Abstract: Disclosed are polymerizable compositions, methods, and articles and coatings related to multi-polymer networks wherein at least one of the polymer networks is based on particles. In an embodiment, the polymerizable compositions comprise at least two parts: 1) a polymer forming part comprising one or more compounds comprising a polymerizable group, wherein a composition consisting of the polymer forming part, if 90% or more polymerized, has a Tg of less than 25° C. and a prescribed volume average cross-link density at 100° C.; and 2) swellable particles comprising cross-links and having a Tg of less than 25° C. and a prescribed cross-link density. The swellable particles swell to a prescribed swelling ratio by mass from their non-swollen state if the swellable particles are swollen to equilibrium in a mixture consisting of the polymer forming part and the swellable particles.

Abstract: The invention relates to a method for the preparation of a transparent antiballistic article. The method comprises providing a plurality of anisotropic polymeric film layers, stacking the film layers to form an assembly and compressing the thus formed assembly at a temperature and pressure sufficient to consolidate the film layers, whereby the temperature is not more than 50° C. below the melting temperature of the polymer, the pressure is at least 80 MPa and sufficiently high to obtain an optical transparency according of at least 50% transmission. The invention also relates to a ballistic resistant article having an energy absorption for 17 grain FSP according to the STANAG 2920 standard of at least 10 J/(kg/m2) and an optical transparency according of at least 50% transmission.

Abstract: The invention relates to a process for the preparation of polyamide nanofibers by electrospinning, wherein the process is a multi-nozzle electrospinning process with the use of a multi-nozzle device or a nozzle-free electrospinning with the use of nozzle free device, comprising steps wherein a high voltage is applied, a polymer solution comprising a polymer and a solvent is fed to the multi-nozzle device or the nozzle free device and transformed under the influence of the high voltage into charged jet streams the jet streams are deposited on a substrate or taken up by a collector, and the polymer in the jet streams solidifies thereby forming nanofibres, and wherein the polymer comprises a semi-crystalline polyamide having a C/N ratio of at most 5.5 and a weight average molecular weight (Mw) of at most 35,000. The invention also relates polyamide nanofibers made by the electrospinning process, as well as to products made thereof and use thereof.

Abstract: The invention relates to a method for the preparation of a transparent antiballistic article. The method comprises providing a plurality of anisotropic polymeric film layers, stacking the film layers to form an assembly and compressing the thus formed assembly at a temperature and pressure sufficient to consolidate the film layers, whereby the temperature is not more than 50° C. below the melting temperature of the polymer, the pressure is at least 80 MPa and sufficiently high to obtain an optical transparency according of at least 50% transmission. The invention also relates to a ballistic resistant article having an energy absorption for 17 grain FSP according to the STANAG 2920 standard of at least 10 J/(kg/m2) and an optical transparency according of at least 50% transmission.

Abstract: The invention relates to a radiation-curable primary coating composition comprising 0.6-10 vol % of particles which when cured has an equilibrium modulus of about 1.5 MPa or less, and a cavitation strength at which a tenth cavity appears (?10cav) of at least about 1.1 MPa.