Patents by Inventor Martin Holer

Martin Holer has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 6803392
    Abstract: Aqueous storage-stable, non-sedimenting photoinitiator suspensions comprising (a) a mono- or bis-acylphosphine oxide of formula (I), wherein R1 is C1-C20alkyl; C2-C20alkyl interrupted by one or more O atoms; C1-C12alkoxy; phenyl-C1-C4alkyl; or phenyl that is unsubstituted or substituted by C1C20alkyl, C1-C12alkoxy, halogen, cyclopentyl, cyclohexyl, C2-C12alkenyl, C2-C18alkyl interrupted by one or more O atoms, and/or by phenyl-C1-C4alkyl; or R1 is biphenylyl; R2 is an aromatic radical or has one of the meanings give for R1; R3 and R4 are each independently of the other C1-C12alkyl, C1-C12alkoxy or halogen; and R5 is hydrogen, C1-C12alkyl, C1-C12alkoxy or halogen; (b) a dispersant; and (c) water are suitable especially in the photopolymerisation of aqueous formulations comprising ethylenically unsaturated monomers.
    Type: Grant
    Filed: March 18, 2002
    Date of Patent: October 12, 2004
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Manfred Köhler, Beat Michael Aebli, Martin Holer, Ernst Eckstein, Jean-Pierre Wolf
  • Patent number: 5726310
    Abstract: 2-(2,4-Dihydroxyphenyl)-4,6-bis(2,4-dimethylphenyl)-s-triazine is prepared by reacting cyanuric chloride with m-xylene at a temperature of 0.degree.-110.degree. C. in the presence of a Lewis acid and at least one inert chlorinated aromatic solvent to give the intermediate 2-chloro-4,6-bis(2,4-dimethylphenyl)-s-triazine. This intermediate, without being isolated, is then reacted with resorcinol to give the final desired product 2-(2,4-dihydroxyphenyl)-4,6-bis(2,4-dimethylphenyl)-s-triazine in good yield.
    Type: Grant
    Filed: December 3, 1996
    Date of Patent: March 10, 1998
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Ivan Orban, Martin Holer, Andre Kaufmann
  • Patent number: 5616787
    Abstract: The invention relates to a process for the preparation of polyalkylated aromatic carboxylic acids of formula I ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5 are each independently of one another hydrogen, C.sub.1 -C.sub.20 alkyl, halogen or C.sub.5 -C.sub.8 cycloalkyl, with the proviso that at least two of the substituents R.sub.1, R.sub.2, R.sub.3, R.sub.4 or R.sub.5 are alkyl and/or cycloalkyl, by reacting corresponding aromatic hydrocarbons with carbon dioxide, which reaction is carried out observing special ratios of temperature and pressure. The invention furthermore relates to a one-pot process for the preparation of the corresponding acyl halides.
    Type: Grant
    Filed: October 11, 1995
    Date of Patent: April 1, 1997
    Assignee: Ciba-Geigy Corporation
    Inventors: Rinaldo Husler, Ivan Orban, Martin Holer
  • Patent number: 5549847
    Abstract: Highly concentrated flowable dispersions of corrosion inhibitors can be prepared by stirring a filter cake of the corrosion inhibitor with a dispersant and a thickener. These dispersions are storage stable.
    Type: Grant
    Filed: November 23, 1994
    Date of Patent: August 27, 1996
    Assignee: Ciba-Geigy Corporation
    Inventors: Martine Goliro, Martin Holer, Sandor Gati
  • Patent number: 5436322
    Abstract: A process for the preparation of compounds of the formula I is described ##STR1## in which R.sup.1 and R.sup.2 independently of one another are C.sub.1 -C.sub.7 alkyl; and R.sup.3 is hydrogen or halogen, by reaction of a diazonium salt of a 2-nitroaniline in acid aqueous solution with a phenol dispersed in water.The process comprises employing as the dispersant a C.sub.8 -C.sub.20 alkanesulfonic acid or a corresponding alkanesulfonate or a mixture of sulfonic acid and sulfonate together with a polyvinyl alcohol.The resulting compounds of the formula I can advantageously be reacted further to give benzotriazoles of the formula V ##STR2## which are used as light stabilizers.
    Type: Grant
    Filed: September 12, 1994
    Date of Patent: July 25, 1995
    Assignee: Ciba-Geigy Corporation
    Inventors: Ivan Orban, Martin Holer
  • Patent number: 5196142
    Abstract: Storage-stable, non-sedimenting emulsions comprisinga) 10 to 80% by weight, based on the emulsion, of one or more anti-oxidants,b) 0.25 to 10% by weight, based on the emulsion, of a surfactant in the form of a fatty acid salt of formula R-COOY, wherein R is straight chain or branched C.sub.3 -C.sub.18 alkyl or straight chain or branched C.sub.3 -C.sub.18 -alkenyl, or is phenyl(C.sub.3 -C.sub.18)alkyl, and Y is an alkali metal, which salt is prepared in situ from the fatty acid,c) 0.25 to 10% by weight, based on the emulsion, of a co-surfactant in the form of an alcohol of the general formula R'--OH, wherein R' is straight chain or branched C.sub.4 -C.sub.19 alkyl or straight chain or branched C.sub.4 -C.sub.19 alkenyl, or is phenyl(C.sub.4 -C.sub.19)alkyl, andd) water to make up 100%.The emulsions are used for stabilizing emulsion-polymerized polymers and copolymers such as ABS.
    Type: Grant
    Filed: August 2, 1991
    Date of Patent: March 23, 1993
    Assignee: Ciba-Geigy Corporation
    Inventors: Hans Mollet, Martin Holer
  • Patent number: 5130429
    Abstract: Process for the methylation of compounds at least one group of the formula (I) ##STR1## by means of a mixture of formaldehyde and formic acid in a reaction medium consisting of an aromatic hydrocarbon solvent.
    Type: Grant
    Filed: November 27, 1991
    Date of Patent: July 14, 1992
    Assignee: Ciba-Geigy Corporation
    Inventors: Piero Piccinelli, Ivan Orban, Martin Holer, Valerio Borzatta
  • Patent number: 5116534
    Abstract: Storage-stable, non-sedimenting emulsions containinga) 10 to 40% by weight, based on the emulsion, of (A) phenolic antioxidants and antioxidants from the series comprising (B) thiodipropionic acid esters or/and (C) organic phosphites,b) 0.25 to 10% by weight, based on the emulsion, of a surfactant of the formula R-COOY, in which R is alkyl having 3 to 18 atoms, alkenyl having 3 to 18 C atoms or phenyl-C.sub.3 -C.sub.18 alkyl and Y is an alkali metal,0.25 to 10% by weight, based on the emulsion, of an alcohol of the formula R'-OH, in which R' is alkyl having 4 to 19 C atoms, alkenyl having 4 to 19 C atoms or phenyl-C.sub.4 C.sub.19 alkyl, andwater as the remainder to make 100% by weight.The emulsions are employed in particular for stabilizing emulsion-polymerized polymers and copolymers, for example ABS.
    Type: Grant
    Filed: January 18, 1991
    Date of Patent: May 26, 1992
    Assignee: Ciba-Geigy Corporation
    Inventors: Hans Mollet, Martin Holer
  • Patent number: 5059347
    Abstract: Storage-stable, non-sedimenting emulsions comprisinga) 10 to 80% by weight, based on the emulsion, of one or more antioxidants,b) 0.25 to 10% by weight, based on the emulsion, of a surfactant in the form of a fatty acid salt of formula R-COOY, wherein R is straight chain or branched C.sub.3 -C.sub.18 alkyl or straight chain or branched C.sub.3 -C.sub.18 -alkenyl, or is phenyl(C.sub.3 -C.sub.18)alkyl, and Y is an alkali metal, which salt is prepared in situ from the fatty acid,c) 0.25 to 10% by weight, based on the emulsion, of a co-surfactant in the form of an alcohol of the general formula R'--OH, wherein R' is straight chain or branched C.sub.4 -C.sub.19 alkyl or straight chain or branched C.sub.4 -C.sub.19 alkenyl, or is phenyl(C.sub.4 -C.sub.19)alkyl, andd) water to make up 100%.The emulsion are used for stabilizing emulsion-polymerized polymers and copolymers such as ABS.
    Type: Grant
    Filed: August 17, 1989
    Date of Patent: October 22, 1991
    Assignee: Ciba-Geigy Corporation
    Inventors: Hans Mollet, Martin Holer