Patents by Inventor Manuel Moliner Marin

Manuel Moliner Marin has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 10875780
    Abstract: The present invention relates to a new process for synthesising a crystalline material comprising structure Beta zeolite in nanocrystalline form, and which can comprise at least the following steps: (i) preparing a mixture comprising at least one source of water, at least one source of a tetravalent element Y, at least one source of a trivalent element X, at least one source of an alkali cation or alkaline earth metal cation (A), and at least one organic molecule selected from a monocyclic quaternary ammonium R1R2CycloN+, and a quaternary ammonium substituted with a cycloalkyl group R3R4R5R6N+. The molar composition of the mixture is: n X2O3:YO2:a A:m OSDA1:z H2O; ii) crystallising the mixture; and iii) recovering the crystalline material.
    Type: Grant
    Filed: June 5, 2018
    Date of Patent: December 29, 2020
    Assignees: UNIVERSITAT POLITECNICA DE VALENCIA, CONSEJO SUPERIOR DE INVESTIGACIONES CIENTIFICAS (CSIC)
    Inventors: Cecilia Gertrudis Paris Carrizo, Eva Maria Gallego Sanchez, Maria del Rocio Diaz Rey, Marta Evelia Martinez Armero, Maria Cristina Martinez Sanchez, Manuel Moliner Marin, Avelino Corma Canos
  • Patent number: 10792617
    Abstract: The main object of the present invention is to provide a new method for preparing the copper-containing silicoaluminate form of the AEI zeolite structure by means of a direct synthesis methodology. This new process involves combining a organometallic copper-complex with an additional organic molecule capable of directing the crystallisation of the silicoaluminate form of the AEI zeolite structure as organic structure-directing agents (OSDAs).
    Type: Grant
    Filed: March 20, 2020
    Date of Patent: October 6, 2020
    Assignees: Consejo Superior de Investigaciones Cientificas, Universitat Politècnica de València
    Inventors: Avelino Corma Canos, Manuel Moliner Marin, Nuria Martin Garcia
  • Publication number: 20200239784
    Abstract: Systems and methods are provided for selective oxidation of CO and/or C3? hydrocarbonaceous compounds in a reaction environment including hydrocarbons and/or hydrocarbonaceous components. The selective oxidation can be performed by exposing the CO and/or C3? hydrocarbonaceous compounds to a catalytic metal that is encapsulated in a small pore zeolite. The small pore zeolite containing the encapsulated metal can have a sufficiently small pore size to reduce or minimize the types of hydrocarbons or hydrocarbonaceous compounds that can interact with the encapsulated metal.
    Type: Application
    Filed: January 30, 2019
    Publication date: July 30, 2020
    Inventors: Pedro Serna Merino, Jadeene E. Gabay, Avelino Corma Canos, Manuel Moliner Marin
  • Publication number: 20200230552
    Abstract: The main object of the present invention is to provide a new method for preparing the copper-containing silicoaluminate form of the AEI zeolite structure by means of a direct synthesis methodology. This new process involves combining a organometallic copper-complex with an additional organic molecule capable of directing the crystallisation of the silicoaluminate form of the AEI zeolite structure as organic structure-directing agents (OSDAs).
    Type: Application
    Filed: March 20, 2020
    Publication date: July 23, 2020
    Inventors: Avelino Corma Canos, Manuel Moliner Marin, Nuria Martin Garcia
  • Publication number: 20200216326
    Abstract: The present invention relates to a new process for synthesising a crystalline material comprising structure Beta zeolite in nanocrystalline form, and which can comprise at least the following steps: (i) preparing a mixture comprising at least one source of water, at least one source of a tetravalent element Y, at least one source of a trivalent element X, at least one source of an alkali cation or alkaline earth metal cation (A), and at least one organic molecule selected from a monocyclic quaternary ammonium R1R2CycloN+, and a quaternary ammonium substituted with a cycloalkyl group R3R4R5R6N+. The molar composition of the mixture is: n X2O3:YO2:a A:m OSDA1:z H2O; ii) crystallising the mixture; and iii) recovering the crystalline material.
    Type: Application
    Filed: June 5, 2018
    Publication date: July 9, 2020
    Inventors: Cecilia Gertrudis Paris Carrizo, Eva Maria Gallego Sanchez, Maria del Rocio Diaz Rey, Marta Evelia Martinez Armero, Maria Cristina Martinez Sanchez, Manuel Moliner Marin, Avelino Corma Canos
  • Patent number: 10703986
    Abstract: Systems and methods are provided for selective oxidation of CO and/or C3? hydrocarbonaceous compounds in a reaction environment including hydrocarbons and/or hydrocarbonaceous components. The selective oxidation can be performed by exposing the CO and/or C3? hydrocarbonaceous compounds to a catalytic metal that is encapsulated in a small pore zeolite. The small pore zeolite containing the encapsulated metal can have a sufficiently small pore size to reduce or minimize the types of hydrocarbons or hydrocarbonaceous compounds that can interact with the encapsulated metal.
    Type: Grant
    Filed: January 30, 2019
    Date of Patent: July 7, 2020
    Assignee: EXXONMOBIL RESEARCH AND ENGINEERING COMPANY
    Inventors: Pedro Serna Merino, Jadeene E. Gabay, Avelino Corma Canos, Manuel Moliner Marin
  • Patent number: 10703639
    Abstract: Disclosed is a synthesis process of a crystalline material with the CHA structure, which comprises the following steps: i) Preparation of a mixture that comprises one source of water, one source of a tetravalent element Y, one source of an alkaline or alkaline earth cation (A), one source of a trivalent element X, and one organic molecule (OSDA1) with the structure [R1R2R3R4N+]Q?, being the molar composition: n X2O3:YO2:a A:m OSDA1:z H2O, ii) crystallisation of the mixture obtained in i) in a reactor, iii) recovery of the crystalline material obtained in ii).
    Type: Grant
    Filed: April 29, 2019
    Date of Patent: July 7, 2020
    Assignees: Consejo Superior de Investigaciones Cientificas, Universitat Politècnica de València
    Inventors: Avelino Corma Canós, Manuel Moliner Marín, Nuria Martín García
  • Patent number: 10703640
    Abstract: Disclosed is a synthesis process of a crystalline material with the CHA structure, which comprises the following steps: i) Preparation of a mixture that comprises one source of water, one source of a tetravalent element Y, one source of an alkaline or alkaline earth cation (A), one source of a trivalent element X, and one organic molecule (OSDA1) with the structure [R1R2R3R4N+]Q?, being the molar composition: nX2O3:YO2:aA:mOSDA1:zH2O, ii) crystallisation of the mixture obtained in i) in a reactor, iii) recovery of the crystalline material obtained in ii).
    Type: Grant
    Filed: April 29, 2019
    Date of Patent: July 7, 2020
    Assignees: Consejo Superioer de Investigaciones Cientificas, Universitat Politècnica de València
    Inventors: Avelino Corma Canós, Manuel Moliner Marín, Nuria Martín García
  • Patent number: 10703638
    Abstract: Disclosed is a synthesis process of a crystalline material with the CHA structure, which comprises the following steps: i) Preparation of a mixture that comprises one source of water, one source of a tetravalent element Y, one source of an alkaline or alkaline earth cation (A), one source of a trivalent element X, and one organic molecule (OSDA1) with the structure [R1R2R3R4N+]Q?, being the molar composition: n X2O3:YO2:a A:m OSDA1:z H2O, ii) crystallisation of the mixture obtained in i) in a reactor, iii) recovery of the crystalline material obtained in ii).
    Type: Grant
    Filed: April 29, 2019
    Date of Patent: July 7, 2020
    Assignees: Consejo Superior de Investigaciones Cientificas, Universitat Politècnica de València
    Inventors: Avelino Corma Canós, Manuel Moliner Marín, Nuria Martín García
  • Publication number: 20200207631
    Abstract: The present invention relates to a new process for synthesising a crystalline material comprising the zeolite MFI structure in nanocrystalline form, and which can comprise at least the following steps: i) preparing a mixture comprising at least one source of water, at least one source of a tetravalent element Y, at least one source of a trivalent element X, at least one source of an alkali cation or alkaline earth metal cation (A), and at least one organic molecule (OSDA1), wherein OSDA1 is preferably a monocyclic quaternary ammonium with the structure R1R2CycloN+, the molar composition of the mixture being: n X2O3:YO2:a A:m OSDA1:z H2O; ii) crystallising this mixture in a reactor; and iii) recovering the crystalline material obtained.
    Type: Application
    Filed: June 1, 2018
    Publication date: July 2, 2020
    Inventors: Eva Maria Gallego Sanchez, Cecilia Gertrudis Paris Carrizo, Luis-Joaquin Martinez Triguero, Manuel Moliner Marin, Avelino Corma Canos
  • Patent number: 10676367
    Abstract: The present invention relates to a process for the direct synthesis of a material with a CHA zeolite structure in the silicoaluminate form thereof containing copper atoms, which comprises at least the following steps: (i) Preparation of a mixture which contains at least one water source, one copper source, one polyamine, one source of Y tetravalent element, one source of X trivalent element, the tetraethylammonium cation as the only OSDA and one source of alkaline or alkaline earth (A) cations, and wherein the synthesis mixture has the following molar composition: YO2:aX2O3:bOSDA:cA:dH2O:eCu:fpolyamine (ii) Crystallization of the mixture obtained in (i) in a reactor; (iii) Recovery of the crystalline material obtained in (ii).
    Type: Grant
    Filed: May 3, 2016
    Date of Patent: June 9, 2020
    Assignees: Consejo Superior de Investigaciones Cientificas, Universitat Politècnica de València
    Inventors: Avelino Corma Canós, Manuel Moliner Marín, Nuria Martin Garcia
  • Patent number: 10646826
    Abstract: The present invention provides a new method for preparing the copper-containing silicoaluminate form of the AEI zeolite structure by means of a direct synthesis methodology. This new process involves combining a organometallic copper-complex with an additional organic molecule capable of directing the crystallization of the silicoaluminate form of the AEI zeolite structure as organic structure-directing agents (OSDAs).
    Type: Grant
    Filed: April 14, 2016
    Date of Patent: May 12, 2020
    Assignees: Consejo Superior de Investigaciones Cientificas, Universitat Politècnica de València
    Inventors: Avelino Corma Canós, Manuel Moliner Marín, Nuria Martín García
  • Patent number: 10526208
    Abstract: A synthesis process for a crystalline material with the AEI zeolite structure, comprising (i) preparation of a mixture containing, at least, water, one zeolite with the FAU crystal structure as the only source of silicon and aluminum, a cyclic ammonium cation with alkyl substituents as the OSDA, and a source of alkaline or alkaline-earth cations (A), wherein the synthesis mixture has the following molar composition: SiO2:a Al2O3:b OSDA:c A:d H2O where a ranges between 0.001 and 0.2; where b ranges between 0.01 and 2; where c ranges between 0 and 2; where d ranges between 1 and 200; and wherein the mixture is free from phosphorous and fluorinated species, (ii) crystallisation of the mixture and, (iii) recovery of the crystalline material. Also, preparation of catalysts based on the AEI zeolite and application as a catalysts in processes including the selective catalytic reduction of NOx.
    Type: Grant
    Filed: April 14, 2016
    Date of Patent: January 7, 2020
    Assignees: Consejo Superior de Investigaciones Cientificas, Universitat Politència de València
    Inventors: Avelino Corma Canós, Manuel Moliner Marín, Nuria Martín García
  • Patent number: 10486975
    Abstract: Disclosed is a synthesis process of a crystalline material with the CHA structure, which comprises the following steps: i) Preparation of a mixture that comprises one source of water, one source of a tetravalent element Y, one source of an alkaline or alkaline earth cation (A), one source of a trivalent element X, and one organic molecule (OSDA1) with the structure [R1R2R3R4N+]Q?, being the molar composition: n X2O3:YO2:a A:m OSDA1:z H2O, ii) crystallisation of the mixture obtained in i) in a reactor, iii) recovery of the crystalline material obtained in ii).
    Type: Grant
    Filed: April 29, 2019
    Date of Patent: November 26, 2019
    Assignees: Consejo Superior de Investigaciones Científicas, Universitat Politècnica de València
    Inventors: Avelino Corma Canós, Manuel Moliner Marín, Nuria Martín García
  • Patent number: 10486976
    Abstract: Disclosed is a synthesis process of a crystalline material with the CHA structure, which comprises the following steps: i) Preparation of a mixture that comprises one source of water, one source of a tetravalent element Y, one source of an alkaline or alkaline earth cation (A), one source of a trivalent element X, and one organic molecule (OSDA1) with the structure [R1R2R3R4N+]Q?, being the molar composition: n X2O3:YO2:a A:m OSDA1:z H2O, ii) crystallisation of the mixture obtained in i) in a reactor, iii) recovery of the crystalline material obtained in ii).
    Type: Grant
    Filed: April 29, 2019
    Date of Patent: November 26, 2019
    Assignees: Consejo Superior de Investigaciones Cientificas, Universitat Politècnica de València
    Inventors: Avelino Corma Canós, Manuel Moliner Marín, Nuria Martín García
  • Patent number: 10427098
    Abstract: A method for the removal of nitrogen oxides from exhaust, flue or off gas by selective catalytic reduction in presence of ammonia as a reductant, comprising the steps of contacting the exhaust gas together with the ammonia or a precursor thereof with an SCR catalyst comprising a Fe-AEI zeolite material essentially free of alkali metal ions (Alk), having the following molar compositions: SiO2:oAl2O3:pFe:qAlk wherein o is in the range from 0.001 to 0.2; wherein p is in the range from 0.001 to 0.2; wherein Alk is one or more of alkali metal ions and wherein q is below 0.02.
    Type: Grant
    Filed: January 30, 2017
    Date of Patent: October 1, 2019
    Assignee: Umicore AG & Co. KG
    Inventors: Nuria Martín García, Manuel Moliner Marín, Avelino Corma Canós, Joakim Reimer Thøgersen, Peter Nicolai Ravnborg Vennestrøm
  • Publication number: 20190275504
    Abstract: A method for the removal of nitrous oxide from off gas by direct decomposition or by selective catalytic reduction in presence of a reducing agent, comprising the steps of contacting the gas directly or together with the reducing agent or a precursor thereof with a catalyst comprising an Fe-AEI zeolite material essentially free of alkali metal ions (Alk) and having the following molar compositions: SiO2:o Al2O3:p Fe:q Alk wherein o is in the range from 0.001 to 0.2; wherein p is in the range from 0.001 to 0.2; wherein Alk is one or more of alkali ions and wherein q is less than 0.02.
    Type: Application
    Filed: January 30, 2017
    Publication date: September 12, 2019
    Inventors: Nuria Martín García, Manuel Moliner Marín, Avelino Corma Canós, Joakim Reimer Thøgersen, Peter Nicolai Ravnborg Vennestrøm
  • Publication number: 20190256366
    Abstract: Disclosed is a synthesis process of a crystalline material with the CHA structure, which comprises the following steps: i) Preparation of a mixture that comprises one source of water, one source of a tetravalent element Y, one source of an alkaline or alkaline earth cation (A), one source of a trivalent element X, and one organic molecule (OSDA1) with the structure [R1R2R3R4N+]Q?, being the molar composition: n X2O3:YO2:a A:m OSDA1:z H2O, ii) crystallisation of the mixture obtained in i) in a reactor, iii) recovery of the crystalline material obtained in ii).
    Type: Application
    Filed: April 29, 2019
    Publication date: August 22, 2019
    Inventors: Avelino Corma Canós, Manuel Moliner Marín, Nuria Martín García
  • Publication number: 20190248664
    Abstract: Disclosed is a synthesis process of a crystalline material with the CHA structure, which comprises the following steps: i) Preparation of a mixture that comprises one source of water, one source of a tetravalent element Y, one source of an alkaline or alkaline earth cation (A), one source of a trivalent element X, and one organic molecule (OSDA1) with the structure [R1R2R3R4N+]Q?, being the molar composition: n X2O3:YO2:a A:m OSDA:z H2O, ii) crystallisation of the mixture obtained in i) in a reactor, iii) recovery of the crystalline material obtained in ii).
    Type: Application
    Filed: April 29, 2019
    Publication date: August 15, 2019
    Inventors: Avelino Corma Canós, Manuel Moliner Marín, Nuria Martín García
  • Publication number: 20190248663
    Abstract: Disclosed is a synthesis process of a crystalline material with the CHA structure, which comprises the following steps: i) Preparation of a mixture that comprises one source of water, one source of a tetravalent element Y, one source of an alkaline or alkaline earth cation (A), one source of a trivalent element X, and one organic molecule (OSDA1) with the structure [R1R2R3R4N+]Q?, being the molar composition: n X2O3:YO2:a A:m OSDA1:z H2O, ii) crystallisation of the mixture obtained in i) in a reactor, iii) recovery of the crystalline material obtained in ii).
    Type: Application
    Filed: April 29, 2019
    Publication date: August 15, 2019
    Inventors: Avelino Corma Canós, Manuel Moliner Marín, Nuria Martín García