Patents by Inventor Marcel Frick

Marcel Frick has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 7057024
    Abstract: Black-dyeing aqueous inks comprising 20 to 95% by weight of at least one dye (A), together with 5 to 80% by weight of at least one dye chosen from the group consisting of (B) and (C), based on the total weight of the dyes (A), (B) and (C) in the ink, and 1 to 40% by weight of a water-miscible organic solvent, based on the total weight of the ink, the dye (A) containing, as the colouring part of the molecule, one or more radicals of the formula (I), (II), (III) or (IV) the dye (B) containing, as the coloring part of the molecule, one or more mono- or disazo radicals containing sulfo groups or one or more radicals of the formula (V), (VI), (VII) or (VIII) and the dye (C) containing, as the coloring part of the molecule, one or more mono- or disazo radicals containing sulfo groups or one or more radicals of the abovementioned formula (V), (VI), (VII) or (VIII) and one or more radicals of the abovementioned formula (I), (II), (III) or (IV), in which (G)0-2 is 0 to 2 identical or different substituen
    Type: Grant
    Filed: January 30, 2002
    Date of Patent: June 6, 2006
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Urs Lehmann, Athanassios Tzikas, Marcel Frick
  • Patent number: 6551364
    Abstract: Dye mixtures which comprise at least one 1:2 cobalt complex dye of the formazan compound of the formula in which X is substituted or unsubstituted C1-C8alkyl, phenyl, naphthyl, furyl or thienyl, R1 and R2 independently of one another are hydrogen or substituted or unsubstituted C1-C8alkyl, phenyl or naphthyl, m is a number from 1 to 4 and the rings I, II, III and IV may be further substituted, together with at least one anthraquinone dye of the formula (2) as defined in claim 1, or together with at least one 1:2 chromium or 1:2 cobalt complex dye of two identical or different azo compounds from the group comprising the compounds of the formulae (3), (4), (5) and (6) as defined in claim 1; and novel 1:2 cobalt complex formazan dyes. The dye mixtures are particularly suitable for dyeing or printing natural and synthetic polyamide fiber materials, dyeings or prints having good fastnesses being obtained.
    Type: Grant
    Filed: February 22, 2001
    Date of Patent: April 22, 2003
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Urs Lehmann, Marcel Frick
  • Patent number: 6521032
    Abstract: Inks comprising a dye of formula (1) wherein X is hydroxy, unsubstituted or hydroxy-substituted C1-C4alkyl, vinyl or a radical —CH2—CH2—Z, wherein Z is a group removable under alkaline conditions or is C1-C24alkoxy unsubstituted or substituted in the alkyl moiety, which may further be interrupted in the alkyl moiety by oxygen; phenoxy unsubstituted or substituted in the phenyl ring; C1-C4alkylthio unsubstituted or substituted in the alkyl moiety; phenylthio unsubstituted or substituted in the phenyl ring; amino; N-mono- or N,N-di-C1-C24alkylamino unsubstituted or substituted in the alkyl moiety, which may further be interrupted in the alkyl moiety by oxygen or by a radical —NR1— in which R1 is hydrogen or unsubstituted or further substituted C1-C4alkyl; C10-C20terpeneamino; C5-C7cycloalkylamino unsubstituted or substituted in the cycloalkyl ring; phenyl- or naphthyl-amino or N—C1-C4alkyl-N-phenyl- or N—C1-C4alkyl-N-naphthyl-amino unsubstituted or su
    Type: Grant
    Filed: September 25, 2000
    Date of Patent: February 18, 2003
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Urs Lehmann, Marcel Frick
  • Publication number: 20030024435
    Abstract: Black-dyeing aqueous inks comprising
    Type: Application
    Filed: January 29, 2002
    Publication date: February 6, 2003
    Inventors: Urs Lehmann, Athanassios Tzikas, Marcel Frick
  • Patent number: 6500247
    Abstract: Black-dyeing aqueous inks having good black shades without a shade change in artificial light and outstanding lightfastness comprising 20 to 95% by weight of at least one dye (A), together with 5 to 80% by weight of at least one dye chosen from the group consisting of (B) and (C), based on the total weight of the dyes (A), (B) and (C) in the ink, and 1 to 40% by weight of a water-miscible organic solvent, based on the total weight of the ink, the dye (A) containing, as the colouring part of the molecule, one or more radicals of the formula (I), (II), (III) or (IV) the dye (B) containing, as the colouring part of the molecule, one or more mono- or disazo radicals containing sulfo groups or one or more radicals of the formula (V), (VI), (VII) or (VIII) and the dye (C) containing, as the colouring part of the molecule, one or more mono- or disazo radicals containing sulfo groups or one or more radicals of the formulae (V), (VI), (VII) or (VII) and one or more radicals of the f
    Type: Grant
    Filed: February 1, 2000
    Date of Patent: December 31, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Urs Lehmann, Althanassios Tzikas, Marcel Frick
  • Patent number: 6428582
    Abstract: Dye mixtures which comprise at least one 1:2 cobalt complex dye of the formazan compound of the formula in which X is substituted or unsubstituted C1-C8alkyl, phenyl, naphthyl, furyl or thienyl, R1 and R2 independently of one another are hydrogen or substituted or unsubstituted C1-C8alkyl, phenyl or naphthyl, m is a number from 1 to 4 and the rings I, II, III and IV may be further substituted, together with at least one anthraquinone dye of the formula (2) as defined in claim 1, or together with at least one 1:2 chromium or 1:2 cobalt complex dye of two identical or different azo compounds from the group comprising the compounds of the formulae (3), (4), (5) and (6) as defined in claim 1; and novel 1:2 cobalt complex formazan dyes. The dye mixtures are particularly suitable for dyeing or printing natural and synthetic polyamide fiber materials, dyeings or prints having good fastnesses being obtained.
    Type: Grant
    Filed: January 29, 1996
    Date of Patent: August 6, 2002
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Urs Lehmann, Marcel Frick
  • Patent number: 6281339
    Abstract: Monoazo, polyazo, metal complex azo, anthraquinone, phthalocyanine, formazan or dioxazine dyes comprising at least one structural unit of formula (1) wherein Z is C1-C24alkoxy unsubstituted or substituted in the alkyl moiety, or uninterrupted or interrupted in the alkyl moiety by oxygen; phenoxy unsubstituted or substituted in the phenyl ring; C1-C4alkylthio unsubstituted or substituted in the alkyl moiety; phenylthio unsubstituted or substituted in the phenyl ring; amino; N-mono- or N,N-di-C1-C24-alkylamino, unsubstituted or substituted in the alkyl moiety, or uninterrupted or interrupted in the alkyl moiety by oxygen or by a radical —NR1— in which R1 is hydrogen or C1-C4alkyl; C10-C20terpeneamino; C5-C7cycloalkylamino unsubstituted or substituted in the cycloalkyl ring; phenyl- or naphthyl-amino or N—C1-C4alkyl-N-phenyl- or N—C1-C4alkyl-N-naphthyl-amino, each unsubstituted or substituted in the aryl moiety; morpholino; piperazin-1-yl or piperidin-1-yl, and X is hyd
    Type: Grant
    Filed: September 13, 2000
    Date of Patent: August 28, 2001
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Urs Lehmann, Marcel Frick
  • Publication number: 20010013149
    Abstract: Process for dyeing or printing paper, films of plastic or fiber material containing hydroxyl groups or containing nitrogen with reactive dyes, which comprises using at least one reactive dye of the formula (1) from the following group a) and at least one reactive dye from the following groups b), c) and d):
    Type: Application
    Filed: January 31, 2001
    Publication date: August 16, 2001
    Inventors: Peter Scheibli, Peter Aeschlimann, Urs Lehmann, Marcel Frick
  • Publication number: 20010014733
    Abstract: Dye mixtures which comprise at least one 1:2 cobalt complex dye of the formazan compound of the formula 1
    Type: Application
    Filed: February 22, 2001
    Publication date: August 16, 2001
    Inventors: Urs Lehmann, Marcel Frick
  • Patent number: 6265554
    Abstract: Dyes of formula (1) wherein Z is C10-C20terpeneamino; or N-mono- or N,N-di-C1-C16alkylamino unsubstituted or substituted in the alkyl moiety by phenyl (which may itself be substituted by carboxy, carbamoyl, sulfo or by sulfamoyl), amino, C2-C4alkanoylamino, hydroxy, sulfo, sulfato, carboxy, carbamoyl or by sulfamoyl, which further may be interrupted in the alkyl moiety by one, two or three oxygen atoms or —NH— groups, yield bluish magenta prints and dyeings having good light-fastness properties and a high colour brilliance.
    Type: Grant
    Filed: September 25, 2000
    Date of Patent: July 24, 2001
    Assignee: Ciba Specialty Chemicals Corp.
    Inventors: Urs Lehmann, Marcel Frick
  • Patent number: 6241789
    Abstract: Process for dyeing or printing paper, films of plastic or fibre material containing hydroxyl groups or containing nitrogen with reactive dyes, which comprises using at least one reactive dye of the formula (1) from the following group a) and at least one reactive dye from the following groups b), c) and d): a) green- or blue-dyeing reactive dyes of the formula (1) b) blue-dyeing reactive dyes of the formula (2) or (3) c) red-dyeing reactive dyes of the formula (4) d) yellow- or orange-dyeing reactive dyes of the formula (5)
    Type: Grant
    Filed: April 3, 2000
    Date of Patent: June 5, 2001
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Peter Scheibli, Peter Aeschilmann, Urs Lehmann, Marcel Frick
  • Patent number: 6063137
    Abstract: Process for dyeing or printing paper, films of plastic or fibre material containing hydroxyl groups or containing nitrogen with reactive dyes, which comprises using at least one reactive dye of the formula (1) from the following group a) and at least one reactive dye from the following groups b), c) and d):a) green- or blue-dyeing reactive dyes of the formula (1) ##STR1## b) blue-dyeing reactive dyes of the formula (2) or (3) ##STR2## c) red-dyeing reactive dyes of the formula (4) ##STR3## d) yellow- or orange-dyeing reactive dyes of the formula (5) ##STR4##
    Type: Grant
    Filed: December 8, 1998
    Date of Patent: May 16, 2000
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Peter Scheibli, Peter Aeschlimann, Urs Lehmann, Marcel Frick
  • Patent number: 5973147
    Abstract: Process for dichromatic or trichromatic dyeing or printing of natural or synthetic polyamide fibre material, which comprises using at least one blue-dyeing fibre-reactive anthraquinone dye of the formula ##STR1## in which R.sub.1 and R.sub.2 independently of one another are hydrogen or substituted or unsubstitutedC.sub.1 -C.sub.12 alkyl,X.sub.1 is halogen,B.sub.1 is an organic bridge member andV.sub.1 is an aliphatic or aromatic amine containing a fibre-reactive group,together with at least one fibre-reactive sulfo group containing yellow- or orange-dyeing dye ortogether with at least one fibre-reactive sulfo group containing red-dyeing dye. Level dyeings with good fastness properties are obtained.
    Type: Grant
    Filed: May 8, 1998
    Date of Patent: October 26, 1999
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Urs Lehmann, Marcel Frick, Klaus Hannemann
  • Patent number: 5944855
    Abstract: Process for dichromatic or trichromatic dyeing or printing of natural or synthetic polyamide fiber material, which comprises using at least one blue-dyeing fiber-reactive anthraquinone dye of the formula in which R.sub.1 and R.sub.2 independently of one another are hydrogen or substituted or unsubstituted C.sub.1 -C.sub.12 alkyl, X.sub.1 is halogen, B.sub.1 is an organic bridge member and V.sub.1 is an aliphatic or aromatic amine containing a fibre-reactive group, together with at least one fiber-reactive sulfo group containing yellow- or orange-dyeing dye or together with at least one fiber-reactive sulfo group containing red-dyeing dye. Level dyeings with good fastness properties are obtained.
    Type: Grant
    Filed: May 8, 1998
    Date of Patent: August 31, 1999
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Urs Lehmann, Marcel Frick, Klaus Hannemann
  • Patent number: 5779740
    Abstract: Process for dichromatic or trichromatic dyeing or printing of natural or synthetic polyamide fibre material, which comprises using at least one blue-dyeing fibre-reactive anthraquinone dye of the formula ##STR1## in which R.sub.1 and R.sub.2 independently of one another are hydrogen or substituted or unsubstituted C.sub.1 -C.sub.12 alkyl,X.sub.1 is halogen,B.sub.1 is an organic bridge member andV.sub.1 is an aliphatic or aromatic amine containing a fibre-reactive group, together with at least one fibre-reactive sulfo group containing yellow- or orange-dyeing dye or together with at least one fibre-reactive sulfo group containing red-dyeing dye. Level dyeings with good fastness properties are obtained.
    Type: Grant
    Filed: November 19, 1996
    Date of Patent: July 14, 1998
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Urs Lehmann, Marcel Frick, Klaus Hannemann
  • Patent number: 5760195
    Abstract: Reactive dyes of the formula ##STR1## wherein D is a radical of the formula ##STR2## and R.sub.1, R.sub.2, R.sub.3, X.sub.1 and V.sub.1 are as defined in claim 1, are particularly suitable for dyeing or printing natural or synthetic polyamide fibre materials.
    Type: Grant
    Filed: November 19, 1996
    Date of Patent: June 2, 1998
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Urs Lehmann, Marcel Frick
  • Patent number: 5760194
    Abstract: Reactive dyes of the formula ##STR1## in which D is a radical of the formula ##STR2## are particularly suitable for dyeing or printing natural or synthetic polyamide fibre materials.
    Type: Grant
    Filed: November 19, 1996
    Date of Patent: June 2, 1998
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Urs Lehmann, Marcel Frick
  • Patent number: 5667534
    Abstract: Dye mixtures which comprise at least one 1:2 chromium complex dye of the formula (1) ##STR1## together with at least one 1:2 chromium or 1:2 cobalt complex dye of two identical or two different azo compounds from the group consisting of compounds of the formulae (2), (3) and (4) or together with at least one 1:2 cobalt complex dye of the formazan compound of the formula (5) or together with at least one anthraquinone dye of the formula (6). The dyes of formulae (1) are defined herein.
    Type: Grant
    Filed: December 20, 1995
    Date of Patent: September 16, 1997
    Assignee: Ciba-Geigy Corporation
    Inventors: Urs Lehmann, Marcel Frick
  • Patent number: 5504227
    Abstract: Anthraquinone dyes of formula ##STR1## wherein R.sub.2 and R.sub.2 are each independently of the other hydrogen or C.sub.1 -C.sub.4 alkyl,X is a C.sub.2 -C.sub.22 alkylene radical which is interrupted by 1, 2 or 3 members selected from the group consisting of --NH--, --N(CH.sub.3)-- or --O-- and which is unsubstituted or substituted by hydroxyl, sulfo or sulfato; ora C.sub.1 -C.sub.4 alkylene-phenylene-C.sub.1 -C.sub.4 alkylene radical which is unsubstituted or substituted in the phenylene ring by C.sub.1 -C.sub.4 alkyl, C.sub.1 -C.sub.4 alkoxy, C.sub.2 -C.sub.
    Type: Grant
    Filed: March 8, 1995
    Date of Patent: April 2, 1996
    Assignee: Ciba-Geigy Corporation
    Inventors: Urs Lehmann, Marcel Frick