Patents by Inventor Manfred Kreczinski

Manfred Kreczinski has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 10882768
    Abstract: Contaminated wastewater from the preparation of isophorone, isophoronenitrile and isophoronediamine is treated by A) 1. treating the wastewater from the preparation of isophoronenitrile from the reaction of isophorone with hydrogen cyanide by alkaline hydrolysis of isophoronenitrile to isophorone, and the salts of hydrogen cyanide within a pH range of 12.0 to 13.7 and at temperatures of 60 to 200° C. and 2. processing the wastewater from A) 1. by an oxidation, or B) treating the wastewater from the preparation of isophoronenitrile from the reaction of isophorone with hydrogen cyanide by an oxidation, or C) processing the wastewater from A) 1. and the wastewater from the preparation of isophorone and/or the wastewater from the preparation of isophoronediamine by an oxidation.
    Type: Grant
    Filed: September 6, 2018
    Date of Patent: January 5, 2021
    Assignee: Evonik Operations GmbH
    Inventors: Manfred Kreczinski, Robert Jansen, Matthias Woyciechowski
  • Patent number: 10669293
    Abstract: The present invention relates to a process for preparing isocyanate containing alkoxysilane groups, in which, in the sequence of steps A) to D), A) alkoxysilanoalkylamine is reacted with urea in the presence of an alcohol, optionally in the presence of at least one catalyst, to give alkoxysilanoalkylurethane, B) simultaneously or successively, if used, the catalyst is removed and/or deactivated, and low boilers, medium boilers and/or high boilers are removed, C) purified alkoxysilanoalkylurethane is thermally cleaved to release isocyanate containing alkoxysilane groups and by-product, leaving bottoms material, and D) isocyanate containing alkoxysilane groups and by-product are separated from one another and from bottoms material and collected, in which, in step C), i) the bottoms material is wholly or partly discharged from the cleavage apparatus, ii) subjected to thermal treatment and/or purification and/or an aftertreatment in the presence of alcohol and iii) the material removed, after thermal treatment
    Type: Grant
    Filed: March 18, 2019
    Date of Patent: June 2, 2020
    Assignee: Evonik Operations GmbH
    Inventors: Manfred Kreczinski, Stephan Kohlstruk, Dirk Hoppe, Emmanouil Spyrou
  • Patent number: 10633401
    Abstract: The invention relates to a process for preparing isocyanate containing alkoxysilane groups, in which, in the sequence of steps A) to D), A) alkoxysilano(cyclo)alkylamine is reacted with dialkyl carbonate in the presence of a basic catalyst to give alkoxysilano(cyclo)alkylurethane, B) simultaneously or successively, the catalyst is deactivated, and low boilers, solids, salt burdens and/or high boilers are removed, C) alkoxysilano(cyclo)alkylurethane obtained after B) is thermally cleaved to release isocyanate containing alkoxysilane groups and by-product, leaving bottoms material, and D) isocyanate containing alkoxysilane groups and by-product are separated from one another and from bottoms material and collected, wherein the process regime at least of steps C) to D) is continuous.
    Type: Grant
    Filed: March 15, 2019
    Date of Patent: April 28, 2020
    Assignee: Evonik Operations GmbH
    Inventors: Manfred Kreczinski, Stephan Kohlstruk, Emmanouil Spyrou, Dirk Hoppe
  • Patent number: 10626131
    Abstract: The invention relates to a process for preparing isocyanate containing alkoxysilane groups, in which, in the sequence of steps A) to D), A) alkoxysilano(cyclo)alkylamine is reacted with dialkyl carbonate in the presence of a basic catalyst to give alkoxysilano(cyclo)alkylurethane, B) simultaneously or successively, the catalyst is removed and/or deactivated, and low boilers, solids, salt burdens and/or high boilers are removed, C) alkoxysilano(cyclo)alkylurethane obtained after B) is thermally cleaved to release isocyanate containing alkoxysilane groups and by-product, leaving bottoms material, and D) isocyanate containing alkoxysilane groups and by-product are separated from one another and from bottoms material and collected, wherein the basic catalyst is a guanidine base.
    Type: Grant
    Filed: March 15, 2019
    Date of Patent: April 21, 2020
    Assignee: Evonik Operations GmbH
    Inventors: Manfred Kreczinski, Stephan Kohlstruk, Emmanouil Spyrou, Dirk Hoppe
  • Patent number: 10611782
    Abstract: The invention relates to a process for preparing isocyanate containing alkoxysilane groups, in which, in the sequence of steps A) to D), A) haloalkylalkoxysilane is reacted with metal cyanate and alcohol to give alkoxysilanoalkylurethane, B) alkoxysilanoalkylurethane is freed of low boilers, solids, salt burdens and/or high boilers and optionally purified, C) alkoxysilanoalkylurethane obtained after B) is thermally cleaved to release isocyanate containing alkoxysilane groups and by-product, leaving bottoms material, and D) isocyanate containing alkoxysilane groups and by-product are separated from one another and from cleavage bottoms material and collected, wherein the process regime at least of steps C) to D) is continuous.
    Type: Grant
    Filed: March 18, 2019
    Date of Patent: April 7, 2020
    Assignee: Evonik Operations GmbH
    Inventors: Manfred Kreczinski, Stephan Kohlstruk, Emmanouil Spyrou, Dirk Hoppe
  • Patent number: 10538684
    Abstract: A coating composition that includes an allophanate-containing compound can offer improved scratch resistance. The coating composition includes A) at least one allophanate-containing compound having the formula (1): wherein R, R1-R6 are each independently identical or different hydrocarbyl radicals having 1-8 carbon atoms, which may be branched or cyclic, or else may be integrated together to form a cyclic system, and m and n are each independently 0-2, B) a binder, C) optionally, an aliphatic or cycloaliphatic polyisocyanate having an NCO functionality of at least 2, D) optionally, a catalyst, E) optionally, an auxiliary and/or additive, and, F) optionally, a solvent.
    Type: Grant
    Filed: October 7, 2016
    Date of Patent: January 21, 2020
    Assignee: Evonik Operations GmbH
    Inventors: Emmanouil Spyrou, Tobias Unkelhaeusser, Sabine Naumann, Manfred Kreczinski, Holger Loesch, Alina Meier, Uwe Korek
  • Publication number: 20190300549
    Abstract: The invention relates to a process for preparing isocyanate containing alkoxysilane groups, in which, in the sequence of steps A) to D), A) alkoxysilano(cyclo)alkylamine is reacted with dialkyl carbonate in the presence of a basic catalyst to give alkoxysilano(cyclo)alkylurethane, B) simultaneously or successively, the catalyst is removed and/or deactivated, and low boilers, solids, salt burdens and/or high boilers are removed, C) alkoxysilano(cyclo)alkylurethane obtained after B) is thermally cleaved to release isocyanate containing alkoxysilane groups and by-product, leaving bottoms material, and D) isocyanate containing alkoxysilane groups and by-product are separated from one another and from bottoms material and collected, wherein the basic catalyst is a guanidine base.
    Type: Application
    Filed: March 15, 2019
    Publication date: October 3, 2019
    Applicant: Evonik Degussa GmbH
    Inventors: Manfred Kreczinski, Stephan Kohlstruk, Emmanouil Spyrou, Dirk Hoppe
  • Publication number: 20190300551
    Abstract: The invention relates to a process for preparing isocyanate containing alkoxysilane groups, in which, in the sequence of steps A) to D), A) haloalkylalkoxysilane is reacted with metal cyanate and alcohol to give alkoxysilanoalkylurethane, B) alkoxysilanoalkylurethane is freed of low boilers, solids, salt burdens and/or high boilers and optionally purified, C) alkoxysilanoalkylurethane obtained after B) is thermally cleaved to release isocyanate containing alkoxysilane groups and by-product, leaving bottoms material, and D) isocyanate containing alkoxysilane groups and by-product are separated from one another and from cleavage bottoms material and collected, wherein the process regime at least of steps C) to D) is continuous.
    Type: Application
    Filed: March 18, 2019
    Publication date: October 3, 2019
    Applicant: Evonik Degussa GmbH
    Inventors: Manfred Kreczinski, Stephan Kohlstruk, Emmanouil Spyrou, Dirk Hoppe
  • Publication number: 20190300553
    Abstract: The present invention relates to a process for preparing isocyanate containing alkoxysilane groups, in which, in the sequence of steps A) to D), A) alkoxysilanoalkylamine is reacted with urea in the presence of an alcohol, optionally in the presence of at least one catalyst, to give alkoxysilanoalkylurethane, B) simultaneously or successively, if used, the catalyst is removed and/or deactivated, and low boilers, medium boilers and/or high boilers are removed, C) purified alkoxysilanoalkylurethane is thermally cleaved to release isocyanate containing alkoxysilane groups and by-product, leaving bottoms material, and D) isocyanate containing alkoxysilane groups and by-product are separated from one another and from bottoms material and collected, in which, in step C), i) the bottoms material is wholly or partly discharged from the cleavage apparatus, ii) subjected to thermal treatment and/or purification and/or an aftertreatment in the presence of alcohol and iii) the material removed, after thermal treatment
    Type: Application
    Filed: March 18, 2019
    Publication date: October 3, 2019
    Applicant: Evonik Degussa GmbH
    Inventors: Manfred Kreczinski, Stephan Kohlstruk, Dirk Hoppe, Emmanouil Spyrou
  • Publication number: 20190300550
    Abstract: The invention relates to a process for preparing isocyanate containing alkoxysilane groups, in which, in the sequence of steps A) to D), A) alkoxysilano(cyclo)alkylamine is reacted with dialkyl carbonate in the presence of a basic catalyst to give alkoxysilano(cyclo)alkylurethane, B) simultaneously or successively, the catalyst is deactivated, and low boilers, solids, salt burdens and/or high boilers are removed, C) alkoxysilano(cyclo)alkylurethane obtained after B) is thermally cleaved to release isocyanate containing alkoxysilane groups and by-product, leaving bottoms material, and D) isocyanate containing alkoxysilane groups and by-product are separated from one another and from bottoms material and collected, pa wherein the process regime at least of steps C) to D) is continuous.
    Type: Application
    Filed: March 15, 2019
    Publication date: October 3, 2019
    Applicant: Evonik Degussa GmbH
    Inventors: Manfred Kreczinski, Stephan Kohlstruk, Emmanouil Spyrou, Dirk Hoppe
  • Patent number: 10351579
    Abstract: A monoallophanate can be used in paint or adhesive compositions. The monoallophanate has the formula 1: where R, R1-R6 are each independently identical or different hydrocarbyl radicals having 1-8 carbon atoms, which may be branched or cyclic, or else may be integrated together to form a cyclic system, and m and n are each independently 0-2.
    Type: Grant
    Filed: October 11, 2016
    Date of Patent: July 16, 2019
    Assignee: Evonik Degussa GmbH
    Inventors: Emmanouil Spyrou, Manfred Kreczinski, Tobias Unkelhaeusser, Sabine Naumann, Holger Loesch, Marion Ewald, Thomas Weihrauch
  • Publication number: 20190002316
    Abstract: Contaminated wastewater from the preparation of isophorone, isophoronenitrile and isophoronediamine is treated by A) 1. treating the wastewater from the preparation of isophoronenitrile from the reaction of isophorone with hydrogen cyanide by alkaline hydrolysis of isophoronenitrile to isophorone, and the salts of hydrogen cyanide within a pH range of 12.0 to 13.7 and at temperatures of 60 to 200° C. and 2. processing the wastewater from A) 1. by an oxidation, or B) treating the wastewater from the preparation of isophoronenitrile from the reaction of isophorone with hydrogen cyanide by an oxidation, or C) processing the wastewater from A) 1. and the wastewater from the preparation of isophorone and/or the wastewater from the preparation of isophoronediamine by an oxidation.
    Type: Application
    Filed: September 6, 2018
    Publication date: January 3, 2019
    Applicant: Evonik Degussa GmbH
    Inventors: Manfred Kreczinski, Robert Jansen, Matthias Woyciechowski
  • Patent number: 10144662
    Abstract: Contaminated wastewater from the preparation of isophorone, isophoronenitrile and isophoronediamine is treated by A) 1. treating the wastewater from the preparation of isophoronenitrile from the reaction of isophorone with hydrogen cyanide by alkaline hydrolysis of isophoronenitrile to isophorone, and the salts of hydrogen cyanide within a pH range of 12.0 to 13.7 and at temperatures of 60 to 200° C., and 2. processing the wastewater from A) 1. by an oxidation, or B) treating the wastewater from the preparation of isophoronenitrile from the reaction of isophorone with hydrogen cyanide by an oxidation, or C) processing the wastewater from A) 1. and the wastewater from the preparation of isophorone and/or the wastewater from the preparation of isophoronediamine by an oxidation.
    Type: Grant
    Filed: November 24, 2015
    Date of Patent: December 4, 2018
    Assignee: Evonik Degussa GmbH
    Inventors: Manfred Kreczinski, Robert Jansen, Matthias Woyciechowski
  • Publication number: 20180327432
    Abstract: A monoallophanate can be used in paint or adhesive compositions. The monoallophanate has the formula 1: where R, R1-R6 are each independently identical or different hydrocarbyl radicals having 1-8 carbon atoms, which may be branched or cyclic, or else may be integrated together to form a cyclic system, and m and n are each independently 0-2.
    Type: Application
    Filed: October 11, 2016
    Publication date: November 15, 2018
    Applicant: EVONIK DEGUSSA GMBH
    Inventors: Emmanouil Spyrou, Manfred Kreczinski, Tobias Unkelhaeusser, Sabine Naumann, Holger Loesch, Marion Ewald, Thomas Weihrauch
  • Publication number: 20180312713
    Abstract: A coating composition that includes an allophanate-containing compound can offer improved scratch resistance. The coating composition includes A) at least one allophanate-containing compound having the formula (1): wherein R, R1-R6 are each independently identical or different hydrocarbyl radicals having 1-8 carbon atoms, which may be branched or cyclic, or else may be integrated together to form a cyclic system, and m and n are each independently 0-2, B) a binder, C) optionally, an aliphatic or cycloaliphatic polyisocyanate having an NCO functionality of at least 2, D) optionally, a catalyst, E) optionally, an auxiliary and/or additive, and, F) optionally, a solvent.
    Type: Application
    Filed: October 7, 2016
    Publication date: November 1, 2018
    Applicant: Evonik Degussa GmbH
    Inventors: Emmanouil Spyrou, Tobias Unkelhaeusser, Sabine Naumann, Manfred Kreczinski, Holger Loesch, Alina Meier, Uwe Korek
  • Patent number: 9994472
    Abstract: Treatment of the wastewater from isophorone production comprising neutralization, filtration and a downstream chemical oxidation process and subsequent reduction. The invention relates to treatment of the wastewater from isophorone (IP) production comprising neutralization, filtration and a downstream chemical oxidation process and subsequent reduction.
    Type: Grant
    Filed: October 18, 2016
    Date of Patent: June 12, 2018
    Assignee: Evonik Degussa GmbH
    Inventors: Yue Chang, Manfred Kreczinski, Martin Maier, Matthias Woyciechowski
  • Publication number: 20170166464
    Abstract: The invention relates to the treatment of the wastewater from isophorone production (IP) by high-pressure wet oxidation.
    Type: Application
    Filed: December 9, 2016
    Publication date: June 15, 2017
    Applicant: Evonik Degussa GmbH
    Inventors: Yue CHANG, Manfred KRECZINSKI, Martin MAIER, Matthias WOYCIECHOWSKI
  • Publication number: 20170107133
    Abstract: Treatment of the wastewater from isophorone production comprising neutralization, filtration and a downstream chemical oxidation process and subsequent reduction. The invention relates to treatment of the wastewater from isophorone (IP) production comprising neutralization, filtration and a downstream chemical oxidation process and subsequent reduction.
    Type: Application
    Filed: October 18, 2016
    Publication date: April 20, 2017
    Applicant: Evonik Degussa GmbH
    Inventors: Yue CHANG, Manfred KRECZINSKI, Martin MAIER, Matthias WOYCIECHOWSKI
  • Patent number: 9593135
    Abstract: The present invention relates to a composition comprising (A) an isocyanate of formula (I) OCN-A-SiR1R2R3 (I), wherein A is straight-chain, branched, substituted and/or unsubstituted aliphatic hydrocarbyl of 1 to 12 carbon atoms or substituted or unsubstituted cycloaliphatic hydrocarbyl of 4 to 18 carbon atoms, wherein R1 is selected from the group comprising —O—Ralk, wherein R2 and R3 are each independently selected from the group of substituents comprising —Ralk and —O—Ralk, and wherein —Ralk is hydrocarbyl of 1 to 6 carbon atoms, and B) a Bronstedt or Lewis acid or a compound which releases a Bronstedt or Lewis acid at room temperature; and also to a process for producing a stabilized alkoxysilane-containing isocyanate comprising the step of adding a Lewis or Bronstedt acid or a compound which releases a Bronstedt or Lewis acid at room temperature to an alkoxysilane-containing isocyanate.
    Type: Grant
    Filed: September 25, 2013
    Date of Patent: March 14, 2017
    Assignee: EVONIK DEGUSSA GmbH
    Inventors: Emmanouil Spyrou, Manfred Kreczinski, Holger Loesch, Andrea Thesing, Lars Hellkuhl
  • Publication number: 20160152496
    Abstract: Contaminated wastewater from the preparation of isophorone, isophoronenitrile and isophoronediamine is treated by A) 1. treating the wastewater from the preparation of isophoronenitrile from the reaction of isophorone with hydrogen cyanide by alkaline hydrolysis of isophoronenitrile to isophorone, and the salts of hydrogen cyanide within a pH range of 12.0 to 13.7 and at temperatures of 60 to 200° C., and 2. processing the wastewater from A) 1. by an oxidation, or B) treating the wastewater from the preparation of isophoronenitrile from the reaction of isophorone with hydrogen cyanide by an oxidation, or C) processing the wastewater from A) 1. and the wastewater from the preparation of isophorone and/or the wastewater from the preparation of isophoronediamine by an oxidation.
    Type: Application
    Filed: November 24, 2015
    Publication date: June 2, 2016
    Applicant: Evonik Degussa GmbH
    Inventors: Manfred KRECZINSKI, Robert JANSEN, Matthias WOYCIECHOWSKI