Patents by Inventor Mark Wilton Smale

Mark Wilton Smale has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 7160833
    Abstract: A spray-dried composition comprising the reaction product of a magnesium halide, a solvent, an electron donor compound, and a transition metal compound and an inert filler comprising substantially spherical particles having an average particle size ranging from about 1 ?m to about 12 ?m, and a polymerization process using the same.
    Type: Grant
    Filed: July 13, 2004
    Date of Patent: January 9, 2007
    Assignee: Dow Global Technologies Inc.
    Inventors: Burkhard Eric Wagner, Mark Wilton Smale, Robert James Jorgensen
  • Publication number: 20040259723
    Abstract: A spray-dried composition comprising the reaction product of a magnesium halide, a solvent, an electron donor compound, and a transition metal compound and an inert filler comprising substantially spherical particles having an average particle size ranging from about 1 &mgr;m to about 12 &mgr;m, and a polymerization process using the same.
    Type: Application
    Filed: July 13, 2004
    Publication date: December 23, 2004
    Inventors: Burkhard Eric Wagner, Mark Wilton Smale, Robert James Jorgensen
  • Patent number: 6806221
    Abstract: A method of making a spray-dried composition using a solution or mixture comprising the reaction product of a magnesium halide, a solvent, an electron donor compound, and a transition metal compound and an inert filler comprising substantially spherical particles having an average particle size ranging from 1 &mgr;m to about 12 &mgr;m.
    Type: Grant
    Filed: July 15, 2002
    Date of Patent: October 19, 2004
    Assignee: Dow Global Technologies Inc.
    Inventors: Burkhard Eric Wagner, Robert James Jorgensen, Mark Wilton Smale
  • Publication number: 20040010100
    Abstract: A spray-dried composition comprising an inert porous filler and a reaction product of 1) a mixture or reaction product of a magnesium halide, a solvent, an electron donor compound, and a transition metal compound. The filler is substantially spherical and has an average particle size ranging from about 1 &mgr;m to about 12 &mgr;m. Methods of making spray-dried compositions, catalysts and polymerization processes employing such are also described.
    Type: Application
    Filed: July 15, 2002
    Publication date: January 15, 2004
    Inventors: Burkhard Eric Wagner, Robert James Jorgensen, Mark Wilton Smale
  • Patent number: 5744556
    Abstract: A process for the gas-phase polymerization of polymers which allows for the introduction of an unsupported polymerization catalyst system into the gas-phase reactor, wherein the unsupported polymerization catalyst system comprises (i) a non-volatile materials fraction containing a polymerization catalyst; (ii) a solvent fraction which is at least partially miscible with the non-volatile materials fraction and which is sufficiently volatile to allow for the formation of polymerization catalyst particles when the mixture of the solvent fraction and the non-volatile materials fraction is sprayed into the reactor; (iii) a compressed fluid; and (iv) optionally a slowly vaporizing solvent.
    Type: Grant
    Filed: September 13, 1996
    Date of Patent: April 28, 1998
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventors: George Ernest Keller, Keith Ernest Carmichael, Jean Bowman Cropley, Eldon Ronald Larsen, Arakalud Venkatapathia Ramamurthy, Mark Wilton Smale, Timothy Todd Wenzel, Clark Curtis Williams
  • Patent number: 5674795
    Abstract: Metallocene-containing catalyst compositions that include inert filler, a method for their preparation, and a method for their use in production of polyolefins are disclosed and claimed. The catalyst compositions contain solid particles of a mixture comprising a) a metallocene catalyst; b) a cocatalyst capable of activating said metallocene catalyst; and c) particulate filler material having an average particle size of less than about 10 micrometers that is unreactive with the metallocene catalyst and the cocatalyst. They are prepared by spray drying a slurry of the constituents.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: October 7, 1997
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventors: Eric Paul Wasserman, Mark Wilton Smale, Timothy Roger Lynn, Robert Converse Brady, III, Frederick John Karol
  • Patent number: 5672669
    Abstract: Metallocene-containing catalyst compositions that include inert filler, a method for their preparation, and a method for their use in production of polyolefins are disclosed and claimed. The catalyst compositions contain solid particles of a mixture comprising a) a metallocene catalyst; b) a cocatalyst capable of activating said metallocene catalyst; and c) particulate filler material having an average particle size of less than about 10 micrometers that is unreactive with the metallocene catalyst and the cocatalyst. They are prepared by spray drying a slurry of the constituents.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: September 30, 1997
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventors: Eric Paul Wasserman, Mark Wilton Smale, Timothy Roger Lynn, Robert Converse Brady III, Frederick John Karol
  • Patent number: 5648310
    Abstract: Metallocene-containing catalyst compositions that include inert filler, a method for their preparation, and a method for their use in production of polyolefins are disclosed and claimed. The catalyst compositions contain solid particles of a mixture comprising a) a metallocene catalyst; b) a cocatalyst capable of activating said metallocene catalyst; and c) particulate filler material having an average particle size of less than about 10 micrometers that is unreactive with the metallocene catalyst and the cocatalyst. They are prepared by spray drying a slurry of the constituents.
    Type: Grant
    Filed: June 26, 1995
    Date of Patent: July 15, 1997
    Assignee: Union Carbide Chemicals & Plastics Technology Corporation
    Inventors: Eric Paul Wasserman, Mark Wilton Smale, Timothy Roger Lynn, Robert Converse Brady, III, Frederick John Karol