Patents by Inventor Marc H. Anthonis

Marc H. Anthonis has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 12559377
    Abstract: Disclosed is a method of synthesizing a molecular sieve of MWW framework type, and molecular sieves so synthesized. The method comprises preparing a synthesis mixture for forming a molecular sieve of MWW framework type, said synthesis mixture comprising water, a silicon source, a source of a trivalent element X, a potassium cation source, a structure directing agent R, and a source of another alkali metal cation M.
    Type: Grant
    Filed: June 28, 2021
    Date of Patent: February 24, 2026
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Sina Sartipi, Marc H. Anthonis, Aaron W. Peters, Mariame Akouche, Scott J. Weigel
  • Publication number: 20250115486
    Abstract: The present disclosure relates to a method of making crystalline materials of *BEA framework type. The present disclosure also relates to crystalline materials of *BEA framework type obtainable by said method and uses thereof. The method of making includes using 1,1-(pentane-1,5-diyl)bis(1-propylpyrrolidinium) dication as a structure directing agent for forming the crystalline materials of *BEA framework type.
    Type: Application
    Filed: October 4, 2024
    Publication date: April 10, 2025
    Inventors: Marc H. ANTHONIS, Sina SARTIPI, Scott J. WEIGEL
  • Publication number: 20250001404
    Abstract: Disclosed is a method of synthesizing aluminum-rich molecular sieve of *MRE framework type, comprising the steps of preparing a synthesis mixture comprising at least one source of silica, at least one source of alumina having a low water solubility, at least one source of hydroxide ions, at least one source of alkali and/or alkaline earth metal M, at least one source of diquaternary alkylammonium structure directing agent R, water and optional seed crystals.
    Type: Application
    Filed: August 26, 2021
    Publication date: January 2, 2025
    Inventors: Sina Sartipi, Marc H. Anthonis, Scott J. Weigel, Allen W. Burton
  • Publication number: 20240101435
    Abstract: Disclosed is a method of synthesizing a molecular sieve of MWW framework type, and molecular sieves so synthesized. The method comprises preparing a synthesis mixture for forming a molecular sieve of MWW framework type, said synthesis mixture comprising water, a silicon source, a source of a trivalent element X, a structure directing agent R, a source of alkali or alkaline earth metal cation M, and a source of poly(diallyldimethyl ammonium) cation (PDDA).
    Type: Application
    Filed: March 2, 2022
    Publication date: March 28, 2024
    Inventors: Sina Sartipi, Marc H. Anthonis, Aaron W. Peters, Scott J. Weigel
  • Publication number: 20240001335
    Abstract: Methods are provided for synthesizing metal-organic framework compositions using synthesis mixtures with elevated solids content and/or elevated kinematic viscosity. The methods can allow for formation of MOF-274 metal-organic framework compositions, such as EMM-67 (a mixed-metal MOF-274 metal-organic composition). More generally, the methods can allow for formation of MOF structures that include multi-ring disalicylate organic linkers using synthesis mixtures that contain a reduced or minimized amount of solvent, such as down to having substantially no solvent in the synthesis mixture.
    Type: Application
    Filed: July 1, 2022
    Publication date: January 4, 2024
    Inventors: Anna C. IVASHKO, Aaron W. PETERS, Preeti KAMAKOTI, Scott J. WEIGEL, Matthew T. KAPELEWSKI, Nicole M. HERB, Roxana PEREZ VELEZ, Marc H. ANTHONIS, Doron LEVIN, Tara L. REDDINGTON
  • Publication number: 20240002417
    Abstract: Methods are provided for synthesizing metal organic framework compositions in an aqueous environment and/or in a mixed alcohol/water solvent. The methods can allow for formation of MOF-274 metal organic framework compositions, such as EMM-67 (a mixed metal MOF-274 metal organic framework composition). More generally, the methods can allow for formation of MOF structures that include disalicylate linkers in an aqueous environment and/or in a mixed alcohol/water solvent.
    Type: Application
    Filed: July 1, 2022
    Publication date: January 4, 2024
    Inventors: Anna C. IVASHKO, Carter W. ABNEY, Nicole M. HERB, Preeti KAMAKOTI, Aaron W. PETERS, Matthew T. KAPELEWSKI, Marc H. ANTHONIS, Roxana PEREZ VELEZ, Nadya A. HRYCENKO, Doron LEVIN, Tara L. REDDINGTON, Scott J. WEIGEL
  • Publication number: 20230264965
    Abstract: Disclosed is a method of synthesizing a molecular sieve of MWW framework type, and molecular sieves so synthesized. The method comprises preparing a synthesis mixture for forming a molecular sieve of MWW framework type, said synthesis mixture comprising water, a silicon source, a source of a trivalent element X, a potassium cation source, a structure directing agent R, and a source of another alkali metal cation M.
    Type: Application
    Filed: June 28, 2021
    Publication date: August 24, 2023
    Inventors: Sina Sartipi, Marc H. Anthonis, Aaron W. Peters, Mariame Akouche
  • Patent number: 11542446
    Abstract: Methods are provided for using a molecular sieve catalyst for dewaxing formed using a synthesis mixture comprising a morphology modifier. The catalyst may be used, for example, for production of a lubricant base stock. For example, ZSM-48 crystals formed using the morphology modifier (and/or formulated catalysts made using such crystals) can have an increased activity and/or can provide an improved yield during catalytic dewaxing of lubricant base stocks.
    Type: Grant
    Filed: August 14, 2019
    Date of Patent: January 3, 2023
    Assignee: Exxon Mobil Technology and Engineering Company
    Inventors: Preeti Kamakoti, Scott J. Weigel, Stephen J. McCarthy, Shifang L. Luo, Sina Sartipi, Martine Dictus, Marc H. Anthonis, Helge Jaensch
  • Patent number: 11318450
    Abstract: Processes are provided for preparing molecular sieves. The process involves preparing a synthesis mixture for the molecular sieve wherein the synthesis mixture includes a morphology modifier L selected from the group consisting of nonionic surfactants, anionic surfactants, sugars and combinations thereof.
    Type: Grant
    Filed: August 20, 2019
    Date of Patent: May 3, 2022
    Assignee: ExxonMobil Research & Engineering Company
    Inventors: Preeti Kamakoti, Scott J. Weigel, Karl G. Strohmaier, Helge Jaensch, Marc H. Anthonis, Martine Dictus, Brita Engels, Darryl D. Lacy, Sina Sartipi
  • Patent number: 11318451
    Abstract: Processes are provided for preparing molecular sieves of framework structure MEI, TON, MRE, MWW, MFS, MOR, FAU, EMT, or MSE. The process involves preparing a synthesis mixture for the molecular sieve wherein the synthesis mixture includes a morphology modifier L selected from the group consisting of cationic surfactants having a quaternary ammonium group comprising at least one hydrocarbyl group having at least 12 carbon atoms, nonionic surfactants, anionic surfactants, sugars and combinations thereof.
    Type: Grant
    Filed: August 20, 2019
    Date of Patent: May 3, 2022
    Assignee: ExxonMobil Research & Engineering Company
    Inventors: Preeti Kamakoti, Scott J. Weigel, Karl G. Strohmaier, Helge Jaensch, Marc H. Anthonis, Martine Dictus, Brita Engels, Darryl D. Lacy, Sina Sartipi, Brandon J. O'Neill
  • Patent number: 11111153
    Abstract: Processes are provided for preparing molecular sieves for use as catalysts. The process involves preparing a synthesis mixture for the molecular sieve wherein the synthesis mixture includes a morphology modifier which may be selected from cationic surfactants having a single quaternary ammonium group comprising at least one hydrocarbyl group having at least 12 carbon atoms, nonionic surfactants, anionic surfactants, sugars, and combinations thereof.
    Type: Grant
    Filed: August 20, 2019
    Date of Patent: September 7, 2021
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Preeti Kamakoti, Scott J. Weigel, Karl G. Strohmaier, Helge Jaensch, Marc H. Anthonis, Martine Dictus, Brita Engels, Darryl D. Lacy, Sina Sartipi
  • Patent number: 10899627
    Abstract: A method of synthesising a molecular sieve of DDR framework type. The method comprises: preparing a synthesis mixture capable of forming a molecular sieve of DDR framework type, said synthesis mixture comprising water, a silicon source, optionally a source of a trivalent element X, optionally a source of a pentavalent element Z, optionally a source of hydroxide ions, optionally a source of a metal cation M, a structure directing agent, and seed crystals having a framework type selected from CHA and LEV; said synthesis mixture being substantially free from fluoride ions; heating said synthesis mixture under static crystallization conditions for a time sufficient to form crystals of said molecular sieve of DDR framework type, said crystallization conditions including a temperature of from 100° C. to 220° C.; and, recovering said crystals of the molecular sieve of DDR framework type from the synthesis mixture.
    Type: Grant
    Filed: June 4, 2020
    Date of Patent: January 26, 2021
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Marc H. Anthonis, Antonie Jan Bons, Machteld M. Mertens
  • Publication number: 20200399136
    Abstract: A method of synthesising a molecular sieve of DDR framework type. The method comprises: preparing a synthesis mixture capable of forming a molecular sieve of DDR framework type, said synthesis mixture comprising water, a silicon source, optionally a source of a trivalent element X, optionally a source of a pentavalent element Z, optionally a source of hydroxide ions, optionally a source of a metal cation M, a structure directing agent, and seed crystals having a framework type selected from CHA and LEV; said synthesis mixture being substantially free from fluoride ions; heating said synthesis mixture under static crystallization conditions for a time sufficient to form crystals of said molecular sieve of DDR framework type, said crystallization conditions including a temperature of from 100° C. to 220° C.; and, recovering said crystals of the molecular sieve of DDR framework type from the synthesis mixture.
    Type: Application
    Filed: June 4, 2020
    Publication date: December 24, 2020
    Inventors: Marc H. Anthonis, Antonie Jan Bons, Machteld M. Mertens
  • Publication number: 20200063042
    Abstract: Methods are provided for using a molecular sieve catalyst for dewaxing formed using a synthesis mixture comprising a morphology modifier. The catalyst may be used, for example, for production of a lubricant base stock. For example, ZSM-48 crystals formed using the morphology modifier (and/or formulated catalysts made using such crystals) can have an increased activity and/or can provide an improved yield during catalytic dewaxing of lubricant base stocks.
    Type: Application
    Filed: August 14, 2019
    Publication date: February 27, 2020
    Inventors: Preeti Kamakoti, Scott J. Weigel, Stephen J. McCarthy, Shifang L. Luo, Sina Sartipi, Martine Dictus, Marc H. Anthonis, Helge Jaensch
  • Publication number: 20200062604
    Abstract: Processes are provided for preparing molecular sieves for use as catalysts. The process involves preparing a synthesis mixture for the molecular sieve wherein the synthesis mixture includes a morphology modifier which may be selected from cationic surfactants having a single quaternary ammonium group comprising at least one hydrocarbyl group having at least 12 carbon atoms, nonionic surfactants, anionic surfactants, sugars, and combinations thereof.
    Type: Application
    Filed: August 20, 2019
    Publication date: February 27, 2020
    Inventors: Preeti Kamakoti, Scott J. Weigel, Karl G. Strohmaier, Helge Jaensch, Marc H. Anthonis, Martine Dictus, Brita Engels, Darryl D. Lacy, Sina Sartipi
  • Publication number: 20200061592
    Abstract: Processes are provided for preparing molecular sieves. The process involves preparing a synthesis mixture for the molecular sieve wherein the synthesis mixture includes a morphology modifier L selected from the group consisting of nonionic surfactants, anionic surfactants, sugars and combinations thereof.
    Type: Application
    Filed: August 20, 2019
    Publication date: February 27, 2020
    Inventors: Preeti Kamakoti, Scott J. Weigel, Karl G. Strohmaier, Helge Jaensch, Marc H. Anthonis, Martine Dictus, Brita Engels, Darryl D. Lacy, Sina Sartipi
  • Publication number: 20200061593
    Abstract: Processes are provided for preparing molecular sieves of framework structure MEI, TON, MRE, MWW, MFS, MOR, FAU, EMT, or MSE. The process involves preparing a synthesis mixture for the molecular sieve wherein the synthesis mixture includes a morphology modifier L selected from the group consisting of cationic surfactants having a quaternary ammonium group comprising at least one hydrocarbyl group having at least 12 carbon atoms, nonionic surfactants, anionic surfactants, sugars and combinations thereof.
    Type: Application
    Filed: August 20, 2019
    Publication date: February 27, 2020
    Inventors: Preeti Kamakoti, Scott J. Weigel, Karl G. Strohmaier, Helge Jaensch, Marc H. Anthonis, Martine Dictus, Brita Engels, Darryl D. Lacy, Sina Sartipi, Brandon J. O'Neill
  • Patent number: 9725327
    Abstract: A method of making a crystalline molecular sieve of MFI framework type, preferably ZSM-5, from a synthesis mixture comprising at least one source of tetravalent element (Y), at least one source of trivalent element (X), at least one source of alkali metal hydroxide (MOH), at least one structure directing; (R) and water, said synthesis mixture having the following molar composition: YO2, (p)X2O3: (q) MOH: (r) R: (s) H2O, wherein (p) is from 0.005 to 0.025, (q) is from 0.05 to 0.5, (r) is from 0.05 to 0.15 and (s) is from 35 to 45, wherein the ratio of the largest dimension (L) to the smallest dimension (S) of each crystal of the molecular sieve product is at least 5, and the smallest dimension (S) is from 20 nm to 200 nm.
    Type: Grant
    Filed: November 14, 2013
    Date of Patent: August 8, 2017
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Machteld Maria Wilfried Mertens, Marc H. Anthonis, Antonie Jan Bons, Brita Engels, Wilfried Jozef Mortier, Jane Chi-ya Cheng
  • Publication number: 20150298982
    Abstract: A method of making a crystalline molecular sieve of MFI framework type, preferably ZSM-5, from a synthesis mixture comprising at least one source of tetravalent element (Y), at least one source of trivalent element (X), at least one source of alkali metal hydroxide (MOH), at least one structure directing agent (R) and water, said synthesis mixture having the following molar composition: YO2:(p) X2O3:(q) MOH:(r) R:(s) H2O, wherein (p) is from 0.005 to 0.025, (q) is from 0.05 to 0.5, (r) is from 0.05 to 0.15 and (s) is from 35 to 45, wherein the ratio of the largest dimension (L) to the smallest dimension (S) of each crystal of the molecular sieve product is at least 5, and the smallest dimension (S) is from 20 nm to 200 nm.
    Type: Application
    Filed: November 14, 2013
    Publication date: October 22, 2015
    Inventors: Machteld Maria Wilfried Mertens, Marc H. Anthonis, Antonie Jan Bons, Brita Engels, Wilfried Jozef Mortier, Jane Chi-ya Cheng
  • Patent number: 7670589
    Abstract: The synthesis of a crystalline material, in particular, a high silica zeolite, comprising a chabazite-type framework molecular sieve is conducted in the presence of an organic directing agent having the formula: [R1R2R3N—R4]+Q? wherein R1 and R2 are independently selected from hydrocarbyl groups and hydroxy-substituted hydrocarbyl groups having from 1 to 3 carbon atoms, provided that R1 and R2 may be joined to form a nitrogen-containing heterocyclic structure, R3 is an alkyl group having 2 to 4 carbon atoms and R4 is selected from a 4- to 8-membered cycloalkyl group, optionally, substituted by 1 to 3 alkyl groups each having from 1 to 3 carbon atoms; and a 4- to 8-membered heterocyclic group having from 1 to 3 heteroatoms, said heterocyclic group being, optionally, substituted by 1 to 3 alkyl groups each having from 1 to 3 carbon atoms and the or each heteroatom in said heterocyclic group being selected from the group consisting of O, N, and S, or R3 and R4 are hydrocarbyl groups having from 1 to 3 carbon a
    Type: Grant
    Filed: September 14, 2006
    Date of Patent: March 2, 2010
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Guang Cao, Machteld Maria Mertens, Matu J. Shah, Marc H. Anthonis, Hailian Li, Anil S. Guram, Robert J. Saxton, Mark T. Muraoka, Jeffrey C. Yoder, Anthony F. Volpe, Jr.