Abstract: Process of refrigeration induced by an external stimulus comprising the application of an external stimulus selected among hydrostatic pressure, uniaxial pressure, electric field and illumination with light, to an organic-inorganic hybrid material of crystalline structure with hexagonal packing, of formula ABX3 (I), where A is a given monovalent organic cation or a given mixture of monovalent organic cations or a given mixture of monovalent organic cations and monovalent inorganic cations, B is a given divalent metal cation, a given mixture of divalent metal cations, or a given 50/50% atomic mixture of a monovalent cation and a trivalent cation, and X is a halide anion or a mixture thereof. A device with cooling capacity induced by an external stimulus, comprising the above organic-inorganic hybrid material.