Abstract: A method for the preparation of an electrode comprising a substrate made of an aluminium based material, vertically aligned carbon nanotubes and an electrically conductive polymer matrix, the method comprising the following successive steps: (a) synthesising, on a substrate made of an aluminium based material, a carpet of vertically aligned carbon nanotubes according to the technique of CVD (Chemical Vapour Deposition) at a temperature less than or equal to 650° C.; (b) electrochemically depositing the polymer matrix on the carbon nanotubes from an electrolyte solution including at least one precursor monomer of the matrix, at least one ionic liquid and at least one protic or aprotic solvent. Further disclosed is the prepared electrode and a device for storing and returning electricity such as a supercapacitor comprising the electrode.

Abstract: A method for providing a substrate made of a porous carbonaceous material with vertically aligned carbon nanotubes, the method having a first step of depositing a ceramic underlayer on the substrate followed by a second step of synthesizing, by catalytic chemical vapour deposition, the vertically aligned carbon nanotubes on the substrate obtained after the first step, the carbon source necessary for the synthesis during this second step being injected in a direction substantially perpendicular to the plane of the substrate and at a pressure less than 8104 Pa (800 mbar). The use of the substrate for preparing an electrode such as a supercapacitor electrode.

Abstract: A composite comprises vertically aligned carbon nanotubes (VACNT) on a substrate and additional disordered carbon deposited on the outer face of the nanotubes. This additional carbon is not amorphous but comprises graphitic domains. This composite can be prepared by a chemical vapor deposition (CVD) process in the presence of a catalyst on a metal substrate at atmospheric pressure. It can be used as an electrode in electronic and electrotechnical devices, such as supercapacitors.

Abstract: A method for the preparation of an electrode comprising a substrate made of an aluminium based material, vertically aligned carbon nanotubes and an electrically conductive polymer matrix, the method comprising the following successive steps: (a) synthesising, on a substrate made of an aluminium based material, a carpet of vertically aligned carbon nanotubes according to the technique of CVD (Chemical Vapour Deposition) at a temperature less than or equal to 650° C.; (b) electrochemically depositing the polymer matrix on the carbon nanotubes from an electrolyte solution including at least one precursor monomer of the matrix, at least one ionic liquid and at least one protic or aprotic solvent. Further disclosed is the prepared electrode and a device for storing and returning electricity such as a supercapacitor comprising the electrode.

Abstract: The present invention concerns a method for preparing a suspension of carbon nanotubes in an aqueous solution comprising the following successive steps consisting of subjecting an aqueous solution containing carbon nanotubes and a surfactant to at least one cycle of freezing in liquid nitrogen and thawing; and subjecting said thawed solution to an ultrasound treatment. The present invention also concerns a suspension of carbon nanotubes, and in particular a suspension of long carbon nanotubes, that can be prepared by such a method.

Abstract: A device is disclosed for detecting at least one chemical compound comprising at least one carbon nanotube with several graphene layers, on which is grafted at least one molecule bearing group G1 capable of reacting with the chemical compound or a precursor of such a group G1. The uses and the method of making such a device is also disclosed.

Abstract: The present invention concerns a method for preparing a suspension of carbon nanotubes in an aqueous solution comprising the following successive steps consisting of subjecting an aqueous solution containing carbon nanotubes and a surfactant to at least one cycle of freezing in liquid nitrogen and thawing; and subjecting said thawed solution to an ultrasound treatment. The present invention also concerns a suspension of carbon nanotubes, and in particular a suspension of long carbon nanotubes, that can be prepared by such a method.

Abstract: The invention relates to a method for continuously manufacturing aligned nanostructures on a running support, which comprises conveying the support through a heated space and synthesising, in this space, aligned nanostructures on the support by catalytic chemical vapour deposition. The heated space is divided into n consecutive zones in the conveying direction of the support (n being an integer ?2), and the synthesis of the nanostructures results from heating and injection operations, in each of these n zones, of a flux of an aerosol containing a catalytic precursor and a source precursor of the material of the nanostructures to be formed, carried by a carrier gas. The injection operations are made by modifying, in at least two of the n zones, at least one parameter chosen among the flow rate of the carrier gas flux, the chemical composition of the carrier gas, the mass concentration of the catalytic precursor in the catalytic precursor and source precursor mixture.

Abstract: The invention relates to the growth of carbon nanotubes on a substrate, in particular a carbon or metal substrate on which the growth of such nanotubes is usually difficult. Accordingly, the invention includes a first phase that comprises depositing a ceramic sub-layer, followed by a second phase that comprises depositing carbon nanotubes on said sub-layer in a single step and in a single and same growth reactor. The growth can advantageously be carried out by chemical vapor deposition.

Abstract: The present invention relates to a material comprising (i) nanotubes or nanowires aligned with each other in a vertical matrix and (ii) a matrix arranged between the nanotubes or the nanowires, at least one organic polymer being covalently grafted to at least two of said nanotubes or to at least two of said nanowires. The present invention also relates to a method for preparing such a material or to its uses.

Abstract: A device is disclosed for detecting at least one chemical compound comprising at least one carbon nanotube with several graphene layers, on which is grafted at least one molecule bearing group G1 capable of reacting with the chemical compound or a precursor of such a group G1. The uses and the method of making such a device is also disclosed.

Abstract: Method for preparing carbon nanotubes or nitrogen-doped carbon nanotubes by pyrolysis, in a reaction chamber, of a liquid containing at least one liquid hydrocarbon precursor of carbon or at least one liquid compound precursor of carbon and nitrogen consisting of carbon atoms, nitrogen atoms and optionally hydrogen atoms and/or atoms of other chemical elements such as oxygen, and optionally at least one metal compound precursor of a catalyst metal, in which said liquid is formed under pressure into finely divided liquid particles such as droplets by a specific injection system, preferably a periodic injection system, and the finely divided particles, such as droplets, formed in this way are conveyed by a carrier gas stream and introduced into the reaction chamber, where the deposition and growth of the carbon nanotubes or nitrogen-doped carbon nanotubes take place.

Abstract: The invention relates to the growth of carbon nanotubes on a substrate, in particular a carbon or metal substrate on which the growth of such nanotubes is usually difficult. Accordingly, the invention includes a first phase that comprises depositing a ceramic sub-layer, followed by a second phase that comprises depositing carbon nanotubes on said sub-layer in a single step and in a single and same growth reactor. The growth can advantageously be carried out by chemical vapour deposition.

Abstract: Method for preparing carbon nanotubes or nitrogen-doped carbon nanotubes by pyrolysis, in a reaction chamber, of a liquid containing at least one liquid hydrocarbon precursor of carbon or at least one liquid compound precursor of carbon and nitrogen consisting of carbon atoms, nitrogen atoms and optionally hydrogen atoms and/or atoms of other chemical elements such as oxygen, and optionally at least one metal compound precursor of a catalyst metal, in which said liquid is formed under pressure into finely divided liquid particles such as droplets by a specific injection system, preferably a periodic injection system, and the finely divided particles, such as droplets, formed in this way are conveyed by a carrier gas stream and introduced into the reaction chamber, where the deposition and growth of the carbon nanotubes or nitrogen-doped carbon nanotubes take place.