Abstract: Disclosed herein is a multifunctional catalyst system comprising a substrate; and a catalyst pair disposed upon the substrate; wherein the catalyst pair comprises a first catalyst and a second catalyst; and wherein the first catalyst initiates or facilitates the reduction of carbon dioxide to carbon monoxide while the second catalyst initiates or facilitates the conversion of carbon monoxide to an organic compound. Disclosed herein is a method comprising reducing carbon dioxide to carbon monoxide in a first reaction catalyzed by a first catalyst; and reacting carbon monoxide with hydrogen in a second reaction catalyzed by second catalyst; wherein the first catalyst and the second catalyst are disposed upon a single substrate.

Abstract: An article comprises a textured surface disposed on a substrate. The surface has an effective liquid wettability sufficient to generate, with a reference liquid, a contact angle in a range from about 120° to about 180°. The surface comprises a material having a nominal liquid wettability sufficient to generate, with the reference liquid, a nominal contact angle in a range from about 60° to about 90°, the material comprising at least one material selected from the group consisting of a polymer and a ceramic. The properties of the surface may include low-drag or low-friction, self-cleaning capability, and resistance to icing, fouling, and fogging, and the like. Methods of making such a surface are also described.