Patents by Inventor Martin Heus

Martin Heus has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Publication number: 20150321995
    Abstract: The invention relates to glutamic acid N,N-diacetic acid (GLDA) of the formula GLDA-YmHn, wherein m is less than 0.5, n+m=4, Y is a monovalent cation that is not a proton, in the form of crystals, a process to make these crystals, and their uses, in particular in detergent compositions.
    Type: Application
    Filed: December 12, 2013
    Publication date: November 12, 2015
    Inventors: Cornelis Elizabeth Johannus Van Lare, Roy Gérard Doppen, Martin Heus, Elwin Schomaker, Paul Verwer
  • Patent number: 9080133
    Abstract: The present invention relates to glutamic acid N,N-diacetic amide, potassium or sodium glutamate N,N-diacetic amide, glutamic acid N-acetic amide N-acetonitrile, potassium or sodium glutamate N-acetic amide N-acetonitrile, to processes to prepare such compounds and the use thereof.
    Type: Grant
    Filed: August 14, 2008
    Date of Patent: July 14, 2015
    Assignee: AKZO NOBEL N.V.
    Inventors: Tjerk Oedse Boonstra, Martin Heus, Axel Carstens, Jim Lepage
  • Patent number: 8551312
    Abstract: The invention relates to a process for the production of an amino acid having at least one secondary or tertiary amino group and three or more carboxyl groups or its salt with less than an equivalent of alkaline metal based on the number of carboxyl groups, said process comprising reducing alkali metal ions from an aqueous solution of an alkali metal salt of an amino acid having at least one secondary or tertiary amino group and three or more carboxyl groups and acidifying the amino carboxylate starting material by first performing a chemical acidification step using an organic or inorganic acid to get a compound in which at least one of the groups is protonated, and in a subsequent step further acidifying the amino carboxylate starting material and reducing alkali metal ions from an aqueous solution of the partially acidified alkali metal salt of the amino acid having at least one secondary or tertiary amino group and three or more carboxyl groups by electrodialysis, wherein the electrodialysis is performed
    Type: Grant
    Filed: November 27, 2007
    Date of Patent: October 8, 2013
    Assignee: Akzo Nobel N.V.
    Inventors: Martin Heus, Hans Lammers, Arie Volmer
  • Publication number: 20130209806
    Abstract: The present invention relates to a coated particle containing a particle and a coating, wherein the particle contains glutamic acid N,N-diacetic acid or a partial salt thereof of the formula HnYm-GLDA, wherein Y is a cation, selected from the group of sodium, potassium and mixtures thereof, n+m=4, and wherein the coating contains at least one salt that contains as a cation at least one of sodium, potassium or lithium and as anion at least one of silicate sulfate, carbonate, chloride, nitrate, percarbonate, glycolate, oxalate, citrate, stearate, lactate, succinate, malonate, maleate, diglycolate, and fumarate, to a process to prepare such a particle, and, to the use thereof.
    Type: Application
    Filed: June 27, 2011
    Publication date: August 15, 2013
    Applicant: AKZO NOBEL CHEMICALS INTERNATIONAL B.V.
    Inventors: Cornelis Elizabeth Johannus Van Lare, Martin Heus
  • Patent number: 8399705
    Abstract: The present invention relates to an alkalimetal salt of glutamic acid-N,N-diacetic acid (GLDA) of the formula NaxKyHzGLDA, wherein x is equal to or more than 2 and lower than 4 and y is more than 0 and equal to or lower than 2, x+y is 3.5-4, and x+y+z=4, to processes to prepare such salt and the use thereof.
    Type: Grant
    Filed: August 14, 2008
    Date of Patent: March 19, 2013
    Assignee: Akzo Nobel N.V.
    Inventors: Tjerk Oedse Boonstra, Martin Heus
  • Publication number: 20120142964
    Abstract: The present invention relates to a process comprising the reaction of a cyanide with an amino acid and an aldehyde, characterized in that the cyanide is a cyanide salt, the amino acid is aspartic acid and/or glutamic acid in the acidic form, and the process is performed under acidic pH by the addition of between 0 and 1 equivalent of an acid based on the amount of aspartic or glutamic acid.
    Type: Application
    Filed: June 3, 2010
    Publication date: June 7, 2012
    Applicant: AZKO NOBEL CHEMICALS INTERNATIONAL B.V.
    Inventors: Hans Lammkers, Martin Heus, Tjerk Oedse Boonstra, Adrianus Maria Reichwein
  • Publication number: 20120004147
    Abstract: The present invention relates to a coated particle including a particle including at least one chelating agent of the formula COOH—CHX—N—(CH2—COOH)2, wherein X stands for carboxyalkyl, alkyl, hydroxyalkyl or aminoalkyl, and alkyl is a C1-C4 alkyl group, and the coating on the particle includes at least one scale-inhibiting additive, a process to prepare such particle, and to the use thereof in detergents, in oil field applications, in agriculture and in water treatment.
    Type: Application
    Filed: December 24, 2009
    Publication date: January 5, 2012
    Applicant: AKZO NOBEL N.V.
    Inventors: Johannes Wilhelmus Franciscus Lucas Seetz, Jéróme Mercanton, Paul Michael Ferm, Martin Heus, Zoltán Szilágyi, Cornelis Elizabeth Johannus van Lare
  • Publication number: 20100324334
    Abstract: The present invention relates to an alkalimetal salt of glutamic acid-N,N-diacetic acid (GLDA) of the formula NaxKyHzGLDA, wherein x is equal to or more than 2 and lower than 4 and y is more than 0 and equal to or lower than 2, x+y is 3.5-4, and x+y+z=4, to processes to prepare such salt and the use thereof.
    Type: Application
    Filed: August 14, 2008
    Publication date: December 23, 2010
    Applicant: AKZO NOBEL N.V.
    Inventors: Tjerk Oedse Boonstra, Martin Heus
  • Publication number: 20100311998
    Abstract: The present invention relates to ionic liquids of the formula: (Mm+)xH+ynN+R1R2R3R4Z—N(—CHXCOO?)pY2-p or (Mm+)xH+ynP+R1R2R3R4Z—N(—CHXCOO?)pY2-p wherein any one of R1 to R4 independently represents a hydrogen, alkyl, cycloalkyl, aryl or aralkyl group that may be unsubstituted or substituted with one or more groups selected from OH, Cl, Br, F, I, phenyl, NH2, CN, NO2, an ether group, COOR5, CHO, COR5 or OR5, wherein R5 is an alkyl or cycloalkyl group, and wherein two of the groups R1 to R4 together with the N atom may form a heteroaromatic or heterocyclic group such as a pyridinium, pyrrolidinium or imidazolium group; the Z—N(—CHXCOO?)pY2-p is the anion derived from a chelating agent, wherein Z is a group selected from hydrogen, alkyl, an alkyl group optionally substituted with one or more carboxylate groups, hydroxyl groups and/or optionally containing one or more ether functionalities, or Z is a group of the formula —CH2—CHR6—R7—N—(CH2COO?)2, R6 is hydrogen or a C1-C3 alkyl group, R7 is a single bond, a C1-C3
    Type: Application
    Filed: July 31, 2008
    Publication date: December 9, 2010
    Applicant: AKZO NOBEL N.V.
    Inventors: Cornelia Adriana De Wolf, Boris Kuzmanovic, Johanna Hendrika Bemelaar, Cornelis Johannes Govardus Van Strien, Martin Heus, Antoon Ten Kate
  • Publication number: 20100222610
    Abstract: The present invention relates to glutamic acid N,N-diacetic amide, potassium or sodium glutamate N,N-diacetic amide, glutamic acid N-acetic amide N-acetonithle, potassium or sodium glutamate N-acetic amide N-acetonitrile, to processes to prepare such compounds and the use thereof.
    Type: Application
    Filed: August 14, 2008
    Publication date: September 2, 2010
    Applicant: AKZO NOBEL N.V.
    Inventors: Tjerk Oedse Boonstra, Martin Heus, Axel Carstens, Jim Lepage
  • Publication number: 20100126864
    Abstract: The invention relates to a process for the production of an amino acid having at least one secondary or tertiary amino group and three or more carboxyl groups or its salt with less than an equivalent of alkaline metal based on the number of carboxyl groups, said process comprising reducing alkali metal ions from an aqueous solution of an alkali metal salt of an amino acid having at least one secondary or tertiary amino group and three or more carboxyl groups and acidifying the amino carboxylate starting material by first performing a chemical acidification step using an organic or inorganic acid to get a compound in which at least one of the groups is protonated, and in a subsequent step further acidifying the amino carboxylate starting material and reducing alkali metal ions from an aqueous solution of the partially acidified alkali metal salt of the amino acid having at least one secondary or tertiary amino group and three or more carboxyl groups by electrodialysis, wherein the electrodialysis is performed
    Type: Application
    Filed: November 27, 2007
    Publication date: May 27, 2010
    Applicant: Akzo Nobel N.V.
    Inventors: Martin Heus, Hans Lammers, Arie Volmer
  • Patent number: 7211682
    Abstract: The invention pertains to an aqueous solution of a sodium salt xNa+ yH+ of the chelating compound of formula I: wherein x=2.1–2.7, y=0.9–0.3, and x+y=3. The invention further pertains to a container comprising at least 0.5 kg of said aqueous solution and to a method of preparing an aqueous solution comprising at least 45 wt % of the sodium salt xNa+ yH+ of the chelating compound of formula I from Na3-HEDTA, comprising the steps of electrodialysing an aqueous solution containing less than 42 wt % of Na3-HEDTA using a bipolar membrane, thereby converting the trisodium salt solution to the solution of the sodium salt of formula I with x=2.1–2.7, y=0.9–0.3, and x+y=3.
    Type: Grant
    Filed: July 13, 2004
    Date of Patent: May 1, 2007
    Assignee: Akzo Nobel N.V.
    Inventors: Martin Heus, Hans Lammers, Jim Lepage
  • Publication number: 20070015930
    Abstract: The invention pertains to an aqueous solution of a sodium salt xNa+ yH+ of the chelating compound of formula I: wherein x=2.1?2.7, y=0.9?0.3, and x+y=3. The invention further pertains to a container comprising at least 0.5 kg of said aqueous solution and to a method of preparing an aqueous solution comprising at least 45 wt % of the sodium salt xNa+ yH+ of the chelating compound of formula I from Na3-HEDTA, comprising the steps of electrodialysing an aqueous solution containing less than 42 wt % of Na3-HEDTA using a bipolar membrane, thereby converting the trisodium salt solution to the solution of the sodium salt of formula I with x=2.1?2.7, y=0.9?0.3, and x+y=3.
    Type: Application
    Filed: July 13, 2004
    Publication date: January 18, 2007
    Inventors: Martin Heus, Hans Lammers, Jim Lepage
  • Patent number: 6627580
    Abstract: Chelating agents (chelants) of the general structure: wherein: n=2-4 whereby at least two of X are of formula III Y=COOH, —PO3H2 or o-hydroxyphenyl R1, R2 and R3 are independently H or C1-C8 alkyls m=1, 2 or 3 and most preferably m=1 Z and Z1 are unsubstituted or substituted C C+=C or CH or N Z1, Z2, Z′1, and Z′2 are independently selected from H (or nothing for Z2 and Z′2 if C* is N) and C1-C10 groups that optionally contain one or more N atoms (optionally attached directly to C*), whereby one of the pairs Z/Z1, Z/Z2 and Z1/Z2 and one of the pairs Z′/Z′1, Z′1/Z′2 and Z′1/Z′2 may be connected to form substituted or unsubstituted (hetero)(poly)cyclic structures of less than 20 atoms C* is either part of an aromatic (hetero)(poly)cyclic structure or linked by a double bond to Z or Z2 and/or Z′ or Z′2.
    Type: Grant
    Filed: April 25, 2002
    Date of Patent: September 30, 2003
    Assignee: Akzo Nobel N.V.
    Inventors: Christer L. Hakanson, Martin Heus
  • Patent number: 6492549
    Abstract: A process for the preparation of alkylene diamine triacetic acid (derivatives) which comprises the conversion of an alkylene diamine (derivative) to a metal salt of an alkylene diamine triacetic acid (derivative). The reaction is carried out in the presence of a polyvalent metal ion Ma+ and the entire reaction is carried out under hydrolyzing conditions if any of the reactants contain or form nitrile or amide groups.
    Type: Grant
    Filed: January 2, 2001
    Date of Patent: December 10, 2002
    Assignee: Akzo Novel NV
    Inventors: Marcellinus Alexander Van Doorn, Johannes Wilhelmus Driessen, Tjerk Oedse Boonstra, Martin Heus
  • Publication number: 20020156308
    Abstract: Chelating agents (chelants) of the general structure: 1
    Type: Application
    Filed: April 25, 2002
    Publication date: October 24, 2002
    Inventors: Christer L. Hakanson, Martin Heus
  • Patent number: 6458980
    Abstract: Chelating agents (chelants) of the general structure: wherein: n=2-4 X=—CR1R2—, or whereby at least two of X are of formula III Y=COOH, —PO3H2 or o-hydroxyphenyl R1, R2 and R3 are independently H or C1-C8 alkyls m=1, 2 or 3 and most preferably m=1 Z and Z1 are unsubstituted or substituted C C*=C or CH or N Z1, Z2, Z′1, and Z′2 are independently selected from H (or nothing for Z2 and Z′2 if C* is N) and C1-C10 groups that optionally contain one or more N atoms (optionally attached directly to C*), whereby one of the pairs Z/Z1, Z/Z2 and Z1/Z2 and one of the pairs Z′/Z′1, Z′1/Z′2 and Z′/Z′2 may be connected to form substituted or unsubstituted (hetero)(poly)cyclic structures of less than 20 atoms. C* is either part of an aromatic (hetero)(poly)cyclic structure or linked by a double bond to Z or Z2 and/or Z′ or Z′2.
    Type: Grant
    Filed: April 7, 2000
    Date of Patent: October 1, 2002
    Assignee: Akzo Nobel NV
    Inventors: Christer L. Hakanson, Martin Heus
  • Publication number: 20010007042
    Abstract: A process for the preparation of alkylene diamine triacetic acid (derivatives) which comprises the conversion of an alkylene diamine (derivative) to a metal salt of an alkylene diamine triacetic acid (derivative). The reaction is carried out in the presence of a polyvalent metal ion Ma+ and the entire reaction is carried out under hydrolyzing conditions if any of the reactants contain or form nitrile or amide groups.
    Type: Application
    Filed: January 2, 2001
    Publication date: July 5, 2001
    Inventors: Marcellinus Alexander Van Doorn, Johannes Wilhelmus Driessen, Tjerk Oedse Boonstra, Martin Heus