Abstract: The present invention describes an electrochemical system (1) to electrochemically reduce carbon monoxide (CO) into liquid methanol and gaseous H2, comprising an electrochemical cell with an anodic compartment with an anode (2) with a current collector (2A), at least a catalyst to electrochemically oxidize H2O, and a cathodic compartment with a cathodic electrolyte solution comprising the solvent (3), and a cathodic supporting electrolyte, the solvent (3) being water at basic pH of between 10.5 and 13.5, the reagent CO; a cathode (4) which comprises, on a current collector (4A) which is electrochemically inert, at least a cobalt molecular catalyst (4B) to electrochemically reduce CO into liquid methanol and the gas H2, a power supply (5) providing the energy necessary to trigger the electrochemical reactions involving the reagent.

Abstract: The present invention concerns a flow cell electrolyzer (1) to electrochemically reduce reagent gas CO2 into gaseous CO, with an anodic compartment comprising an anode (2) with a current collector, and on the current collector, at least a catalyst to electrochemically oxidize H2O to O2, an anodic electrolyte solution (3) at a controlled flow rate Qa, comprising: a solvent, and an anodic electrolyte, the solvent being water at neutral or basic pH; a cathodic compartment comprising a cathodic electrolyte solution (6), at a controlled flow rate Qc, comprising: the solvent, and a cathodic electrolyte, the solvent being water at neutral or basic pH, a gas diffusion porous cathode (9) which comprises, on a gas diffusion porous current cathode collector which is electrochemically inert, at least a molecular catalyst on a surface S to electrochemically reduce CO2 into CO, with a by-production of H2, the molecular catalyst being chosen between the list with the metal chosen among: Iron, Cobalt: metal porphyrin with on

Abstract: The present invention describes an electrochemical system (1) to electrochemically reduce carbon monoxide (CO) into liquid methanol and gaseous H2, comprising an electrochemical cell with an anodic compartment with an anode (2) with a current collector (2A), at least a catalyst to electrochemically oxidize H2O, and a cathodic compartment with a cathodic electrolyte solution comprising the solvent (3), and a cathodic supporting electrolyte, the solvent (3) being water at basic pH of between 10.5 and 13.5, the reagent CO; a cathode (4) which comprises, on a current collector (4A) which is electrochemically inert, at least a cobalt molecular catalyst (4B) to electrochemically reduce CO into liquid methanol and the gas H2, a power supply (5) providing the energy necessary to trigger the electrochemical reactions involving the reagent.

Abstract: Method and photo-electrochemical system using Cu(In,Ga)Se2 CIGS for reducing electrochemically CO2 into CO using as catalyst a metal complex with quaterpyridine ligand, the electrochemical cell comprising a cathode, an anode, a cathodic electrolyte comprising water as the solvent, and a power supply providing the energy necessary to trigger the electrochemical reactions.

Abstract: A method of maintaining a desired level of a dispersed liquid within an occupiable semi-enclosed space is provided. The method includes: providing a liquid diffusion appliance including a liquid to be dispersed; operating the liquid diffusion appliance to disperse the liquid into the occupiable semi-enclosed space throughout a treatment period in which the occupiable space is subjected to entry and exit of occupants to and from the occupiable semi-enclosed space; sensing the concentration of one or more chemical components of the dispersed liquid within the occupiable semi-enclosed space; and modifying the operation of the liquid diffusion appliance based on the concentration of the one or more chemical components of the dispersed liquid within the occupiable semi-enclosed space to achieve a desired concentration.

Abstract: The present invention relates to photochemical compositions comprising: a solution comprising an organic solvent, preferably selected from dimethylformamide, acetonitrile, and mixtures thereof with water, a sacrificial electron donor; a proton donor having a pKa in acetonitrile greater than or equal to 28; a photosensitizer whose reduced state has a standard redox potential more negative than ?1.45 V vs SCE; and a metal porphyrin complex of formula (I) as defined in claim 1, useful in the production of CH4 from CO2 or CO by photochemical catalysis, to a photochemical cell comprising same and to a method for producing CH4 from CO2 or CO by photochemical catalysis using same.

Abstract: The present invention relates to the use of complexes of water soluble porphyrins of formula (I). The present invention relates to water soluble porphyrins of formula (I), wherein R1 to R11 and R1? to R8? are as defined in claim 1, their iron complexes, use thereof as catalysts for the selective electrochemical reduction of CO2 into CO, electrochemical cells comprising them, and methods for reducing electrochemically CO2 into CO using said complexes or said electrochemical cells, thereby producing CO or syngas.

Abstract: The present invention relates to photochemical compositions comprising: a solution comprising an organic solvent, preferably selected from dimethylformamide, acetonitrile, and mixtures thereof with water, a sacrificial electron donor; a proton donor having a pKa in acetonitrile greater than or equal to 28; a photosensitizer whose reduced state has a standard redox potential more negative than ?1.45V vs SCE; and a metal porphyrin complex of formula (I) as defined in claim 1, useful in the production of CH4 from CO2 or CO by photochemical catalysis, to a photochemical cell comprising same and to a method for producing CH4 from CO2 or CO by photochemical catalysis using same.

Abstract: A removable replaceable cartridge for use with a liquid diffusing device. The cartridge includes a venturi, a conduit extending to the venturi, a mixing area and an outlet path for atomizing and dispersing a liquid within the cartridge. A diffusion device including a removable replaceable cartridge received within a housing. The housing includes a source of compressed gas which is directed into the cartridge. A venturi head with a unitary body for use with a diffusion device.

Abstract: The present invention relates to porphyrins of formula (I): wherein R1 to R6, R1? to R6?, X, X? Y and Y? are as described in claim 1. The invention also relates to complexes of said porphyrins with transition metals, in particular iron, preferably as Fe(III) or Fe(0) complex, and salts thereof, use thereof as catalysts for the selective electrochemical reduction of CO2 into CO, electrochemical cells comprising said complexes, and a method for selectively reducing electrochemically CO2 into CO using said complexes.

Abstract: A removable replaceable cartridge for use with a liquid diffusing device. The cartridge includes a venturi, a conduit extending to the venturi, a mixing area and an outlet path for atomizing and dispersing a liquid within the cartridge. A diffusion device including a removable replaceable cartridge received within a housing. The housing includes a source of compressed gas which is directed into the cartridge. A venturi head with a unitary body for use with a diffusion device.

Abstract: The present invention relates to the use of complexes of water soluble porphyrins of formula (I) below wherein R1 to R10 and R1? to R10? are as defined in claim 1, with iron as catalysts for the selective electrochemical reduction of CO2 into CO, electrochemical cells comprising them, and methods for reducing electrochemically CO2 into CO using said complexes, or said electrochemical cells, thereby producing CO or syngas, in water as the solvent.

Abstract: The present invention relates to porphyrins of formula (I): wherein R1 to R6, R1? to R6?, X, X? Y and Y? are as described in claim 1. The invention also relates to complexes of said porphyrins with transition metals, in particular iron, preferably as Fe(III) or Fe(0) complex, and salts thereof, use thereof as catalysts for the selective electrochemical reduction of CO2 into CO, electrochemical cells comprising said complexes, and a method for selectively reducing electrochemically CO2 into CO using said complexes.

Abstract: A method and system of controlling operation of a diffusion appliance to treat the atmosphere within an enclosed space. The appliance may be programmed to operate according to a control scheme specifying a flow rate of liquid to a diffusion means and a periodic operation of the diffusion means. Control schemes may be associated with different volumes of spaces to be treated by the appliance. Anti-fatigue schemes may provide variation of the flow rate or periodic operation of the appliance. Initiation controls schemes may be used to start treatment of the space before the appliance is programmed to operate according to one of the control schemes.

Abstract: A removable replaceable cartridge for use with a liquid diffusing device. The cartridge includes a venturi, a conduit extending to the venturi, a mixing area and an outlet path for atomizing and dispersing a liquid within the cartridge. A diffusion device including a removable replaceable cartridge received within a housing. The housing includes a source of compressed gas which is directed into the cartridge. A venturi head with a unitary body for use with a diffusion device.

Abstract: The present invention relates to catalysts for the production of CO gas through electrochemical CO2 reduction. In particular, the present invention relates to an electrochemical cell comprising an iron porphyrin as the catalyst for the CO2 reduction into CO, a method of performing electrochemical reduction of CO2 using said electrochemical cell thereby producing CO gas, and a method of performing electrochemical reduction of CO2 using said iron porphyrin catalyst thereby producing CO gas.

Abstract: A method and system of controlling operation of a diffusion appliance to treat the atmosphere within an enclosed space. The appliance may be programmed to operate according to a control scheme specifying a flow rate of liquid to a diffusion means and a periodic operation of the diffusion means. Control schemes may be associated with different volumes of spaces to be treated by the appliance. Anti-fatigue schemes may provide variation of the flow rate or periodic operation of the appliance. Initiation controls schemes may be used to start treatment of the space before the appliance is programmed to operate according to one of the control schemes.

Abstract: The present invention relates to catalysts for the production of CO gas through electrochemical CO2 reduction. In particular, the present invention relates to an electrochemical cell comprising an iron porphyrin as the catalyst for the CO2 reduction into CO, a method of performing electrochemical reduction of CO2 using said electrochemical cell thereby producing CO gas, and a method of performing electrochemical reduction of CO2 using said iron porphyrin catalyst thereby producing CO gas.