Patents by Inventor Mark C. SCHAAPMAN
Mark C. SCHAAPMAN has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Publication number: 20250091970Abstract: A hydrogenated decarboxylated rosin acid (HDCR) composition is disclosed comprising, based on total weight of the composition, a plurality of hydrogenated decarboxylated rosin acid (HDCR) components. The HDCR composition contains: (a) 45 to 100 wt. % of the HDCR components have C19 carbons and a MW of 262 g/mol; (b) up to 50 wt. % of the HDCR components have C19 carbons and a MW of 256 g/mol; (c) up to 20 wt. % of the HDCR components have C19 carbons and a MW of 252 g/mol, or C19 carbons and a MW of 260 g/mol; and (d) up to 25 wt. % of the HDCR components have C13 carbons and a MW of 180 g/mol. The HDCR composition has an oxygen content of <0.5%. The HDCR composition shows enhanced oxidative stability and Gardner color, and can be used in fertilizer coatings, cleaning agents, defoamers, cosmetics, lubricants, etc.Type: ApplicationFiled: September 17, 2024Publication date: March 20, 2025Applicant: Kraton CorporationInventors: Pieter Eduard, Arnold P. den Hartog, Mark C. Schaapman
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Patent number: 11634584Abstract: Disclosed are compositions which include an ethylene polymer derived from at least one polar monomer with one or more ester groups, and a rosin ester. The rosin ester can have a low hydroxyl number (e.g., a hydroxyl number seven or less), a low acid number (e.g., an acid number of ten or less), a relatively low PAN number (e.g., a PAN number less than twenty-five), a relatively high third moment or third power average molecular weight (Mz), (e.g., an Mz value in between 2500 and 12000 g/mol), a low sulfur content (e.g., a sulfur content lower than 600 ppm prior to antioxidant addition) or combinations thereof. The compositions can exhibit a high heat stress resistance (e.g., a heat stress pass temperature value higher than 52° C. or in between 48° C. and 60° C.) and/or improved viscosity stability and/or color stability upon thermal aging and/or improved compatibility.Type: GrantFiled: March 22, 2021Date of Patent: April 25, 2023Assignee: KRATON CORPORATIONInventors: Jos H. M. Lange, Mark C. Schaapman, Justyna J. Hinc
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Publication number: 20210206976Abstract: Disclosed are compositions which include an ethylene polymer derived from at least one polar monomer with one or more ester groups, and a rosin ester. The rosin ester can have a low hydroxyl number (e.g., a hydroxyl number seven or less), a low acid number (e.g., an acid number of ten or less), a relatively low PAN number (e.g., a PAN number less than twenty-five), a relatively high third moment or third power average molecular weight (Mz), (e.g., an Mz value in between 2500 and 12000 g/mol), a low sulfur content (e.g., a sulfur content lower than 600 ppm prior to antioxidant addition) or combinations thereof. The compositions can exhibit a high heat stress resistance (e.g., a heat stress pass temperature value higher than 52° C. or in between 48° C. and 60° C.) and/or improved viscosity stability and/or color stability upon thermal aging and/or improved compatibility.Type: ApplicationFiled: March 22, 2021Publication date: July 8, 2021Applicant: Kraton Chemical, LLCInventors: Jos H.M. Lange, Mark C. Schaapman, Justyna J. Hinc
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Patent number: 10954389Abstract: Disclosed are compositions which include an ethylene polymer derived from at least one polar monomer with one or more ester groups, and a rosin ester. The rosin ester can have a low hydroxyl number (e.g., a hydroxyl number seven or less), a low acid number (e.g., an acid number of ten or less), a relatively low PAN number (e.g., a PAN number less than twenty-five), a relatively high third moment or third power average molecular weight (Mz), (e.g., an Mz value in between 2500 and 12000 g/mol), a low sulfur content (e.g., a sulfur content lower than 600 ppm prior to antioxidant addition) or combinations thereof. The compositions can exhibit a high heat stress resistance (e.g., a heat stress pass temperature value higher than 52° C. or in between 48° C. and 60° C.) and/or improved viscosity stability and/or color stability upon thermal aging and/or improved compatibility.Type: GrantFiled: July 1, 2019Date of Patent: March 23, 2021Assignee: Kraton Chemical, LLCInventors: Jos H. M. Lange, Mark C. Schaapman, Justyna J. Hinc
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Patent number: 10822302Abstract: A method to reduce the aldehyde content of a pine chemical composition is disclosed. The pine chemical composition is selected from gum turpentine, gum rosin, CST BLS, CTO, depitched CTO, DTO, TOH, TOR, TOP, TOFA, fractionated TOFA, TOFA dimer, TOFA trimer, TOFA monomer, isostearic acid, stearic acid, and ester- and amide derivatives thereof. The pine chemical composition is treated with an aldehyde scavenger such as anthranilamide at a temperature between 20° C. to 300° C., for 1 minute to 5 hours.Type: GrantFiled: November 26, 2019Date of Patent: November 3, 2020Assignee: Kraton Polymers LLCInventors: Jos H. M. Lange, Mark C. Schaapman
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Publication number: 20200165191Abstract: A method to reduce the aldehyde content of a pine chemical composition is disclosed. The pine chemical composition is selected from gum turpentine, gum rosin, CST BLS, CTO, depitched CTO, DTO, TOH, TOR, TOP, TOFA, fractionated TOFA, TOFA dimer, TOFA trimer, TOFA monomer, isostearic acid, stearic acid, and ester- and amide derivatives thereof. The pine chemical composition is treated with an aldehyde scavenger such as anthranilamide at a temperature between 20° C. to 300° C., for 1 minute to 5 hours.Type: ApplicationFiled: November 26, 2019Publication date: May 28, 2020Applicant: Kraton Polymers LLCInventors: Jos H. M. Lange, Mark C. Schaapman
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Patent number: 10611926Abstract: A light color or a low color rosin or a rosin ester composition is disclosed. Significant color improvement can be obtained for a low color rosin, or a rosin ester by using a co-catalyst. In one embodiment, the co-catalyst has a triplet formation quantum yield (?T) of greater than 0.5 and a triplet lifetime (?T) of greater than 0.5 microseconds In another embodiment, the co-catalyst is selected from acridone, anthrone, 9-fluorenone, thioxanthone, xanthone, derivatives and combinations thereof.Type: GrantFiled: June 30, 2018Date of Patent: April 7, 2020Assignee: Kraton Polymers LLCInventor: Mark C. Schaapman
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Publication number: 20190322869Abstract: Disclosed are compositions which include an ethylene polymer derived from at least one polar monomer with one or more ester groups, and a rosin ester. The rosin ester can have a low hydroxyl number (e.g., a hydroxyl number seven or less), a low acid number (e.g., an acid number of ten or less), a relatively low PAN number (e.g., a PAN number less than twenty-five), a relatively high third moment or third power average molecular weight (Mz), (e.g., an Mz value in between 2500 and 12000 g/mol), a low sulfur content (e.g., a sulfur content lower than 600 ppm prior to antioxidant addition) or combinations thereof. The compositions can exhibit a high heat stress resistance (e.g., a heat stress pass temperature value higher than 52° C. or in between 48° C. and 60° C.) and/or improved viscosity stability and/or color stability upon thermal aging and/or improved compatibility.Type: ApplicationFiled: July 1, 2019Publication date: October 24, 2019Applicant: KRATON CHEMICAL, LLCInventors: Jos H. M. Lange, Mark C. Schaapman, Justyna J. Hinc
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Publication number: 20190002733Abstract: A light color or a low color rosin or a rosin ester composition is disclosed. Significant color improvement can be obtained for a low color rosin, or a rosin ester by using a co-catalyst. In one embodiment, the co-catalyst has a triplet formation quantum yield (?T) of greater than 0.5 and a triplet lifetime (?T) of greater than 0.5 microseconds In another embodiment, the co-catalyst is selected from acridone, anthrone, 9-fluorenone, thioxanthone, xanthone, derivatives and combinations thereof.Type: ApplicationFiled: June 30, 2018Publication date: January 3, 2019Applicant: KRATON POLYMERS LLCInventor: MARK C. SCHAAPMAN
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Publication number: 20180223136Abstract: Disclosed are compositions which include an ethylene polymer derived from at least one polar monomer with one or more ester groups, which polymerize with ethylene, (e.g., a copolymer derived from ethylene and vinyl acetate or a copolymer derived from ethylene and n-butyl acrylate) and a rosin ester. The rosin ester can have a low hydroxyl number (e.g., a hydroxyl number six or five or less), a low acid number (e.g., an acid number of ten or less), a low PAN number (e.g., a PAN number of eight or less), or combinations thereof. The compositions can exhibit improved viscosity stability and/or color stability and/or a decreased amount of char particle formation upon thermal aging.Type: ApplicationFiled: April 6, 2018Publication date: August 9, 2018Applicant: Arizona Chemical Company, LLCInventors: Josephus Hubertus Maria Lange, Mark C. Schaapman, Erik Kelderman
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Publication number: 20180086942Abstract: Novel oligoester compositions having desirable user and/or process-desired combination of properties. The oligoester compositions are derived from one or more rosin; one or more polyhydric alcohol; and one or more polyfunctional carboxylic acid. The carboxylic acids have 5 to 19 carbon atoms. The one or more polyfunctional carboxylic acids may be polyfunctional carboxylic acids and aliphatic dicarboxylic acids. In some embodiments, the novel oligoester compositions are suitable for use in adhesives, road markings, and automotive industry, for example. Also disclosed herein are methods of producing the novel oligoester compositions.Type: ApplicationFiled: September 23, 2017Publication date: March 29, 2018Applicant: Kraton Chemical, LLCInventors: Jos H. M. Lange, Mark C. Schaapman
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Publication number: 20170190935Abstract: An oligoester composition which is a reaction product of a reactant mixture comprising one or more rosins; at least 15% by weight of one or more monocarboxylic acids; and one or more polyhydric alcohols. A method for preparing an oligoester composition comprising (a) esterifying a mixture comprising one or more rosins, one or more monocarboxylic acids, and optionally one or more polycarboxylic acids with one or more polyhydric alcohols to form the oligoester composition. An oligoester composition which is an esterification reaction product of one or more rosins, one or more monocarboxylic acids, one or more polyhydric alcohols, and optionally one or more polycarboxylic acids, wherein the composition has a weight average molecular weight of from 500 g/mol to 8,000 g/mol and a Tg of between ?80° C. and 100° C.Type: ApplicationFiled: December 30, 2016Publication date: July 6, 2017Applicant: Arizona Chemical Company, LLCInventors: Mark C. Schaapman, Jos H.M. Lange, Pieter Eduard, Ronnie Zeeman
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Publication number: 20160222259Abstract: Disclosed are compositions which include an ethylene polymer derived from at least one polar monomer with one or more ester groups, which polymerize with ethylene, (e.g., a copolymer derived from ethylene and vinyl acetate or a copolymer derived from ethylene and n-butyl acrylate) and a rosin ester. The rosin ester can have a low hydroxyl number (e.g., a hydroxyl number six or five or less), a low acid number (e.g., an acid number of ten or less), a low PAN number (e.g., a PAN number of eight or less), or combinations thereof. The compositions can exhibit improved viscosity stability and/or color stability and/or a decreased amount of char particle formation upon thermal aging.Type: ApplicationFiled: September 26, 2014Publication date: August 4, 2016Applicant: Arizona Chemical Company, LLCInventors: Josephus Hubertus Maria LANGE, Mark C. SCHAAPMAN, Erik KELDERMAN