Patents by Inventor Mario Vierle
Mario Vierle has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 10392306Abstract: Proposed is a polycondensation product comprising as monomer components at least one aryl polyoxyalkylene ether, at least one vicinally disubstituted aromatic compound, at least one aldehyde and also optionally further aromatic compounds; processes for preparing same, and also use thereof as dispersant for aqueous suspensions of inorganic binders and as grinding assistant for inorganic binders.Type: GrantFiled: October 31, 2016Date of Patent: August 27, 2019Assignee: Construction Research & Technology GmbHInventors: Frank Dierschke, Torben Gädt, Uwe Gehrig, Michael Melchart, Mario Vierle, Peter Schwesig, Klaus Hartl, Madalina Andreea Stefan, Tatiana Mitkina, Maxim Pulkin
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Publication number: 20170044064Abstract: Proposed is a polycondensation product comprising as monomer components at least one aryl polyoxyalkylene ether, at least one vicinally disubstituted aromatic compound, at least one aldehyde and also optionally further aromatic compounds; processes for preparing same, and also use thereof as dispersant for aqueous suspensions of inorganic binders and as grinding assistant for inorganic binders.Type: ApplicationFiled: October 31, 2016Publication date: February 16, 2017Inventors: Frank DIERSCHKE, Torben GÄDT, Uwe GEHRIG, Michael MELCHART, Mario VIERLE, Peter SCHWESIG, Klaus HARTL, Madalina Andreea STEFAN, Tatiana MITKINA, Maxim PULKIN
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Patent number: 9284395Abstract: The present invention relates to a process for the continuous preparation of polymers in a polymerization apparatus, where the starting materials comprise at least one olefinically unsaturated polyether macromonomer and at least one olefinically unsaturated acid monomer and at least one free-radical initiator and the polymerization is carried out at temperatures in the range from ?20 to +120° C., wherein the polymerization apparatus comprises at least one loop reactor which has at least one feed line for the starting materials and at least one outlet, where the loop reactor comprises at least one reaction zone which comprises internal cooling and mixing elements and which has a volume-based heat removal power of at least 10 kW/m3·K. Furthermore, the use of the polymer of the invention as dispersant for hydraulic binders is disclosed.Type: GrantFiled: December 9, 2013Date of Patent: March 15, 2016Assignee: Construction Research & Technology GmbHInventors: Christian Schwede, Günter Kaiser, Andreas Brodhagen, Mario Vierle
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Publication number: 20150315318Abstract: The present invention relates to a process for the continuous preparation of polymers in a polymerization apparatus, where the starting materials comprise at least one olefinically unsaturated polyether macromonomer and at least one olefinically unsaturated acid monomer and at least one free-radical initiator and the polymerization is carried out at temperatures in the range from ?20 to +120° C., wherein the polymerization apparatus comprises at least one loop reactor which has at least one feed line for the starting materials and at least one outlet, where the loop reactor comprises at least one reaction zone which comprises internal cooling and mixing elements and which has a volume-based heat removal power of at least 10 kW/m3·K. Furthermore, the use of the polymer of the invention as dispersant for hydraulic binders is disclosed.Type: ApplicationFiled: December 9, 2013Publication date: November 5, 2015Inventors: Christian SCHWEDE, Günter KAISER, Andreas BRODHAGEN, Mario VIERLE
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Patent number: 9162926Abstract: The invention relates to a method for producing a hydraulic binder, comprising contacting a composition comprising cement clinker, before, during or after the grinding procedure, with (a) a defoaming agent and (b) 0.0005% to 2% by weight, based on the total composition, of at least one air-introducing compound, the defoaming agent (a) comprising 0.0001% to 0.5% by weight, based on the total composition, of at least one defoaming agent of the formula R10—(CmH2m—O—)x—(CdH2d—O—)c—H and the ratio of (a) to (b) being between 1:1 to 1:200.Type: GrantFiled: April 22, 2013Date of Patent: October 20, 2015Assignee: Construction Research & Technology, GmbHInventors: Mario Vierle, Martin Ernst, Madalina Andreea Stefan
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Patent number: 9045377Abstract: The invention concerns a process for the preparation of a hardening accelerator composition by reaction of a water-soluble calcium compound with a water-soluble silicate compound and by reaction of a calcium compound with a silicon dioxide containing component under alkaline conditions, in both cases the reaction being carried out in the presence of a polycondensate containing at least one structural unit consisting of an aromatic or heteroaromatic moiety bearing a polyether side chain and at least one structural unit consisting of an aromatic or heteroaromatic moiety bearing at least one phosphoric acid ester group and/or its salt. The invention concerns a composition of calcium silicate hydrate and the polycondensate, its use as hardening accelerator and for the reduction of the permeability of hardened compositions.Type: GrantFiled: August 12, 2010Date of Patent: June 2, 2015Assignee: Construction Research & Technology GmbHInventors: Luc Nicoleau, Gerhard Albrecht, Klaus Lorenz, Eva Jetzlsperger, Daniel Fridrich, Thomas Wohlhaupter, Reinhard Dorfner, Hubert Leitner, Mario Vierle, Dirk Schmitt, Michael Braeu, Christoph Hesse, Sabrina Montero Pancera, Siegfried Zuern, Michael Kutschera
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Publication number: 20150114266Abstract: The invention relates to a method for producing a hydraulic binder, comprising contacting a composition comprising cement clinker, before, during or after the grinding procedure, with (a) a defoaming agent and (b) 0.0005% to 2% by weight, based on the total composition, of at least one air-introducing compound, the defoaming agent (a) comprising 0.0001% to 0.5% by weight, based on the total composition, of at least one defoaming agent of the formula R10—(CmH2m—O—)x—(CdH2d—O—)c—H and the ratio of (a) to (b) being between 1:1 to 1:200.Type: ApplicationFiled: April 22, 2013Publication date: April 30, 2015Inventors: Mario Vierle, Martin Ernst, Madalina Andreea Stefan
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Publication number: 20150080500Abstract: Proposed is a polycondensation product comprising as monomer components at least one aryl polyoxyalkylene ether, at least one vicinally disubstituted aromatic compound, at least one aldehyde and also optionally further aromatic compounds; processes for preparing same, and also use thereof as dispersant for aqueous suspensions of inorganic binders and as grinding assistant for inorganic binders.Type: ApplicationFiled: April 3, 2013Publication date: March 19, 2015Inventors: Frank Dierschke, Torben Gädt, Uwe Gehrig, Michael Melchart, Mario Vierle, Peter Schwesig, Klaus Hartl, Madalina Andreea Stefan, Tatiana Mitkina, Maxim Pulkin
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Patent number: 8907016Abstract: The invention relates to a polymer composition containing 5 to 95% by weight of a copolymer H and 2 to 60% by weight of a copolymer K, the copolymers H and K each having polyether macromonomer structural units and acid monomer structural units, which are present in the copolymers H and K in each case in a molar ratio of 1:20 to 1:1, and at least 20 mol % of all structural units of the copolymer H and at least 25 mol % of all structural units of the copolymer K being present in each case in the form of acid monomer structural units, the polyether macromonomer structural units of the copolymer H having side chains containing in each case at least 5 ether oxygen atoms, the number of ether oxygen atoms per side chain of the polyether macromonomer structural units of the copolymer H varying in such a way that the corresponding frequency distribution diagram, in which the number of ether oxygen atoms per side chain of a polyether macromonomer structural unit is plotted along the abscissa and the associated frequencType: GrantFiled: November 25, 2009Date of Patent: December 9, 2014Assignee: Construction Research & Technology GmbHInventors: Mario Vierle, Klaus Lorenz, Gerhard Albrecht, Christian Scholz, Petra Wagner, Barbara Wimmer
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Patent number: 8772377Abstract: The invention relates to a polymer composition containing 3 to 95% by weight of a copolymer H and 3 to 95% by weight of a copolymer K, the copolymers H and K each having polyether macromonomer structural units and acid monomer structural units, which are present in the copolymers H and K in each case in a molar ratio of 1:20 to 1:1, and at least 20 mol % of all structural units of the copolymer H and at least 25 mol % of all structural units of the copolymer K being present in each case in the form of acid monomer structural units, the polyether macromonomer structural units of the copolymers H and K having side chains containing in each case at least 5 ether oxygen atoms, the number of ether oxygen atoms per side chain of the polyether macromonomer structural units of the copolymers H and K varying in each case in such a way that the corresponding frequency distribution diagrams, in which the number of ether oxygen atoms per side chain of a polyether macromonomer structural unit is plotted in each case alongType: GrantFiled: November 25, 2009Date of Patent: July 8, 2014Assignee: Construction Research & Technology GmbHInventors: Klaus Lorenz, Mario Vierle, Gerhard Albrecht, Barbara Wimmer, Petra Wagner, Christian Scholz
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Patent number: 8653186Abstract: The invention concerns a process for the preparation of a hardening accelerator composition by reaction of a water-soluble calcium compound with a water-soluble silicate compound and a process for the preparation of a hardening accelerator composition by reaction of a calcium compound with a silicon dioxide containing component under alkaline conditions, in both cases the reaction of the water-soluble calcium compound with the water-soluble silicate compound being carried out in the presence of an aqueous solution which contains a water-soluble comb polymer suitable as a plasticizer for hydraulic binders. The invention concerns also a composition of calcium silicate hydrate and comb polymer, its use as hardening accelerator and for the reduction of the permeability of hardened compositions.Type: GrantFiled: September 2, 2009Date of Patent: February 18, 2014Assignee: Construction Research & Technology GmbHInventors: Luc Nicoleau, Gerhard Albrecht, Klaus Lorenz, Eva Jetzlsperger, Daniel Fridrich, Thomas Wohlhaupter, Reinhard Dorfner, Hubert Leitner, Mario Vierle, Dirk Schmitt, Michael Braeu, Christoph Hesse, Sabrina Montero Pancera, Siegfried Zuern, Michael Kutschera
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Patent number: 8648158Abstract: The invention relates to a process for the preparation of copolymer in a continuous mode of operation in a polymerization apparatus, comprising a polymerization reactor having feed lines and an outflow, free radical polymerization initiator, an acid monomer and polyether macromonomer being passed as monomeric starting materials into the polymerization reactor through the feed lines, initiator, monomeric starting materials and copolymer-containing reaction composition thermostated at ?20 to +120° C.Type: GrantFiled: January 12, 2009Date of Patent: February 11, 2014Assignee: Construction Research & Technology GmbHInventors: Christian Schwede, Mario Vierle, Timo Mangel, Gerhard Albrecht, Volker Herzog, Klaus Arlt
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Patent number: 8536252Abstract: A process for the preparation of a copolymer in semicontinuous operation in a polymerization apparatus, comprising a polymerization reactor connected to a metering device, acid monomer being initially taken in the metering device and polyether macromonomer, acid monomer and water in the polymerization reactor, acid monomer being metered from the metering device into the polymerization reactor, the metering of the acid monomer being effected with the proviso that at least 70 mol % of the acid monomer metered in altogether are metered in the course of 5 to 19 minutes at a metering rate that is constant or varies to a limited extent.Type: GrantFiled: November 25, 2009Date of Patent: September 17, 2013Assignee: Construction Research & Technology GmbHInventors: Gerhard Albrecht, Helmut Mack, Klaus Lorenz, Mario Vierle, Silke Flakus, Petra Wagner, Christian Scholz, Harald Grassl, Barbara Wimmer
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Publication number: 20130233552Abstract: The water retention agents according to the invention are outstandingly suitable as additives in construction chemistry systems and in the development, exploitation and completion of underground mineral oil and natural gas deposits and in deep wells, their effect being particularly advantageous at increased temperatures and because of their lack of influence on the rheological properties of the well slurries.Type: ApplicationFiled: April 30, 2013Publication date: September 12, 2013Applicant: BASF SEInventors: Yulia Fogel, Mario Vierle, Andrea Assmann, Mathias Bauer, Gerhard Albrecht
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Patent number: 8461232Abstract: The invention relates to a polymer composition containing 3 to 90% by weight of a copolymer H and 3 to 90% by weight of a copolymer K, the copolymers H and K each having polyether macromonomer structural units and acid monomer structural units, which are present in the copolymers H and K in each case in a molar ratio of 1:20 to 1:1, and at least 20 mol % of all structural units of the copolymer H and at least 25 mol % of all structural units of the copolymer K being present in each case in the form of acid monomer structural units, at least 60 mol % of the polyether macromonomer structural units of the copolymer H being represented by the isoprenol polyether derivative structural units and at least 60 mol % of the polyether macromonomer structural units of the copolymer K being represented by the vinyloxy polyether derivative structural units.Type: GrantFiled: November 25, 2009Date of Patent: June 11, 2013Assignee: Construction Research & Technology GmbHInventors: Mario Vierle, Klaus Lorenz, Silke Flakus, Petra Wagner, Christian Scholz, Barbara Wimmer, Manfred Bichler, Angelika Hartl, Martin Winklbauer
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Publication number: 20120216724Abstract: The invention concerns a process for the preparation of a hardening accelerator composition by reaction of a water-soluble calcium compound with a water-soluble silicate compound and by reaction of a calcium compound with a silicon dioxide containing component under alkaline conditions, in both cases the reaction being carried out in the presence of an aqueous solution of a water-soluble polymer, which contains sulphonic acid and/or sulphonate groups and aromatic groups. The invention concerns also the reaction product of said processes and its use as hardening accelerator for building materials.Type: ApplicationFiled: August 13, 2010Publication date: August 30, 2012Applicant: Construction Research & Technology GmbHInventors: Luc Nicoleau, Gerhard Albrecht, Klaus Lorenz, Mario Vierle, Michael Breau, Christoph Hesse
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Publication number: 20120220696Abstract: The invention concerns a process for the preparation of a hardening accelerator composition by reaction of a water-soluble calcium compound with a water-soluble silicate compound and by reaction of a calcium compound with a silicon dioxide containing component under alkaline conditions, in both cases the reaction being carried out in the presence of a polycondensate containing at least one structural unit consisting of an aromatic or heteroaromatic moiety bearing a polyether side chain and at least one structural unit consisting of an aromatic or heteroaromatic moiety bearing at least one phosphoric acid ester group and/or its salt. The invention concerns a composition of calcium silicate hydrate and the polycondensate, its use as hardening accelerator and for the reduction of the permeability of hardened compositions.Type: ApplicationFiled: August 12, 2010Publication date: August 30, 2012Inventors: Luc Nicoleau, Gerhard Albrecht, Klaus Lorenz, Eva Jetzlsperger, Daniel Fridrich, Thomas Wohlhaupter, Reinhard Dorfner, Hubert Leitner, Mario Vierle, Dirk Schmitt, Michael Braeu, Christoph Hesse, Sabrina Montero Pancera, Siegfried Zuern, Michael Kutschera
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Publication number: 20120041105Abstract: The invention relates to a polymer composition containing 3 to 90% by weight of a copolymer H and 3 to 90% by weight of a copolymer K, the copolymers H and K each having polyether macromonomer structural units and acid monomer structural units, which are present in the copolymers H and K in each case in a molar ratio of 1:20 to 1:1, and at least 20 mol % of all structural units of the copolymer H and at least 25 mol % of all structural units of the copolymer K being present in each case in the form of acid monomer structural units, at least 60 mol % of the polyether macromonomer structural units of the copolymer H being represented by the isoprenol polyether derivative structural units and at least 60 mol % of the polyether macromonomer structural units of the copolymer K being represented by the vinyloxy polyether derivative structural units.Type: ApplicationFiled: November 25, 2009Publication date: February 16, 2012Inventors: Mario Vierle, Klaus Lorenz, Silke Flakus, Petra Wagner, Christian Scholz, Barbara Wimmer, Manfred Bichler, Angelika Hartl, Martin Winklbauer
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Publication number: 20120041106Abstract: The invention relates to a polymer composition containing 5 to 95% by weight of a copolymer H and 2 to 60% by weight of a copolymer K, the copolymers H and K each having polyether macromonomer structural units and acid monomer structural units, which are present in the copolymers H and K in each case in a molar ratio of 1:20 to 1:1, and at least 20 mol % of all structural units of the copolymer H and at least 25 mol % of all structural units of the copolymer K being present in each case in the form of acid monomer structural units, the polyether macromonomer structural units of the copolymer H having side chains containing in each case at least 5 ether oxygen atoms, the number of ether oxygen atoms per side chain of the polyether macromonomer structural units of the copolymer H varying in such a way that the corresponding frequency distribution diagram, in which the number of ether oxygen atoms per side chain of a polyether macromonomer structural unit is plotted along the abscissa and the associated frequencType: ApplicationFiled: November 25, 2009Publication date: February 16, 2012Inventors: Mario Vierle, Klaus Lorenz, Gerhard Albrecht, Christian Scholz, Petra Wagner, Barbara Wimmer
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Publication number: 20120041104Abstract: The invention relates to a polymer composition containing 3 to 95% by weight of a copolymer H and 3 to 95% by weight of a copolymer K, the copolymers H and K each having polyether macromonomer structural units and acid monomer structural units, which are present in the copolymers H and K in each case in a molar ratio of 1:20 to 1:1, and at least 20 mol % of all structural units of the copolymer H and at least 25 mol % of all structural units of the copolymer K being present in each case in the form of acid monomer structural units, the polyether macromonomer structural units of the copolymers H and K having side chains containing in each case at least 5 ether oxygen atoms, the number of ether oxygen atoms per side chain of the polyether macromonomer structural units of the copolymers H and K varying in each case in such a way that the corresponding frequency distribution diagrams, in which the number of ether oxygen atoms per side chain of a polyether macromonomer structural unit is plotted in each case alongType: ApplicationFiled: November 25, 2009Publication date: February 16, 2012Inventors: Klaus Lorenz, Mario Vierle, Barbara Wimmer, Petra Wagner, Christian Schôlz