic formula: ##STR1## wherein one of X and Y is a keto moiety having the structure: ##STR2## and the other of X and Y is a carbinol moiety having the structure: ##STR3## wherein R is C.sub.1 -C.sub.5 alkyl. Addition of one or more hydroxy cyclohexenone derivatives having the formula: ##STR4## to consumable materials is indicated to produce: In perfumes, colognes and perfumed articles, green, minty, herbaceous, strong fruity aromas with earthy, mossy notes.
    Type: Grant
    Filed: November 15, 1977
    Date of Patent: October 10, 1978
    Assignee: International Flavors & Fragrances Inc.
    Inventors: Kenneth K. Light, Bette M. Spencer, Joaquin F. Vinals, Jacob Kiwala, Manfred Hugo Vock, Edward J. Shuster
  • Patent number: 4117015
    Abstract: Described is the compound 1-acetyl-3,3-dimethyl-(2-propenyl)cyclohexane, a process for preparing same by means of reacting an allylic halide with acetyl-3,3-dimethylcyclohexane using a phase transfer agent and in a two phase system according to the reaction: ##STR1## wherein X is chloro or bromo, processes for adding 1-acetyl-3,3-dimethyl-(2-propenyl)cyclohexane to comsumable materials whereby:(i) In foodstuffs and medicinal products, fruity, pineapple, allyl-caproate-like, galbanum and woody aroma characteristics are augmented or enhanced and rosey, ionone, oriental-like and woody flavor characteristics are augmented or enhanced; and(ii) In perfumes and perfumed articles, sweet, earthy, animal aromas with pineapple and ambery nuances and tobacco/animal notes are imparted, augmented and/or enhancedAnd flavor compositions and perfume compositions containing 1-acetyl-3,3-dimethyl-(2-propenyl)cyclohexane.
    Type: Grant
    Filed: February 4, 1977
    Date of Patent: September 26, 1978
    Assignee: International Flavors & Fragrances Inc.
    Inventors: John B. Hall, Mark A. Sprecker, Frederick Louis Schmitt, Manfred Hugo Vock
  • Patent number: 4115406
    Abstract: Described is the novel compound group, 2-alkyl-4-phenyl-dihydropyrans having the generic structure: ##STR1## where one of the dashed lines is a carbon-carbon double bond and the other of the dashed lines is a carbon-carbon single bond, R.sup.1 is one of C.sub.1 -C.sub.3 alkyl, and R is one of C.sub.2 -C.sub.4 alkyl, a process for producing same; a process comprising adding to tobacco an amount sufficient to augment the flavor or aroma of such tobacco of one or more of said pyran compounds; flavor formulations for use in conjunction with tobacco products containing one or more of such pyrans; a process comprising adding to foodstuffs, foodstuff flavorings, chewing gums, chewing gum flavorings, toothpaste and toothpaste flavorings one or more of said pyran compounds in a quantity sufficient to augment or enhance neroli-like and grape-like flavors, and flavoring compositions containing said pyran compounds.
    Type: Grant
    Filed: October 31, 1977
    Date of Patent: September 19, 1978
    Assignee: International Flavors & Fragrances Inc.
    Inventors: Joaquin Francisco Vinals, Jacob Kiwala, Denis E. Hruza, Sr., John B. Hall, Manfred Hugo Vock
  • Patent number: 4108876
    Abstract: Processes and compositions are described for use in foodstuff flavors and as foodstuff article aroma and taste augmenting and enhancing materials of at least one alpha-substituted alkylidene methionals having the structure: ##STR1## wherein R.sub.1 or R.sub.2 is one of the moieties: ##STR2## AND THE OTHER IS HYDROGEN OR METHYL. Addition of one or more alpha-substituted alkylidene methionals to foodstuff flavorings or to foostuffs is indicated to produce the following aroma and flavor characteristics, in the alternative taken together:AromaPotato; Methional-like; Green; Hydrolyzed vegetable protein-like; Chicken-like; Cabbage; Green potato; Green weedy; Broccoli-like; and Green bean-like.FlavorPotato; Metallic; Sulfury-green; Cabbage-like; Chicken; Mushroom-like; Green-weedy; Broccoli-like; and Green bean-like. The compounds of our invention are useful in augmenting or enhancing the flavor and aroma nuances of vegetable (including potato and cabbage) and chicken flavors.
    Type: Grant
    Filed: August 24, 1977
    Date of Patent: August 22, 1978
    Assignee: International Flavors & Fragrances Inc.
    Inventors: Donald Arthur Withycombe, Anne Hruza, Manfred Hugo Vock, Christopher Giacino, Braja Dulal Mookherjee, Alan Owen Pittet, William L. Schreiber
  • Patent number: 4107093
    Abstract: Compositions are described for the use in perfume and cologne of the compound ##STR1## or of mixtures of the compounds ##STR2## to produce fruity, woody, piney aromas with armoise and floral nuances and slight chocolate undertones.
    Type: Grant
    Filed: July 28, 1977
    Date of Patent: August 15, 1978
    Assignee: International Flavors & Fragrances Inc.
    Inventors: Mark A. Sprecker, Manfred Hugo Vock, Frederick Louis Schmitt, John B. Hall, James Milton Sanders
  • Patent number: 4107184
    Abstract: Novel 3-furyl alkyl disulfides having the formula: ##STR1## wherein R.sub.1 is C.sub.1 -C.sub.7 lower alkyl or C.sub.5 -C.sub.6 cycloalkyl; R.sub.2 and R.sub.3 are each selected from the group consisting of hydrogen and methyl, at least one of R.sub.2 and R.sub.3 being methyl provided that when R.sub.1 is methyl, each of R.sub.2 and R.sub.3 is methyl, such 3-furyl alkyl disulfides being useful in altering, modifying or enhancing the organoleptic properties of foodstuffs.
    Type: Grant
    Filed: October 7, 1975
    Date of Patent: August 15, 1978
    Assignee: International Flavors & Fragrances Inc.
    Inventors: William J. Evers, Howard H. Heinsohn, Jr., Manfred Hugo Vock
  • Patent number: 4107094
    Abstract: Processes and compositions are described for the use in foodstuff, chewing gum, toothpaste and medicinal product flavor and aroma and perfume aroma augmenting, enhancing, modifying and imparting compositions and as foodstuff, chewing gum, toothpaste, medicinal product, perfume and perfumed article aroma imparting materials of 3,3-dimethyl-2(3-butenyl) norbornanol-2 (hereinafter referred to as the "norbornanol derivative" having the structure: ##STR1## (which structure is intended to cover both the "endo" and the "exo" isomers thereof) produced by a process which comprises reacting an allylic Grignard reagent having the structure: ##STR2## wherein X is chloro, bromo or iodo with camphene oxide having the structure: ##STR3## by either "exo" camphene oxide or "endo" camphene oxide or a mixture of "exo" and "endo" camphene oxide.
    Type: Grant
    Filed: September 19, 1977
    Date of Patent: August 15, 1978
    Assignee: International Flavors & Fragrances Inc.
    Inventors: Kenneth K. Light, Manfred Hugo Vock, Edward J. Shuster, Frederick Louis Schmitt
  • Patent number: 4107209
    Abstract: The compounds 1-[3-(methylthio)butyryl]-2,6,6-trimethyl-cyclohexene and/or the corresponding 1,3-cyclohexadiene analog having the generic structure: ##STR1## wherein the dashed line could be a single or a double carbon-carbon bond and processes and compositions containing same are described for the use in foodstuff, chewing gum, toothpaste and medicinal product flavor and aroma, tobacco flavor and aroma and perfume and perfumed article aroma augmenting and enhancing compositions and for use in foodstuffs, tobacco, perfume and perfumed article aroma imparting compositions; produced by a process illustrated by the reaction: ##STR2## The above-mentioned compounds produce: (A) In food flavorings, sweet, black tea-like, cocoa-like, damascenone-like, chocolate-like, dried fruit-like, rose petal-like aroma characteristics and sweet, black-tea-like, cocoa-like, damascenone-like, chocolate-like, tobacco-like, dried fruit-like and rose petal-like flavor characteristics;(b) In tobacco, a sweet honey-like, rich, slightly
    Type: Grant
    Filed: March 3, 1977
    Date of Patent: August 15, 1978
    Assignee: International Flavors & Fragrances Inc.
    Inventors: Richard A. Wilson, Braja Dulal Mookherjee, Anne Sanderson Hruza, Manfred Hugo Vock, Louis Schmitt Frederick, Joaquin Francisco Vinals
  • Patent number: 4102928
    Abstract: Described is a process for preparing a genus of substituted 1-acetyl-3,3-dimethylcyclohexanes having the structure: ##STR1## wherein R.sub.1 or one or both of R.sub.2 and/or R.sub.3 is allyl or methallyl and the other of R.sub.1 or R.sub.2 and/or R.sub.3 is hydrogen, a process for preparing same by means of reacting an allyl or a methallyl halide with acetyl-3,3-dimethyl-cyclohexane using a base according to the reaction: ##STR2## wherein R is allyl or methallyl and wherein X is chloro or bromo.
    Type: Grant
    Filed: December 22, 1976
    Date of Patent: July 25, 1978
    Assignee: International Flavors & Fragrances Inc.
    Inventors: John B. Hall, Mark A. Sprecker, Frederick Louis Schmitt, Manfred Hugo Vock
  • Patent number: 4102763
    Abstract: Processes and compositions are described for the use in foodstuff, chewing gum, toothpaste and medicinal product flavor and aroma and perfume aroma augmenting, enhancing, modifying and imparting compositions and as foodstuff, chewing gum, toothpaste, medicinal product, perfume and perfumed article aroma imparting materials of 1-(3,3-dimethyl-2-norbornyl)-2-propanone (hereinafter referred to as the "norbornylpropanone derivative") having the structure: ##STR1## (which structure is intended to cover both the "endo" and the "exo" isomers thereof).
    Type: Grant
    Filed: July 28, 1977
    Date of Patent: July 25, 1978
    Assignee: International Flavors & Fragrances Inc.
    Inventors: William L. Schreiber, James N. Siano, Manfred Hugo Vock, Edward J. Shuster
  • Patent number: 4103036
    Abstract: Processes and compositions are described for the use in foodstuff, chewing gum, toothpaste and medicinal product flavor and aroma, tobacco flavor and aroma, perfume and perfumed article aroma augmenting, enhancing and imparting compositions and as foodstuff, chewing gum, toothpaste, medicinal product, tobacco, perfume and perfumed article aroma imparting materials of one or more derivatives of 1-acetyl-3,3-dimethylcyclohexane having the generic formula: ##STR1## wherein one of the dashed lines may be a carbon-carbon single bond or a carbon-carbon double bond and the other of the dashed lines is a carbon-carbon single bond and R is hydrogen or methyl.
    Type: Grant
    Filed: July 28, 1977
    Date of Patent: July 25, 1978
    Assignee: International Flavors & Fragrances Inc.
    Inventors: Mark A. Sprecker, Manfred Hugo Vock, Frederick Louis Schmitt, John B. Hall, James Milton Sanders
  • Patent number: 4098910
    Abstract: Novel 3-furyl alkyl disulfides having the formula: ##STR1## wherein R.sub.1 is C.sub.1 -C.sub.7 lower alkyl or C.sub.5 -C.sub.6 cycloalkyl; R.sub.2 and R.sub.3 are each selected from the group consisting of hydrogen and methyl, at least one of R.sub.2 or R.sub.3 being methyl provided that when R.sub.1 is methy, each of R.sub.2 and R.sub.3 is methyl, such 3-furyl alkyl disulfides being useful in altering the organoleptic properties of foodstuffs.
    Type: Grant
    Filed: February 19, 1975
    Date of Patent: July 4, 1978
    Assignee: International Flavors & Fragrances Inc.
    Inventors: William J. Evers, Howard H. Heinsohn, Jr., Manfred Hugo Vock
  • Patent number: 4097416
    Abstract: Described are the compounds 1-(2-propenyl)-3-(4-methyl-3-pentenyl)-.DELTA..sup.3 -cyclohexene-1-carboxaldehyde and 1-(2-propenyl)-4-(4-methyl-3-pentenyl)-.DELTA..sup.3 -cyclohexene-1-carboxaldehyde; and a process for preparing same by means of reacting an -cyclohexene-1-carboxaldehyde using a phase transfer agent in a two phase system according to the reaction: ##STR1## wherein the carboxaldehyde moiety is bonded to the alpha-carbon atom or the beta-carbon atom, X is chloro or bromo and M is alkali metal, processes for adding such 1-(2-propenyl)-(4-methyl-3-pentenyl)-.DELTA..sup.3 -cyclohexene-1-carboxaldehydes to consumable materials whereby:In perfumes sweet, fruity, lavender notes with citrus, floral and balsam nuances are imparted, augmented and/or enhanced.
    Type: Grant
    Filed: August 24, 1977
    Date of Patent: June 27, 1978
    Assignee: International Flavors & Fragrances Inc.
    Inventors: John B. Hall, Mark A. Sprecker, Manfred Hugo Vock, Edward J. Shuster, Joaquin Vinals, Robert M. Novak
  • Patent number: 4097615
    Abstract: Processes and compositions are described for the use in foodstuff flavors and as foodstuff aroma and taste augmenting and enhancing materials of 3-propylthio-4-heptanol having the structure: ##STR1##
    Type: Grant
    Filed: February 4, 1977
    Date of Patent: June 27, 1978
    Assignee: International Flavors & Fragrances Inc.
    Inventors: William J. Evers, Howard H. Heinsohn, Jr., Manfred Hugo Vock
  • Patent number: 4094823
    Abstract: Described are methods for preparing foodstuffs, flavoring compositions for foodstuffs, tobacco compositions, flavoring compositions for tobacco, perfume compositions, ingredients for perfume compositions, perfumed articles and ingredients for perfumed articles by including therein one or more C.sub.1 -C.sub.6 alkyl-2-methyl-3,4-pentadienoates in order to produce:(a) In food flavorings, sweet, fruity, winey, strawberry, tagette oil-like, pear and/or apple-like aromas and sweet, fruity, winey, creamy, strawberry, tagette oil-like, pear and/or apple tastes;(b) In perfumes, berry, chamomile, wormwood, apple and/or pineapple notes; and(c) In tobaccos, sweet, woody and/or fruity notes;As well as the novel compounds, isobutyl-2-methyl-3,4-pentadienoate and n-hexyl-2-methyl-3,4-pentadienoate.
    Type: Grant
    Filed: May 5, 1976
    Date of Patent: June 13, 1978
    Assignee: International Flavors & Fragrances Inc.
    Inventors: John B. Hall, Denis E. Hruza, Manfred Hugo Vock, Joaquin Vinals, Edward J. Shuster