Abstract: Methods are provided for characterizing the stability of a distillate fraction using a quartz crystal microbalance apparatus, such as a distillate fraction derived at least in part from a pre-refined crude oil. A sample can be aged for an aging period in a quartz crystal microbalance apparatus, and a frequency value for the sample in the quartz crystal microbalance apparatus can be determined before and after the aging period to determine a frequency difference. This frequency difference can be correlated directly with the ability of a jet fuel fraction to satisfy a stability test standard, such as a jet fuel breakpoint stability. The methods can also include using a temperature profile during characterization that can reduce or minimize operator error during the characterization.

Abstract: Methods are provided for characterizing the stability of a distillate fraction using a quartz crystal microbalance apparatus, such as a distillate fraction derived at least in part from a pre-refined crude oil. A sample can be aged for an aging period in a quartz crystal microbalance apparatus, and a frequency value for the sample in the quartz crystal microbalance apparatus can be determined before and after the aging period to determine a frequency difference. This frequency difference can be correlated directly with the ability of a jet fuel fraction to satisfy a stability test standard, such as a jet fuel breakpoint stability. The methods can also include using a temperature profile during characterization that can reduce or minimize operator error during the characterization.

Abstract: A method for determining the amount and rate of corrosion which has occurred on the surface of a process unit by measuring corrosion with a corrosion sensor and measuring at least one parameter inside the process unit. Corrosion on the internal surfaces of a process unit can then be determined.

Abstract: Methods are provided for characterizing the stability of a distillate fraction using a quartz crystal microbalance apparatus, such as a distillate fraction derived at least in part from a pre-refined crude oil. A sample can be aged for an aging period in a quartz crystal microbalance apparatus, and a frequency value for the sample in the quartz crystal microbalance apparatus can be determined before and after the aging period to determine a frequency difference, This frequency difference can be correlated directly with the ability of a jet fuel fraction to satisfy a stability test standard, such as a jet fuel breakpoint stability. The methods can also include using a temperature profile during characterization that can reduce or minimize operator error during the characterization.

Abstract: Methods are provided for characterizing the stability of a distillate fraction using a quartz crystal microbalance apparatus, such as a distillate fraction derived at least in part from a pre-refined crude oil. A sample can be aged for an aging period in a quartz crystal microbalance apparatus, and a frequency value for the sample in the quartz crystal microbalance apparatus can be determined before and after the aging period to determine a frequency difference. This frequency difference can be correlated directly with the ability of a jet fuel fraction to satisfy a stability test standard, such as a jet fuel breakpoint stability. The methods can also include using a temperature profile during characterization that can reduce or minimize operator error during the characterization.

Abstract: In various aspects, methods and systems are provided for monitoring catalyst bed levels using multiple sensors that are temporarily installed in a reactor during catalyst loading. The multiple sensors are able to take distance measurements at substantially the same time and at predetermined time intervals so as to provide a catalyst time profile. The catalyst time profile allows an operator monitor catalyst levels during and after catalyst loading. Once catalyst loading is completed, the multiple sensors are removed from the reactor.

Abstract: Method of controlling the operation of a combustion device to provide safe and reliable operation while reducing NOx emission that includes providing a flow of fuel and diluent at a determined volume ratio to a flame in the combustion device; providing a flame stability sensor to generate a measurement of a characteristic of the flame, providing a flow measurement for each of the fuel and diluent, and controlling the determined volume ratio of fuel:diluent using the measurement from the flame stability sensor and/or flow measurements. A combustion system incorporating this method also is included.

Abstract: A system and method for optimizing the response of a metal loss sensor which is configured in a way that its insertion depth and orientation in the process fluid are adjustable. These adjustments affect local turbulence and thereby enable achieving a desired corrosion rate at the metal loss sensor. Corrosion rate comparison between the metal loss sensor and pressure containment boundary can be measured directly or indirectly by computing wall shear stresses at the sensor and the pressure containment boundary.

Abstract: Mechanical oscillators employ the use of resonance parameters, frequency and the quality factor Q, for the measurement of corrosion or deposition. The ability of a mechanical oscillator to measure small amounts of metal loss or deposition is not only dependent upon the mechanical design but is limited by the precision in determining the resonance frequency and Q. Methods for measuring these resonance parameters with a high precision in the presence of noise are provided. The increased degree of precision improves the utility of these devices as sensitive probes for corrosion and deposition (fouling) measurement. The increased degree of precision is enabled in part by employing curve fitting consistent with modeling the mechanical oscillator as a simple harmonic oscillator. This curve fitting procedure, combined with averaging and utilizing signal processing parameters to mitigate noise effects, adds precision in measuring resonance parameters.

Abstract: Method of determining a total HF concentration metric in an environment including measuring an uncorrected HF concentration metric in the environment based on a first infrared absorption measurement at a wavelength corresponding to a vibrational frequency of a non-hydrogen bonded gas phase HF molecule; determining an ambient H2O concentration metric in the environment available for reaction with the non-hydrogen bonded gas phase HF molecules at or about the time of obtaining the first infrared absorption measurement; calculating a HF hydrate concentration metric in the environment based on the uncorrected HF concentration metric, the ambient H2O concentration metric and a reaction equilibrium relationship between the non-hydrogen bonded gas phase HF molecule and the HF hydrate; and determining the total HF concentration metric in the environment based on the uncorrected HF concentration metric and an amount of HF determined by the HF hydrate concentration metric.

Abstract: A system transports a device into a piece of industrial equipment for the purpose of collecting data inside of the industrial equipment. In an embodiment, the industrial equipment is a furnace and the device is an IR camera. The system opens a door covering an opening on the furnace, moves the IR camera inside of the furnace for a short time, the IR camera captures images, and the system removes the camera from the furnace and closes the door.

Abstract: Method of determining a total HF concentration metric in an environment including measuring an uncorrected HF concentration metric in the environment based on a first infrared absorption measurement at a wavelength corresponding to a vibrational frequency of a non-hydrogen bonded gas phase HF molecule; determining an ambient H2O concentration metric in the environment available for reaction with the non-hydrogen bonded gas phase HF molecules at or about the time of obtaining the first infrared absorption measurement; calculating a HF hydrate concentration metric in the environment based on the uncorrected HF concentration metric, the ambient H2O concentration metric and a reaction equilibrium relationship between the non-hydrogen bonded gas phase HF molecule and the HF hydrate; and determining the total HF concentration metric in the environment based on the uncorrected HF concentration metric and an amount of HF determined by the HF hydrate concentration metric.

Abstract: The present invention describes the connecting of a corrodible material with a non-corrodible material by electron beam welding so that the corrodible material is not affected by non-corrodible material during the welding process. Employing an electron beam welding process not only minimizes unintended alloying of the corrodible element but also minimizes the width of the weld heat affected and fusion zones. This fabrication method is necessary to ensure that the corrodible element faithfully replicates the wastage of the subject metal.

Abstract: The prior art describes the application of mechanical oscillators for the measurement of corrosion and/or deposition. Mechanical oscillators employ the use of resonance parameters, frequency and the quality factor Q, for the measurement of corrosion or deposition. However, the prior art does not consider the required precision for measuring frequency or Q in the presence of noise to make these measurements. In particular, the ability of the mechanical oscillator to measure small amounts of metal loss or deposition is not only dependent upon the mechanical design but is limited by the precision in determining the resonance frequency and Q. The present invention discloses methods for measuring these resonance parameters with a high precision in the presence of noise. This degree of precision is required to maximize the utility of these devices as sensitive probes for corrosion and deposition (fouling) measurement.

Abstract: A system transports a device into a piece of industrial equipment for the purpose of collecting data inside of the industrial equipment. In an embodiment, the industrial equipment is a furnace and the device is an IR camera. The system opens a door covering an opening on the furnace, moves the IR camera inside of the furnace for a short time, the IR camera captures images, and the system removes the camera from the furnace and closes the door.

Abstract: The present invention is a tuning fork oscillator for detection and measurement of corrosive or foreign materials. The elements include a means for mechanical excitation, and a mechanical oscillator, wherein said mechanical oscillator has a resonant frequency, f, and a quality factor, Q. A fuse fixed to the oscillator to change oscillator amplitude to or from essentially zero to resonance amplitude. In a preferred embodiment, the tuning fork has one region compatible with the service fluid and the other region is incompatible with the service fluid or other contaminant. The sensor alarms when a measured amount of the incompatible material has been removed or deposited.

Abstract: A method and system for controlling fouling in a hydrocarbon refining process that includes measuring a level of a particulate in a process stream of the hydrocarbon refining process in communication with a hydrocarbon refinery component, identifying an effective amount of additive capable of reducing particulate-induced fouling based at least in part on the measured level of the particulate in the process stream, and introducing the effective amount of additive to the hydrocarbon refining process.

Abstract: Method of controlling the operation of a combustion device to provide safe and reliable operation while reducing NOx emission that includes providing a flow of fuel and diluent at a determined volume ratio to a flame in the combustion device; providing a flame stability sensor to generate a measurement of a characteristic of the flame, providing a flow measurement for each of the fuel and diluent, and controlling the determined volume ratio of fuel:diluent using the measurement from the flame stability sensor and/or flow measurements. A combustion system incorporating this method also is included.

Abstract: The present invention is a mechanical oscillator for detection and measurement of corrosive foreign materials. The elements include a mechanical oscillator that is mechanically excited, wherein the mechanical oscillator has a resonant frequency, f, and a quality factor, Q. A fuse fixed to the oscillator to change oscillator amplitude to and from essentially zero to resonance amplitude. In a preferred embodiment, the mechanical oscillator has the shape of a tuning fork where one region is compatible with the service fluid and the other region is incompatible with the service fluid or other contaminant. The sensor alarms when a measured amount of the incompatible material has been removed or the physical strength of the material has been compromised.

Abstract: The present invention is a mechanical oscillator metal loss sensor for use in a corrosive or erosive environment. The elements include a mechanical oscillator that is mechanical excited with two regions that corrode differently, where the regions are determined to affect specific influences on the resonance parameters, wherein said mechanical oscillator has a resonant frequency, f, and a quality factor, Q. In a preferred embodiment, the mechanical oscillator has the shape of a tuning fork.