Abstract: The present invention relates to a process for the preparation of an ester comprising an after-treatment of the ester to give an ester in granule form of defined particle size distribution, a device for carrying out this process, a process for the preparation of a thermoplastic composition comprising the ester prepared according to the invention, a process for the production of a shaped article comprising the ester according to the invention or the thermoplastic composition according to the invention, a process for the production of a packed product, a process for the production of an at least partly coated object, and uses of the esters according to the invention as an additive in various compositions.

Abstract: A spray gun to apply dual component media has a gun housing with an application nozzle, a mixing system for combining the components and a material channel in the gun housing for introducing the first component into the mixing system, a needle shut-off mechanism sliding along its longitudinal axis and guided in the gun housing, at least one reagent channel in the needle shut-off mechanism to introduce the second component into the mixing system and/or into the material channel, at least one outlet opening arranged in the reagent channel away from the longitudinal axis to release the second component from the reagent channel, at least one control device to slide the needle shut-off mechanism inside the gun housing, and at least one metering device to alter the cross-section of the at least one outlet opening.

Abstract: The invention relates to a process for the oxidation of organic compounds by means of oxygen, in which, in a first step, the organic compound and at least part of the oxygen required for the oxidation are introduced into a first reaction zone which is operated isothermally and with backmixing and, in a second step, the reaction mixture from the first reaction zone is introduced into a second reaction zone which is operated adiabatically. The invention further relates to a reactor for carrying out the process, which comprises at least one isothermal reaction zone (3, 5) and an adiabatic reaction zone (7) which are arranged in a reactor shell (8), with each isothermal reaction zone (3, 5) being configured in the form of a jet loop reactor and the adiabatic reaction zone (7) being configured as a bubble column.

Abstract: A method and a device perform selective laser sintering. In the method for laser sintering, energy is applied linearly to a cross-sectional surface of the component to be produced in order to compact the powdery material. In the case of components with cross-sectional surfaces that have a curved contour, the application of energy can be guided in a line-shaped manner following the curved contour so that the contour of the workpiece that develops is continuously replicated. Advantageously, irregularities in the contour, which are caused by the raster predetermined by the laser sintering method, can thus be largely avoided. The device for laser sintering includes a powder delivery unit which can rotate about a rotational axis located in the interior of an annularly closed cross-section of the workpiece to be produced.

Abstract: Process for obtaining formic acid by thermal separation of a stream comprising formic acid and a tertiary amine (I), in which a liquid stream comprising formic acid, tertiary amine (I) and water is produced by combining tertiary amine (I) and a formic acid source in the presence of water, water and organic decomposition products of the tertiary amine (I) are removed and formic acid is removed by distillation from the resulting liquid stream in a distillation apparatus, wherein the stream comprising water and organic decomposition products of the tertiary amine (I) which have been separated off is separated into two liquid phases, the upper liquid phase is removed and the lower, water-comprising liquid phase is recirculated to the formic acid source.

Abstract: The invention relates to a process for oxidizing at least one organic substance with oxygen, which comprises the following steps: (a) adding the at least one organic substance as a liquid and an oxygenous gas stream to a first reaction stage to form a reaction mixture, at least some of the oxygen reacting with the organic compound to form a reaction product, (b) adding the reaction mixture from the first reaction stage to an adiabatically operated reaction stage in which the unconverted organic substance reacts further at least partly to give the product. The invention further relates to an apparatus for performing the process.

Abstract: The present invention relates to a process for the preparation of an ester in a reactor, wherein at least one of at least two different catalysts is an electron donor and a further catalyst is a sulphur-containing proton donor; a device, a process for the preparation of a thermoplastic composition comprising the ester prepared according to the invention, a process for the production of a shaped article comprising the ester according to the invention or the thermoplastic composition according to the invention, a process for the production of a packed product, a process for the production of an at least partly coated object, and uses of the esters according to the invention as an additive in various compositions.

Abstract: Process for preparing formic acid by hydrogenation of carbon dioxide in the presence of a catalyst comprising an element of group 8, 9 or 10 of the Periodic Table, a tertiary amine and a polar solvent at a pressure of from 0.2 to 30 MPa abs and a temperature of from 20 to 200° C. to form two liquid phases, separation of the two liquid phases, wherein the liquid phase (B) enriched with the tertiary amine is recirculated to the hydrogenation reactor and the formic acid/amine adduct from the liquid phase (A) enriched with the formic acid/amine adduct and the polar solvent is thermally dissociated into free formic acid and free tertiary amine in a distillation unit and the tertiary amine liberated in the dissociation and the polar solvent are recirculated to the hydrogenation reactor.

Abstract: The present invention relates to a packaging comprising a container surrounding a container interior, wherein at least the inner surface of the container in contact with the container interior is produced from a composition which comprises a thermoplastic polymer, and a plasticizer composition comprising a polymeric plasticizer and a polyol ester, and wherein the container is at least partly filled with a lipophilic packed product.

Abstract: The present invention relates to a process for the production of a packaging which is at least partly filled with a lipophilic packed product and comprises a container (1) and a closure (2) having a seal (3), comprising as process steps i) provision of a container which has an opening (4) and which is at least partly filled with a lipophilic packed product; ii) provision of a closure which is suitable for closing the container having the opening; iii) application of a composition to at least a part of the inner surfaces of the closure, wherein the composition is obtainable by mixing a particulate thermoplastic polymer with a plasticizer composition comprising a polymeric plasticizer and a polyol ester; iv) heating of the composition applied to at least a part of the inner surfaces of the closure to a temperature which is sufficient to gel the composition; v) cooling of the gelled composition; vi) closing of the container with the closure.

Abstract: The present invention relates to a process for the preparation of an ester in a reactor, a device, a process for the preparation of a thermoplastic composition comprising the ester prepared according to the invention, a process for the production of a shaped article comprising the ester according to the invention or the thermoplastic composition according to the invention, a process for the production of a packed product, a process for the production of an at least partly coated object, and uses of the esters according to the invention as an additive in various compositions.

Abstract: The present invention relates to a process for the preparation of an ester in a reactor, wherein at least a portion of the process components is led in a delivery stream outside the reactor over a heat transfer surface as a film, the ratio of the delivery stream to the heat transfer surface being in a range of from 0.25 to 3 m/h, a device, a process for the preparation of a thermoplastic composition comprising the ester prepared according to the invention, a process for the production of a shaped article comprising the ester according to the invention or the thermoplastic composition according to the invention, a process for the production of a packed product, a process for the production of an at least partly coated object, and uses of the esters according to the invention as an additive in various compositions.

Abstract: Glycidyl 2-propylheptanoate, glycidyl 4-methyl-2-propylhexanoate or a mixture of these (referred to collectively for short as glycidyl ester).

Abstract: The present invention relates to a process for the preparation of an ester from a polyol which is solid at 25° C. and a carboxylic acid component which contains at least 50 wt. % of at least one mono- or polyunsaturated aliphatic carboxylic acid, based on the total weight of the carboxylic acid component, in a reactor under reduced pressure. The invention also provides a device, a process for the preparation of a thermoplastic composition comprising the ester prepared according to the invention, a process for the production of a shaped article comprising the ester according to the invention or the thermoplastic composition according to the invention, a process for the production of a packed product, a process for the production of an at least partly coated object, and uses of the esters according to the invention as an additive in various compositions.

Abstract: An arrangement for detection of the sharpness of chopper knives that can be moved relative to a shear bar includes a sensor that detects the effective cutting forces directly or indirectly and an evaluation arrangement connected to the sensor. The evaluation arrangement integrates the measured values of the sensor over time in order to generate information concerning the sharpness of the chopper knives.

Abstract: A process for preparing formic acid by reacting carbon dioxide with hydrogen in a hydrogenation reactor in the presence of a catalyst comprising an element of group 8, 9 or 10 of the Periodic Table, a tertiary amine and a polar solvent to form formic acid-amine adducts which are subsequently dissociated thermally into formic acid and tertiary amine.

Abstract: A method of producing a turbine blade is provided, wherein the turbine blade is produced by an additive production method. Cavities and/or lattice structures can be produced in one and the same process. The additive production method also allows drainage slots, heating openings, and/or other holes or, as the case may be, recesses to be provided in the turbine blade while the turbine blade is being produced. Holes can furthermore be furnished completely or partially with a lattice structure.

Abstract: The invention relates to an electric machine (100) comprising a stator (107) and a rotor (101), wherein the rotor (101) comprises a hollow shaft (102), wherein a closed hollow space (103) is formed by means of the hollow shaft (102), wherein the closed hollow space (103) is provided for receiving a cooling agent, wherein a three-dimensional transport structure (200) is provided in the closed hollow chamber (103) for transporting the cooling agent. The three-dimensional structure can, for example, be produced by means of applying an adaptive material.

Abstract: A monolithic substrate of glass or glass ceramics and methods for manufacturing are provided, where the substrate has a lightweight structure. The lightweight structure includes recesses that are delimited by webs, such webs forming tetragonal or four-corner-shaped pockets. Due to the lightweight structure, the weight of the substrate can be significantly reduced, and at the same time a high rigidity can be ensured. The substrate can be used as a mirror support or a mirror and can be employed terrestrially and/or extra-terrestrially.

Abstract: A method produces a marked object. To be able to create markings in a particularly flexible way, it is provided that the object is produced by an additive production process, at least one marking being formed in the object during the additive production process. The method makes many degrees of freedom possible in the design of the marking. For example, the method makes it possible in a very simple way for two- or three-dimensional structures to be concealed within the object during the additive production process. In addition or as an alternative, production parameters can be varied, whether stochastically or deterministically, to produce variations in density. For example, a porous microstructure may be produced as a marking. It is also possible for basic material in the object to be left untreated or to be differently treated, so that it forms the marking.