Patents by Inventor Mari S. Rosen

Mari S. Rosen has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11896965
    Abstract: The invention relates to oligomerization of olefins, such as ethylene, to higher olefins, such as a mixture of 1-hexene and 1-octene, using a catalyst system that comprises a) a source of chromium b) one or more activators and c) a phosphacycle-containing ligating compound. Additionally, the invention relates to a phosphacycle-containing ligating compound and a process for making said compound.
    Type: Grant
    Filed: October 14, 2022
    Date of Patent: February 13, 2024
    Assignee: Dow Global Technologies LLC
    Inventors: Jerzy Klosin, Kara A. Milbrandt, Scott D. Boelter, David R. Wilson, Mari S. Rosen, Dean M. Welsh, Peter M. Margl, Kyoung Moo Koh, David M. Pearson, Rafael Huacuja
  • Publication number: 20240034830
    Abstract: Polyurethanes are made by curing a reaction mixture containing a polyether polyol that contains residues of a zinc hexacyanocobaltate catalyst complex. The reaction mixture contains certain chelating agents in small quantities. The amount of cobalt that is extractable from the polyurethane is reduced.
    Type: Application
    Filed: July 12, 2021
    Publication date: February 1, 2024
    Inventors: Adam L. Grzesiak, Jacob W. Strother, Nolan T. McDougal, Richard J. Keaton, David S. Laitar, Mari S. Rosen, Kaoru Aou, Thomas P. Willumstad
  • Publication number: 20230356207
    Abstract: Embodiments relate to a method of producing a modified double metal cyanide complex, a method of producing a monol or polyol that includes providing the modified double metal cyanide complex, an alkylene oxide polymerization process that includes providing the modified double metal cyanide complex, a batch, semi-batch, or continuous manufacturing process that includes providing the modified double metal cyanide complex, and a polyether polyol prepared using the batch, semi-batch, or continuous manufacturing process that includes providing the modified double metal cyanide complex.
    Type: Application
    Filed: July 17, 2023
    Publication date: November 9, 2023
    Inventors: David K. Steelman, David A. Babb, Joost Depicker, Jasmijn Kuijper, Mari S. Rosen
  • Publication number: 20230322968
    Abstract: Embodiments of the present application are directed to procatalysts, and catalyst systems including procatalysts, including a metal-ligand complex having the structure of formula (I): [Formula I]
    Type: Application
    Filed: May 28, 2021
    Publication date: October 12, 2023
    Applicant: Dow Global Technologies LLC
    Inventors: Rhett A. Baillie, Hien Q. Do, Andrew M. Camelio, Johnathan E. Delorbe, Mari S. Rosen, Philip P. Fontaine, David M. Pearson
  • Patent number: 11745174
    Abstract: Embodiments relate to a method of producing a modified double metal cyanide complex, a method of producing a monol or polyol that includes providing the modified double metal cyanide complex, an alkylene oxide polymerization process that includes providing the modified double metal cyanide complex, a batch, semi-batch, or continuous manufacturing process that includes providing the modified double metal cyanide complex, and a polyether polyol prepared using the batch, semi-batch, or continuous manufacturing process that includes providing the modified double metal cyanide complex.
    Type: Grant
    Filed: May 10, 2018
    Date of Patent: September 5, 2023
    Assignee: Dow Global Technologies LLC
    Inventors: David K. Steelman, David A. Babb, Joost Depicker, Jasmijn Kuijper, Mari S. Rosen
  • Publication number: 20230250202
    Abstract: Embodiments of the present application are directed to procatalysts, and catalyst systems including procatalysts, including a metal-ligand complex having the structure of formula (I):
    Type: Application
    Filed: May 28, 2021
    Publication date: August 10, 2023
    Applicant: Dow Global Technologies LLC
    Inventors: Rhett A. Baillie, Johnathan E. Delorbe, Andrew M. Camelio, Hien Q. Do, Philip P. Fontaine, David M. Pearson, Mari S. Rosen, Brad C. Bailey
  • Publication number: 20230203216
    Abstract: Embodiments of the present application are directed to procatalysts, and catalyst systems including procatalysts, including a metal-ligand complex having the structure of formula (I): [Formula I].
    Type: Application
    Filed: May 28, 2021
    Publication date: June 29, 2023
    Applicant: Dow Global Technologies LLC
    Inventors: Rhett A. Baillie, David M. Pearson, Hien Q. Do, Johnathan E. DeLorbe, Philip P. Fontaine, Mari S. Rosen, Andrew M. Camelio
  • Publication number: 20230112954
    Abstract: The invention relates to oligomerization of olefins, such as ethylene, to higher olefins, such as a mixture of 1-hexene and 1-octene, using a catalyst system that comprises a) a source of chromium b) one or more activators and c) a phosphacycle-containing ligating compound. Additionally, the invention relates to a phosphacycle-containing ligating compound and a process for making said compound.
    Type: Application
    Filed: October 14, 2022
    Publication date: April 13, 2023
    Applicant: Dow Global Technologies LLC
    Inventors: Jerzy Klosin, Kara A. Milbrandt, Scott D. Boelter, David R. Wilson, Mari S. Rosen, Dean M. Welsh, Peter M. Margl, Kyoung Moo Koh, David M. Pearson, Rafael Huacuja
  • Patent number: 11623209
    Abstract: The invention relates to oligomerization of olefins, such as ethylene, to higher olefins, such as a mixture of 1-hexene and 1-octene, using a catalyst system that comprises a) a source of chromium b) one or more activators and c) a phosphacycle-containing ligating compound. Additionally, the invention relates to a phosphacycle-containing ligating compound and a process for making said compound.
    Type: Grant
    Filed: February 11, 2022
    Date of Patent: April 11, 2023
    Assignee: Dow Global Technologies LLC
    Inventors: Jerzy Klosin, Kara A. Milbrandt, Scott D. Boelter, David R. Wilson, Mari S. Rosen, Dean M. Welsh, Peter M. Margl, Kyoung Moo Koh, David M. Pearson, Rafael Huacuja
  • Publication number: 20230095201
    Abstract: Polyethers are prepared by polymerizing an alkylene oxide in the presence of a starter, an aluminum compound that has at least one hydrocarbyl substituent, and a cyclic amidine. The phosphorus-nitrogen base is present in only a small molar ratio relative to the amount of starter. The presence of such small amounts of cyclic amidine greatly increases the catalytic activity of the system, compared to the case in which the aluminum compound is used by itself. The product polyethers have low amounts of unsaturated polyether impurities and little or no unwanted high molecular weight fraction. Polymers of propylene oxide have very low proportions of primary hydroxyl groups.
    Type: Application
    Filed: January 27, 2021
    Publication date: March 30, 2023
    Inventors: Anne-Catherine Bédard, Matthew E. Belowich, Mari S. Rosen, Sandra Varinia Bernales Candia, David A. Babb, Clark H. Cummins, Richard J. Keaton, Matthew M. Yonkey
  • Publication number: 20230092304
    Abstract: Polyethers are prepared by polymerizing an alkylene oxide in the presence of a starter, an aluminum compound that has at least one hydrocarbyl substituent, and a phosphorus-nitrogen base. The phosphorus-nitrogen base is present in only a small molar ratio relative to the amount of starter. The presence of such small amounts of phosphorus-nitrogen base greatly increases the catalytic activity of the system, compared to the case in which the aluminum compound is used by itself. The product polyethers have low amounts of unsaturated polyether impurities and little or no unwanted high molecular weight fraction. Polymers of propylene oxide have very low proportions of primary hydroxyl groups.
    Type: Application
    Filed: January 27, 2021
    Publication date: March 23, 2023
    Inventors: Anne-Catherine Bédard, Matthew E. Belowich, Mari S. Rosen, Sandra Varinia Bernales Candia, David A. Babb, Clark H. Cummins, Richard J. Keaton, Matthew M. Yonkey, Peter J. Waller
  • Patent number: 11571690
    Abstract: Embodiments relate to a method of producing a modified double metal cyanide complex, a method of producing a monol or polyol that includes providing the modified double metal cyanide complex, an alkylene oxide polymerization process that includes providing the modified double metal cyanide complex, a batch, semi-batch, or continuous manufacturing process that includes providing the modified double metal cyanide complex, and a polyether polyol prepared using the batch, semi-batch, or continuous manufacturing process that includes providing the modified double metal cyanide complex.
    Type: Grant
    Filed: May 10, 2018
    Date of Patent: February 7, 2023
    Assignee: Dow Global Technologies LLC
    Inventors: David K. Steelman, David A. Babb, Joost Depicker, Jasmijn Kuijper, Mari S. Rosen
  • Publication number: 20220403061
    Abstract: Embodiments are directed towards the use of a supported biphenylphenol polymerization catalyst made from a biphenylphenol polymerization precatalyst of Formula I via a gas-phase or slurry-phase polymerization process under gas-phase or slurry-phase polymerization conditions to make a polymer.
    Type: Application
    Filed: November 4, 2020
    Publication date: December 22, 2022
    Applicant: Dow Global Technologies LLC
    Inventors: Angela I. Padilla-Acevedo, Andrew J. Young, Roger L. Kuhlman, Ruth Figueroa, Susan Brown, Matthew E. Belowich, David R. Neithamer, Jerzy Klosin, David M. Pearson, Mari S. Rosen, Bethany M. Neilson, Johnathan E. DeLorbe, Leslie E. O'Leary
  • Patent number: 11491474
    Abstract: The invention relates to oligomerization of olefins, such as ethylene, to higher olefins, such as a mixture of 1-hexene and 1-octene, using a catalyst system that comprises a) a source of chromium b) one or more activators and c) a phosphacycle-containing ligating compound. Additionally, the invention relates to a phosphacycle-containing ligating compound and a process for making said compound.
    Type: Grant
    Filed: April 16, 2021
    Date of Patent: November 8, 2022
    Assignee: Dow Global Technologies LLC
    Inventors: Jerzy Klosin, Kara A. Milbrandt, Scott D. Boelter, David R. Wilson, Mari S. Rosen, Dean M. Welsh, Peter M. Margl, Kyoung Moo Koh, David M. Pearson, Rafael Huacuja
  • Publication number: 20220176363
    Abstract: The invention relates to oligomerization of olefins, such as ethylene, to higher olefins, such as a mixture of 1-hexene and 1-octene, using a catalyst system that comprises a) a source of chromium b) one or more activators and c) a phosphacycle-containing ligating compound. Additionally, the invention relates to a phosphacycle-containing ligating compound and a process for making said compound.
    Type: Application
    Filed: February 11, 2022
    Publication date: June 9, 2022
    Applicant: Dow Global Technologies LLC
    Inventors: Jerzy Klosin, Kara A. Milbrandt, Scott D. Boelter, David R. Wilson, Mari S. Rosen, Dean M. Welsh, Peter M. Margl, Kyoung Moo Koh, David M. Pearson, Rafael Huacuja
  • Patent number: 11260381
    Abstract: The invention relates to oligomerization of olefins, such as ethylene, to higher olefins, such as a mixture of 1-hexene and 1-octene, using a catalyst system that comprises a) a source of chromium b) one or more activators and c) a phosphacycle-containing ligating compound. Additionally, the invention relates to a phosphacycle-containing ligating compound and a process for making said compound.
    Type: Grant
    Filed: December 3, 2020
    Date of Patent: March 1, 2022
    Assignee: Dow Global Technologies LLC
    Inventors: Jerzy Klosin, Kara A. Milbrandt, Scott D. Boelter, David R. Wilson, Mari S. Rosen, Dean M. Welsh, Peter M. Margl, Kyoung Moo Koh, David M. Pearson, Rafael Huacuja
  • Publication number: 20210268487
    Abstract: The invention relates to oligomerization of olefins, such as ethylene, to higher olefins, such as a mixture of 1-hexene and 1-octene, using a catalyst system that comprises a) a source of chromium b) one or more activators and c) a phosphacycle-containing ligating compound. Additionally, the invention relates to a phosphacycle-containing ligating compound and a process for making said compound.
    Type: Application
    Filed: April 16, 2021
    Publication date: September 2, 2021
    Applicant: Dow Global Technologies LLC
    Inventors: Jerzy Klosin, Kara A. Milbrandt, Scott D. Boelter, David R. Wilson, Mari S. Rosen, Dean M. Welsh, Peter M. Margl, Kyoung Moo Koh, David M. Pearson, Rafael Huacuja
  • Patent number: 11066489
    Abstract: Embodiments are directed to a catalyst system comprising metal ligand complexes and processes for polyolefin polymerization using the metal ligand complex having the following structure: where each X is selected from the group consisting of —(CH2)SiRX3.
    Type: Grant
    Filed: September 19, 2018
    Date of Patent: July 20, 2021
    Assignee: Dow Global Technologies LLC
    Inventors: Arkady L. Krasovskiy, David R. Wilson, Bryan D. Stubbert, Tulaza Vaidya, Jerzy Klosin, Edmund M. Carnahan, Philip P. Fontaine, Mari S. Rosen
  • Patent number: 11066428
    Abstract: Embodiments are directed to a catalyst system comprising metal-ligand complexes and processes for polyolefin polymerization using the metal-ligand complex having the following structure, Formula (I), where X is selected from the group consisting of —(CH2)SiRX3.
    Type: Grant
    Filed: September 20, 2018
    Date of Patent: July 20, 2021
    Assignee: Dow Global Technologies LLC
    Inventors: Bryan D. Stubbert, Arkady L. Krasovskiy, Tulaza Vaidya, Jerzy Klosin, Edmund M. Carnahan, Philip P. Fontaine, Mari S. Rosen, David R. Wilson
  • Publication number: 20210198425
    Abstract: Embodiments relate to a method of producing a modified double metal cyanide complex, a method of producing a monol or polyol that includes providing the modified double metal cyanide complex, an alkylene oxide polymerization process that includes providing the modified double metal cyanide complex, a batch, semi-batch, or continuous manufacturing process that includes providing the modified double metal cyanide complex, and a polyether polyol prepared using the batch, semi-batch, or continuous manufacturing process that includes providing the modified double metal cyanide complex.
    Type: Application
    Filed: May 10, 2018
    Publication date: July 1, 2021
    Inventors: David K. Steelman, David A. Babb, Joost Depicker, Jasmijn Kuijper, Mari S. Rosen