Abstract: Methods of preparing a dry powder blend co-coagulating conductive carbon black particles and fibrillizable polytetrafluoroethylene particles from an aqueous dispersion and drying the co-coagulate are described. Dry powders prepared by such methods and electrodes prepared from such powders are also described.

Abstract: The process is described for recycling a heat-treated solid article including a fluorinated polymer having a fluorinated polymer backbone chain and a plurality of groups represented by formula —SO3Z, wherein Z is independently a hydrogen, an alkali-metal cation, or a quaternary ammonium cation. The heat-treated solid article was previously heated at a temperature of at least 100° C. The process includes heating the heat-treated solid article in the presence of water and base to form a fluorinated polymer salt solution, allowing the fluorinated polymer salt solution to cool, and converting the fluorinated polymer salt solution to fluorinated polymer solution wherein Z is hydrogen by cation exchange.

Abstract: A composite includes a fluorinated polymer and nanoparticles of a metal salt. The metal salt has a solubility product of not more than 1×10?4. The fluorinated polymer includes a fluorinated polymer backbone chain and a plurality of groups represented by formula —SO2X, in which each X is independently —NZH, —NZSO2(CF2)1-6SO2X?, —NZ[SO2(CF2)dSO2NZ]1-10SO2(CF2)dSO2X? or —OZ, and Z is independently a hydrogen, an alkali-metal cation, or a quaternary ammonium cation, X? is independently —NZH or —OZ, and each d is independently 1 to 6. A polymer electrolyte membrane, an electrode, and a membrane electrode assembly including the composite are also provided.

Abstract: The process produces a fluorinated olefin from a fluorinated copolymer having at least one of sulfonic acid groups, carboxylic acid groups, or salts thereof. The process includes heating the fluorinated copolymer at a first temperature not more than 450° C. to decompose at least one of the sulfonic acid groups, carboxylic acid groups, or salts thereof to form a partially pyrolyzed intermediate and subsequently heating the partially pyrolyzed intermediate at a second temperature of at least 550° C. to produce the fluorinated olefin.

Abstract: The present disclosure relates to a film usable for roll-to-roll processing of flexible electronic devices, the film comprising a composite material comprising a polymer and hexagonal boron nitride particles, wherein the hexagonal boron nitride particles comprise platelet-shaped hexagonal boron nitride particles. The present disclosure further relates to a process for producing said film, and to the use of said film.

Abstract: A fluoropolymer coating composition is described comprising an aqueous liquid medium, fluoropolymer particles dispersed in the aqueous liquid medium, and at least one aziridine compound. The aziridine compound comprises at least two aziridine groups (i.e. polyaziridine) or at least one aziridine group and at least one alkoxy silane group. In another embodiment, an article is described comprising a substrate wherein a surface of the substrate comprises a coating comprising fluoropolymer particles; and a reaction product of at least one aziridine compound comprising at least two aziridine groups or at least one aziridine group and at least one alkoxy silane group. The coating can be utilized as a primer for bonding a non-fluorinated substrate to a fluoropolymer film and/or the coating can be used as an (e.g. outer exposed) surface layer. In some embodiments, the article may be the (e.g. backside) film of a photovoltaic module.

Abstract: A fluoropolymer coating composition is described comprising an aqueous liquid medium, fluoropolymer particles dispersed in the aqueous liquid medium, and at least one aziridine compound. The aziridine compound comprises at least two aziridine groups (i.e. polyaziridine) or at least one aziridine group and at least one alkoxy silane group. In another embodiment, an article is described comprising a substrate wherein a surface of the substrate comprises a coating comprising fluoropolymer particles; and a reaction product of at least one aziridine compound comprising at least two aziridine groups or at least one aziridine group and at least one alkoxy silane group. The coating can be utilized as a primer for bonding a non-fluorinated substrate to a fluoropolymer film and/or the coating can be used as an (e.g. outer exposed) surface layer. In some embodiments, the article may be the (e.g. backside) film of a photovoltaic module.

Abstract: A fluoropolymer coating composition is described comprising an aqueous liquid medium, fluoropolymer particles dispersed in the aqueous liquid medium, and at least one aziridine compound. The aziridine compound comprises at least two aziridine groups (i.e. polyaziridine) or at least one aziridine group and at least one alkoxy silane group. In another embodiment, an article is described comprising a substrate wherein a surface of the substrate comprises a coating comprising fluoropolymer particles; and a reaction product of at least one aziridine compound comprising at least two aziridine groups or at least one aziridine group and at least one alkoxy silane group. The coating can be utilized as a primer for bonding a non-fluorinated substrate to a fluoropolymer film and/or the coating can be used as an (e.g. outer exposed) surface layer. In some embodiments, the article may be the (e.g. backside) film of a photovoltaic module.

Abstract: Described herein is a composition comprising (i) a hydrofluorothermoplastic polymer, wherein the hydrofluorothermoplastic polymer is derived from: (a) 50-85 mol % tetrafluoroethene; (b) 2-15 mol % hexafluoropropene; (c) 10-35 mol % vinylidene fluoride; and (d) 0.1 to 5 mol % of a bromine-containing monomer; and (ii) a perhalogenated thermoplastic polymer. Such compositions can be used in multilayer constructions in, for example, fuel hose applications.

Abstract: A capacitor comprises an electrically conductive cylinder, an electrically conductive or semi-conductive cylindrical shell or shell segment arranged concentrically around the electrically conductive cylinder, and a dielectric arranged between the electrically conductive cylinder and the electrically conductive or semi-conductive cylindrical shell or shell segment. The dielectric comprises a particulate composite including a matrix material having a non-zero (e.g. negative) thermal coefficient of relative permittivity and a particulate filler material blended with the matrix material, the particulate filler material having an opposite (e.g. positive thermal) coefficient of relative permittivity. The positive thermal coefficient of relative permittivity is thereby selected such that the capacitance value of the capacitor is constant within a stability margin over a predefined temperature interval.

Abstract: Described herein is a composition comprising a fluorothermoplastic polymer, wherein the fluorothermoplastic polymer is derived from: (a) 60-85 mol % tetrafluoroethene; (b) 2-12 mol % hexafluoropropene; (c) 10-30 mol % vinylidene fluoride; (d) 0.2 to 5 mol % of a bromine-containing monomer. Such compositions can be used in multilayer constructions in, for example, fuel hose applications.

Abstract: Described herein is a composition comprising a fluorothermoplastic polymer, wherein the fluorothermoplastic polymer is derived from: (a) 60-85 mol % tetrafluoroethene; (b) 2-12 mol % hexafluoropropene; (c) 10-30 mol % vinylidene fluoride; (d) 0.2 to 5 mol % of a bromine-containing monomer. Such compositions can be used in multilayer constructions in, for example, fuel hose applications.

Abstract: Described herein is a composition comprising (i) a hydrofluorothermoplastic polymer, wherein the hydrofluorothermoplastic polymer is derived from: (a) 50-85 mol % tetrafluoroethene; (b) 2-15 mol % hexafluoropropene; (c) 10-35 mol % vinylidene fluoride; and (d) 0.1 to 5 mol % of a bromine-containing monomer; and (ii) a perhalogenated thermoplastic polymer. Such compositions can be used in multilayer constructions in, for example, fuel hose applications.

Abstract: Presently described are methods of making coating comprising aqueous fluoropolymer latex dispersions, aqueous fluoropolymer coating compositions, coated substrates, and (e.g. backside) films of photovoltaic cells. In one embodiment, the film comprises at least one fluoropolymer comprising repeat units derived from VF, VDF, or a combination thereof; inorganic oxide nanoparticles; and a compound that reacts with the repeat units derived from VF and VDF to crosslink the fluoropolymer and/or couple the fluoropolymer to the inorganic oxide nanoparticles. In another embodiment, the backside film comprises at least one fluoropolymer comprising repeat units derived from VF, VDF, or a combination thereof; and an amino-substituted organosilane ester or ester equivalent crosslinking compound.

Abstract: A fluoropolymer coating composition is described comprising an aqueous liquid medium, fluoropolymer particles dispersed in the aqueous liquid medium, and at least one aziridine compound. The aziridine compound comprises at least two aziridine groups (i.e. polyaziridine) or at least one aziridine group and at least one alkoxy silane group. In another embodiment, an article is described comprising a substrate wherein a surface of the substrate comprises a coating comprising fluoropolymer particles; and a reaction product of at least one aziridine compound comprising at least two aziridine groups or at least one aziridine group and at least one alkoxy silane group. The coating can be utilized as a primer for bonding a non-fluorinated substrate to a fluoropolymer film and/or the coating can be used as an (e.g. outer exposed) surface layer. In some embodiments, the article may be the (e.g. backside) film of a photovoltaic module.

Abstract: Presently described are methods of making coating comprising aqueous fluoropolymer latex dispersions, aqueous fluoropolymer coating compositions, coated substrates, and (e.g. backside) films of photovoltaic cells. In one embodiment, the film comprises at least one fluoropolymer comprising repeat units derived from VF, VDF, or a combination thereof; inorganic oxide nanoparticles; and a compound that reacts with the repeat units derived from VF and VDF to crosslink the fluoropolymer and/or couple the fluoropolymer to the inorganic oxide nanoparticles. In another embodiment, the backside film comprises at least one fluoropolymer comprising repeat units derived from VF, VDF, or a combination thereof; and an amino-substituted organosilane ester or ester equivalent crosslinking compound.

Abstract: Presently described are methods of making coating comprising aqueous fluoropolymer latex dispersions, aqueous fluoropolymer coating compositions, coated substrates, and (e.g. backside) films of photovoltaic cells. In one embodiment, the film comprises at least one fluoropolymer comprising repeat units derived from VF, VDF, or a combination thereof; inorganic oxide nanoparticles; and a compound that reacts with the repeat units derived from VF and VDF to crosslink the fluoropolymer and/or couple the fluoropolymer to the inorganic oxide nanoparticles. In another embodiment, the backside film comprises at least one fluoropolymer comprising repeat units derived from VF, VDF, or a combination thereof; and an amino-substituted organosilane ester or ester equivalent crosslinking compound.

Abstract: Presently described are methods of making coating comprising aqueous fluoropolymer latex dispersions, aqueous fluoropolymer coating compositions, coated substrates, and (e.g. backside) films of photovoltaic cells. In one embodiment, the film comprises at least one fluoropolymer comprising repeat units derived from VF, VDF, or a combination thereof; inorganic oxide nanoparticles; and a compound that reacts with the repeat units derived from VF and VDF to crosslink the fluoropolymer and/or couple the fluoropolymer to the inorganic oxide nanoparticles. In another embodiment, the backside film comprises at least one fluoropolymer comprising repeat units derived from VF, VDF, or a combination thereof; and an amino-substituted organosilane ester or ester equivalent crosslinking compound.

Abstract: The multilayer film serves as a laminate. In some embodiments, the film is a multilayered structure that, in its base form, encompasses an intermediate layer with first and second outer layer affixed to opposing sides of the intermediate layer. In some embodiments, the first outer layer is a semi-crystalline fluoropolymer. In some embodiments, the intermediate layer includes a polyester and the second outer layer is an olefinic polymer.

Abstract: The multilayer film serves as a laminate. The film is a multilayered structure that, in its base form, encompasses an intermediate layer with first and second outer layer affixed to opposing sides of the intermediate layer. The first outer layer is a semi-crystalline fluoropolymer. The intermediate layer includes a polyester and the second outer layer is an olefinic polymer. The layers are bonded together in the noted order to provide the multilayer film.