Patents by Inventor Marc-Andre LEGARE

Marc-Andre LEGARE has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 10988488
    Abstract: A catalytic process for the metal-free functionalization of sp2-carbons is described herein. The catalytic process is suitable for forming borylated alkenes, arenes and heteroarenes and comprises the use of catalysts comprising a Frustrated Lewis Pair (FLP).
    Type: Grant
    Filed: April 21, 2016
    Date of Patent: April 27, 2021
    Assignee: UNIVERSITÉ LAVAL
    Inventors: Frederic-Georges Fontaine, Marc-Andre Legare, Marc-Andre Courtemanche
  • Patent number: 10821429
    Abstract: Precatalysts and catalytic processes for the functionalization of sp2-carbons using the precatalysts are described herein. The precatalysts comprise an intramolecular Frustrated Lewis Pair (FLP) that is generated in situ from the corresponding precatalyst fluoroborate salts. The precatalyst fluoroborate salts are deprotected in situ to generate catalysts including intramolecular FLPs for the dehydrogenative borylation of alkenes, arenes and heteroarenes. The catalytic process comprises contacting a precatalyst, a functionalization reagent; and a substrate comprising a sp2-H carbon, under conditions to provide a substrate comprising a functionalized sp2 carbon.
    Type: Grant
    Filed: March 4, 2019
    Date of Patent: November 3, 2020
    Assignee: UNIVERSITÉ LAVAL
    Inventors: Frédéric-Georges Fontaine, Marc-André Légaré, Étienne Rochette, Nicolas Bouchard
  • Publication number: 20190262817
    Abstract: Precatalysts and catalytic processes for the functionalization of sp2-carbons using the precatalysts are described herein. The precatalysts comprise an intramolecular Frustrated Lewis Pair (FLP) that is generated in situ from the corresponding precatalyst fluoroborate salts. The precatalyst fluoroborate salts are deprotected in situ to generate catalysts including intramolecular FLPs for the dehydrogenative borylation of alkenes, arenes and heteroarenes. The catalytic process comprises contacting a precatalyst, a functionalization reagent; and a substrate comprising a sp2-H carbon, under conditions to provide a substrate comprising a functionalized sp2 carbon.
    Type: Application
    Filed: March 4, 2019
    Publication date: August 29, 2019
    Inventors: Frédéric-Georges FONTAINE, Marc-André LÉGARÉ, Étienne ROCHETTE
  • Patent number: 10258976
    Abstract: Precatalysts of formula I and IV, and processes for the functionalization of SP2-carbons using the same are described herein. The precatalysts comprise a fluoroborate salt protected intramolecular frustrated lewis pair (FLP). The precatalysts are bench stable with improved stability towards moisture and/or air. The precatalysts can be used to generate in situ the corresponding FLP catalyst.
    Type: Grant
    Filed: December 15, 2016
    Date of Patent: April 16, 2019
    Assignee: UNIVERSITÉ LAVAL
    Inventors: Frédéric-Georges Fontaine, Marc-André Légaré, Étienne Rochette
  • Publication number: 20180280950
    Abstract: Precatalysts of formula I and IV, and processes for the functionalization of SP2-carbons using the same are described herein. The precatalysts comprise a fluoroborate salt protected intramolecular frustrated lewis pair (FLP). The precatalysts are bench stable with improved stability towards moisture and/or air. The precatalysts can be used to generate in situ the corresponding FLP catalyst.
    Type: Application
    Filed: December 15, 2016
    Publication date: October 4, 2018
    Inventors: Frédéric-Georges FONTAINE, Marc-André LÉGARÉ, Étienne ROCHETTE
  • Publication number: 20180094001
    Abstract: A catalytic process for the metal-free functionalization of sp2-carbons is described herein. The catalytic process is suitable for forming borylated alkenes, arenes and heteroarenes and comprises the use of catalysts comprising a Frustrated Lewis Pair (FLP).
    Type: Application
    Filed: April 21, 2016
    Publication date: April 5, 2018
    Applicant: UNIVERSITE LAVAL
    Inventors: Frederic-Georges FONTAINE, Marc-Andre LEGARE, Marc-Andre COURTEMANCHE