Patents by Inventor Mark C. SCHAAPMAN

Mark C. SCHAAPMAN has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11634584
    Abstract: Disclosed are compositions which include an ethylene polymer derived from at least one polar monomer with one or more ester groups, and a rosin ester. The rosin ester can have a low hydroxyl number (e.g., a hydroxyl number seven or less), a low acid number (e.g., an acid number of ten or less), a relatively low PAN number (e.g., a PAN number less than twenty-five), a relatively high third moment or third power average molecular weight (Mz), (e.g., an Mz value in between 2500 and 12000 g/mol), a low sulfur content (e.g., a sulfur content lower than 600 ppm prior to antioxidant addition) or combinations thereof. The compositions can exhibit a high heat stress resistance (e.g., a heat stress pass temperature value higher than 52° C. or in between 48° C. and 60° C.) and/or improved viscosity stability and/or color stability upon thermal aging and/or improved compatibility.
    Type: Grant
    Filed: March 22, 2021
    Date of Patent: April 25, 2023
    Assignee: KRATON CORPORATION
    Inventors: Jos H. M. Lange, Mark C. Schaapman, Justyna J. Hinc
  • Patent number: 11634562
    Abstract: The disclosure relates to tire tread compositions and methods for making. The compositions include a rubber, a rosin ester resin and at least one filler. The rosin ester resin is characterized as having a PAN number of less than 25, an acid number less than 20, a hydroxyl number of less than 30, a combined acid number and hydroxyl value of less than 50. The tire tread composition has a wet grip resistance to rolling resistance indicator ratio ((tan ? at 0° C.)/tan ? at 60° C.) higher than a tire tread composition containing a comparable amount of a rosin ester having a combined acid number and hydroxyl value of more than 50.
    Type: Grant
    Filed: August 5, 2020
    Date of Patent: April 25, 2023
    Assignee: KRATON CORPORATION
    Inventors: Wolfgang Pille-Wolf, Jochem H. W. Vervelde, Jeremie Pichereau, Mark C Schaapman
  • Publication number: 20210206976
    Abstract: Disclosed are compositions which include an ethylene polymer derived from at least one polar monomer with one or more ester groups, and a rosin ester. The rosin ester can have a low hydroxyl number (e.g., a hydroxyl number seven or less), a low acid number (e.g., an acid number of ten or less), a relatively low PAN number (e.g., a PAN number less than twenty-five), a relatively high third moment or third power average molecular weight (Mz), (e.g., an Mz value in between 2500 and 12000 g/mol), a low sulfur content (e.g., a sulfur content lower than 600 ppm prior to antioxidant addition) or combinations thereof. The compositions can exhibit a high heat stress resistance (e.g., a heat stress pass temperature value higher than 52° C. or in between 48° C. and 60° C.) and/or improved viscosity stability and/or color stability upon thermal aging and/or improved compatibility.
    Type: Application
    Filed: March 22, 2021
    Publication date: July 8, 2021
    Applicant: Kraton Chemical, LLC
    Inventors: Jos H.M. Lange, Mark C. Schaapman, Justyna J. Hinc
  • Patent number: 11034858
    Abstract: A three-step method to prepare a light-colored rosin ester is disclosed wherein at least in one of the steps (a) and (c) a co-catalyst is applied and wherein at least in one of the steps (a) and (c) a disproportionation catalyst is applied. In the second step, a distilled rosin is obtained which is esterified with a polyol into a light-colored rosin ester. In one embodiment, the co-catalyst has a triplet formation quantum yield (?T) of greater than 0.5 and a triplet lifetime (?T) of greater than 0.5 microseconds. In another embodiment, the co-catalyst is selected from acridone, anthrone, 9-fluorenone, thioxanthone, xanthone, derivatives and combinations thereof.
    Type: Grant
    Filed: November 19, 2019
    Date of Patent: June 15, 2021
    Assignee: Kraton Polymers LLC
    Inventors: Mark C Schaapman, Jos H. M. Lange
  • Publication number: 20210087369
    Abstract: The disclosure relates to tire tread compositions and methods for making. The compositions include a rubber, a rosin ester resin and at least one filler. The rosin ester resin is characterized as having a PAN number of less than 25, an acid number less than 20, a hydroxyl number of less than 30, a combined acid number and hydroxyl value of less than 50. The tire tread composition has a wet grip resistance to rolling resistance indicator ratio ((tan ? at 0° C.)/tan ? at 60° C.) higher than a tire tread composition containing a comparable amount of a rosin ester having a combined acid number and hydroxyl value of more than 50.
    Type: Application
    Filed: August 5, 2020
    Publication date: March 25, 2021
    Applicant: Kraton Polymers LLC
    Inventors: Wolfgang Pille-Wolf, Jochem H. W. Vervelde, Jeremie Pichereau, Mark C Schaapman
  • Patent number: 10954389
    Abstract: Disclosed are compositions which include an ethylene polymer derived from at least one polar monomer with one or more ester groups, and a rosin ester. The rosin ester can have a low hydroxyl number (e.g., a hydroxyl number seven or less), a low acid number (e.g., an acid number of ten or less), a relatively low PAN number (e.g., a PAN number less than twenty-five), a relatively high third moment or third power average molecular weight (Mz), (e.g., an Mz value in between 2500 and 12000 g/mol), a low sulfur content (e.g., a sulfur content lower than 600 ppm prior to antioxidant addition) or combinations thereof. The compositions can exhibit a high heat stress resistance (e.g., a heat stress pass temperature value higher than 52° C. or in between 48° C. and 60° C.) and/or improved viscosity stability and/or color stability upon thermal aging and/or improved compatibility.
    Type: Grant
    Filed: July 1, 2019
    Date of Patent: March 23, 2021
    Assignee: Kraton Chemical, LLC
    Inventors: Jos H. M. Lange, Mark C. Schaapman, Justyna J. Hinc
  • Patent number: 10822302
    Abstract: A method to reduce the aldehyde content of a pine chemical composition is disclosed. The pine chemical composition is selected from gum turpentine, gum rosin, CST BLS, CTO, depitched CTO, DTO, TOH, TOR, TOP, TOFA, fractionated TOFA, TOFA dimer, TOFA trimer, TOFA monomer, isostearic acid, stearic acid, and ester- and amide derivatives thereof. The pine chemical composition is treated with an aldehyde scavenger such as anthranilamide at a temperature between 20° C. to 300° C., for 1 minute to 5 hours.
    Type: Grant
    Filed: November 26, 2019
    Date of Patent: November 3, 2020
    Assignee: Kraton Polymers LLC
    Inventors: Jos H. M. Lange, Mark C. Schaapman
  • Publication number: 20200199408
    Abstract: A three-step method to prepare a light-colored rosin ester is disclosed wherein at least in one of the steps (a) and (c) a co-catalyst is applied and wherein at least in one of the steps (a) and (c) a disproportionation catalyst is applied. In the second step, a distilled rosin is obtained which is esterified with a polyol into a light-colored rosin ester. In one embodiment, the co-catalyst has a triplet formation quantum yield (?T) of greater than 0.5 and a triplet lifetime (?T) of greater than 0.5 microseconds. In another embodiment, the co-catalyst is selected from acridone, anthrone, 9-fluorenone, thioxanthone, xanthone, derivatives and combinations thereof.
    Type: Application
    Filed: November 19, 2019
    Publication date: June 25, 2020
    Applicant: KRATON POLYMERS LLC
    Inventors: Mark C Schaapman, Jos H. M. Lange
  • Publication number: 20200165191
    Abstract: A method to reduce the aldehyde content of a pine chemical composition is disclosed. The pine chemical composition is selected from gum turpentine, gum rosin, CST BLS, CTO, depitched CTO, DTO, TOH, TOR, TOP, TOFA, fractionated TOFA, TOFA dimer, TOFA trimer, TOFA monomer, isostearic acid, stearic acid, and ester- and amide derivatives thereof. The pine chemical composition is treated with an aldehyde scavenger such as anthranilamide at a temperature between 20° C. to 300° C., for 1 minute to 5 hours.
    Type: Application
    Filed: November 26, 2019
    Publication date: May 28, 2020
    Applicant: Kraton Polymers LLC
    Inventors: Jos H. M. Lange, Mark C. Schaapman
  • Patent number: 10611926
    Abstract: A light color or a low color rosin or a rosin ester composition is disclosed. Significant color improvement can be obtained for a low color rosin, or a rosin ester by using a co-catalyst. In one embodiment, the co-catalyst has a triplet formation quantum yield (?T) of greater than 0.5 and a triplet lifetime (?T) of greater than 0.5 microseconds In another embodiment, the co-catalyst is selected from acridone, anthrone, 9-fluorenone, thioxanthone, xanthone, derivatives and combinations thereof.
    Type: Grant
    Filed: June 30, 2018
    Date of Patent: April 7, 2020
    Assignee: Kraton Polymers LLC
    Inventor: Mark C. Schaapman
  • Publication number: 20190322869
    Abstract: Disclosed are compositions which include an ethylene polymer derived from at least one polar monomer with one or more ester groups, and a rosin ester. The rosin ester can have a low hydroxyl number (e.g., a hydroxyl number seven or less), a low acid number (e.g., an acid number of ten or less), a relatively low PAN number (e.g., a PAN number less than twenty-five), a relatively high third moment or third power average molecular weight (Mz), (e.g., an Mz value in between 2500 and 12000 g/mol), a low sulfur content (e.g., a sulfur content lower than 600 ppm prior to antioxidant addition) or combinations thereof. The compositions can exhibit a high heat stress resistance (e.g., a heat stress pass temperature value higher than 52° C. or in between 48° C. and 60° C.) and/or improved viscosity stability and/or color stability upon thermal aging and/or improved compatibility.
    Type: Application
    Filed: July 1, 2019
    Publication date: October 24, 2019
    Applicant: KRATON CHEMICAL, LLC
    Inventors: Jos H. M. Lange, Mark C. Schaapman, Justyna J. Hinc
  • Patent number: 10435586
    Abstract: An oligoester composition is disclosed, which is a reaction product of a reactant mixture comprising one or more rosins selected from the group consisting of tall oil rosin and gum rosin; at least 15% by weight of one or more monocarboxylic acids comprising 6-36 carbon atoms; and one or more polyhydric alcohols comprising 2-36 carbon atoms, wherein each hydroxyl group of the polyhydric alcohol is separated from the other hydroxyl groups by at least 2 carbon atoms. A method for preparing an oligoester composition is also provided. Also disclosed is an oligoester composition which is an esterification reaction product of one or more rosins, one or more monocarboxylic acids, one or more polyhydric alcohols, and optionally one or more polycarboxylic acids. The composition has a weight average molecular weight of from 500 g/mol to 8,000 g/mol and a Tg of between ?80° C. and 100° C.
    Type: Grant
    Filed: December 30, 2016
    Date of Patent: October 8, 2019
    Assignee: Kraton Chemical, LLC
    Inventors: Mark C Schaapman, Jos H. M. Lange, Pieter Eduard, Ronnie Zeeman
  • Patent number: 10407593
    Abstract: An Oligoester composition obtained from a reactant mixture comprising one or more rosin; one or more polyhydric alcohol selected from the group of polyhydric alcohols having from 2 to 30 carbon atoms, and from 0.5 wt. % to 15 wt. %, based on the weight of all reactants, of one or more polyfunctional carboxylic acids selected from cycloaliphatic dicarboxylic polyfunctional carboxylic acids, and wherein the one or more polyhydric alcohol is present in the mixture for preparation of the Oligoester an amount of from 5 wt. % to 35 wt. %, based on the weight of all reactants. Oligoester composition has a hydroxyl value of from 7 mg KOH/g to 40 mg KOH/g and suitable for use in road marking, adhesives or tire tread.
    Type: Grant
    Filed: September 23, 2017
    Date of Patent: September 10, 2019
    Assignee: Kraton Chemical, LLC
    Inventors: Jos H. M. Lange, Mark C Schaapman
  • Patent number: 10344164
    Abstract: Disclosed are compositions which include an ethylene polymer derived from at least one polar monomer with one or more ester groups, which polymerize with ethylene, (e.g., a copolymer, or low molecular weight copolymer having a relatively high melt index, derived from ethylene and vinyl acetate and/or a copolymer, or low molecular weight copolymer having a relatively high melt index, derived from ethylene and «-buty! acrylate) and a rosin ester. The rosin ester can have a low hydroxy! number (e.g., a hydroxy! number six or five or less), a low acid number (e.g., an acid number of ten or less), a relatively low PAN number (e.g., a PAN number less than twenty-two or in between eight and twenty), a relatively high third moment or third power average molecular weight (Mz), (e.g., an Mz value in between 2500 and 12000 g/mol), a low sulfur content (e.g., a sulfur content lower than 600 ppm prior to antioxidant addition) or combinations thereof. The compositions can exhibit a high heat stress resistance (e.g.
    Type: Grant
    Filed: March 24, 2016
    Date of Patent: July 9, 2019
    Assignee: Kraton Chemical, LLC
    Inventors: Jos H. M. Lange, Mark C Schaapman, Justyna J. Hinc
  • Patent number: 10336922
    Abstract: Disclosed are compositions which include an ethylene polymer derived from at least one polar monomer with one or more ester groups, which polymerize with ethylene, (e.g., a copolymer derived from ethylene and vinyl acetate or a copolymer derived from ethylene and n-butyl acrylate) and a rosin ester. The rosin ester can have a low hydroxyl number (e.g., a hydroxyl number six or five or less), a low acid number (e.g., an acid number of ten or less), a low PAN number (e.g., a PAN number of eight or less), or combinations thereof. The compositions can exhibit improved viscosity stability and/or color stability and/or a decreased amount of char particle formation upon thermal aging.
    Type: Grant
    Filed: April 6, 2018
    Date of Patent: July 2, 2019
    Assignee: Kraton Chemical, LLC
    Inventors: Josephus Hubertus Maria Lange, Mark c Schaapman, Erik Kelderman
  • Publication number: 20190002733
    Abstract: A light color or a low color rosin or a rosin ester composition is disclosed. Significant color improvement can be obtained for a low color rosin, or a rosin ester by using a co-catalyst. In one embodiment, the co-catalyst has a triplet formation quantum yield (?T) of greater than 0.5 and a triplet lifetime (?T) of greater than 0.5 microseconds In another embodiment, the co-catalyst is selected from acridone, anthrone, 9-fluorenone, thioxanthone, xanthone, derivatives and combinations thereof.
    Type: Application
    Filed: June 30, 2018
    Publication date: January 3, 2019
    Applicant: KRATON POLYMERS LLC
    Inventor: MARK C. SCHAAPMAN
  • Publication number: 20180223136
    Abstract: Disclosed are compositions which include an ethylene polymer derived from at least one polar monomer with one or more ester groups, which polymerize with ethylene, (e.g., a copolymer derived from ethylene and vinyl acetate or a copolymer derived from ethylene and n-butyl acrylate) and a rosin ester. The rosin ester can have a low hydroxyl number (e.g., a hydroxyl number six or five or less), a low acid number (e.g., an acid number of ten or less), a low PAN number (e.g., a PAN number of eight or less), or combinations thereof. The compositions can exhibit improved viscosity stability and/or color stability and/or a decreased amount of char particle formation upon thermal aging.
    Type: Application
    Filed: April 6, 2018
    Publication date: August 9, 2018
    Applicant: Arizona Chemical Company, LLC
    Inventors: Josephus Hubertus Maria Lange, Mark C. Schaapman, Erik Kelderman
  • Patent number: 9951254
    Abstract: Disclosed are compositions which include an ethylene polymer derived from at least one polar monomer with one or more ester groups, which polymerize with ethylene, (e.g., a copolymer derived from ethylene and vinyl acetate or a copolymer derived from ethylene and n-butyl acrylate) and a rosin ester. The rosin ester can have a low hydroxyl number (e.g., a hydroxyl number six or five or less), a low acid number (e.g., an acid number of ten or less), a low PAN number (e.g., a PAN number of eight or less), or combinations thereof. The compositions can exhibit improved viscosity stability and/or color stability and/or a decreased amount of char particle formation upon thermal aging.
    Type: Grant
    Filed: September 26, 2014
    Date of Patent: April 24, 2018
    Assignee: Arizona Chemical Company, LLC
    Inventors: Josephus Hubertus Maria Lange, Mark C Schaapman, Erik Kelderman
  • Publication number: 20180105693
    Abstract: Disclosed are compositions which include an ethylene polymer derived from at least one polar monomer with one or more ester groups, which polymerize with ethylene, (e.g., a copolymer, or low molecular weight copolymer having a relatively high melt index, derived from ethylene and vinyl acetate and/or a copolymer, or low molecular weight copolymer having a relatively high melt index, derived from ethylene and «-buty! acrylate) and a rosin ester. The rosin ester can have a low hydroxy! number (e.g., a hydroxy! number six or five or less), a low acid number (e.g., an acid number of ten or less), a relatively low PAN number (e.g., a PAN number less than twenty-two or in between eight and twenty), a relatively high third moment or third power average molecular weight (Mz), (e.g., an Mz value in between 2500 and 12000 g/mol), a low sulfur content (e.g., a sulfur content lower than 600 ppm prior to antioxidant addition) or combinations thereof. The compositions can exhibit a high heat stress resistance (e.g.
    Type: Application
    Filed: March 24, 2016
    Publication date: April 19, 2018
    Applicant: Arizona Chemical Company, LLC
    Inventors: Jos H. M. Lange, Mark C Schaapman, Justyna J. Hinc
  • Publication number: 20180086942
    Abstract: Novel oligoester compositions having desirable user and/or process-desired combination of properties. The oligoester compositions are derived from one or more rosin; one or more polyhydric alcohol; and one or more polyfunctional carboxylic acid. The carboxylic acids have 5 to 19 carbon atoms. The one or more polyfunctional carboxylic acids may be polyfunctional carboxylic acids and aliphatic dicarboxylic acids. In some embodiments, the novel oligoester compositions are suitable for use in adhesives, road markings, and automotive industry, for example. Also disclosed herein are methods of producing the novel oligoester compositions.
    Type: Application
    Filed: September 23, 2017
    Publication date: March 29, 2018
    Applicant: Kraton Chemical, LLC
    Inventors: Jos H. M. Lange, Mark C. Schaapman