Abstract: Platinum and/or palladium containing organopolysiloxane-ammonium compounds containing units represented by the structural formula: ##STR1## in which R.sup.1, R.sup.2 and R.sup.3 represent:R.sup.5 --SiO.sub.3/2 (2)wherein R.sup.5 is an alkylene group and the free valences of oxygen are satisfied by silicon atom and additional groups of the structural formula (2), optionally with the introduction of a crosslinking agent,R.sup.4 can be R.sup.1, R.sup.2, R.sup.3 or hydrogen, alkyl, cycloalkyl or benzyl,Y.sup.x- is MeX.sub.4.sup.2- or MeX.sub.6.sup.2-, wherein Me is platinum or palladium andX is chlorine or bromine, and can further denote a 1 to 3 valent anion of a protonic acid capable of forming a stable salt with an amine, or the hydroxy group, andx is a number from 1 to 3. Methods for the obtaining the polymeric organosiloxane-ammonium-noble metal complexes and as well as the use thereof as catalysts for hydrosilylation and hydrogenation reactions are disclosed.