Abstract: A process is described for replacing at least a portion of the liquid within the annular volume of a casing system within a wellbore with a second liquid. The second liquid is preselected to provide a measure of control of the pressure within the annular volume as the fluid within the volume is being heated.

Abstract: A method and a system for minimizing circulating fluid return losses during drilling of a well bore are disclosed. Circulating fluid, or mud, is heated above conventional temperatures for circulating fluids. The heated circulating fluid then contacts a region of a formation, in which a well bore is to be drilled, maintaining the formation at a relative higher temperature than if no special sources of heat were used to add heat to the circulating fluid. The region, at the relatively higher temperature, has a tendency to expand and to be placed in a relatively higher compressive state as compared to a formation at a lower temperature. Consequently, the use of the heated circulating fluid minimizes fracture initiation and growth and circulation fluid losses into the formation.

Abstract: The present invention provides a method for enhancing the production of hydrocarbons from a subterranean formation. A hydrocarbon bearing formation, surrounding a well bore, is fractured with a fracturing fluid to create one or more fractures in the formation. The formation includes a higher permeability zone and a lower permeability zone with the fractures extending across both the higher and lower permeability zones. The lower permeability zone may contain a substantially higher concentration of hydrocarbons, oil and gas, than does the higher permeability zone which may generally be depleted of hydrocarbons. Proppant is then selectively positioned, such as by allowing the proppant to “float” in a carrier fluid to the top of the fracture, with a majority of the proppant being positioned in the lower permeability zone. The fracture is allowed to close about the proppant to create at least one high conductivity channel in the lower permeability zone.

Abstract: A method and a system for minimizing circulating fluid return losses during drilling of a well bore are disclosed. Circulating fluid, or mud, is heated above conventional temperatures for circulating fluids. The heated circulating fluid then contacts a region of a formation, in which a well bore is to be drilled, maintaining the formation at a relative higher temperature than if no special sources of heat were used to add heat to the circulating fluid. The region, at the relatively higher temperature, has a tendency to expand and to be placed in a relatively higher compressive state as compared to a formation at a lower temperature. Consequently, the use of the heated circulating fluid minimizes fracture initiation and growth and circulation fluid losses into the formation. The system may use a heater mounted on the surface of a well or else on a sea floor to add heat to the circulating fluid.

Abstract: The present invention provides a method for enhancing the production of hydrocarbons from a subterranean formation. A hydrocarbon bearing formation, surrounding a well bore, is fractured with a fracturing fluid to create one or more fractures in the formation. The formation includes a higher permeability zone and a lower permeability zone with the fractures extending across both the higher and lower permeability zones. The lower permeability zone may contain a substantially higher concentration of hydrocarbons, oil and gas, than does the higher permeability zone which may generally be depleted of hydrocarbons. Proppant is then selectively positioned in the fractures using a carrier fluid with a majority of the proppant being positioned in the lower permeability zone. The fracture is allowed to close about the proppant to create at least one high conductivity channel in the lower permeability zone.

Abstract: A process for marking an article in a manner which is optically invisible and difficult to detect. The process is carried out by selecting a laser luminophore which fluoresces in a predetermined portion of the spectrum when exposed to an excitation light of predetermined wavelength and applying the laser luminophore to the article in an amount which is optically invisible when the article is exposed to electromagnetic radiation but which is sufficient for machine detection when the article is exposed to an excitation light of predetermined wavelength.

Abstract: A method of fracturing a subterranean formation, in which subterranean formation being in fluid communication with the surface includes creating a fracture in said subterranean formation, said fracture having more than one fracture faces; and injecting into said fracture an encapsulated formation etching agent, wherein said encapsulated formation etching agent includes a formation etching agent and an encapsulating agent and wherein said formation etching agent etches the fracture faces of the fracture so as to form a flow channel in said formation. The formation etching agent may be selected from mineral acids and mixtures thereof, organic acids and mixtures thereof, mineral acids and mixtures of mineral acids mixed with gelling agent, organic acids and mixtures of organic acids mixed with gelling agent, water soluble hydroxides and mixtures of water soluble hydroxides, and water soluble hydroxides and mixtures of water soluble hydroxides mixed with gelling agent.

Abstract: A liquid hydrocarbon fuel composition comprises at least one tagging agent and a mixture of hydrocarbon components having boiling points in the range of about 100 degrees F. to about 800 degrees F. The tagging agent is present at a concentration in the range of from about 0.5 ppb to about 500 ppb. The tagging agent is elutable by chromatographic analysis of the liquid hydrocarbon fuel composition apart from the hydrocarbon components of the fuel composition. The tagging agent is formed from an organic compound containing elements found at natural isotopic abundance. Preferably, two or more tagging agents are employed in the fuel so that each fuel composition can be assigned a unique tagging agent composition. Analysis techniques are also disclosed.

Abstract: A method is disclosed for identifying the source of a transported chemical shipment. The method employs either a chemical element or an organic compound with one or more atoms that are non-radioactive isotopes generally not found in nature. A small quantity of the isotopic compound is introduced into the storage vessel containing the chemical to be transported prior to shipment of the chemical. Upon arrival at its destination point, a sample of the chemical shipment is analyzed. Matching the isotopic compound found in the chemical with the isotopic compound introduced into the storage vessel prior to shipment is indicative that the shipped chemical is identical to the chemical received. Non-radioactive materials may further be employed for detecting the source of a newly introduced contaminant in a water supply. The chemical substance may be a non-radioactive isotope of the chemical shipment being transported.

Abstract: Rare elements, which can be selected from Ni, Cu, W, Li, N, Ce, Sn, Y, Nd, Nb, Co, La, Pb, Ga, Mo, Th, Cs, Ge, Sm, Gd, Be, Pr, Se, As, Hf, Dy, U, B, Yb, Er, Ta, Br, Ho, Eu, Sb, Tb, Lu, Tl, Hg, I, Bi, Tm, Cd, Ag, In, Se, Pd, Pt Au, He, Te, Rh, Re, Ir, Os, and Ru can be used to tag commodities, including explosive materials, with a unique tagging agent.

Abstract: Rare elements, which can be selected from Ni, Cu, W, Li, N, Ce, Sn, Y, Nd, Nb, Co, La, Pb, Ga, Mo, Th, Cs, Ge, Sm, Gd, Be, Pr, Se, As, Hf, Dy, U, B, Yb, Er, Ta, Br, Ho, Eu, Sb, Tb, Lu, Tl, Hg, I, Bi, Tm, Cd, Ag, In, Se, Pd, Pt, Au, He, Te, Rh, Re, Ir, Os, and Ru can be used to tag commodities, including explosive materials, with a unique tagging agent.

Abstract: A method is disclosed for identifying the source of a transported chemical shipment. The method employs either a chemical element or an organic compound with one or more atoms that are non-radioactive isotopes generally not found in nature. A small quantity of the isotopic compound is introduced into the storage vessel containing the chemical to be transported prior to shipment of the chemical. Upon arrival at its destination point, a sample of the chemical shipment is analyzed. Matching the isotopic compound found in the chemical with the isotopic compound introduced into the storage vessel prior to shipment is indicative that the shipped chemical is identical to the chemical received. Non-radioactive materials may further be employed for detecting the source of a newly introduced contaminant in a water supply. The chemical substance may be a non-radioactive isotope of the chemical shipment being transported.

Abstract: A method is disclosed for identifying the source of a transported chemical shipment. The method employs either a chemical element or an organic compound with one or more atoms that are non-radioactive isotopes generally not found in nature. A small quantity of the isotopic compound is introduced into the storage vessel containing the chemical to be transported prior to shipment of the chemical. Upon arrival at its destination point, a sample of the chemical shipment is analyzed. Matching the isotopic compound found in the chemical with the isotopic compound introduced into the storage vessel prior to shipment is indicative that the shipped chemical is identical to the chemical received. Non-radioactive materials may further be employed for detecting the source of a newly introduced contaminant in a water supply. The chemical substance may be a non-radioactive isotope of the chemical shipment being transported.

Abstract: Ball sealers comprising a polyetheretherketone are introduced into a well to seal well perforations and divert fluid therein. In the preferred embodiment the ball sealers have a density less than the treating fluid.

Abstract: A method for non-abrasively running tubing comprising suspending the tubing from the face of the uppermost collar of the tubing by resting the face upon a support shoulder, making up a new tubular with collar into a tubular unit, attaching a non-abrasive lift unit to a tubular unit, stabbing the new tubular into the upper collar, non-abrasively making the connection tight, and lifting the lift unit to raise the string, the method being appropriately reversed for pulling the string.

Abstract: The invention provides an apparatus for limiting tension produced in a tubular string extending from a packer set in a subterranean well to the well surface. Such apparatus comprises a receptacle secured to the packer and defining an elongated seal bore, and a mandrel telescopically and sealably related to the seal bore, the mandrel being connected to the bottom end of the tubing string. In one embodiment, a collet, incorporated in the receptacle for cooperating with an abutment formed on the mandrel, thereby securing the mandrel and the receptacle in a telescopically contracted position until sufficient tensile force is exerted on the mandrel to cause the collet arms to be expanded by the abutment to permit upward movement of the mandrel relative to the receptacle.

Abstract: A perforator for perforating a subsurface formation surrounding a well bore to ensure perforation of channels in a cement sheath surrounding a casing pipe cemented in said well bore comprising a series of stacked plates, each plate containing spaced apart co-planar, pie-shaped linear charges and a co-planar, pie-shaped non-charged spacer arranged between each of said linear charges. There are preferably four linear charges and four non-charged spacers forming each plate. The linear charges on each plate are spaced angularly from the linear charges on each other plate so that the linear charges are aimed at different angular portions of the bore hole.

Abstract: A well perforator system and method employs an electromagnetic wave frequency receiver, one for each of at least two gun intervals, that receives a transmitted signal conveyed through well tubing from the earth's surface. The signal is converted to an electrical pulse which detonates a blasting cap and fires the gun perforators. Each gun interval is a separate system with different activating frequencies and each is separately activated to assure that all the intervals are fired. A timer may be used to activate the electromagnetic wave receiver after the gun is in the well to prevent accidental surface firing of the guns from stray sources of electromagnetic waves. Once in the well, only the transmitted pulses are able to detonate the guns. Once the last interval is fired, a wave frequency-activated gun above the uppermost gun interval is detonated with circulation shots to penetrate only the tubing. This creates an instant, intense pressure drop across the perforations to help in cleanup.