Patents by Inventor Mark A. Krawczyk
Mark A. Krawczyk has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 9079159Abstract: A process for olefin metathesis is disclosed. The process involves contacting a feedstock comprising a first olefin and a second olefin having a carbon number at least two greater than that of the first olefin with a catalyst comprising a tungsten component on a refractory oxide support, e.g. silica at metathesis conditions to provide a product olefin having an intermediate carbon number between that of the first and second olefin. The catalyst is characterized in that it is first pretreated with hydrogen followed by treatment with ethylene.Type: GrantFiled: April 14, 2011Date of Patent: July 14, 2015Assignee: UOP LLCInventors: Christopher P Nicholas, Mark A. Krawczyk, Kristoffer E. Popp, Jennifer F. Abrahamian
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Patent number: 8895795Abstract: Acid washing of silica supports, used for supported tungsten catalysts, improves the activity of the resulting catalyst (i.e., its conversion level at a given temperature) for the metathesis of olefins, without compromising its selectivity to the desired conversion product(s). Exemplary catalysts and processes include those for the production of valuable light olefins such as propylene from a hydrocarbon feedstock comprising ethylene and butylene.Type: GrantFiled: February 5, 2010Date of Patent: November 25, 2014Assignee: UOP LLCInventors: Mark A. Krawczyk, Kristoffer E. Popp, Christopher P. Nicholas, Jennifer F. Abrahamian
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Patent number: 8722568Abstract: Silica supports having a surface area from about 250 m2/g to about 600 m2/g and an average pore diameter from about 45 ? to about 170 ?, used for supported tungsten catalysts, improves the activity of the resulting catalyst (i.e., its conversion level at a given temperature) for the metathesis of olefins, without compromising its selectivity to the desired conversion product(s). Exemplary catalysts and processes include those for the production of valuable light olefins such as propylene from a hydrocarbon feedstock comprising ethylene and butylene.Type: GrantFiled: July 17, 2012Date of Patent: May 13, 2014Assignee: UOP LLCInventors: Kristoffer E. Popp, Mark A. Krawczyk, Christopher P. Nicholas, Jennifer F. Abrahamian
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Patent number: 8324440Abstract: Silica supports having a surface area from about 250 m2/g to about 600 m2/g and an average pore diameter from about 45 ? to about 170 ?, used for supported tungsten catalysts, improves the activity of the resulting catalyst (i.e., its conversion level at a given temperature) for the metathesis of olefins, without compromising its selectivity to the desired conversion product(s). Exemplary catalysts and processes include those for the production of valuable light olefins such as propylene from a hydrocarbon feedstock comprising ethylene and butylene.Type: GrantFiled: February 5, 2010Date of Patent: December 4, 2012Assignee: UOP LLCInventors: Kristoffer E. Popp, Mark A. Krawczyk, Christopher P. Nicholas, Jennifer F. Abrahamian
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Publication number: 20120283090Abstract: Silica supports having a surface area from about 250 m2/g to about 600 m2/g and an average pore diameter from about 45 ? to about 170 ?, used for supported tungsten catalysts, improves the activity of the resulting catalyst (i.e., its conversion level at a given temperature) for the metathesis of olefins, without compromising its selectivity to the desired conversion product(s). Exemplary catalysts and processes include those for the production of valuable light olefins such as propylene from a hydrocarbon feedstock comprising ethylene and butylene.Type: ApplicationFiled: July 17, 2012Publication date: November 8, 2012Applicant: UOP LLCInventors: Kristoffer E. Popp, Mark A. Krawczyk, Christopher P. Nicholas, Jennifer F. Abrahamian
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Publication number: 20120264990Abstract: A process for olefin metathesis is disclosed. The process involves contacting a feedstock comprising a first olefin and a second olefin having a carbon number at least two greater than that of the first olefin with a catalyst comprising a tungsten component on a refractory oxide support, e.g. silica at metathesis conditions to provide a product olefin having an intermediate carbon number between that of the first and second olefin. The catalyst is characterized in that it is first pretreated with hydrogen followed by treatment with ethylene.Type: ApplicationFiled: April 14, 2011Publication date: October 18, 2012Applicant: UOP LLCInventors: Christopher P Nicholas, Mark A. Krawczyk, Kristoffer E. Popp, Jennifer F. Abrahamian
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Patent number: 8034304Abstract: A process vessel containing both an evaporation zone for evaporating a liquid feed and a treatment zone for treating the resulting vapor comprises an injector having an orifice, the orifice being in the evaporation zone, at least one evaporation surface for evaporating feed and generating vapor, the evaporation surface being located in the evaporation zone, wherein the injector orifice and the evaporation surface are positioned to prevent the formation of a drop at the orifice, a treatment zone for treating the vapor and at least one heater associated with at least a portion of the process vessel.Type: GrantFiled: October 14, 2010Date of Patent: October 11, 2011Assignee: UOP LLCInventors: Arne Karlsson, Ivar M. Dahl, Jonny Engedahl, Mark A. Krawczyk, Ara J. Alexanian
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Publication number: 20110196184Abstract: Silica supports having a surface area from about 250 m2/g to about 600 m2/g and an average pore diameter from about 45 ? to about 170 ?, used for supported tungsten catalysts, improves the activity of the resulting catalyst (i.e., its conversion level at a given temperature) for the metathesis of olefins, without compromising its selectivity to the desired conversion product(s). Exemplary catalysts and processes include those for the production of valuable light olefins such as propylene from a hydrocarbon feedstock comprising ethylene and butylene.Type: ApplicationFiled: February 5, 2010Publication date: August 11, 2011Applicant: UOP LLCInventors: Kristoffer E. POPP, Mark A. KRAWCZYK, Christopher P. NICHOLAS, Jennifer F. ABRAHAMIAN
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Publication number: 20110196185Abstract: Acid washing of silica supports, used for supported tungsten catalysts, improves the activity of the resulting catalyst (i.e., its conversion level at a given temperature) for the metathesis of olefins, without compromising its selectivity to the desired conversion product(s). Exemplary catalysts and processes include those for the production of valuable light olefins such as propylene from a hydrocarbon feedstock comprising ethylene and butylene.Type: ApplicationFiled: February 5, 2010Publication date: August 11, 2011Applicant: UOP LLCInventors: Mark A. KRAWCZYK, Kristoffer E. POPP, Christopher P. NICHOLAS, Jennifer F. ABRAHAMIAN
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Publication number: 20110024057Abstract: A process vessel containing both an evaporation zone for evaporating a liquid feed and a treatment zone for treating the resulting vapor comprises an injector having an orifice, the orifice being in the evaporation zone, at least one evaporation surface for evaporating feed and generating vapor, the evaporation surface being located in the evaporation zone, wherein the injector orifice and the evaporation surface are positioned to prevent the formation of a drop at the orifice, a treatment zone for treating the vapor and at least one heater associated with at least a portion of the process vessel.Type: ApplicationFiled: October 14, 2010Publication date: February 3, 2011Applicant: UOP LLCInventors: Arne Karlsson, Ivar M. Dahl, Jonny Engedahl, Mark A. Krawczyk, Ara J. Alexanian
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Patent number: 7833488Abstract: A process vessel containing both an evaporation zone for evaporating a liquid feed and a treatment zone for treating the resulting vapor comprises an injector having an orifice, the orifice being in the evaporation zone, at least one evaporation surface for evaporating feed and generating vapor, the evaporation surface being located in the evaporation zone, wherein the injector orifice and the evaporation surface are positioned to prevent the formation of a drop at the orifice, a treatment zone for treating the vapor and at least one heater associated with at least a portion of the process vessel.Type: GrantFiled: August 5, 2009Date of Patent: November 16, 2010Assignee: UOP LLCInventors: Arne Karlsson, Ivar M. Dahl, Jonny Engedahl, Mark A. Krawczyk, Ara J. Alexanian
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Publication number: 20090298715Abstract: A process vessel containing both an evaporation zone for evaporating a liquid feed and a treatment zone for treating the resulting vapor comprises an injector having an orifice, the orifice being in the evaporation zone, at least one evaporation surface for evaporating feed and generating vapor, the evaporation surface being located in the evaporation zone, wherein the injector orifice and the evaporation surface are positioned to prevent the formation of a drop at the orifice, a treatment zone for treating the vapor and at least one heater associated with at least a portion of the process vessel.Type: ApplicationFiled: August 5, 2009Publication date: December 3, 2009Applicant: UOP LLCInventors: Arne Karlsson, Ivar M. Dahl, Jonny Engedahl, Mark A. Krawczyk, Ara J. Alexanian
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Patent number: 7588729Abstract: A process vessel containing both an evaporation zone for evaporating a liquid feed and a treatment zone for treating the resulting vapor comprises an injector having an orifice, the orifice being in the evaporation zone, at least one evaporation surface for evaporating feed and generating vapor, the evaporation surface being located in the evaporation zone, wherein the injector orifice and the evaporation surface are positioned to prevent the formation of a drop at the orifice, a treatment zone for treating the vapor and at least one heater associated with at least a portion of the process vessel.Type: GrantFiled: January 11, 2005Date of Patent: September 15, 2009Assignee: UOP LLCInventors: Arne Karlsson, Ivar M. Dahl, Jonny Engedahl, Mark A. Krawczyk, Ara J. Alexanian
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Patent number: 7344891Abstract: A process vessel containing both an evaporation zone for evaporating a liquid feed and a treatment zone for treating the resulting vapor comprises an injector having an orifice, the orifice being in the evaporation zone, at least one evaporation surface for evaporating feed and generating vapor, the evaporation surface being located in the evaporation zone, wherein the injector orifice and the evaporation surface are positioned to prevent the formation of a drop at the orifice, a treatment zone for treating the vapor and at least one heater associated with at least a portion of the process vessel.Type: GrantFiled: January 11, 2005Date of Patent: March 18, 2008Assignee: UOP LLCInventors: Arne Karlsson, Ivar M. Dahl, Jonny Engedahl, Mark A. Krawczyk, Ara J. Alexanian
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Patent number: 7267987Abstract: A process and an assembly for simultaneously evaluating a plurality of catalysts is provided wherein the flow rate of a reactive fluid to each of a plurality of reactors is automatically adjusted based on the measured amount of catalyst sample in each reactor to concurrently obtain a substantially identical fluid space velocity in each of the reactors.Type: GrantFiled: January 6, 2003Date of Patent: September 11, 2007Assignee: UOP LLCInventors: Maureen L. Bricker, J. W. Adriaan Sachtler, Charles P. McGonegal, Mark A. Krawczyk, Ara J. Alexanian, Martin Plassen
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Patent number: 7256044Abstract: An apparatus and a method for rapidly generating a plurality of isolated effluents have been developed. A specific embodiment involves screening a plurality of solids through simultaneously contacting the members of the plurality with a fluid, sampling the resulting fluids, and processing the resulting fluids to, for example, determine changes as compared to the feed fluid or as compared to other resulting fluids.Type: GrantFiled: September 12, 2005Date of Patent: August 14, 2007Assignee: UOP LLCInventors: Arne Karlsson, Mark A. Krawczyk, Ara J. Alexanian, Duncan E. Akporiaye, Ivar M. Dahl
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Patent number: 7141217Abstract: An apparatus and a method for rapidly generating a plurality of isolated effluents have been developed. A specific embodiment involves screening a plurality of solids through simultaneously contacting the members of the plurality with a fluid, sampling the resulting fluids, and processing the resulting fluids to, for example, determine changes as compared to the feed fluid or as compared to other resulting fluids.Type: GrantFiled: December 5, 2002Date of Patent: November 28, 2006Assignee: UOP LLCInventors: Arne Karlsson, Mark A. Krawczyk, Ara J. Alexanian, Duncan E. Akporiaye, Ivar M. Dahl
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Patent number: 7063982Abstract: A process for evaporating a liquid feed and reacting said feed in the presence of catalyst to make product within a reactor having both an evaporation zone and a reaction zone comprises the steps of providing packing in the evaporation zone, providing catalyst in the reaction zone, introducing the liquid feed to the evaporation zone through an injector having an orifice, where the orifice and the packing define a gap that is sufficiently small to interfere with the formation of a liquid drop at the orifice, vaporizing the liquid feed within the evaporation zone to form a vapor, flowing the vapor to the reaction zone and contacting, at reaction conditions, the vapor with a catalyst to form product.Type: GrantFiled: March 12, 2002Date of Patent: June 20, 2006Assignee: UOP LLCInventors: Arne Karlsson, Ivar M. Dahl, Jonny Engedahl, Mark A. Krawczyk, Ara J. Alexianin
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Patent number: 6989131Abstract: A reactor for evaporating liquid feed and reacting said feed in the presence of catalyst to make product comprises a housing having at least one inlet and at least one outlet and encasing an evaporation zone and a reaction zone, an injector passing through the inlet and having an orifice in the evaporation zone for introducing a liquid feed, an insert containing packing for vaporizing the liquid feed where the packing is in the evaporation zone, a receptacle for retaining catalyst in the reaction zone and at least one heater associated with at least a portion of the reactor, wherein the injector orifice and the packing define a gap between the orifice and the packing sufficiently small to interfere with the formation of a drop at the orifice.Type: GrantFiled: March 12, 2002Date of Patent: January 24, 2006Assignee: UOP LLCInventors: Arne Karlsson, Ivar M. Dahl, Jonny Engedahl, Mark A. Krawczyk, Ara J. Alexanian
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Publication number: 20040132194Abstract: A process and an assembly for simultaneously evaluating a plurality of catalysts is provided wherein the flow rate of a reactive fluid to each of a plurality of reactors is automatically adjusted based on the measured amount of catalyst sample in each reactor to concurrently obtain a substantially identical fluid space velocity in each of the reactors.Type: ApplicationFiled: January 6, 2003Publication date: July 8, 2004Inventors: Maureen L. Bricker, J.W. Adriaan Sachtler, Charles P. McGonegal, Mark A. Krawczyk, Ara J. Alexanian, Martin Plassen