Patents by Inventor Markus Brym

Markus Brym has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 11072570
    Abstract: Continuous preparation of polyisobutylene having a content of terminal double bonds of more than 50% by polymerizing isobutene in the presence of a polymerization catalyst customary therefor, by combining a technical 1-butene-, 2-butene- and isobutene-containing C4 hydrocarbon stream together with a stream of pure isobutene and feeding them into the reaction zone in such a way that the steady-state concentration of the isobutene in the combined stream at the feed point of the combined stream into the reaction zone has an average value of at least 40% by weight, and a polymerization plant therefor.
    Type: Grant
    Filed: January 7, 2013
    Date of Patent: July 27, 2021
    Assignee: BASF SE
    Inventors: Thomas Wettling, Stefan Hirsch, Markus Brym, Markus Weis
  • Patent number: 10815327
    Abstract: A copolymer which comprises, in copolymerized form, (A) 60 to 99% by weight of at least one monoethylenically unsaturated polyalkylene oxide monomer of the formula I (I) in which the variables have the following meanings: X is —CH2— or —CO—, if Y is —O—; is —CO—, if Y is —NH—; Y is —O— or —NH—; R1 is hydrogen or methyl; R2 are identical or different C2-C6-alkylene radicals, which may be arranged blockwise or randomly; R3 is hydrogen or C1-C4-alkyl; n is an integer from 25 to 75, (B) 1 to 40% by weight of at least one quaternized nitrogen-containing monoethylenically unsaturated monomer selected from the group consisting of monomers of formula Ha to IId (Ha-IId) in which the variables have the following meanings: R is C1-C4-alkyl or benzyl; R? is hydrogen or methyl; Y is —O— or —NH—; A is C1-C6-alkylene; X— is halide, C1-C4-alkyl sulfate, C1-C4-alkylsulfonate and Ci-C4-alkyl carbonate, (C) 0 to 10% by weight of anionic monoethylenically unsaturated monomers, and (D) 0 to 30% by weight of other nonionic monoeth
    Type: Grant
    Filed: March 31, 2017
    Date of Patent: October 27, 2020
    Assignee: BASF SE
    Inventors: Aaron Flores-Figueroa, Martin Ruebenacker, Rainer Dobrawa, Markus Brym, Dieter Boeckh, Frank Huelskoetter, Glenn Ward, James Goodwin, Melissa Cuthbertson, Stefano Scialla
  • Publication number: 20190359751
    Abstract: A copolymer which comprises, in copolymerized form, (A) 60 to 99% by weight of at least one monoethylenically unsaturated poly-alkylene oxide monomer of the formula I in which the variables have the following meanings: X is —CH2— or —CO—, if Y is —O—; is —CO—, if Y is —NH—; Y is —O— or —NH—; R1 is hydrogen or methyl; R2 are identical or different C2-C6-alkylene radicals, which may be arranged blockwise or randomly; R3 is hydrogen or C1-C4-alkyl; n is an integer from 25 to 75, (B) 1 to 40% by weight of at least one quaternized nitrogen-containing monoethylenically unsaturated monomer selected from the group consisting of monomers of formula IIa to IId in which the variables have the following meanings: R is C1-C4-alkyl or benzyl; R? is hydrogen or methyl; Y is —O— or —NH—; A is C1-C6-alkylene; X— is halide, C1-C4-alkyl sulfate, C1-C4-alkylsulfonate and C1-C4-alkyl carbonate, (C) 0 to 10% by weight of anionic monoethylenically unsaturated monomers, and (D) 0 to 30% by weight of oth
    Type: Application
    Filed: March 31, 2017
    Publication date: November 28, 2019
    Inventors: Aaron FLORE-FIGUEROA, Martin RUEBENACKER, Rainer DOBRAWA, Markus BRYM, Dieter BOECKH, Frank HUELSKOETTER, Glenn WARD, James GOODWIN, Melissa CUTHBERTSON, Stefano SCIALLA
  • Patent number: 9963521
    Abstract: Preparation of isobutene homopolymers having a weight-average molecular weight of 75 000 to 10 000 000 by polymerization of isobutene, by (a) performing the polymerization at ?80° C. to ?190° C., (b) using, as an inert solvent, optionally halogenated C1 to C5 hydrocarbons, (c) using, as a polymerization catalyst, a Lewis acid complex, (d) performing the polymerization in the presence of at least one reaction accelerator in the form of an ethylenically saturated hydrocarbon compound comprising one oxygen atom and no abstractable proton, and (e) performing the polymerization in the presence of at least one chain length regulator comprising one tertiary olefinic carbon atom.
    Type: Grant
    Filed: February 12, 2013
    Date of Patent: May 8, 2018
    Assignee: BASF SE
    Inventors: Thomas Wettling, Stefan Hirsch, Markus Brym, Markus Weis, Rosa Corberan Roc, Klaus Muehlbach, Robert Haschick, Andreas Daiss, Marco-Christian Volland
  • Patent number: 9688791
    Abstract: A polyisobutylene having a total content of vinylidene double bonds of more than 50 mol % and a number-average molecular weight of 500 to 10 000 daltons, where at least 10% of all the vinylidene double bonds in the polyisobutylene are part of one or more side chains composed of at least 2 carbon atoms from the main polyisobutylene chain. Such a polyisobutylene is suitable for production of fuel and lubricant additives.
    Type: Grant
    Filed: July 7, 2014
    Date of Patent: June 27, 2017
    Assignee: BASF SE
    Inventors: Thomas Wettling, Stefan Hirsch, Markus Brym, Markus Weis
  • Publication number: 20160145362
    Abstract: A polyisobutylene having a total content of vinylidene double bonds of more than 50 mol % and a number-average molecular weight of 500 to 10 000 daltons, where at least 10% of all the vinylidene double bonds in the polyisobutylene are part of one or more side chains composed of at least 2 carbon atoms from the main polyisobutylene chain. Such a polyisobutylene is suitable for production of fuel and lubricant additives.
    Type: Application
    Filed: July 7, 2014
    Publication date: May 26, 2016
    Applicant: BASF SE
    Inventors: Thomas WETTLING, Stefan HIRSCH, Markus BRYM, Markus WEIS
  • Patent number: 9238764
    Abstract: The present invention describes two-component coating compositions which for curing require no polyisocyanates or melamine-formaldehyde resins as crosslinkers.
    Type: Grant
    Filed: March 29, 2012
    Date of Patent: January 19, 2016
    Assignee: BASF SE
    Inventors: Markus Brym, Christine Rösch, Christina Haaf, Angelika Maria Steinbrecher, Harald Schäfer, Oihana Elizalde
  • Patent number: 9080129
    Abstract: The present invention relates to hydrophobically modified cationic polymers obtainable by the polymerization of one or more cationic ethylenically unsaturated monomers with an ethylenically unsaturated monomer having anhydride, imide, lactone, carboxylic acid, isocyanate or blocked isocyanate group and a reactive siloxane and processes for preparing them. These polymers are useful i.a. as a depositioning aid of hydrophobic actives onto fibrous substrates.
    Type: Grant
    Filed: July 18, 2013
    Date of Patent: July 14, 2015
    Assignee: BASF SE
    Inventors: Ouidad Benlahmar, Aaron Flores-Figueroa, Volodymyr Boyko, Dieter Boeckh, Markus Brym, Christofer Arisandy, Wolfgang Schrof, Frank Huelskoetter, Yonas Gizaw, Roy Jerome Harrington, Sumanth Narahari Jamadagni, Peter Koenig
  • Patent number: 9056926
    Abstract: A process for preparing aqueous solutions of homo- or copolymers of acrylic acid by means of free-radical polymerization of acrylic acid and optionally water-soluble, monoethylenically unsaturated comonomers in an aqueous medium in the presence of at least one water-soluble initiator and of at least one water-soluble regulator, wherein the polymerization is conducted by means of a continuous process, and wherein, after the polymerization, low molecular weight components are at least partly removed from the resulting aqueous polymer solution. For the polymerization, preference is given to using microstructured mixers and reactors. Preference is given to using at least one reactor and/or mixer with microstructures for the process.
    Type: Grant
    Filed: November 2, 2010
    Date of Patent: June 16, 2015
    Assignee: BASF SE
    Inventors: Matthias Kleiner, Wolfgang Loth, Markus Brym, Elke Gütlich-Hauk, Bolette Urtel, Ruth Wirschem, Jürgen Detering
  • Publication number: 20150045279
    Abstract: Described are oligoamides that improve the color protection properties of detergents and cleaning agents during their use for washing or cleaning colored textile fabrics. The oligoamides are rich in amino groups.
    Type: Application
    Filed: February 12, 2013
    Publication date: February 12, 2015
    Inventors: Roland Ettl, Axel Wilms, Christian Schmidt, Markus Brym, Birgit Glüsen, Mareile Job, Ulrich Pegelow, Carolin Trenka
  • Publication number: 20140349906
    Abstract: The color preservation of detergents and cleaners during their use for the washing or cleaning of colored textiles may be improved through the use of fiber-like polyamides in a washing composition. Color transfer inhibition arises through the use of water-insoluble polyamides when these are present in the form of fibers with a small fiber diameter. This invention relates to fibers, compositions and methods relating to inhibition of color transfer in the washing or cleaning of colored textiles.
    Type: Application
    Filed: August 13, 2014
    Publication date: November 27, 2014
    Inventors: Birgit Gluesen, Mareile Job, Roland Ettl, Evgueni Klimov, Christian Schmidt, Markus Brym
  • Patent number: 8853336
    Abstract: A catalyst complex composed of boron trifluoride and a cocatalyst mixture of 10 to 90% by weight of a monohydric primary C1- to C20-alcohol and 90 to 10% by weight of a monohydric secondary C3- to C20-alcohol, where the molar ratio of boron trifluoride to the sum of all alcohols is 2:1 to 1:10. This catalyst complex is used in the preparation of high-reactivity isobutene homopolymers having a number-average molecular weight of 300 to 50 000, using, as the feedstock, a C4 hydrocarbon mixture comprising at least 20% by weight of isobutene and a total of at least 10% by weight of other C4 olefins.
    Type: Grant
    Filed: February 15, 2013
    Date of Patent: October 7, 2014
    Assignee: BASF SE
    Inventors: Thomas Wettling, Stefan Hirsch, Markus Brym, Markus Weis
  • Patent number: 8822589
    Abstract: Process for the preparation of aqueous formulations, wherein (A) at least one ethylenically unsaturated carboxylic acid, (B) at least one heterocyclic comonomer having at least one permanent cationic charge per molecule and (C-P1) at least one ethylenically unsaturated dicarboxylic acid or its anhydride are subjected to free radical copolymerization with one another in an aqueous medium and, shortly before the end or after the end of the copolymerization, further ethylenically unsaturated dicarboxylic acid (C-P2) or its anhydride is added.
    Type: Grant
    Filed: August 8, 2008
    Date of Patent: September 2, 2014
    Assignee: BASF SE
    Inventors: Markus Brym, Stephan Hueffer, Audrey Renoncourt, Ulrike Mahn, Franz Glocknitzer, Alexandra Bruhn
  • Patent number: 8790424
    Abstract: A copolymer obtainable by free-radical copolymerization of (i) monomer units of the structure M1 in which the variables are each hydrogen, alkyl groups, carboxyl groups or carboxyl derivative moieties, and (ii) monomer units of the structure M2 in which R5 is the radical of a carboxylic ester of the formula -A-CO—O—R10 where A is an alkylene group and R10 is a hydrocarbyl radical, and in which R6, R7 and R8 are each hydrogen or alkyl radicals, and subsequent polymer-analogous reaction of the product formed with a long-chain hydrocarbyl alcohol. This copolymer is suitable for improving the cold flow properties of middle distillate fuels, especially those which consist of or comprise biofuel oils.
    Type: Grant
    Filed: March 28, 2012
    Date of Patent: July 29, 2014
    Assignee: BASF SE
    Inventors: Ivette Garcia Castro, Uwe Rebholz, Irene Troetsch-Schaller, Markus Brym, Jan Strittmatter, Michael Schroers
  • Patent number: 8771374
    Abstract: Process for the production of leather, wherein pelts, pickled pelts or semifinished products are treated with at least one copolymer (A) which is obtainable by copolymerization of the following comonomers: (a) at least one ethylenically unsaturated C3-C10-carboxylic acid or at least one ethylenically unsaturated C4-C10-dicarboxylic acid or its anhydride, (b) at least one (meth)acrylate of an ?-branched C3-C10-alkanol, (c) at least one (meth)acrylate of a primary C4-C20-alkanol.
    Type: Grant
    Filed: May 24, 2012
    Date of Patent: July 8, 2014
    Assignee: BASF SE
    Inventors: Markus Brym, Audrey Renoncourt, Stephan Huffer, Gerhard Wolf, Ulrike Mahn, Edward Bohres, Petra Schocker, Hubertus Peter Bell, Peter Danisch
  • Publication number: 20140024780
    Abstract: The present invention relates to hydrophobically modified cationic polymers obtainable by the polymerization of one or more cationic ethylenically unsaturated monomers with an ethylenically unsaturated monomer having anhydride, imide, lactone, carboxylic acid, isocyanate or blocked isocyanate group and a reactive siloxane and processes for preparing them. These polymers are useful i.a. as a depositioning aid of hydrophobic actives onto fibrous substrates.
    Type: Application
    Filed: July 18, 2013
    Publication date: January 23, 2014
    Inventors: Ouidad Benlahmar, Aaron Flores-Figueroa, Volodymyr Boyko, Dieter Boeckh, Markus Brym, Christofer Arisandy, Wolfgang Schrof, Frank Huelskoetter, Yonas Gizaw, Roy Jerome Harrington, Sumanth Narahari Jamadagni, Peter Koenig
  • Patent number: 8536108
    Abstract: The present application relates to care polymers and fabric and home care compositions comprising such care polymers, as well as processes for making and using such care polymers and such compositions. The performance of the care polymers that Applicants teach, can be further increased by following the emulsification teaching of the present specification and/or combining such care polymers with silicone materials.
    Type: Grant
    Filed: May 11, 2011
    Date of Patent: September 17, 2013
    Assignee: The Procter & Gamble Company
    Inventors: Rajan Keshav Panandiker, Julie Ann Menkhaus, Dieter Boeckh, Rainer Dobrawa, Frank Huelskoetter, Valentin Cepus, Jack Tinsley, Klaus Muehlbach, Markus Brym, Sophia Ebert, Ivette Garcia Castro
  • Publication number: 20130217847
    Abstract: Preparation of isobutene homopolymers having a weight-average molecular weight of 75 000 to 10 000 000 by polymerization of isobutene, by (a) performing the polymerization at ?80° C. to ?190° C., (b) using, as an inert solvent, optionally halogenated C1 to C5 hydrocarbons, (c) using, as a polymerization catalyst, a Lewis acid complex, (d) performing the polymerization in the presence of at least one reaction accelerator in the form of an ethylenically saturated hydrocarbon compound comprising one oxygen atom and no abstractable proton, and (e) performing the polymerization in the presence of at least one chain length regulator comprising one tertiary olefinic carbon atom.
    Type: Application
    Filed: February 12, 2013
    Publication date: August 22, 2013
    Inventors: Thomas WETTLING, Stefan Hirsch, Markus Brym, Markus Weis
  • Publication number: 20130217848
    Abstract: A catalyst complex composed of boron trifluoride and a cocatalyst mixture of 10 to 90% by weight of a monohydric primary C1- to C20-alcohol and 90 to 10% by weight of a monohydric secondary C3- to C20-alcohol, where the molar ratio of boron trifluoride to the sum of all alcohols is 2:1 to 1:10. This catalyst complex is used in the preparation of high-reactivity isobutene homopolymers having a number-average molecular weight of 300 to 50 000, using, as the feedstock, a C4 hydrocarbon mixture comprising at least 20% by weight of isobutene and a total of at least 10% by weight of other C4 olefins.
    Type: Application
    Filed: February 15, 2013
    Publication date: August 22, 2013
    Inventors: Thomas Wettling, Stefan Hirsch, Markus Brym, Markus Weis
  • Publication number: 20130178679
    Abstract: Continuous preparation of polyisobutylene having a content of terminal double bonds of more than 50% by polymerizing isobutene in the presence of a polymerization catalyst customary therefor, by combining a technical 1-butene-, 2-butene- and isobutene-containing C4 hydrocarbon stream together with a stream of pure isobutene and feeding them into the reaction zone in such a way that the steady-state concentration of the isobutene in the combined stream at the feed point of the combined stream into the reaction zone has an average value of at least 40% by weight, and a polymerization plant therefor.
    Type: Application
    Filed: January 7, 2013
    Publication date: July 11, 2013
    Inventors: Thomas WETTLING, Stefan Hirsch, Markus Brym, Markus Weis