Patents by Inventor Marc Jacquin

Marc Jacquin has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20220325365
    Abstract: The present invention relates to a process for treating a lignocellulosic biomass pretreated beforehand (1), said process comprising the extraction of the free sugars from said pretreated biomass using an alcoholic or aqueous-alcoholic extraction solution (2), so as to obtain a liquid phase enriched in free sugars, called liquor (3), and a solid phase depleted in free sugars, called must (4).
    Type: Application
    Filed: March 29, 2022
    Publication date: October 13, 2022
    Applicant: IFP Energies nouvelles
    Inventors: Sophie COUDERC, Marc JACQUIN, Caroline AYMARD
  • Publication number: 20220242840
    Abstract: The invention relates to a process for the production of a mixture of 5-hydroxymethylfurfural and glucose from a feedstock containing fructose in the presence of at least one polar aprotic solvent and of at least one dehydration catalyst, in which process the reaction temperature is less than 90° C.
    Type: Application
    Filed: June 15, 2020
    Publication date: August 4, 2022
    Applicant: IFP Energies Nouvelles
    Inventors: Marc JACQUIN, Damien DELCROIX, Kim LARMIER, Thierry HUARD
  • Patent number: 11261168
    Abstract: The invention relates to a process for synthesizing 5-hydroxymethylfurfural from a fructose-containing feedstock in the presence of at least one aprotic polar solvent and at least one dehydration catalyst, in which process the maximum instantaneous fructose concentration 5.0 wt %.
    Type: Grant
    Filed: December 21, 2018
    Date of Patent: March 1, 2022
    Assignee: IFP Energies nouvelles
    Inventors: Marc Jacquin, Damien Delcroix
  • Patent number: 11084797
    Abstract: The invention relates to a process for converting a feedstock comprising at least one sugar into 5-hydroxymethylfurfural, wherein said feed is brought into contact with one or more inorganic dehydration catalysts and one or more chloride sources in the presence of at least one aprotic polar solvent alone or as a mixture, at a temperature of between 30° C. and 200° C., and at a pressure of between 0.1 MPa and 10 MPa.
    Type: Grant
    Filed: September 25, 2018
    Date of Patent: August 10, 2021
    Assignee: IFP Energies nouvelles
    Inventors: Justine Denis, Marc Jacquin, Damien Delcroix
  • Patent number: 11078173
    Abstract: The invention relates to a novel process for converting a feedstock comprising at least one sugar into 5-hydroxymethylfurfural, wherein said feedstock is brought into contact with one or more organic dehydration catalysts and one or more chloride sources in the presence of at least one aprotic polar solvent alone or as a mixture, at a temperature of between 30° C. and 200° C., and at a pressure of between 0.1 MPa and 10 MPa.
    Type: Grant
    Filed: September 25, 2018
    Date of Patent: August 3, 2021
    Assignee: IFP Energies nouvelles
    Inventors: Justine Denis, Marc Jacquin, Damien Delcroix
  • Publication number: 20210053930
    Abstract: The invention relates to a process for synthesizing 5-hydroxymethylfurfural from a fructose-containing feedstock in the presence of at least one aprotic polar solvent and at least one dehydration catalyst, in which process the maximum instantaneous fructose concentration 5.0 wt %.
    Type: Application
    Filed: December 21, 2018
    Publication date: February 25, 2021
    Applicant: IFP Energies nouvelles
    Inventors: Marc JACQUIN, Damien DELCROIX
  • Patent number: 10829463
    Abstract: The invention relates to a process for separating furanic compounds from a feedstock additionally containing dimethoxysulfoxide (DMSO). These furanic compounds are in particular 5-hydroxymethylfurfural (5-HMF), 2,5-diformylfuran (DFF), 2,5-furanedicarboxylic acid (FDCA) or dimethyl 2,5-furandicarboxylate (DMFDCA). The process successively comprises a) bringing the feedstock into contact with water originating from step c), then b) a liquid-liquid extraction with an organic solvent followed by a back extraction c) by the water added in order to obtain an organic extract rich in furanic compounds. The extract may then be subjected to a crystallization step d) and then a filtration in order to obtain the solid furanic compound. The water-rich or solvent-rich effluents are advantageously recycled respectively to the back extraction and the extraction.
    Type: Grant
    Filed: September 10, 2018
    Date of Patent: November 10, 2020
    Assignee: IFP Energies Nouvelles
    Inventors: Marc Jacquin, Sophie Drozdz
  • Publication number: 20200299250
    Abstract: The invention relates to a process for converting a feedstock comprising at least one sugar into 5-hydroxymethylfurfural, wherein said feed is brought into contact with one or more inorganic dehydration catalysts and one or more chloride sources in the presence of at least one aprotic polar solvent alone or as a mixture, at a temperature of between 30° C. and 200° C., and at a pressure of between 0.1 MPa and 10 MPa.
    Type: Application
    Filed: September 25, 2018
    Publication date: September 24, 2020
    Applicant: IFP Energies nouvelles
    Inventors: Justine DENIS, Marc JACQUIN, Damien DELCROIX
  • Publication number: 20200290984
    Abstract: The invention relates to a novel process for converting a feedstock comprising at least one sugar into 5-hydroxymethylfurfural, wherein said feedstock is brought into contact with one or more organic dehydration catalysts and one or more chloride sources in the presence of at least one aprotic polar solvent alone or as a mixture, at a temperature of between 30° C. and 200° C., and at a pressure of between 0.1 MPa and 10 MPa.
    Type: Application
    Filed: September 25, 2018
    Publication date: September 17, 2020
    Applicant: IFP Energies nouvelles
    Inventors: Justine DENIS, Marc JACQUIN, Damien DELCROIX
  • Patent number: 10766846
    Abstract: The invention relates to a method for producing butadiene that is fed with a butanediol feedstock, with said method comprising at least: a) An esterification step comprising: A reaction section; A separation section producing a butanediol diester effluent, a water effluent, and a carboxylic acid effluent; b) An esterification pyrolysis step; c) A separation step comprising at least: A cooling section producing a liquid pyrolysis effluent and a vapor pyrolysis effluent; A gas-liquid washing section that is fed at the top with a fraction of the carboxylic acid effluent that is obtained from the separation section of step a) and at the bottom with said vapor pyrolysis effluent and producing at the top a butadiene effluent and at the bottom a washing effluent; in which a carboxylic-acid-rich stream comprising at least a portion of the liquid pyrolysis effluent is recycled to step a); d) A separation step.
    Type: Grant
    Filed: October 12, 2017
    Date of Patent: September 8, 2020
    Assignees: IFP Energies Nouvelles, Compagnie Generale des Etablissements Michelin
    Inventors: Marc Jacquin, Nuno Pacheco, Rejane Dastillung, Sophie Couderc, Claire Fauvarque Nuytien
  • Publication number: 20200262803
    Abstract: The invention relates to a process for separating furanic compounds from a feedstock additionally containing dimethoxysulfoxide (DMSO). These furanic compounds are in particular 5-hydroxymethylfurfural (5-HMF), 2,5-diformylfuran (DFF), 2,5-furanedicarboxylic acid (FDCA) or dimethyl 2,5-furandicarboxylate (DMFDCA). The process successively comprises a) bringing the feedstock into contact with water originating from step c), then b) a liquid-liquid extraction with an organic solvent followed by a back extraction c) by the water added in order to obtain an organic extract rich in furanic compounds. The extract may then be subjected to a crystallization step d) and then a filtration in order to obtain the solid furanic compound. The water-rich or solvent-rich effluents are advantageously recycled respectively to the back extraction and the extraction.
    Type: Application
    Filed: September 10, 2018
    Publication date: August 20, 2020
    Applicant: IFP Energies Nouvelles
    Inventors: Marc JACQUIN, Sophie DROZDZ
  • Patent number: 10647624
    Abstract: The invention relates to a method for producing 1,3-butanediene from a butanediol feedstock that includes: a) A step for esterification of butanediol by a carboxylic acid to form the corresponding diester; b) A step for pyrolysis of the diester effluent obtained from step a); c) A step for distillation fed by at least the carboxylic acid effluent obtained from step a), and producing an aqueous distillate and a carboxylic acid residue; d) A step for drying the carboxylic acid that is fed at least by the carboxylic acid residue obtained from step c) and producing a water effluent and a carboxylic acid product that feeds step a).
    Type: Grant
    Filed: December 13, 2016
    Date of Patent: May 12, 2020
    Assignees: IFP Energies nouvelles, Compagnie Generale des Etablissements Michelin
    Inventors: Nuno Pacheco, Margarita Dorato, Marc Jacquin, Rejane Dastillung, Sophie Couderc
  • Patent number: 10526302
    Abstract: The invention relates to a process for the production of 5-hydroxymethylfurfural from a feedstock comprising at least one sugar using a combination of at least one catalyst selected from the homogeneous Lewis acids, the heterogeneous Lewis acids and the heterogeneous bases and at least one homogeneous Brønsted acid catalyst selected from the families of the thioureas, the sulphonic acids and the phosphorus-containing organic compounds, alone or in a mixture, in the presence of at least one aprotic polar solvent, at a temperature comprised between 30° C. and 300° C., and at a pressure comprised between 0.1 MPa and 10 MPa.
    Type: Grant
    Filed: October 17, 2016
    Date of Patent: January 7, 2020
    Assignee: IFP Energies Nouvelles
    Inventors: Myriam Souleymanou, Marc Jacquin, Damien Delcroix
  • Patent number: 10508062
    Abstract: The invention pertains to a method for converting butanediol into butadiene that is fed with a butanediol feedstock, where said method comprises at least an esterification step, a pyrolysis step, and a step for separation of the pyrolysis effluent comprising at least one section for cooling said pyrolysis effluent and producing a liquid pyrolysis effluent and a steam pyrolysis effluent and a gas-liquid washing section that is fed at the top with a fraction of the butanediol diester effluent obtained from the esterification step and at the bottom with the steam pyrolysis effluent, where said section produces a butadiene effluent at the top and a washing effluent at the bottom.
    Type: Grant
    Filed: May 9, 2017
    Date of Patent: December 17, 2019
    Assignees: IFP ENERGIES NOUVELLES, COMPAGNIE GENERALE DES ETABLISSEMENTS MICHELIN
    Inventors: Marc Jacquin, Nuno Pacheco, Claire Fauvarque-Nuytten
  • Patent number: 10463987
    Abstract: The invention relates to a process for purifying an aqueous solution comprising ethanol, acetaldehyde and diethylacetal comprising: a step A) of countercurrent liquid-liquid extraction comprising an extraction section supplied at the top by said aqueous solution as a mixture with at least one fraction of the water/ethanol/acetaldehyde raffinate resulting from the back extraction step B), and at the bottom by an extraction solvent, and producing an extract at the top and a purified feedstock at the bottom; —a step B) of countercurrent liquid-liquid back extraction comprising a back extraction section supplied at the top by an acidic aqueous solution, the pH of which is between 0.5 and 5, and at the bottom by the extract resulting from step A), and producing an extract at the top and a water/ethanol/acetaldehyde raffinate at the bottom.
    Type: Grant
    Filed: October 13, 2017
    Date of Patent: November 5, 2019
    Assignees: IFP Energies Nouvelles, Compagnie Generale des Etablissements Michelin
    Inventors: Celine Hognon, Sophie Drozdz, Marc Jacquin, Damien Leinekugel Le Cocq, Frederic Augier
  • Publication number: 20190300470
    Abstract: The invention relates to a method for producing butadiene that is fed with a butanediol feedstock, with said method comprising at least: a) An esterification step comprising: A reaction section; A separation section producing a butanediol diester effluent, a water effluent, and a carboxylic acid effluent; b) An esterification pyrolysis step; c) A separation step comprising at least: A cooling section producing a liquid pyrolysis effluent and a vapor pyrolysis effluent; A gas-liquid washing section that is fed at the top with a fraction of the carboxylic acid effluent that is obtained from the separation section of step a) and at the bottom with said vapor pyrolysis effluent and producing at the top a butadiene effluent and at the bottom a washing effluent; in which a carboxylic-acid-rich stream comprising at least a portion of the liquid pyrolysis effluent is recycled to step a); d) A separation step.
    Type: Application
    Filed: October 12, 2017
    Publication date: October 3, 2019
    Applicants: IFP Energies Nouvelles, Compagnie Generale des Etablissements Michelin
    Inventors: Marc JACQUIN, Nuno PACHECO, Rejane DASTILLUNG, Sophie COUDERC, Claire FAUVARQUE NUYTIEN
  • Patent number: 10421735
    Abstract: The invention relates to a novel process for the conversion of a feedstock comprising at least one sugar to 5-hydroxymethylfurfural, in which said feedstock is contacted with one or more catalysts of the family of the homogeneous sulphonic acids in the presence of at least one aprotic polar solvent, used alone or in a mixture, at a temperature comprised between 30° C. and 200° C., and at a pressure comprised between 0.
    Type: Grant
    Filed: October 17, 2016
    Date of Patent: September 24, 2019
    Assignee: IFP Energies nouvelles
    Inventors: Myriam Souleymanou, Marc Jacquin, Damien Delcroix
  • Patent number: 10421706
    Abstract: The invention relates to a conversion method that is fed with a diol feedstock that comprises at least 90% by weight of diol and a carboxylic acid feedstock that comprises at least 80% by weight of carboxylic acid. The method comprising at least: An esterification step which is fed with at least the diol feedstock and at least the carboxylic acid feedstock, wherein the carboxylic acid/diol molar ratio at the inlet of the esterification step is between 2 and 6, the esterification step comprises at least one reactive distillation column that has a mixed reaction/separation zone located between two separation zones; and A water elimination step that is fed with distillate from the esterification step that comprises water and producing at least one water effluent.
    Type: Grant
    Filed: February 17, 2016
    Date of Patent: September 24, 2019
    Assignees: IFP Energies Nouvelles, Compagnie Generale des Etablissements Michelin
    Inventors: Romain Richard, Damien Leinekugel Le Cocq, Marc Jacquin, Margarita Dorato, Nuno Pacheco, Claire Rannoux
  • Publication number: 20190232193
    Abstract: The invention relates to a process for purifying an aqueous solution comprising ethanol, acetaldehyde and diethylacetal comprising: a step A) of countercurrent liquid-liquid extraction comprising an extraction section supplied at the top by said aqueous solution as a mixture with at least one fraction of the water/ethanol/acetaldehyde raffinate resulting from the back extraction step B), and at the bottom by an extraction solvent, and producing an extract at the top and a purified feedstock at the bottom; —a step B) of countercurrent liquid-liquid back extraction comprising a back extraction section supplied at the top by an acidic aqueous solution, the pH of which is between 0.5 and 5, and at the bottom by the extract resulting from step A), and producing an extract at the top and a water/ethanol/acetaldehyde raffinate at the bottom.
    Type: Application
    Filed: October 13, 2017
    Publication date: August 1, 2019
    Applicants: IFP Energies Nouvelles, Compagnie Generale des Etablissements Michelin
    Inventors: Celine HOGNON, Sophie DROZDZ, Marc JACQUIN, Damien LEINEKUGEL LE COCQ, Frederic AUGIER
  • Patent number: 10358396
    Abstract: A process for the production of butadiene from an ethanol feed having at least 80% by weight of ethanol, A) converting ethanol into acetaldehyde B) converting an ethanol/acetaldehyde mixture into butadiene, C1) hydrogen treatment, D1) butadiene extraction, a first butadiene purification D2), a subsequent butadiene purification D3), an effluent treatment E1), E2) eliminating impurities and brown oils and F) scrubbing with water.
    Type: Grant
    Filed: September 17, 2015
    Date of Patent: July 23, 2019
    Assignees: IFP Energies nouvelles, Compagnie Generale des Etablissements Michelin, MICHELIN RECHERCHE ET TECHNIQUE S.A.
    Inventors: Rejane Dastillung, Beatrice Fischer, Marc Jacquin, Raphael Huyghe