Patents by Inventor Mark J. Struglinski

Mark J. Struglinski has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5543469
    Abstract: The present invention relates to hydrogenated block copolymers of butadiene and at least one other diene, preferably isoprene. The copolymer is hydrogenated and comprises at least 10% by weight of at least one crystallizable segment and at least one low crystallinity segment.
    Type: Grant
    Filed: January 20, 1995
    Date of Patent: August 6, 1996
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Mark J. Struglinski, Gary W. Ver Strate, Lewis J. Fetters
  • Patent number: 5446221
    Abstract: The present invention is directed to a lubricating oil composition exhibiting improved viscosity index comprising lubricating oil and a viscosity improving effective amount of ethylene alpha-olefin polymer comprising monomer units derived from ethylene and at least one alpha-olefin represented by the formula H.sub.2 C.dbd.CHR.sup.1 wherein R.sup.1 is an alkyl group of from 1 to 18 carbon atoms, wherein said polymer has a number average molecular weight of from above 25,000 to about 500,000, wherein an average of at least about 30 percent of the polymer chains contain terminal ethenylidene unsaturation, and wherein said polymer is prepared in the presence of a catalyst system comprising at least one metallocene and an alumoxane compound.
    Type: Grant
    Filed: May 20, 1994
    Date of Patent: August 29, 1995
    Assignee: Exxon Chemical Patents Inc.
    Inventor: Mark J. Struglinski
  • Patent number: 5427702
    Abstract: The present invention relates to novel multifunctional viscosity modifiers comprising a mixture of derivatized ethylene-alpha olefin copolymers, A and B. Said A copolymer comprising from about 30 to about 60 weight percent monomer units derived from ethylene and said B copolymer comprising from about 60 to about 80 weight percent units derived from ethylene.
    Type: Grant
    Filed: December 11, 1992
    Date of Patent: June 27, 1995
    Assignee: Exxon Chemical Patents Inc.
    Inventors: David Y. Chung, Paul Brice, Steven J. Searis, Mark J. Struglinski, John B. Gardiner
  • Patent number: 5401427
    Abstract: Degraded molecular weight copolymers of ethylene alpha-olefin are provided. The ethylene alpha-olefin copolymers, before degradation, are characterized by having a narrow molecular weight distribution and are comprised of intramolecularly heterogeneous and intermolecularly homogeneous copolymer chains. The degraded copolymers are useful as viscosity index improvers for oils.
    Type: Grant
    Filed: June 18, 1993
    Date of Patent: March 28, 1995
    Assignee: Exxon Chemical Patents Inc.
    Inventors: David Y. Chung, Mark J. Struglinski
  • Patent number: 5348673
    Abstract: Composition of matter useful as multifunctional viscosity index improver for lubricating oil comprising reaction product of: (i) (a) molecular weight degraded ethylene-alpha-olefin copolymer obtained by degrading copolymer of ethylene and at least one other alpha-olefin monomer, said copolymer comprising intramolecularly heterogeneous copolymer chains containing at least one crystallizable segment of methylene units and at least one low crystallinity ethylene-alpha-olefin copolymer segment, wherein said copolymer has a molecular weight distribution characterized by at least one of a ratio of M.sub.w /M.sub.n of less than 2 and a ratio of M.sub.z /M.sub.w of less than 1.8, and said degraded copolymer grafted with (b) ethylenically monounsaturated carboxylic acid material having 1 to 2 carboxylic acid groups or anhydride group to form grafted ethylene copolymer; (ii) about C.sub.50 to about C.sub.
    Type: Grant
    Filed: December 8, 1993
    Date of Patent: September 20, 1994
    Assignee: Exxon Chemical Patents Inc.
    Inventors: David Y. Chung, Antonio Gutierrez, Mark J. Struglinski
  • Patent number: 5312556
    Abstract: A multifunctional viscosity index improver for lubricating oils comprising reaction product of:(i) (a) degraded ethylene-alpha-olefin copolymer obtained by degrading undegraded copolymer of ethylene and at least one other alpha-olefin monomer, said undegraded copolymer comprising intramolecularly heterogeneous copolymer chain containing at least one crystallizable segment of methylene units and at least one low crystallinity ethylene-alpha-olefin copolymer segment, wherein said at least one crystallizable segment comprises at least about 10 weight percent of said copolymer chain and contains at least about 57 weight percent of said copolymer chain and contains at least about 57 weight percent ethylene, wherein said low crystallinity segment contains not greater than about 53 weight percent ethylene, and wherein said copolymer has a molecular weight distribution characterized by at least one of a ratio of M.sub.w /M.sub.n of less than 2 and a ratio of M.sub.z /M.sub.w of less than 1.
    Type: Grant
    Filed: August 6, 1992
    Date of Patent: May 17, 1994
    Assignee: Exxon Chemical Patents Inc.
    Inventors: David Y. Chung, Mark J. Struglinski
  • Patent number: 5310490
    Abstract: The present invention relates to hydrogenated block copolymers of butadiene and at least one other diene, preferably isoprene. The copolymer is hydrogenated and comprises at least 10% by weight of at least one crystallizable segment and at least one low crystallinity segment.
    Type: Grant
    Filed: March 13, 1991
    Date of Patent: May 10, 1994
    Assignee: Exxon Chemical Products Inc.
    Inventors: Mark J. Struglinski, Gary W. Ver Strate, Lewis J. Fetters
  • Patent number: 5310814
    Abstract: The present invention relates to hydrogenated polybutadiene comprising monomeric units of 1,4-butadiene and 1,2-butadiene addition products. The copolymer is hydrogenated and comprises at least 10% by weight of at least one crystallizable segment and at least one low crystallinity segment.
    Type: Grant
    Filed: March 15, 1991
    Date of Patent: May 10, 1994
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Mark J. Struglinski, Gary W. VerStrate, Lewis J. Fetters
  • Patent number: 5290868
    Abstract: An oil soluble nitrogen containing grafted degraded ethylene copolymers useful as multifunctional viscosity index improvers or modifiers, such as VI improver-dispersant additives. The nitrogen containing grafted degraded ethylene copolymers are grafted with an ethylenically unsaturated carboxylic acid grafting material and the grafted degraded ethylene copolymers are then reacted with at least one polyamine containing one primary amine group and at least one or more secondary amine groups.
    Type: Grant
    Filed: September 16, 1992
    Date of Patent: March 1, 1994
    Assignee: Exxon Chemical Patents Inc.
    Inventors: David Y. Chung, Antonio Gutierrez, Mark J. Struglinski
  • Patent number: 5290461
    Abstract: Composition of matter useful as multifunctional viscosity index improver for lubricating oil comprising reaction product of:(i) (a) degraded ethylene-alpha-olefin copolymer obtained by degrading copolymer of ethylene and at least one other alpha-olefin monomer, said copolymer comprising intramolecularly heterogeneous copolymer chains containing at least one crystallizable segment of methylene units and at least one low crystallinity ethylene-alpha-olefin copolymer segment, wherein said at least one crystallizable segment comprises at least about 10 weight percent of said copolymer chain and contains at least about 57 weight percent ethylene, wherein said low crystallinity segment contains not greater than about 53 weight percent ethylene, and wherein said copolymer has a molecular weight distribution characterized by at least one of a ratio of M.sub.w /M.sub.n of less than 2 and a ratio of M.sub.z /M.sub.w of less than 1.
    Type: Grant
    Filed: March 10, 1992
    Date of Patent: March 1, 1994
    Assignee: Exxon Chemical Patents Inc.
    Inventors: David Y. Chung, Antonio Gutierrez, Mark J. Struglinski
  • Patent number: 5262075
    Abstract: Multifunctional viscosity index improver additives for oleaginous composition comprising reaction products of (i)(a) ethylene-alpha-olefin copolymers grafted with (i)(b) carboxylic acid material, further reacted with (ii) at least one of polyamine, polyol, about C.sub.30 -C.sub.400 hydrocarbyl substituted carboxylic acid component together with polyol, or said carboxylic acid component together with polyamine, wherein the copolymer (i)(a) comprises intramolecularly heterogeneous copolymer chains containing at least one crystallizable segment of methylene units and at least one low crystallinity ethylene-alpha-olefin copolymer segment, and wherein said copolymer has a molecular weight distribution characterized by at least one of a ratio of M.sub.w /M.sub.n of less than 2 and a ratio of M.sub.n /M.sub.w of less than 1.8.
    Type: Grant
    Filed: October 26, 1992
    Date of Patent: November 16, 1993
    Assignee: Exxon Chemical Patents Inc.
    Inventors: David Y. Chung, John E. Johnston, Mark J. Struglinski
  • Patent number: 5252238
    Abstract: The present invention is directed to a viscosity index improver for lubricating oil compositions comprising the reaction product of A) a copolymer of ethylene and at least one other alpha-olefin monomer, said copolymer grafted with ethylenically monounsaturated carboxylic acid material and B) amido-amine or thioamido-amine comprising the reaction product of a polyamine and alpha, beta-unsaturated compound of the formula ##STR1## wherein X is oxygen or sulfur, Y is OR.sup.4, --SR.sup.4 or ##STR2## and R.sup.1, R.sup.2, R.sup.3, R.sup.4 and R.sup.5 are independently selected from hydrogen, hydrocarbyl and substituted hydrocarbyl.
    Type: Grant
    Filed: June 27, 1991
    Date of Patent: October 12, 1993
    Assignee: Exxon Chemical Patents Inc.
    Inventors: David Y. Chung, Antonio Gutierrez, John E. Johnston, Mark J. Struglinski, Robert D. Lundberg
  • Patent number: 5244590
    Abstract: Degraded molecular weight copolymers of ethylene alpha-olefin are provided. The ethylene alpha-olefin copolymers, before degradation, are characterized by having a narrow molecular weight distribution and are comprised of intramolecularly heterogeneous and intermolecularly homogeneous copolymer chains. The degraded copolymers are useful as viscosity index improvers for oils.
    Type: Grant
    Filed: July 11, 1991
    Date of Patent: September 14, 1993
    Assignee: Exxon Chemical Patents Inc.
    Inventors: David Y. Chung, Mark J. Struglinski
  • Patent number: 5167848
    Abstract: Oil soluble grafted ethylene-alpha-olefin copolymer useful as a viscosity modifier for oleaginous compositions comprising:(i) backbone copolymer of ethylene and at least one other alpha-olefin monomer, said copolymer comprising intramolecularly heterogeneous copolymer chains containing at least one crystallizable segment of methylene units and at least one low crysallinity ethylene-alpha-olefin copolymer segment, wherein said at least one crystallizable segment comprises at least about 10 weight percent of said copolymer chain and contains at least about 57 weight percent ethylene, wherein said low crystallinity segment contains not greater than about 53 weight percent ethylene, and wherein said copolymer has a molecular weight distribution characterized by at least one of a ratio of M.sub.w /M.sub.n of less than 2 and a ratio of M.sub.w /M.sub.w of less than 1.
    Type: Grant
    Filed: May 30, 1989
    Date of Patent: December 1, 1992
    Assignee: Exxon Chemical Patents Inc.
    Inventors: David Y. Chung, Mark J. Struglinski, John E. Johnston
  • Patent number: 5151204
    Abstract: The present invention is directed to a lubricating oil composition exhibiting improved viscosity index comprising lubricating oil and a viscosity improving effective amount of ethylene alpha-olefin polymer comprising monomer units derived from ethylene and at least one alpha-olefin represented by the formula H.sup.2 C=CHR.sup.1 wherein R.sup.1 is an alkyl group of from 1 to 18 carbon atoms, and wherein said polymer has a number average molecular weight of from above 20,000 to about 500,000, and an average of at least about 30% of the polymer chains contain terminal ethylidene unsaturation.
    Type: Grant
    Filed: February 1, 1990
    Date of Patent: September 29, 1992
    Assignee: Exxon Chemical Patents Inc.
    Inventor: Mark J. Struglinski
  • Patent number: 5118433
    Abstract: Composition of matter useful as multifunctional viscosity index improver for lubricating oil comprising reaction product of:(i)(a) degraded ethylene-alpha-olein copolymer obtained by degrading copolymer of ethylene and at least one other alpha-olefin monomer, said copolymer comprising intramolecularly heterogeneous copolymer chains containing at least one crystallizable segment of methylene units and at least one low crystallinity ethylene-alpha-olefin copolymer segment, wherein said at least one crystallizable segment comprises at least about 10 weight percent of said copolymer chain and contains at least about 57 weight percent ethylene, wherein said low crystallinity segment contains not greater than about 53 weight percent ethylene, and wherein said copolymer has a molecular weight distribution characterized by at least one of a ratio of M.sub.w /M.sub.n of less than 2 and a ratio of M.sub.z /M.sub.w of less than 1.
    Type: Grant
    Filed: October 12, 1989
    Date of Patent: June 2, 1992
    Assignee: Exxon Chemical Patents Inc.
    Inventors: David Y. Chung, Antonio Gutierrez, Mark J. Struglinski
  • Patent number: 5068047
    Abstract: Degraded molecular weight copolymers of ethylene alpha-olefin are provided. The ethylene alpha-olefin copolymers, before degradation, are characterized by having a narrow molecular weight distribution and are comprised of intramolecularly heterogeneous and intermolecularly homogeneous copolymer chains. The degraded copolymers are useful as viscosity index improvers for oils.
    Type: Grant
    Filed: October 12, 1989
    Date of Patent: November 26, 1991
    Assignee: Exxon Chemical Patents, Inc.
    Inventors: David Y. Chung, Mark J. Struglinski
  • Patent number: 5053151
    Abstract: The present invention is directed to a viscosity index improver for lubricating oil compositions comprising the reaction product of A a copolymer of ethylene and at least one other alpha-olefin monomer, said copolymer grafted with ethylenically monoansaturataed carboxylic acid material and B amido-amine or thioamido-amine comprising the reaction product of a polyamine and alpha, beta-unsaturated compound of the formula ##STR1## wherein X is oxygen or sulfur, Y is OR.sup.4, --SR.sup.4 or ##STR2## and R.sup.1, R.sup.2, R.sup.3 R.sup.4 and R.sup.5 are independently selected from hydrogen, hydrocarbyl and substituted hydrocarbyl.
    Type: Grant
    Filed: May 30, 1989
    Date of Patent: October 1, 1991
    Assignee: Exxon Chemical Patents Inc.
    Inventors: David Y. Chung, Antonio Gutierrez, John E. Johnston, Mark J. Struglinski, Robert D. Lundberg
  • Patent number: 4900461
    Abstract: The present invention relates to novel copolymers of alpha-olefins comprised of intramolecularly heterogeneous and intermolecularly homogeneous copolymer chains.
    Type: Grant
    Filed: May 13, 1988
    Date of Patent: February 13, 1990
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Gary Ver Strate, Ricardo Bloch, Mark J. Struglinski, John E. Johnston, Roger K. West
  • Patent number: 4804794
    Abstract: The present invention relats to novel copolymers of alpha-olefins comprised of intramolecularly heterogeneous and intermolecularly homogeneous copolymer chains.
    Type: Grant
    Filed: July 13, 1987
    Date of Patent: February 14, 1989
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Gary Ver Strate, Ricardo Bloch, Mark J. Struglinski, John E. Johnston, Roger K. West