Patents by Inventor Mario Fryberg
Mario Fryberg has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 7235284Abstract: There is described a recording sheet for ink jet printing comprising a polyethylene coated paper support having coated onto the front side of said support one ink receiving layer comprising a mixture of gelatin and rice starch.Type: GrantFiled: March 18, 1998Date of Patent: June 26, 2007Assignee: Ilford Imaging Switzerland GmbHInventors: Mario Fryberg, Stefan Schuttel, Hiroshi Tomimasu
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Patent number: 5916673Abstract: A recording sheet for ink jet printing comprising a support having coated onto said support one or more layers receptive for aqueous inks, said coating comprising at least one film forming, hydrophilic polymer or a mixture of film forming hydrophilic polymers and imbedded in this film at least one trivalent salt of a metal of the Group IIIb series of the periodic table of elements or complexes which comprise trivalent ions of the metals of Group IIIb of the periodic table of the elements. In another embodiment the salts or complexes of Group IIIb elements are coated directly on the substrate surface without the presence of the film forming polymer.Type: GrantFiled: July 31, 1997Date of Patent: June 29, 1999Assignee: Ilford AGInventors: Mario Fryberg, Roland Kurzen, Klaus Haarmann, Diane L. Blednick, Daniel R. Rogers
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Patent number: 5702866Abstract: This subject invention relates to novel dihydrazide compounds useful as dot-promoting agents in photographic image systems, methods for making them, and to photographic materials which comprise these compounds.Type: GrantFiled: October 24, 1996Date of Patent: December 30, 1997Assignee: Ilford A.G.Inventors: Mario Fryberg, Otto Gottel, Thomas Stauner
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Patent number: 5686222Abstract: This subject invention relates to novel dihydrazide compounds useful as dot-promoting agents in photographic image systems, methods for making them, and to photographic materials which comprise these compounds.Type: GrantFiled: December 6, 1996Date of Patent: November 11, 1997Assignee: Ilford A.G.Inventors: Mario Fryberg, Otto Gottel, Thomas Stauner
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Patent number: 4576885Abstract: A photographic silver dye bleach material which contains a compound of the formula ##STR1## in which R is a substituted alkyl, R.sub.1 is substituted or unsubstituted alkyl, p is 1 or 2, q is 0 or 1, p+q having to be 1 or 2, and n is 1 to 20, or a salt of this compound.The benzoquinones used deactivate bleach catalysts which diffuse beyond the silver image area produced by development of the exposed material. The silver dye bleach material containing these compounds is therefore distinguished by high contrast, high sharpness and good color reproduction.Type: GrantFiled: January 16, 1984Date of Patent: March 18, 1986Assignee: Ciba-Geigy AGInventors: Mario Fryberg, Heinrich Schaller, Rolf Steiger, Heinz Peter
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Patent number: 4568752Abstract: Recording material for color photography, which contains, in at least one silver halide emulsion layer, at least one yellow coupler of the formula ##STR1## in which R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are alkyl, cycloalkyl or aryl, X.sub.1, X.sub.2, X.sub.3 and X.sub.4 are radicals detachable during the coupling reaction and Y.sub.1 and Y.sub.2 are halogen, alkyl, alkoxy, alkylmercapto, --CN, --COOH, carbalkoxy, --NH.sub.2, --NHR.sub.5, --NR.sub.5 R.sub.6 or --NHCOR.sub.5, in which R.sub.5 and R.sub.6 are alkyl or phenyl, Z is a divalent bridge member and r is 1 or 2.Photographic colored images with excellent spectral absorption characteristics and good resistance to light, heat and moisture are obtained by exposing the recording material image-wise and developing.Type: GrantFiled: December 10, 1984Date of Patent: February 4, 1986Assignee: Ciba-Geigy AGInventor: Mario Fryberg
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Patent number: 4471048Abstract: Compounds of the formula ##STR1## in which R.sub.1, R.sub.2 and R.sub.3 independently of one another are hydrogen, alkyl or alkoxy and R.sub.2 additionally represents a radical of the formula ##STR2## in which R.sub.1 and R.sub.3 have the abovementioned meanings, R.sub.4 is unsubstituted or substituted phenoxy or unsubstituted or substituted amino and R.sub.5 is hydrogen or a radical of the formula ##STR3## in which R.sub.1, R.sub.3 and R.sub.4 have the abovementioned meanings and R.sub.2 ' has the same meanings as R.sub.1 and R.sub.3 are suitable development accelerators in the development of exposed, photographic materials containing silver halide.They accelerate the reduction of the exposed silver salt to silver and increase the speed of photographic material.Type: GrantFiled: August 24, 1983Date of Patent: September 11, 1984Assignee: Ciba Geigy AGInventors: Mario Fryberg, Viktor Weiss
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Patent number: 4465763Abstract: A process for the production of photographic color images by the silver dye bleach process, by exposure, silver development, dye formation, dye bleach, silver bleach and fixing of a photographic material which, in a light-sensitive silver halide emulsion layer or in an adjacent layer, contains, dispersed in oil, an oil-soluble triazene of the formula ##STR1## and an oil-soluble coupling component of the formula ##STR2## in which Ar.sub.1 is aryl or an aromatic heterocyclic radical, R.sub.1 is hydrogen, alkyl, aryl, hydroxyl, --(CH.sub.2 CH.sub.2 O).sub.r --L.sub.1 or --OL.sub.1, in which L.sub.1 is alkyl and r is 1, 2 or 3, or R.sub.1 is ##STR3## in which V is hydrogen or alkyl, and R.sub.2 is alkyl, aryl or --(CH.sub.2 CH.sub.2 O).sub.r --L.sub.1, or R.sub.1 and R.sub.2, conjointly with the nitrogen atom to which they are bonded, form a ring, A.sub.1 and A.sub.2 independently of one another are an amine of the formula --NT.sub.1 T.sub.2, in which T.sub.1 and T.sub.Type: GrantFiled: May 4, 1983Date of Patent: August 14, 1984Assignee: Ciba Geigy AGInventors: Eddy Forte, Mario Fryberg, Gerald Jan
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Patent number: 4436811Abstract: Compounds of the formula ##STR1## in which R.sub.1, R.sub.2 and R.sub.3 independently of one another are hydrogen, alkyl or alkoxy and R.sub.2 additionally represents a radical of the formula ##STR2## in which R.sub.1 and R.sub.3 have the abovementioned meanings, R.sub.4 is unsubstituted or substituted phenoxy or unsubstituted or substituted amino and R.sub.5 is hydrogen or a radical of the formula ##STR3## in which R.sub.1, R.sub.3 and R.sub.4 have the abovementioned meanings and R.sub.2 ' has the same meanings as R.sub.1 and R.sub.3 are suitable development accelerators in the development of exposed, photographic materials containing silver halide.They accelerate the reduction of the exposed silver salt to silver and increase the speed of photographic material.Type: GrantFiled: June 22, 1982Date of Patent: March 13, 1984Assignee: Ciba-Geigy AGInventors: Mario Fryberg, Viktor Weiss
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Patent number: 4407935Abstract: The compounds of the formula ##STR1## in which R is amino, cyclic amino, aryloxy or a group of the formula ##STR2## in which L is a radical of the formula .dbd.N-Z, with Z being alkyl or cycloalkyl, or is a heterocyclic radical, aryleneoxy or oxyaryleneoxy and R' and R" are hydrogen, alkyl or halogen, and x and y are 0, 1, 2 or 3, are suitable development accelerators for the development of exposed photographic materials containing silver halide. They accelerate the reduction of the exposed silver salt to silver and thus enhance the sensitivity of the photographic material.Type: GrantFiled: January 15, 1982Date of Patent: October 4, 1983Assignee: Ciba-Geigy AGInventors: Mario Fryberg, David G. Leppard
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Patent number: 4404273Abstract: A process for the production of photographic color images by the silver dye bleach process, by exposure, silver development, dye formation, dye bleach, silver bleach and fixing of a photographic material which, in a light-sensitive silver halide emulsion layer or in an adjacent layer, contains, dispersed in oil, an oil-soluble triazene of the formula ##STR1## and an oil-soluble coupling component of the formula ##STR2## in which Ar.sub.1 is aryl or an aromatic heterocyclic radical, R.sub.1 is hydrogen, alkyl, aryl, hydroxyl, --(CH.sub.2 CH.sub.2 O).sub.r --L.sub.1 or --OL.sub.1, in which L.sub.1 is alkyl and r is 1, 2 or 3, or R.sub.1 is ##STR3## in which V is hydrogen or alkyl, and R.sub.2 is alkyl, aryl or --(CH.sub.2 CH.sub.2 O).sub.r --L.sub.1, or R.sub.1 and R.sub.2, conjointly with the nitrogen atom to which they are bonded, form a ring, A.sub.1 and A.sub.2 independently of one another are an amine of the formula --NT.sub.1 T.sub.2, in which T.sub.1 and T.sub.Type: GrantFiled: December 2, 1981Date of Patent: September 13, 1983Assignee: Ciba-Geigy AGInventors: Eddy Forte, Mario Fryberg, Gerald Jan
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Patent number: 4379819Abstract: A color-photographic recording material for the silver dye bleach process, which contains oil-soluble azo dyes of the formula ##STR1## in which R.sub.1 is hydrogen, alkyl, alkoxy, alkenyl, acyl, carbalkoxy, acylamino, carbamide, sulfonamide, alkylsulfone, arylsulfone, aryloxy, arylsulfonic acid ester, hydroxyl, cyano, nitro or halogen, R.sub.2 is hydrogen, alkyl, alkoxy, carbalkoxy, carbamide, sulfonamide, alkylsulfone, arylsulfone, aryloxy, cyano, nitro or halogen, R.sub.3 is hydrogen, alkyl, alkoxy, phenoxy, sulfonamide, alkylsulfone, sulfonic acid ester, cyano, nitro, halogen, carbalkoxy, carbamide or phosphoric acid diester, R.sub.4 is hydrogen, alkyl, alkoxy, carbalkoxy, carbamide, sulfonamide, acylamino, alkylsulfone, arylsulfone, hydroxyl, cyano, nitro or halogen, R.sub.5 is hydrogen, alkyl or carbalkoxy, X.sub.1 is hydrogen, alkyl, alkoxy, acylamino, alkylsulfonamide or hydroxyl, Y.sub.Type: GrantFiled: April 28, 1981Date of Patent: April 12, 1983Assignee: Ciba-Geigy AGInventors: John Lenoir, Gerald Jan, Mario Fryberg
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Patent number: 4359521Abstract: Light-sensitive color photographic material which contains on a base in at least one silver halide emulsion layer or an interlayer which is assigned to this and does not contain silver halide, at least one DIR coupler of the formula ##STR1## in which R is alkyl having 1 to 18 carbons atoms or aryl, D is hydrogen, optionally substituted alkyl having 1 to 18 carbon atoms, cycloalkyl having 3 to 10 carbon atoms, alkenyl having 2 to 18 carbon atoms, cycloalkenyl having 5 to 10 carbon atoms, aralkyl having 7 to 18 carbon atoms, cyano or halogen and G is a optionally substituted aliphatic hydrocarbon radical having 1 to 18 carbon atoms, the sum of the carbon atoms in the substituents D and G being at least 5, L.sub.1 is hydrogen or alkyl having 1 to 5 carbon atoms, L.sub.Type: GrantFiled: December 19, 1979Date of Patent: November 16, 1982Assignee: Ciba-Geigy AGInventors: Mario Fryberg, Remon Hagen, John G. V. Scott
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Patent number: 4248961Abstract: Light-sensitive recording material for color photography is provided which contains, in at least one silver halide emulsion layer, a yellow coupler of the formula ##STR1## in which R and R' are alkyl, cycloalkyl or aryl and X.sub.1 and X.sub.2 are radicals which are detachable during the coupling reaction, Y is halogen, alkyl, alkoxy, alkylmercapto, --CN, --COOH, carbalkoxy, --NH.sub.2, --NHR.sub.1, --NR.sub.1 R.sub.2 or --NHCOR.sub.1, in which R.sub.1 and R.sub.2 are alkyl or phenyl, Z is alkyl having 5 to 40 carbon atoms, alkoxy having 5 to 40 carbon atoms, cycloalkoxy having 5 to 12 carbon atoms or aralkyl; alkoxyalkyl, alkoxycycloalkyl, cycloalkoxyalkyl, optionally substituted phenoxyalkyl, alkylamino- and dialkylamino-alkyl, optionally substituted arylamino- and diarylamino-alkyl, alkylmercaptoalkyl or optionally substituted arylmercaptoalkyl, in which radicals the sum of the carbon atoms in each case is 6 to 40; or --COOR.sub.3, --COR.sub.3, --NR.sub.3 R.sub.4, --CONR.sub.3 R.sub.4, --NR.sub.4 COR.sub.Type: GrantFiled: May 2, 1979Date of Patent: February 3, 1981Assignee: Ciba-Geigy AGInventors: Remon Hagen, Mario Fryberg
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Patent number: 4238564Abstract: Recording material for color photography, which contains, in at least one silver halide emulsion layer, at least one yellow coupler of the formula ##STR1## in which R.sub.1, R.sub.2, and R.sub.3 and R.sub.4 are alkyl, cycloalkyl or aryl, X.sub.1, X.sub.2, X.sub.3 and X.sub.4 are radicals detachable during the coupling reaction and Y.sub.1 and Y.sub.2 are halogen, alkyl, alkoxy, alkylmercapto, --CN, --COOH, carbalkoxy, --NH.sub.2, --NHR.sub.5, --NR.sub.5 R.sub.6 or --NHCOR.sub.5, in which R.sub.5 and R.sub.6 are alkyl or phenyl, Z is a divalent bridge member and r is 1 or 2.Photographic colored images with excellent spectral absorption characteristics and good resistance to light, heat and moisture are obtained by exposing the recording material image-wise and developing.Type: GrantFiled: June 11, 1979Date of Patent: December 9, 1980Assignee: Ciba-Geigy AktiengesellschaftInventor: Mario Fryberg
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Patent number: 4229577Abstract: Color photographic material is provided which contains at least one silver halide emulsion layer containing a yellow color coupler of the formula ##STR1## wherein G is the radical of a yellow coupler which is bonded to the heterocyclic ring by means of the active methylene group, Z is --CO-- or --SO.sub.2 --, M is hydrogen if Z is --CO--, or a substituent and R is hydrogen or a substituent.The new two-equivalent yellow couplers lead due to their improved reactivity (high maximum density), minimal fog and high fastness to light and outstanding spectral properties of the dyestuffs formed therefrom to a color photographic material of advantageous properties.Type: GrantFiled: April 27, 1978Date of Patent: October 21, 1980Assignee: Ciba-Geigy AGInventors: Graham Evans, Mario Fryberg, Thomas Stauner, Paul Tschopp, David G. Leppard
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Patent number: 4115121Abstract: Color photographic material is provided which contains at least one silver halide emulsion layer containing a yellow color coupler of the formula ##STR1## wherein G is the radical of a yellow coupler which is bonded to the heterocyclic ring by means of the active methylene group, Z is --CO-- or --SO.sub.2 --, M is hydrogen if Z is --CO--; or a substituent and R is hydrogen or a substituent.Type: GrantFiled: March 30, 1977Date of Patent: September 19, 1978Assignee: Ciba-Geigy AGInventors: Graham Evans, Mario Fryberg, Thomas Stauner, Paul Tschopp, David G. Leppard