Patents by Inventor Markku Vahteri
Markku Vahteri has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 10364310Abstract: The present invention relates to a process for producing ethylene copolymers in a multistage process comprising at least one slurry phase polymerization stage and at least one gas phase polymerization stage in the presence of Ziegler Natta catalyst comprising a solid catalyst component, a cocatalyst of a compound of group 13 metal and an external additive selected from alkoxysilanes of formula (I) R1nSi(OR2)4-n, (I) where n is an integer 0 to 3, each R1 are equal or different and are selected among H, halogen, alkyl groups of 1 to 6 10 carbon atoms optionally substituted with one or more halogen atoms, alkenyl groups of 2 to 6 carbon atoms optionally substituted with one or more halogen atoms, and aryl groups of 6 to 12 carbon atoms optionally substituted with one or more halogen atoms, or the R1 groups can form with the Si atom they are linked to a ring of 3 to 8 ring atoms, provided that all R1 are not hydrogen, R2 are equal or different and are selected among alkyl groups of 1 to 6 carbon atoms optionallyType: GrantFiled: February 4, 2016Date of Patent: July 30, 2019Assignee: BOREALIS AGInventors: Victor Sumerin, Joseph Thorman, Jani Aho, Markku Vahteri, Ravindra Tupe, Jarmo Kela
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Publication number: 20190119419Abstract: A process for producing copolymers of ethylene and at least one alpha-olefin having from 4 to 10 carbon atoms in the presence of a solid Ziegler-Natta catalyst comprising of magnesium, titanium, halogen and an internal organic compound, the copolymer having a density of from 906 to 937 kg/m3 and a melt flow rate MFR21 measured at 190° C. under 21.6 kg load of from 3 to 150 g/10 min. The process includes the steps of (A) homopolymerising ethylene or copolymerising ethylene and a first alpha-olefin having from 4 to 10 carbon atoms in a first polymerisation stage in the presence of the polymerisation catalyst, hydrogen and optionally the first alpha-olefin; (B) copolymerising ethylene and a second alpha-olefin having from 4 to 10 carbon atoms in a second polymerisation stage in the presence of the first homo- or copolymer of ethylene and the Ziegler-Natta catalyst; and (C) recovering the polymer mixture.Type: ApplicationFiled: June 23, 2016Publication date: April 25, 2019Inventors: Alexandra Romina ALBUNIA, Ravindra TUPE, Victor SUMERIN, John JAMIESON, Jani AHO, Markku VAHTERI, Jarmo KELA, Renate ECKMAYR
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Publication number: 20180346622Abstract: The present invention relates to a film comprising at least one layer which comprises a polymer composition comprising (a) a multimodal polymer of ethylene.Type: ApplicationFiled: November 18, 2015Publication date: December 6, 2018Inventors: Jarmo Kela, Peter Niedersuss, Jari Aarila, Markku Vahteri, Floran Prades, John Jamieson, Willem Wever
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Publication number: 20180148570Abstract: The present invention is directed to a multimodal polyethylene copolymer comprising a first and a second copolymer of ethylene and at least two alpha-olefin comonomers. The multimodal polyethylene copolymer is highly suitable for the production of films providing high impact strength in the sense of high Dart drop impact strength (DDI) and low extractables. The invention further presents final articles such as films made therefrom.Type: ApplicationFiled: May 30, 2016Publication date: May 31, 2018Applicant: BOREALIS AGInventors: Ravindra TUPE, John JAMIESON, Jarmo KELA, Alexandra Romina ALBUNIA, Ricardo GODOY-LOPEZ, Markku VAHTERI
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Patent number: 9951213Abstract: The present invention is a process for producing low density copolymers of ethylene and alpha-olefins having from 4 to 10 carbon atoms in three polymerization stages in the presence of an olefin polymerization catalyst where a low molecular weight copolymer of ethylene is produced in two of the stages and a high molecular weight copolymer in one of the stages. The resulting copolymers have a low density of not more than 920 kg/m3.Type: GrantFiled: December 12, 2014Date of Patent: April 24, 2018Assignee: BOREALIS AGInventors: Ravindra Tupe, Jani Aho, Markku Vahteri, Tuomas Noopila, Jarmo Kela
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Publication number: 20180079899Abstract: The present invention is directed to a multimodal polyethylene copolymer comprising a first and a second copolymer of ethylene and at least two alpha-olefin comonomers. Such multimodal copolymers are highly suitable for conversion processes that require a high Draw Down Ratio, like the production of thin films. Such multimodal polyethylene copolymers provide a good impact strength in the sense of a high Dart drop impact strength (DDI) and good isotropy of the films produces thereof. The invention further presents final articles such as films made therefrom.Type: ApplicationFiled: May 30, 2016Publication date: March 22, 2018Applicant: BOREALIS AGInventors: Ravindra TUPE, John JAMIESON, Jarmo KELA, Alexandra Romina ALBUNIA, Ricardo GODOY-LOPEZ, Markku VAHTERI
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Publication number: 20180030179Abstract: The present invention relates to a process for producing ethylene copolymers in a multistage process comprising at least one slurry phase polymerization stage and at least one gas phase polymerization stage in the presence of Ziegler Natta catalyst comprising a solid catalyst component, a cocatalyst of a compound of group 13 metal and an external additive selected from alkoxysilanes of formula (I) R1nSi(OR2)4-n, (I) where n is an integer 0 to 3, each R1 are equal or different and are selected among H, halogen, alkyl groups of 1 to 6 10 carbon atoms optionally substituted with one or more halogen atoms, alkenyl groups of 2 to 6 carbon atoms optionally substituted with one or more halogen atoms, and aryl groups of 6 to 12 carbon atoms optionally substituted with one or more halogen atoms, or the R1 groups can form with the Si atom they are linked to a ring of 3 to 8 ring atoms, provided that all R1 are not hydrogen, R2 are equal or different and are selected among alkyl groups of 1 to 6 carbon atoms optionallyType: ApplicationFiled: February 4, 2016Publication date: February 1, 2018Inventors: Victor SUMERIN, Joseph THORMAN, Jani AHO, Markku VAHTERI, Ravindra TUPE, Jarmo KELA
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Publication number: 20170327678Abstract: The present invention relates to a polymer composition, to the use of the polymer composition in film applications and to a film comprising the polymer composition of the invention.Type: ApplicationFiled: November 18, 2015Publication date: November 16, 2017Inventors: Jarmo Kela, Peter Niedersuss, Jari Aarila, Markku Vahteri, Floran Prades, John Jamieson, Willem Wever
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Publication number: 20160272799Abstract: The present invention is a process for producing low density copolymers of ethylene and alpha-olefins having from 4 to 10 carbon atoms in three polymerization stages in the presence of an olefin polymerization catalyst where a low molecular weight copolymer of ethylene is produced in two of the stages and a high molecular weight copolymer in one of the stages. The resulting copolymers have a low density of not more than 920 kg/m3.Type: ApplicationFiled: December 12, 2014Publication date: September 22, 2016Inventors: Ravindra TUPE, Jani AHO, Markku VAHTERI, Tuomas NOOPILA, Jarmo KELA
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Patent number: 9434798Abstract: An ethylene polymer with a density of less than 955 kg/m3 obtained by polymerisation with a single-site catalyst and having a shear thinning index SHI2.7/210 of less than 5 wherein ethylene polymer comprises two components.Type: GrantFiled: November 25, 2013Date of Patent: September 6, 2016Assignee: BOREALIS AGInventors: Esa Kokko, Anneli Pakkanen, Markku Vahteri, Magnus Palmlof, Jeroen Oderkerk
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Patent number: 9234061Abstract: A multimodal ethylene copolymer with a density of at least 940 kg/m3 having an MFR21 in the range of 1 to 30 g/10 min and a Fmax/?I ratio of less than 60 cN/s; said ethylene copolymer comprising at least three components (I) an ethylene and optionally at least one C3-20 alpha olefin comonomer component forming 30 to 60 wt % of said ethylene copolymer; (II) an ethylene and optionally at least one C3-20 alpha olefin comonomer second component forming 30 to 60 wt % of said ethylene copolymer: and (III) an ethylene and optionally at least one C3-20 alpha olefin comonomer third component forming 3 to 20 wt % of said ethylene copolymer; wherein at least one of components (II) or (III) is a copolymer.Type: GrantFiled: March 28, 2013Date of Patent: January 12, 2016Assignee: BOREALIS AGInventors: Markku Vahteri, Antti Tynys, Erik Eriksson, Magnus Palmlöf, Tuomas Noopila, Ilke Senol, Saeid Kheirandish
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Patent number: 9017784Abstract: The present invention relates to a pipe made of a polyethylene composition comprising a polyethylene base resin, which comprises c. an ethylene copolymer as fraction (A), and d. an ethylene homo- or copolymer as fraction (B), with fraction (A) having a lower molecular weight than fraction (B), wherein the polyethylene base resin is obtainable in a polymerization process in which a single-site catalyst (SSC) is used in the polymerization of at least one of fractions (A) and (B), the base resin having (i) a density of below 940 kg/m3, and (ii) a MFR5 at 190° C./5.00 kg of at least 0.20 g/10 min, and the polyethylene composition having a time to failure of at least 250 h measured according to ISO 1167 at 95° C. and 4.3 MPa.Type: GrantFiled: November 21, 2007Date of Patent: April 28, 2015Assignee: Borealis Technology OyInventors: Magnus Palmlöf, Solveig Johansson, Markku Vähteri
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Publication number: 20150051364Abstract: A multimodal ethylene copolymer with a density of at least 940 kg/m3 having an MFR21 in the range of 1 to 30 g/10 min and a Fmax/?1 ratio of less than 60 cN/s; said ethylene copolymer comprising at least three components (I) an ethylene and optionally at least one C3-20 alpha olefin comonomer component forming 30 to 60 wt % of said ethylene copolymer; (II) an ethylene and optionally at least one C3-20 alpha olefin comonomer second component forming 30 to 60 wt % of said ethylene copolymer: and (III) an ethylene and optionally at least one C3-20 alpha olefin comonomer third component forming 3 to 20 wt % of said ethylene copolymer; wherein at least one of components (II) or (III) is a copolymer.Type: ApplicationFiled: March 28, 2013Publication date: February 19, 2015Applicant: BOREALIS AGInventors: Markku Vahteri, Antti Tyns, Erik Eriksson, Magnus Palmlöf
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Publication number: 20140183797Abstract: An ethylene polymer with a density of less than 955 kg/m3 obtained by polymerisation with a single-site catalyst and having a shear thinning index SHI2.7/210 of less than 5 wherein ethylene polymer comprises two components.Type: ApplicationFiled: November 25, 2013Publication date: July 3, 2014Applicant: BOREALIS AGInventors: ESA KOKKO, ANNELI PAKKANEN, MARKKU VAHTERI, MAGNUS PALMLOF, JEROEN ODERKERK
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Patent number: 8623482Abstract: The present invention deals with coated pipes having a layer of multimodal polyethylene. The multimodal ethylene copolymer is a copolymer of ethylene with one or more alpha-olefin comonomers having from 4 to 10 carbon atoms and has a weight average molecular weight of from 70000 g/mol to 250000 g/mol, the ratio of the weight average molecular weight to the number average molecular weight, Mw/Mn, of from 15 to 50, a melt index MFR2 of from 0.05 g/10 min to 5 g/10 min, a melt index MFR5 of from 0.5 to 10 g/10 min and a density of from 930 kg/m to 955 kg/m3.Type: GrantFiled: December 9, 2008Date of Patent: January 7, 2014Assignee: Borealis Technology OyInventors: Martin Anker, Siw Bodil Fredriksen, Pal Christian Bentzrod, Mats Backman, Leif Leiden, Markku Vahteri, Petri Rekonen
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Patent number: 8461280Abstract: A multimodal linear low density polyethylene polymer having a final density of 900 to 940 kg/m3, and containing at least one ?-olefin comonomer in addition to ethylene comprising: (A) 30 to 60 wt % of a lower molecular weight component being an ethylene homopolymer or a copolymer of ethylene and at least one ?-olefin; and (B) 70 to 40 wt % of a higher molecular weight component being a copolymer of ethylene and at least one ?-olefin, said ?-olefin being the same or different from any ?-olefin used in component (A) but with the proviso that both components (A) and (B) are not polymers of ethylene and butane alone; wherein the multimodal LLDPE has a dart drop of at least 700 g; and wherein components (A) and (B) are obtainable using a Ziegler-Natta catalyst.Type: GrantFiled: December 5, 2008Date of Patent: June 11, 2013Assignee: Borealis Technology OyInventors: Virginie Eriksson, Marjo Vaananen, Markku Vahteri, Thomas Garoff, Petri Rekonen, Jari Hatonen, Siw Bodil Fredriksen, Katrin Nord-Varhaug, Marit Seim, Jorunn Nilsen, Irene Helland
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Patent number: 8445599Abstract: The present inventions relates to a process for producing polyethylene compositions comprising polymerizing polyethylene resins in a cascaded multi-stage reaction in which the reaction steps are performed in at least two slurry phase reactors (A) and (B) and at least one gas phase reactor (C) which are arranged in series in any order wherein in reactor (A) a low molecular weight ethylene homo- or copolymer fraction having a MFR2 of 100 to 2000 g/10 min, in reactor (B) a low molecular weight ethylene homo- or copolymer fraction having an MFR2 of 100 to 2000 g/10 min, and in reactor (C) a high molecular weight ethylene copolymer fraction are polymerized, and further comprising a compounding step after polymerization, wherein the final polyethylene composition has a MFR21 of 3 to 50 g/10 min, the melt flow rates being determined according to ISO 1133.Type: GrantFiled: October 16, 2009Date of Patent: May 21, 2013Assignee: Borealis AGInventors: Bill Gustafsson, Jari Hatonen, Petri Rekonen, Markku Vahteri, Siw Bodil Fredriksen, Arild Follestad, Karl Isak Skau
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Patent number: 8361578Abstract: Coated pipes have a layer of multimodal polyethylene. The multimodal ethylene copolymer is a copolymer of ethylene with one or more alpha-olefin comonomers having from 4 to 10 carbon atoms and has a weight average molecular weight of from 70000 g/mol to 250000 g/mol, the ratio of the weight average molecular weight to the number average molecular weight, Mw/Mn, of from 15 to 50, a melt index MFR2 of from 0.05 g/10 min to 5 g/10 min, a melt index MFR5 of from 0.5 to 10 g/10 min and a density of from 930 kg/m3 to 955 kg/m3.Type: GrantFiled: December 8, 2008Date of Patent: January 29, 2013Assignee: Borealis Technology OYInventors: Mats Backman, Martin Anker, Siw Bodil Fredriksen, Leif Leiden, Markku Vahteri, Petri Rekonen
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Patent number: 8142871Abstract: The present invention deals with coated pipes having a layer of multimodal polyethylene. The multimodal ethylene copolymer is a copolymer of ethylene with one or more alpha-olefin comonomers having from 4 to 10 carbon atoms and has a weight average molecular weight of from 70000 g/mol to 250000 g/mol and a melt index MFR2 of from 0.05 g/10 min to 5 g/10 min, a melt index MFR5 of from 0.5 to 10 g/10 min and a density of from 945 kg/m3 to 958 kg/m3. The coatings have a high stiffness, good properties at elevated temperatures and acceptable stress-cracking properties.Type: GrantFiled: December 10, 2008Date of Patent: March 27, 2012Assignee: Borealis Technology OYInventors: Martin Anker, Siw Bodil Fredriksen, Pal Christian Bentzrod, Mats Bäckman, Leif Leiden, Markku Vahteri, Petri Rekonen
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Publication number: 20110288237Abstract: The present inventions relates to a process for producing polyethylene compositions comprising polymerising polyethylene resins in a cascaded multi-stage reaction in which the reaction steps are performed in at least two slurry phase reactors (A) and (B) and at least one gas phase reactor (C) which are arranged in series in any order wherein in reactor (A) a low molecular weight ethylene homo- or copolymer fraction having a MFR2 of 100 to 2000 g/10 min, in reactor (B) a low molecular weight ethylene homo- or copolymer fraction having an MFR2 of 100 to 2000 g/10 min, and in reactor (C) a high molecular weight ethylene copolymer fraction are polymerised, and further comprising a compounding step after polymerisation, wherein the final polyethylene composition has a MFR21 of 3 to 50 g/10 min, the melt flow rates being determined according to ISO 1133, a multimodal polymer composition comprising a polyethylene resin comprising (i) a first low molecular weight ethylene homo- or copolymer fraction having a MFR2Type: ApplicationFiled: October 16, 2009Publication date: November 24, 2011Applicant: BOREALIS AGInventors: Bill Gustafsson, Jari Hatonen, Petri Rekonen, Markku Vahteri, Siw Bodil Fredriksen, Arild Follestad, Karl Isak Skau