Abstract: A method of purifying an aromatic carboxylic acid halide, for example p-phenoxybenzoyl chloride, comprising the steps of: (a) adding an acidic catalyst, for example a molecular sieve, to the acid halide; (b) heating the resulting mixture of the acidic catalyst and the acid halide to a temperature of about 180.degree. C. to about 250.degree. C. for a period of at least 0.5 hours; (c) distilling the mixture to obtain acid halide substantially free of aldehyde and the halo derivative thereof. Optionally, a reactive aromatic compound may be added to the mixture of the acid halide and the acidic catalyst before the heating step. The process is particularly useful for providing aromatic acid halides of sufficient purity for preparing melt stable aromatic polyketones.