Abstract: An apparatus for carrying out a carbon monoxide shift reaction, which includes converting carbon monoxide and water into carbon dioxide and hydrogen, the converting proceeding in a liquid phase with removal of a product gas including carbon dioxide and hydrogen, is provided. The apparatus includes dry methanol, as a first solvent in a first region for an absorption of carbon monoxide with simultaneous formation of methyl formate, and water, as a second solvent in a second region for a liberation of the product gas in order to avoid losses of hydrogen in a carbon dioxide region.

Abstract: A process for carrying out a carbon monoxide shift reaction is provided. In the implementation of the carbon monoxide shift reaction, including the conversion of carbon monoxide and water into carbon dioxide and hydrogen, this conversion takes place in the liquid phase and involves separation of the product gases carbon dioxide and/or hydrogen, where as a first solvent dry methanol is used, for the absorption of carbon monoxide with simultaneous formation of a methyl formate, as a second solvent, in the area of release of the product gases, water is used, for avoiding hydrogen losses in a carbon dioxide area.

Abstract: A method is provided for separating a cleaned useful gas from a gas mixture substantially containing carbon dioxide, at least one useful gas, and at least one hazardous substance. The carbon dioxide is condensed, and the liquid carbon dioxide that is enriched with the hazardous substance is separated from the useful gas. The hazardous material is then separated from the liquid carbon dioxide by adsorption, and one part of the cleaned liquid carbon dioxide is fed into the useful gas to absorb hazardous substances still contained in the useful gas.

Abstract: A process for removing harmful substances from a gas steam which includes carbon dioxide and substances of value, such as at least one of the gases hydrogen H2 carbon monoxide CO, nitrogen N2 or noble gases, and harmful substances such as a substance from the group of mercury, sulphur, mercury compounds or sulphur compounds, wherein a carbon dioxide condensation is performed in order to obtain liquid carbon dioxide, adsorptive removal of the harmful substances from the condensed carbon dioxide is performed to remove the harmful substances from the carbon dioxide. A process temperature of less than ?30° C. but great than ?70° C. is maintained.

Abstract: A method for converting carbon monoxide and water into carbon dioxide and hydrogen, with simultaneous removal of one or more products, is described. The method includes the following steps: in a first reactor, carbon monoxide from the gas phase is bound in a first solvent and converted into formate, in a third reactor, formate is decomposed and resultant hydrogen H2 is removed, and in a second reactor a solid which is a hydrogen-carbonate salt or a carbonate salt is removed. The thermal decomposition of the solid and the expulsion of the carbon dioxide are carried out in an additional fourth reactor, optionally in a second solvent. Further presented is an apparatus for converting carbon monoxide and water into carbon dioxide and hydrogen, including a fourth reactor which thermally decomposes solids formed in the course of the reaction, and gives off carbon dioxide.

Abstract: A process for carrying out a carbon monoxide shift reaction is provided. In the implementation of the carbon monoxide shift reaction, including the conversion of carbon monoxide and water into carbon dioxide and hydrogen, this conversion takes place in the liquid phase and involves separation of the product gases carbon dioxide and/or hydrogen, where as a first solvent dry methanol is used, for the absorption of carbon monoxide with simultaneous formation of a methyl formate, as a second solvent, in the area of release of the product gases, water is used, for avoiding hydrogen losses in a carbon dioxide area.