Abstract: This invention is directed to single-component alkoxy silicon sealants and methods of making the sealants. The sealants are made from a masterbatch M that includes at least one organopolysiloxane A having terminal and/or pendant alkoxylated groups and at least one mineral filler B.

Abstract: The invention relates to a method of preparing polyorganosiloxanes containing at least one functional group using a lithium silanolate catalyst. A polyorganosiloxane, having at least one hydroxyl group, is reacted with a polyalkoxysilane having the formula (R1)a(R2)bSi(OR3)4-(a+b) (I), where R1 is an alkyl radical, a cycloalkyl radical, or an aryl radical; R2 is —(Z)m-(X)n, wherein m=0 or 1, n=1 or 2; Z is a divalent hydrocarbon residue; X is an unsaturated hydrocarbon radical when m=0 and, when m=1, X is chlorine, bromine, iodine, —O—CO—CR4?CR5R6 (in which R4, R5 and R6 each represent a hydrogen atom, an alkyl radical and/or a phenyl radical), —RF (in which RF is a perfluorinated residue), —NHR7 (in which R7 is a hydrogen atom, an alkyl radical, or a radical-R8—NH2, wherein R8 is Z), or —SH; R3 is an alkyl radical; a=0, 1, 2 or 3; b=0 or 1 and a+b=0, 1, 2 or 3, with the additional condition that the sum a+b=3, symbol b cannot be equal to 0.

Abstract: The invention relates to polyorganosiloxane monocomponent compounds (POS) which are stable when stored without humidity and crosslinking into elastomer in the presence of water. The inventive compounds comprise at least one type of crosslinkable linear polyorganosiloxane (POS), a mineral filler and a crosslinking catalyst of formula (I) which provides said compound with an excellent compromise between cross linking kinetics and a storage stability (i.e. more than 6 months).

Abstract: This invention is directed to single-component alkoxy silicon sealants and methods of making the sealants. The sealants are made from a masterbatch M that includes at least one organopolysiloxane A having terminal and/or pendant alkoxylated groups and at least one mineral filler B.

Abstract: The invention concerns an aqueous dispersion capable of crosslinking by condensation into elastomer by eliminating water in the presence of a polycondensation catalyst, comprising, dispersed in a continuous aqueous phase, an organic phase containing at least one polymer including a polyether chain, optionally branched, bearing, per molecule, at least one terminal alkoxysilyl unit and at least two —OR groups borne by one or more silicon atoms, the dispersion containing further an emulsifier adapted to the formation of the dispersion and a polycondensation catalyst. The polymer preferably comprises at least two terminal alkoxysilyl units corresponding to the following formula (a): (R1—O)n(R2)mSi—, wherein n is 1, 2 or 3 and m is 0, 1 or 2, with n+m=3, the R1 groups, mutually identical or different, the R2 groups, mutually identical or different to R1, are selected from the linear or branched C1-C8 alkyl groups.

Abstract: The invention relates to a method of preparing polyorganosiloxanes containing at least one functional group using a lithium silanolate catalyst. A polyorganosiloxane, having at least one hydroxyl group, is reacted with a polyalkoxysilane having the formula (R1)a(R2)bSi(OR3)4?(a+b) (I), where R1 is an alkyl radical, a cycloalkyl radical, or an aryl radical; R2 is —(Z)m—(X)n, wherein m=0 or 1, n=1 or 2; Z is a divalent hydrocarbon residue; X is an unsaturated hydrocarbon radical when m=0 and, when m=1, X is chlorine, bromine, iodine, —O—CO—CR4?CR5R6 (in which R4, R5 and R6 each represent a hydrogen atom, an alkyl radical and/or a phenyl radical), —RF (in which RF is a perfluorinated residue), —NHR7 (in which R7 is a hydrogen atom, an alkyl radical, or a radical-R8—NH2, wherein R8 is Z), or —SH; R3 is an alkyl radical; a=0,1,2 or 3; b=0 or 1 and a+b=0, 1,2 or 3, with the additional condition that the sum a+b=3, symbol b cannot be equal to 0.

Abstract: The invention concerns a single-constituent polycondensation polyorganosiloxane composition comprising a filler. The invention concerns single-constituent polyorganosiloxane (POS) compositions storage-stable in the absence of humidity and crosslinkable, in the presence of water, into elastomer, compositions comprising at least one crosslinkable linear polyorganopolysiloxane POS, a filler and a crosslinking catalyst, the POS having alkoxy, oxime, acyl and/or enoxy, preferably alkoxy, ends, and the composition being essentially free of hydroxylated POS at the ends and the catalyst comprising a vanadium compound and a titanium compound.

Abstract: Single-component silicone compositions which are stable on storage in the absence of moisture and which crosslink by polycondensation reactions catalyzed using a mixed titanium/metal catalyst to give non-yellowing elastomers which adhere to various supports, the reactions being carried out at ambient temperature and in the presence of water; each single-component POS composition comprises: 100 parts by weight of linear diorganopolysiloxane(s) A functionalized at the chain ends by functional group Rfo of alkoxy, acyloxy, iminoxy or enoxy type; 0 to 30 parts by weight of polysiloxane resin(s) B; 0 to 15 parts by weight of crosslinking agent(s) C; 0 to 2 parts by weight of aliphatic alcohol(s) E; 0 to 30 parts by weight of non-functionalized and unreactive linear diorganopolysiloxane(s) F; 2 to 40 parts by weight of inorganic filler G; 0 to 20 parts by weight of auxiliary agent(s) H; and 1 to 150 ?g.

Abstract: Single-component polyorganosiloxane (POS) compositions which are stable on storage in the absence of moisture and which crosslink, in the presence of water, into an elastomer, contain at least one crosslinkable linear polyorganopolysiloxane POS, an inorganic filler and a crosslinking catalyst, wherein the POS exhibits non-hydroxylated functionalized endgroups, in particular alkoxy, oxime, acyl and/or enoxy endgroups, preferably alkoxy endgroups, said compositions being essentially devoid of POS possessing hydroxylated endgroups and said catalyst being a vanadium compound.

Abstract: The invention relates to polyorganosiloxane monocomponent compounds (POS) which are stable when stored without humidity and crosslinking into elastomer in the presence of water. The inventive compounds comprise at least one type of crosslinkable linear polyorganosiloxane (POS), a mineral filler and a crosslinking catalyst of formula (I) which provides said compound with an excellent compromise between cross linking kinetics and a storage stability (i.e. more than 6 months).

Abstract: Single-component silicone compositions which are stable on storage in the absence of moisture and which crosslink by polycondensation reactions catalyzed using a mixed titanium/metal catalyst to give non-yellowing elastomers which adhere to various supports, the reactions being carried out at ambient temperature and in the presence of water; each single-component POS composition comprises: 100 parts by weight of linear diorganopolysiloxane(s) A functionalized at the chain ends by functional group Rfo of alkoxy, acyloxy, iminoxy or enoxy type; 0 to 30 parts by weight of polysiloxane resin(s) B; 0 to 15 parts by weight of crosslinking agent(s) C; 0 to 2 parts by weight of aliphatic alcohol(s) E; 0 to 30 parts by weight of non-functionalized and unreactive linear diorganopolysiloxane(s) F; 2 to 40 parts by weight of inorganic filler G; 0 to 20 parts by weight of auxiliary agent(s) H; and 1 to 150 ?g.

Abstract: Single-component polyorganosiloxane (POS) compositions which are stable on storage in the absence of moisture and which crosslink, in the presence of water, into an elastomer, contain at least one crosslinkable linear polyorganopolysiloxane POS, an inorganic filler and a crosslinking catalyst, wherein the POS exhibits non-hydroxylated functionalized endgroups, in particular alkoxy, oxime, acyl and/or enoxy endgroups, preferably alkoxy endgroups, said compositions being essentially devoid of POS possessing hydroxylated endgroups and said catalyst being a vanadium compound.

Abstract: The invention concerns a method for preparing a precipitated silica in a silicone oil, said suspension being useable for producing silicones crosslinkable by polyaddition, polycondensation or condensation by dehydrogenation (elastomers). The invention aims at solving the problem of finding a compromise between cost, rheology and mechanical properties of the final elastomers. Therefor, the invention provides a method for preparing a precipitated silica suspension treated with trimethylchlorosilane, in the presence of hexamethyldisiloxane, in a crosslinkable silicone oil. HCl can be used. Grafting of hydrophobic units on the silica and incorporation of the polyorganosiloxane silicone material are carried out during one single processing sequence, without passing through the powder form for the silica. Sodium silicate promoting MQ resin can be incorporated in the reaction medium. One of the characteristics of the inventive method is that it does not at all comprise a step involving dried hydrophobic silica.

Abstract: The invention concerns a method for preparing a precipitated silica suspension in a silicone oil, said suspension being useable for producing silicones crosslinkable by polyaddition, polycondensation or condensation by dehydrogenation (elastomers). The invention aims at solving the problem of finding a compromise between cost, rheology and mechanical properties of the final elastomers. Therefore, the invention provides a method for preparing a precipitated silica suspension treated with trimethylchlorosilane, in the presence of hexamethyldisiloxane, in a crosslinkable silicone oil. HCl can be used. Grafting of the hydrophobic units on the silica and incorporation of the polyorganosiloxane silicone material are carried out during one single processing sequence, without passing through the powder form for the silica. Sodium silicate promoting MQ resin can be incorporated in the reaction medium.