Patents by Inventor Mansour Ali Al-Herz

Mansour Ali Al-Herz has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11939539
    Abstract: Embodiments of the present disclosure are directed to a method of processing a hydrocarbon feed includes fractionating the hydrocarbon feed into a light stream and a heavy stream, hydrotreating the heavy stream to form a hydrotreated heavy stream, combining the light stream and the hydrotreated heavy stream to form a upgraded feed stream, and feeding the upgraded feed stream to a single Fluid Catalytic Cracking (FCC) reaction zone, thereby producing a product stream comprising light olefins. The light stream may comprise hydrocarbons boiling at less than 343° C. and the heavy stream may comprise hydrocarbons boiling at greater than 343° C. The FCC reaction zone may be operated in a down-flow configuration and the FCC may be operated under high severity conditions.
    Type: Grant
    Filed: June 9, 2023
    Date of Patent: March 26, 2024
    Assignee: Saudi Arabian Oil Company
    Inventors: Mansour Ali Al-Herz, Ali Al Jawad, Qi Xu, Aaron Akah, Musaed Salem Al-Ghrami
  • Patent number: 11905475
    Abstract: A method of processing a hydrocarbon feed may comprise fractionating the hydrocarbon feed into a light stream, a middle stream and a heavy stream; hydrotreating the heavy stream to form a hydrotreated heavy stream; feeding the light stream to a first Fluid Catalytic Cracking (FCC) reaction zone; feeding the middle stream to a second FCC reaction zone; and feeding the hydrotreated heavy stream to a third Fluid Catalytic Cracking (FCC) reaction zone. The light stream may comprise hydrocarbons boiling at less than 200° C. The middle stream may comprise hydrocarbons boiling at from 200° C. to 370° C. The heavy stream may comprise hydrocarbons boiling at greater than greater than 370° C. Each of the first and second FCC reaction zones may operate under more severe operating conditions than the third FCC reaction zone.
    Type: Grant
    Filed: February 2, 2023
    Date of Patent: February 20, 2024
    Assignee: Saudi Arabian Oil Company
    Inventors: Mansour Ali Al-Herz, Ali Al Jawad, Qi Xu, Aaron Akah, Musaed Salem Al-Ghrami
  • Patent number: 11898110
    Abstract: A method of processing a hydrocarbon feed may comprise fractionating the hydrocarbon feed into a light stream, a middle stream, and a heavy stream; hydrotreating the heavy stream to form a hydrotreated heavy stream; and feeding the light stream, middle stream, and the hydrotreated heavy stream to a single Fluid Catalytic Cracking (FCC) reaction zone, thereby producing a product stream comprising light olefins. The light stream may be exposed to more severe FCC cracking conditions than the middle stream and the middle stream may be exposed to more severe FCC cracking conditions than the hydrotreated heavy stream, within the same FCC reaction zone. The single FCC reaction zone may be operated in a down-flow configuration and under high severity conditions.
    Type: Grant
    Filed: February 2, 2023
    Date of Patent: February 13, 2024
    Assignee: Saudi Arabian Oil Company
    Inventors: Mansour Ali Al-Herz, Ali Al Jawad, Qi Xu, Aaron Akah, Musaed Salem Al-Ghrami
  • Publication number: 20240010926
    Abstract: A process for converting crude oil to light olefins, aromatics, or both, includes contacting a crude oil with an FCC catalyst composition in a catalytic cracking system at a temperature of greater than or equal to 580° C., a weight ratio of the FCC catalyst to the crude oil of from 2:1 to 10:1, and a residence time of from 0.1 seconds to 60 seconds. Contacting causes at least a portion of hydrocarbons in the crude oil to undergo cracking reactions to produce a cracked effluent comprising at least olefins. The FCC catalyst composition for producing olefins and aromatics from crude oil includes ultrastable Y-type zeolite impregnated with lanthanum, ZSM-5 zeolite impregnated with phosphorous, an alumina binder, colloidal silica, and a matrix material comprising Kaolin clay.
    Type: Application
    Filed: July 6, 2022
    Publication date: January 11, 2024
    Applicant: Saudi Arabian Oil Company
    Inventors: Mansour Ali Al-Herz, Musaed Salem Al-Ghrami, Qi Xu, Aaron Akah
  • Patent number: 11866662
    Abstract: According to one embodiment of the present disclosure, a method of processing a hydrocarbon feed may comprise fractionating the hydrocarbon feed into a light stream, a middle stream, and a residue stream, hydrotreating the residue stream to form a hydrotreated residue stream; and feeding the light stream, middle stream, and the hydrotreated residue stream to a single Fluid Catalytic Cracking (FCC) reaction zone, thereby producing a product stream comprising light olefins. The light stream and the hydrotreated residue streams may be exposed to more severe FCC cracking conditions than the middle stream, within the same FCC reaction zone. The single FCC reaction zone may be operated in a down-flow configuration and the single FCC reaction zone may be operated under high severity conditions.
    Type: Grant
    Filed: February 2, 2023
    Date of Patent: January 9, 2024
    Assignee: Saudi Arabian Oil Company
    Inventors: Mansour Ali Al-Herz, Ali Al Jawad, Qi Xu, Aaron Akah, Musaed Salem Al-Ghrami, Lianhui Ding
  • Patent number: 11866663
    Abstract: Embodiments of the present disclosure are directed to a method of processing a hydrocarbon feed includes fractionating the hydrocarbon feed into a light stream and a heavy stream, hydrotreating the heavy stream to form a hydrotreated heavy stream, combining the light stream and the hydrotreated heavy stream to form a upgraded feed stream, and feeding the upgraded feed stream to a single Fluid Catalytic Cracking (FCC) reaction zone, thereby producing a product stream comprising light olefins. The light stream may comprise hydrocarbons boiling at less than 540° C. and the heavy stream may comprise hydrocarbons boiling at greater than 540° C. The FCC reaction zone may be operated in a down-flow configuration and the FCC may be operated under high severity conditions.
    Type: Grant
    Filed: February 2, 2023
    Date of Patent: January 9, 2024
    Assignee: Saudi Arabian Oil Company
    Inventors: Mansour Ali Al-Herz, Ali Al Jawad, Qi Xu, Aaron Akah, Musaed Salem Al-Ghrami
  • Patent number: 11866651
    Abstract: A process for converting crude oil may comprise contacting a crude oil with one or more hydroprocessing catalysts to produce a hydroprocessed effluent and contacting the hydroprocessed effluent with a fluidized catalytic cracking (FCC) catalyst composition in an FCC system to produce cracked effluent comprising at least olefins. The crude oil may have an API gravity from 30 to 35. The FCC system may operate at a temperature of greater than or equal to 580° C., a weight ratio of the FCC catalyst composition to the crude oil of from 2:1 to 10:1, and a residence time of from 0.1 seconds to 60 seconds. The FCC catalyst composition may comprise ultrastable Y-type zeolite (USY zeolite) impregnated with lanthanum; ZSM-5 zeolite impregnated with phosphorous; an alumina binder; colloidal silica; and a matrix material comprising Kaolin clay.
    Type: Grant
    Filed: November 9, 2022
    Date of Patent: January 9, 2024
    Assignee: Saudi Arabian Oil Company
    Inventors: Mansour Ali Al Herz, Aaron Akah, Qi Xu, Lianhui Ding, Bander A. Al Ghamdi
  • Patent number: 11866659
    Abstract: A method of processing a hydrocarbon feed may comprise fractionating the hydrocarbon feed into a light stream and a heavy stream, where the light stream includes hydrocarbons boiling at less than 370° C., and the heavy stream includes hydrocarbons boiling at greater than greater than 370° C., hydrotreating the heavy stream to form a hydrotreated heavy stream, feeding the light stream to a first Fluid Catalytic Cracking (FCC) reaction zone, thereby producing a light product stream which includes light olefins, and feeding the hydrotreated heavy stream to a second Fluid Catalytic Cracking (FCC) reaction zone, thereby producing a heavy product stream which includes light olefins, where the first FCC reaction zone operates under more severe operating conditions than the second FCC reaction zone.
    Type: Grant
    Filed: February 2, 2023
    Date of Patent: January 9, 2024
    Assignee: Saudi Arabian Oil Company
    Inventors: Mansour Ali Al-Herz, Ali Al Jawad, Qi Xu, Aaron Akah, Musaed Salem Al-Ghrami
  • Patent number: 11866660
    Abstract: A process for converting crude oil may comprise contacting a crude oil with one or more hydroprocessing catalysts to produce a hydroprocessed effluent and contacting the hydroprocessed effluent with a fluidized catalytic cracking (FCC) catalyst composition in an FCC system to produce cracked effluent comprising at least olefins. The crude oil may have an API gravity from 25 to 29. The FCC system may operate at a temperature of greater than or equal to 580° C., a weight ratio of the FCC catalyst composition to the crude oil of from 2:1 to 10:1, and a residence time of from 0.1 seconds to 60 seconds. The FCC catalyst composition may comprise ultrastable Y-type zeolite (USY zeolite) impregnated with lanthanum; ZSM-5 zeolite impregnated with phosphorous; an alumina binder; colloidal silica; and a matrix material comprising Kaolin clay.
    Type: Grant
    Filed: November 9, 2022
    Date of Patent: January 9, 2024
    Assignee: Saudi Arabian Oil Company
    Inventors: Mansour Ali Al Herz, Aaron Akah, Qi Xu, Lianhui Ding, Bander A. Al Ghamdi
  • Patent number: 11866661
    Abstract: According to one embodiment of the present disclosure, a method of processing a hydrocarbon feed includes fractionating the hydrocarbon feed into a light stream and a heavy stream; hydrotreating the heavy stream to form a hydrotreated heavy stream; feeding the light stream and the hydrotreated heavy stream to a single Fluid Catalytic Cracking (FCC) reaction zone, thereby producing a product stream which includes light olefins. The light stream may be exposed to more severe FCC cracking conditions than the heavy stream, within the same FCC reaction zone. The single FCC reaction zone may be operated in a down-flow configuration and the FCC may be operated under high severity conditions. The light stream may include hydrocarbons boiling at less than 371° C. and the heavy stream may include hydrocarbons boiling at greater than 371° C.
    Type: Grant
    Filed: February 2, 2023
    Date of Patent: January 9, 2024
    Assignee: Saudi Arabian Oil Company
    Inventors: Mansour Ali Al-Herz, Ali Al Jawad, Qi Xu, Aaron Akah, Musaed Salem Al-Ghrami, Zhonglin Zhang, Luis A. Rojas Cordova
  • Patent number: 11827855
    Abstract: A process for converting crude oil to light olefins, aromatics, or both, includes contacting a crude oil with an FCC catalyst composition in a fluidized catalytic cracking system at a temperature of greater than or equal to 580° C., a weight ratio of the FCC catalyst to the crude oil of from 2:1 to 10:1, and a residence time of from 0.1 seconds to 60 seconds. Contacting causes at least a portion of hydrocarbons in the crude oil to undergo cracking reactions to produce a cracked effluent comprising at least olefins. The FCC catalyst composition for producing olefins and aromatics from crude oil includes ultrastable Y-type zeolite impregnated with lanthanum, ZSM-5 zeolite impregnated with phosphorous, where the nano-ZSM-5 zeolite has an average particle size of from 0.01 ?m to 0.2 ?m, an alumina binder, colloidal silica, and a matrix material comprising Kaolin clay.
    Type: Grant
    Filed: July 6, 2022
    Date of Patent: November 28, 2023
    Assignee: Saudi Arabian Oil Company
    Inventors: Mansour Ali Al-Herz, Musaed Salem Al-Ghrami, Qi Xu, Aaron Akah
  • Patent number: 11814593
    Abstract: According to at least one aspect of the present disclosure, a process for processing a crude oil with an API between 30 and 35 degrees includes contacting the crude oil with one or more hydroprocessing catalysts to produce a hydroprocessed effluent. The hydroprocessed effluent is passed to an HS-FCC unit, where the hydroprocessed effluent is contacted with a cracking catalyst composition comprising nano-ZSM-5 zeolite and an ultrastable Y-type zeolite (USY zeolite) to form a cracked effluent comprising at least one product. The HS-FCC catalyst composition further comprises nano-ZSM-5 zeolite that has an average particle size of from 0.01 micrometers (?m) to 0.2 ?m, USY zeolite impregnated with lanthanum, an alumina binder, colloidal silica, and a matrix material comprising Kaolin clay. The cracked effluent comprises at least olefins, aromatic compounds, or both.
    Type: Grant
    Filed: December 12, 2022
    Date of Patent: November 14, 2023
    Assignee: Saudi Arabian Oil Company
    Inventors: Mansour Ali Al Herz, Aaron Akah, Qi Xu, Lianhui Ding, Bander Al Ghamdi
  • Patent number: 11814594
    Abstract: According to at least one aspect of the present disclosure, a process for processing a crude oil with an API between 25 and 29 degrees includes contacting the crude oil with one or more hydroprocessing catalysts to produce a hydroprocessed effluent. The hydroprocessed effluent is passed to an HS-FCC unit, where the hydroprocessed effluent is contacted with a cracking catalyst composition comprising nano-ZSM-5 zeolite and an ultrastable Y-type zeolite (USY zeolite) to form a cracked effluent comprising at least one product. The HS-FCC catalyst composition further comprises nano-ZSM-5 zeolite that has an average particle size of from 0.01 micrometers (?m) to 0.2 ?m, USY zeolite impregnated with lanthanum, an alumina binder, colloidal silica, and a matrix material comprising Kaolin clay. The cracked effluent comprises at least olefins, aromatic compounds, or both.
    Type: Grant
    Filed: December 12, 2022
    Date of Patent: November 14, 2023
    Assignee: Saudi Arabian Oil Company
    Inventors: Mansour Ali Al Herz, Aaron Akah, Qi Xu, Lianhui Ding, Bander Al Ghamdi
  • Patent number: 11485917
    Abstract: According to at least one aspect of the present disclosure, a method for processing a heavy oil includes introducing the heavy oil to a hydroprocessing unit, the hydroprocessing unit being operable to hydroprocess the heavy oil to form a hydroprocessed effluent by contacting the heavy oil feed with an HDM catalyst, an HDS catalyst, and an HDA catalyst. The hydroprocessed effluent is passed directly to a HS-FCC unit, the HS-FCC unit being operable to crack the hydroprocessed effluent to form a cracked effluent comprising at least one product. The cracked effluent is passed out of the HS-FCC unit. The heavy oil has an API gravity of from 25 degrees to 50 degrees and at least 20 wt. % of the hydroprocessed effluent passed to the HS-FCC unit has a boiling point less than 225 degrees ° C.
    Type: Grant
    Filed: February 17, 2021
    Date of Patent: November 1, 2022
    Assignee: Saudi Arabian Oil Company
    Inventors: Mansour Ali Al-Herz, Musaed Salem Al-Ghrami
  • Patent number: 11230672
    Abstract: According to one more embodiments, petrochemical products may be produced from a hydrocarbon material by a process that may comprise separating the hydrocarbon material into at least a lesser boiling point fraction, a medium boiling point fraction, and a greater boiling point fraction. The process may further comprise cracking at least a portion of the lesser boiling point fraction and the medium boiling point fraction in a second reactor unit in the presence of a second catalyst at a reaction temperature of from 500° C. to 700° C. to produce a second cracking reaction product, wherein the lesser boiling point fraction enters the second reactor unit upstream of wherein the medium boiling point fraction enters the second reactor.
    Type: Grant
    Filed: September 1, 2020
    Date of Patent: January 25, 2022
    Assignee: Saudi Arabian Oil Company
    Inventors: Mansour Ali Al Herz, Abdennour Bourane, Ali Al Jawad, Alberto Lozano Ballesteros
  • Publication number: 20210171845
    Abstract: According to at least one aspect of the present disclosure, a method for processing a heavy oil includes introducing the heavy oil to a hydroprocessing unit, the hydroprocessing unit being operable to hydroprocess the heavy oil to form a hydroprocessed effluent by contacting the heavy oil feed with an HDM catalyst, an HDS catalyst, and an HDA catalyst. The hydroprocessed effluent is passed directly to a HS-FCC unit, the HS-FCC unit being operable to crack the hydroprocessed effluent to form a cracked effluent comprising at least one product. The cracked effluent is passed out of the HS-FCC unit. The heavy oil has an API gravity of from 25 degrees to 50 degrees and at least 20 wt. % of the hydroprocessed effluent passed to the HS-FCC unit has a boiling point less than 225 degrees ° C.
    Type: Application
    Filed: February 17, 2021
    Publication date: June 10, 2021
    Applicant: Saudi Arabian Oil Company
    Inventors: Mansour Ali Al-Herz, Musaed Salem Al-Ghrami
  • Patent number: 10954457
    Abstract: According to at least one aspect of the present disclosure, a method for processing a heavy oil includes introducing the heavy oil to a hydroprocessing unit, the hydroprocessing unit being operable to hydroprocess the heavy oil to form a hydroprocessed effluent by contacting the heavy oil feed with an HDM catalyst, an HDS catalyst, and an HDA catalyst. The hydroprocessed effluent is passed directly to a HS-FCC unit, the HS-FCC unit being operable to crack the hydroprocessed effluent to form a cracked effluent comprising at least one product. The cracked effluent is passed out of the HS-FCC unit. The heavy oil has an API gravity of from 25 degrees to 50 degrees and at least 20 wt. % of the hydroprocessed effluent passed to the HS-FCC unit has a boiling point less than 225 degrees ° C.
    Type: Grant
    Filed: February 13, 2019
    Date of Patent: March 23, 2021
    Assignee: Saudi Arabian Oil Company
    Inventors: Mansour Ali Al-Herz, Musaed Salem Al-Ghrami
  • Publication number: 20200255753
    Abstract: According to at least one aspect of the present disclosure, a method for processing a heavy oil includes introducing the heavy oil to a hydroprocessing unit, the hydroprocessing unit being operable to hydroprocess the heavy oil to form a hydroprocessed effluent by contacting the heavy oil feed with an HDM catalyst, an HDS catalyst, and an HDA catalyst. The hydroprocessed effluent is passed directly to a HS-FCC unit, the HS-FCC unit being operable to crack the hydroprocessed effluent to form a cracked effluent comprising at least one product. The cracked effluent is passed out of the HS-FCC unit. The heavy oil has an API gravity of from 25 degrees to 50 degrees and at least 20 wt. % of the hydroprocessed effluent passed to the HS-FCC unit has a boiling point less than 225 degrees ° C.
    Type: Application
    Filed: February 13, 2019
    Publication date: August 13, 2020
    Applicant: Saudi Arabian Oil Company
    Inventors: Mansour Ali Al-Herz, Musaed Salem Al-Ghrami
  • Patent number: 10427142
    Abstract: Provided here are zirconium-substituted hierarchical zeolite compositions and methods of preparing such catalytic compositions. One such method involves subjecting the zirconium-substituted zeolite to a framework modification process using a single template to produce a framework-modified zeolite, followed by subjecting the framework-modified zeolite to an ion exchange process to produce a hierarchical zeolite composition. Also provided are methods of catalytic cracking of hydrocarbon feedstocks using these zirconium-substituted hierarchical zeolite compositions.
    Type: Grant
    Filed: March 29, 2019
    Date of Patent: October 1, 2019
    Assignees: KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS, SAUDI ARABIAN OIL COMPANY
    Inventors: Mansour Ali Al-Herz, Musaed Salem Al-Ghrami, Mohammed Abdul Bari Siddiqui, Mian Rahat Saeed, Rabindran Jermy Balasamy
  • Patent number: 10350585
    Abstract: Provided here are zirconium-substituted hierarchical zeolite compositions and methods of preparing such catalytic compositions. One such method involves subjecting the zirconium-substituted zeolite to a framework modification process using a single template to produce a framework-modified zeolite, followed by subjecting the framework-modified zeolite to an ion exchange process to produce a hierarchical zeolite composition. Also provided are methods of catalytic cracking of hydrocarbon feedstocks using these zirconium-substituted hierarchical zeolite compositions.
    Type: Grant
    Filed: August 14, 2018
    Date of Patent: July 16, 2019
    Assignee: Saudi Arabian Oil Company
    Inventors: Mansour Ali Al-Herz, Musaed Salem Al-Ghrami, Mohammed Abdul Bari Siddiqui, Mian Rahat Saeed, Rabindran Jermy Balasamy