Abstract: Methods and systems for controlling bubble size and bubble decay rate of glass foams formed during submerged combustion melting. Flowing a molten mass of foamed glass comprising molten glass and bubbles entrained therein into an apparatus downstream of a submerged combustion melter. The downstream apparatus has a floor, a roof, and a sidewall structure connecting the floor and roof. The foamed glass has glass foam of glass foam bubbles on its top surface, and the downstream apparatus defines a space for a gaseous atmosphere above and in contact with the glass foam. The downstream apparatus includes heating components to heat or maintain temperature of the foamed glass. Adjusting composition of the atmosphere above the glass foam, and/or contacting the foam with a liquid or solid composition controls bubble size of the glass foam bubbles, and/or foam decay rate.

Abstract: Methods and systems for de-stabilizing foam produced in submerged combustion melters. A molten mass of glass and bubbles is flowed into an apparatus downstream of a submerged combustion melter. The downstream apparatus includes a floor, a roof and a wall connecting the floor and roof, but is devoid of submerged combustion burners and other components that would increase turbulence of the molten mass. The molten mass has foam on at least a portion of a top surface of the molten mass. Certain methods include imposing a de-stabilizing force directly to the foam or to the molten mass and foam, where the de-stabilizing force may be a vibratory force, an acoustic wave force, a particulate-based force, or a non-particulate-based mechanical force. Systems for carrying out the methods are described.

Abstract: Submerged combustion systems and methods of use to produce glass. One system includes a submerged combustion melter having a roof, a floor, a wall structure connecting the roof and floor, and an outlet, the melter producing an initial foamy molten glass. One or more non-submerged auxiliary burners are positioned in the roof and/or wall structure and configured to deliver combustion products to impact at least a portion of the bubbles with sufficient force and/or heat to burst at least some of the bubbles and form a reduced foam molten glass.

Abstract: Primary inorganic feedstock material is introduced into the melting region of an SCM melter. The material is heated with a burner to form a turbulent melt matrix. The burner exit is disposed below the top surface of the turbulent melt matrix. A mixture of secondary inorganic material and organic material is introduced into the melting region below the top surface of the turbulent melt mixture. The mixture is heated with the burner to incorporate the secondary inorganic material into the turbulent melt matrix and combust at least some of the organic material to produce heat.

Abstract: Controlling foam in apparatus downstream of a melter by adjustment of alkali oxide content in the melter. One method includes feeding a feedstock into a submerged combustion melter (SCM) apparatus having an internal space containing a flowing or non-flowing molten mass of foamed glass comprising molten glass and bubbles entrained therein, the molten mass having glass foam comprising glass foam bubbles on at least a portion of a top surface of the molten mass. The molten mass from the SCM is routed to a downstream apparatus, stability of the glass foam in the downstream apparatus is observed, and alkali oxide percentage fed to the SCM apparatus is adjusted based on the observation to positively or negatively affect the foam stability. Systems for carrying out the methods, and the products of the methods are also considered novel and inventive.

Abstract: A method of forming a rope material from a loose feed scrap includes a number of operations to mechanically bind the loose feed scrap. The feed scrap is collected. The feed scrap is twisted and compressed, operations that may be performed simultaneously. This twisted and compressed feed scrap, now in the form of a rope material, is then fed into a melter system.

Abstract: A submerged combustion melter includes a floor, a roof, and a sidewall structure connecting the floor and roof defining an internal space. A first portion of the internal space defines a melting zone, and a second portion defines a fining zone immediately downstream of the melting zone. One or more combustion burners in either the floor, roof, the sidewall structure, or any combination of these, are configured to emit the combustion gases from a position under a level of, and positioned to transfer heat to and produce, a turbulent molten mass of glass containing bubbles in the melting zone. The fining zone is devoid of combustion burners or other apparatus or components that would increase turbulence above that in the melting zone. The melter may include a treating zone that stabilizes or destabilizes bubbles and/or foam. Processes of using the melters are a feature of the disclosure.

Abstract: Combustion burner panels, submerged combustion melters including one or more of the panels, and methods of making the same are disclosed. In certain embodiments, the burner panel includes a panel body having first and second major surfaces, at least one oxidant through-passage extending from the first to the second major surface, and at least one fuel through-passage extending from the first to the second major surface. Oxidant and fuel delivery conduits are positioned in the respective passages. The oxidant and fuel delivery conduits include proximal and distal ends, at least some of the distal ends positioned away from the first major surface of the panel body. In other embodiments the burner panels include a frame enclosing a porous material having through passages for fuel and oxidant. The burner panels may enable delaying combustion in a submerged combustion melter, and therefore promote burner life and melter campaign length.

Abstract: Apparatus includes a first and second conduits configured to form an annulus between them. An adjustable structure includes a body having an upper surface, a lower surface, and a circumferential surface abutting a portion of the internal surface of the second conduit. The structure is adjustable axially in relation to and removably attached to the first conduit via a hub. The hub defines a central passage for fuel or oxidant. The body has one or more non-central through passages configured such that flow of an oxidant or fuel therethrough causes the fuel or oxidant to intersect flow of fuel or oxidant exiting from the central passage in a region above the upper surface of the body.

Abstract: Submerged combustion systems and methods of use to produce glass. One system includes a submerged combustion melter having a roof, a floor, a wall structure connecting the roof and floor, and an outlet, the melter producing an initial foamy molten glass. One or more non-submerged auxiliary burners are positioned in the roof and/or wall structure and configured to deliver combustion products to impact at least a portion of the bubbles with sufficient force and/or heat to burst at least some of the bubbles and form a reduced foam molten glass.

Abstract: Methods and systems for de-stabilizing foam produced in submerged combustion melters. A molten mass of glass and bubbles is flowed into an apparatus downstream of a submerged combustion melter. The downstream apparatus includes a floor, a roof and a wall connecting the floor and roof, but is devoid of submerged combustion burners and other components that would increase turbulence of the molten mass. The molten mass has foam on at least a portion of a top surface of the molten mass. One method includes directly impinging an impinging composition onto at least a portion of the foam in the downstream apparatus. Systems for carrying out the methods are described.

Abstract: Processes and systems for producing glass fibers having regions devoid of glass using submerged combustion melters, including feeding a vitrifiable feed material into a feed inlet of a melting zone of a melter vessel, and heating the vitrifiable material with at least one burner directing combustion products of an oxidant and a first fuel into the melting zone under a level of the molten material in the zone. One or more of the burners is configured to impart heat and turbulence to the molten material, producing a turbulent molten material comprising a plurality of bubbles suspended in the molten material, the bubbles comprising at least some of the combustion products, and optionally other gas species introduced by the burners. The molten material and bubbles are drawn through a bushing fluidly connected to a forehearth to produce a glass fiber comprising a plurality of interior regions substantially devoid of glass.

Abstract: Apparatus includes a first and second conduits configured to form an annulus between them. An adjustable structure includes a body having an upper surface, a lower surface, and a circumferential surface abutting a portion of the internal surface of the second conduit. The structure is adjustable axially in relation to and removably attached to the first conduit via a hub. The hub defines a central passage for fuel or oxidant. The body has one or more non-central through passages configured such that flow of an oxidant or fuel therethrough causes the fuel or oxidant to intersect flow of fuel or oxidant exiting from the central passage in a region above the upper surface of the body.

Abstract: A submerged combustion melter includes a floor, a roof, and a sidewall structure connecting the floor and roof defining an internal space. A first portion of the internal space defines a melting zone, and a second portion defines a fining zone immediately downstream of the melting zone. One or more combustion burners in either the floor, roof, the sidewall structure, or any combination of these, are configured to emit the combustion gases from a position under a level of, and positioned to transfer heat to and produce, a turbulent molten mass of glass containing bubbles in the melting zone. The fining zone is devoid of combustion burners or other apparatus or components that would increase turbulence above that in the melting zone. The melter may include a treating zone that stabilizes or destabilizes bubbles and/or foam. Processes of using the melters are a feature of the disclosure.

Abstract: Processes and systems for producing glass fibers having regions devoid of glass using submerged combustion melters, including feeding a vitrifiable feed material into a feed inlet of a melting zone of a melter vessel, and heating the vitrifiable material with at least one burner directing combustion products of an oxidant and a first fuel into the melting zone under a level of the molten material in the zone. One or more of the burners is configured to impart heat and turbulence to the molten material, producing a turbulent molten material comprising a plurality of bubbles suspended in the molten material, the bubbles comprising at least some of the combustion products, and optionally other gas species introduced by the burners. The molten material and bubbles are drawn through a bushing fluidly connected to a forehearth to produce a glass fiber comprising a plurality of interior regions substantially devoid of glass.

Abstract: Methods and systems for de-stabilizing foam produced in submerged combustion melters. A molten mass of glass and bubbles is flowed into an apparatus downstream of a submerged combustion melter. The downstream apparatus includes a floor, a roof and a wall connecting the floor and roof, but is devoid of submerged combustion burners and other components that would increase turbulence of the molten mass. The molten mass has foam on at least a portion of a top surface of the molten mass. One method includes directly impinging an impinging composition onto at least a portion of the foam in the downstream apparatus. Systems for carrying out the methods are described.

Abstract: A method comprises flowing an oxidant and a fuel into a submerged combustion burner in a glass tank furnace, the glass tank furnace receiving a feed of glass forming material and producing molten glass, the burner and furnace comprising a melting system. The melting system has a variable system vibration and/or oscillation due to the nature of submerged combustion. One method includes predicting a value of at least one property, such as viscosity, of the molten glass using the variable system vibration and/or oscillation.

Abstract: Submerged combustion burners having a burner body and a burner tip connected thereto. The burner body has an external conduit and first and second internal conduits substantially concentric therewith, forming first and second annuli for passing a cooling fluid therethrough. A burner tip body is connected to the burner body at ends of the external and second internal conduits. The burner tip includes a generally central flow passage for a combustible mixture, the flow passage defined by an inner wall of the burner tip. The burner tip further has an outer wall and a crown connecting the inner and outer walls. The inner and outer walls, and the crown are comprised of same or different materials having greater corrosion and/or fatigue resistance than at least the external burner conduit.

Abstract: Processes of controlling submerged combustion melters, and systems for carrying out the methods. One process includes feeding vitrifiable material into a melter vessel, the melter vessel including a fluid-cooled refractory panel in its floor, ceiling, and/or sidewall, and heating the vitrifiable material with a burner directing combustion products into the melting zone under a level of the molten material in the zone. Burners impart turbulence to the molten material in the melting zone. The fluid-cooled refractory panel is cooled, forming a modified panel having a frozen or highly viscous material layer on a surface of the panel facing the molten material, and a sensor senses temperature of the modified panel using a protected thermocouple positioned in the modified panel shielded from direct contact with turbulent molten material. Processes include controlling the melter using the temperature of the modified panel. Other processes and systems are presented.

Abstract: Apparatus includes a first and second conduits configured to form an annulus between them. An adjustable structure includes a body having an upper surface, a lower surface, and a circumferential surface abutting a portion of the internal surface of the second conduit. The structure is adjustable axially in relation to and removably attached to the first conduit via a hub. The hub defines a central passage for fuel or oxidant. The body has one or more non-central through passages configured such that flow of an oxidant or fuel therethrough causes the fuel or oxidant to intersect flow of fuel or oxidant exiting from the central passage in a region above the upper surface of the body.