Patents by Inventor Marvin R. Havens

Marvin R. Havens has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 5180615
    Abstract: A flexible sheet material and bags made therefrom for packaging electrostatically sensitive items such as electronic circuit boards. The sheet has a metal layer and an antistatic layer. The outer surface of the bag has a high non-conductive surface resistivity greater than or equal to 10.sup.8 ohms/square, yet the bag protects the packaged item from static voltage by preventing the capacitive coupling of the voltage through the bag to the item packaged therein.
    Type: Grant
    Filed: December 13, 1989
    Date of Patent: January 19, 1993
    Assignee: W.R. Grace & Co.-Conn.
    Inventor: Marvin R. Havens
  • Patent number: 5175033
    Abstract: A flexible sheet material and bags made therefrom for packaging electrostatically sensitive items such as electronic circuit boards. The sheet has a metal layer that is adhesively laminated to an antistatic polymeric layer, the instant bag being of improved metal layer to antistatic layer adhesion. The metal outer surface of the bag has a high non-conductive surface resistivity greater than or equal to 10.sup.8 ohms/square, yet the bag protects the packaged item from static voltage by preventing the capacitive coupling of the voltage through the bag to the item packaged therein.
    Type: Grant
    Filed: June 22, 1990
    Date of Patent: December 29, 1992
    Assignee: W. R. Grace & Co.-Conn.
    Inventor: Marvin R. Havens
  • Patent number: 5171641
    Abstract: An acid copolymer/quaternary amine mixture is disclosed which is permanently antistatic. The acid copolymer is a copolymer of (i) a major amount by mol % of an alpha-olefin of the formula RCH.dbd.CH.sub.2 wherein R is H or C.sub.1 to C.sub.8 alkyl, and (ii) a minor amount by mol % of an alpha,beta-ethylenically unsaturated carboxylic acid. The quaternary amine is of the formula [(R.sup.1)(R.sup.2)(R.sup.3)(R.sup.4)N].sup.+ [X].sup.- wherein R.sup.1 is selected from H, aryl, or C.sub.1 to C.sub.50 alkyl optionally having one or more non-contiguous C.dbd.O or NHC.dbd.O or --S-- or --O-- in the carbon chain, or the same as R.sup.2 ; each of R.sup.2, R.sup.3, and R.sup.4 is the same or different and selected from H, C.sub.1 to C.sub.18 alkyl optionally substituted with one or more OH or from --(R.sup.5 --O).sub.a --H where a is an integer from 1 to 10 and R.sup.5 is ethylene or propylene; and X is an anion selected from chloride, bromide, iodide, nitrate, fluoborate, phosphate, C.sub.1 to C.sub.
    Type: Grant
    Filed: July 25, 1990
    Date of Patent: December 15, 1992
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: William P. Roberts, Marvin R. Havens
  • Patent number: 5153075
    Abstract: An acid copolymer/quaternary amine mixture is disclosed which is permanently antistatic. The acid copolymer is a copolymer of (i) a major amount by mol % of an alpha-olefin of the formula RCH.dbd.CH.sub.2 wherein R is H or C.sub.1 to C.sub.8 alkyl, and (ii) a minor amount by mol % of an alpha,beta-ethylenically unsaturated carboxylic acid. The quaternary amine is of the formula [(R.sup.1)(R.sup.2)(R.sup.3)(R.sup.4)N]+ [X]- wherein R.sup.1 is selected from H, aryl, or C.sub.1 to C.sub.50 alkyl optionally having one or more non-contiguous C.dbd.O or NHC.dbd.O or --S-- or --O-- in the carbon chain, or the same as R.sup.2 ; each of R.sup.2, R.sup.3, and R.sup.4 is the same or different and selected from H, C.sub.1 to C.sub.18 alkyl optionally substituted with one or more OH or from --(R.sup.5 --O).sub.a --H where a is an integer from 1 to 10 and R.sup.5 is ethylene or propylene; and X is an anion selected from chloride, bromide, iodide, fluoride, nitrate, fluoborate, phosphate, C.sub.1 to C.sub.
    Type: Grant
    Filed: July 25, 1990
    Date of Patent: October 6, 1992
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Marvin R. Havens, William P. Roberts
  • Patent number: 5110530
    Abstract: Striped films of the invention can have two or more preferably polymeric layers, of which at least one continuous or discontinuous layer includes a pigmented resin. The striped film is produced by modifying conventional coextrusion dies to restrict the flow of a pigmented melt stream. The result is a striped film useful for identifying the contents of a package made from the film, tamper evidence, counterfeit protection and verification of properties. The stripes can be of one or more colors, and vary in width and spacing. The pigment can be a material visible in ordinary light, or a material invisible in ordinary light but visible in e.g. ultraviolet light.
    Type: Grant
    Filed: September 7, 1990
    Date of Patent: May 5, 1992
    Assignee: W. R. Grace & Co.-Conn.
    Inventor: Marvin R. Havens
  • Patent number: 5096761
    Abstract: A masking film suitable for masking during electrostatic spray painting is disclosed. In one embodiment the masking film is made from an acid copolymer/quaternary amine mixture which is permanently antistatic. The acid copolymer is a copolymer of (i) a major amount by mol % of an alpha-olefin of the formula RCH.dbd.CH.sub.2 wherein R is H or C.sub.1 to C.sub.8 alkyl, and (ii) a minor amount by mol % of an alpha,beta-ethylenically unsaturated carboxylic acid. The quaternary amine is of the formula [(R.sup.1)(R.sup.2)(R.sup.3)(R.sup.4)N].sup.+ [X].sup.- wherein R.sup.1 is selected from H, aryl, or C.sub.1 to C.sub.50 alkyl optionally having one or more non-contiguous C.dbd.O or NHC.dbd.O or --S-- or --O-- in the carbon chain, or the same as R.sup.2 ; each of R.sup.2, R.sup.3, and R.sup.4 is the same or different and selected from H, C.sub.1 to C.sub.18 alkyl optionally substituted with one or more OH or from --(R.sup.5 --O).sub.a --H where a is an integer from 1 to 10 and R.sup.
    Type: Grant
    Filed: July 25, 1990
    Date of Patent: March 17, 1992
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: William P. Roberts, Charles R. Morgan, Marvin R. Havens
  • Patent number: 5064699
    Abstract: A semi-rigid, heat-sealable laminate with permanent antistatic characteristics comprising a semi-rigid packaging material having a coating of heat-sealable antistatic plastic. The antistatic plastic is a film of a modified acid copolymer. The modified acid copolymer is selected from (I) a mixture of (A) a polymer containing carboxylic acid moieties and (B) an antistatically effective amount of a quaternary amine, or (II) the acid/base reaction product of (A) a polymer containing carboxylic acid moieties and (C) an antistatically effective amount of an organic or inorganic base.
    Type: Grant
    Filed: March 6, 1990
    Date of Patent: November 12, 1991
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Marvin R. Havens, Stephen L. Fowler, William P. Roberts, Cynthia L. Ebner
  • Patent number: 5033253
    Abstract: Disclosed is a skin packaging film for skin packaging high profile and/or heavy articles. The film comprises linear ethylene/alpha-olefin copolymer. In one embodiment, the film is antistatic and may be employed for skin packaging of electro-static sensitive items such as circuit boards.
    Type: Grant
    Filed: November 17, 1989
    Date of Patent: July 23, 1991
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Marvin R. Havens, Stephen L. Fowler, George J. McCrary, Jr., Alfred P. Engelmann
  • Patent number: 5025922
    Abstract: Disclosed is a thermoplastic polymeric composition having antistatic characteristics and a method to make same. The composition comprises a thermoplastic polymer in admixture with an antistatic agent. In one embodiment the polymer is nylon 12 and the agent is N-butyl benzenesulfonamide. Also disclosed is the antistatic polymeric composition in a film, which is useful for packaging static sensitive devices such as electronic circuit boards, or for packaging devices that must be protected from static electricity such as devices in a medical operating room where explosive oxygen and/or ether are present.
    Type: Grant
    Filed: June 9, 1989
    Date of Patent: June 25, 1991
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Marvin R. Havens, Joseph R. Lovin
  • Patent number: 5024792
    Abstract: Disclosed is a film having antistatic characteristics and a method to make the film. The film comprises a blend of polyether block amide copolymer with an aromatic sulfonamide antistatic agent.
    Type: Grant
    Filed: October 19, 1989
    Date of Patent: June 18, 1991
    Assignee: W. R. Grace & Co.-Conn.
    Inventor: Marvin R. Havens
  • Patent number: 5001015
    Abstract: Disclosed is a film having antistatic characteristics and a method to make the film. The film comprises a blend of polyolefin with an antistatic agent chosen from fatty acid esters of polyhydroxy alcohols, polyalkoxylated compounds or mixtures thereof.
    Type: Grant
    Filed: January 22, 1990
    Date of Patent: March 19, 1991
    Assignee: W. R. Grace & Co.-Conn.
    Inventor: Marvin R. Havens
  • Patent number: 4999252
    Abstract: An acid copolymer/quaternary amine mixture is disclosed which is permanently antistatic. The acid copolymer is a copolymer of (i) a major amount by mol % of an alpha-olefin of the formula RCH.dbd.CH.sub.2 wherein R is H or C.sub.1 to C.sub.8 alkyl, and (ii) a minor amount by mol % of an alpha,beta-ethylenically unsaturated carboxylic acid. The quaternary amine is of the formula [(R.sup.1)(R.sup.2)(R.sup.3)(R.sup.4)N].sup.+ [X].sup.- wherein R.sup.1 is selected from H, aryl, or C.sub.1 to C.sub.50 alkyl optionally having one or more non-contiguous C.dbd.O or NHC.dbd.O or --S-- or --O-- in the carbon chain, or the same as R.sup.2 ; each of R.sup.2, R.sup.3, and R.sup.4 is the same or different and selected from H, C.sub.1 to C.sub.18 alkyl optionally substituted with one or more OH or from --(R.sup.5 --O).sub.a --H where a is an integer from 1 to 10 and R.sup.5 is ethylene or propylene; and X is an anion selected from chloride, bromide, iodide, fluoride, nitrate, fluoborate, phosphate, C.sub.1 to C.sub.
    Type: Grant
    Filed: September 26, 1988
    Date of Patent: March 12, 1991
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Marvin R. Havens, William P. Roberts
  • Patent number: 4899521
    Abstract: Disclosed is a film having antistatic characteristics and a method to make the film. The film comprises a blend of polyether block amide copolymer with an aromatic sulfonamide antistatic agent.
    Type: Grant
    Filed: September 28, 1987
    Date of Patent: February 13, 1990
    Assignee: W. R. Grace & Co. - Conn.
    Inventor: Marvin R. Havens
  • Patent number: 4898771
    Abstract: Disclosed is a thermoplastic polymeric composition having antistatic characteristics and a method to make same. The composition comprises a thermoplastic polymer in admixture with an antistatic agent. In one embodiment the polymer is polyethylene and the agent is a mixture of polyethoxylated cetyl alcohol and glyceryl monostearate. Also disclosed is the antistatic polymeric composition in a film, which is useful for packaging static sensitive devices such as electronic circuit boards, or for packaging devices that must be protected from static electricity such as devices in a medical operating room where explosive oxygen and/or ether are present.
    Type: Grant
    Filed: September 21, 1988
    Date of Patent: February 6, 1990
    Assignee: W. R. Grace & Co.-Conn.
    Inventor: Marvin R. Havens
  • Patent number: 4882894
    Abstract: Disclosed is a thermoplastic polymeric composition having antistatic characteristics and a method to make same. The composition comprises a thermoplastic polymer in admixture with an antistatic agent. In one embodiment the polymer is nylon 12 and the agent is N-butyl benzenesulfonamide. Also disclosed is the antistatic polymeric composition in a film, which is useful for packaging static sensitive devices such as electronic circuit boards, or for packaging devices that must be protected from static electricity such as devices in a medical operating room where explosive oxygen and/or ether are present.
    Type: Grant
    Filed: October 14, 1986
    Date of Patent: November 28, 1989
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: Marvin R. Havens, Joseph R. Lovin
  • Patent number: 4848566
    Abstract: A blow molded container provides protection for electrically sensitive devices by including antistatic agents in the outer layer and electrically conductive agents in the inner layer of a multilayer parison used to form a container. The invention renders the use of separate antistatic foam pads unnecessary by providing an antistatic surface in the container when closed.
    Type: Grant
    Filed: February 22, 1988
    Date of Patent: July 18, 1989
    Assignee: W. R. Grace & Co.
    Inventors: Marvin R. Havens, Robert R. Wilkie
  • Patent number: 4800115
    Abstract: Disclosed is a thermoplastic plymeric composition having antistatic characteristics and a method to make same. The composition comprises a thermoplastic polymer in admixture with an antistatic agent. In one embodiment the polymer is polyethylene and the agent is a mixture of polyethoxylated cetyl alcohol and glyceryl monostearate. Also disclosed is the antistatic polymeric composition in a film, which is useful for packaging static sensitive devices such as electronic circuit boards, or for packaging devices that must be protected from static electricity such as devices in a medical operating room where explosive oxygen and/or ether are present.
    Type: Grant
    Filed: October 14, 1986
    Date of Patent: January 24, 1989
    Assignee: W. R. Grace & Co.
    Inventor: Marvin R. Havens
  • Patent number: 4698111
    Abstract: This invention relates to films made from vinylidene chloride polymers or copolymers. Specifically, this invention relates to a method and composition for lowering the oxygen permeability and enhancing the thermal stability of mono-layer and multi-layer packaging films having a plasticized layer of vinylidene chloride copolymer film.
    Type: Grant
    Filed: December 19, 1986
    Date of Patent: October 6, 1987
    Assignee: W. R. Grace & Co., Cryovac Div.
    Inventor: Marvin R. Havens
  • Patent number: 4686148
    Abstract: This invention relates to films made from vinylidene chloride polymers or copolymers. Specifically, this invention relates to a method and composition for lowering the oxygen permeability and enhancing the thermal stability of mono-layer and multi-layer packaging films having a plasticized layer of vinylidene chloride copolymer film.
    Type: Grant
    Filed: July 15, 1985
    Date of Patent: August 11, 1987
    Assignee: W. R. Grace & Co., Cryovac Div.
    Inventor: Marvin R. Havens
  • Patent number: 4256317
    Abstract: Valve packing system comprising a compacted body of expanded graphite material having an apparent bulk density 1.6 to 2.0 times its apparent bulk density prior to compaction and positioned in stuffing box with zero clearance between each of valve stem and said stuffing box, and a pair of flat carbon guide rings retaining said compacted body and machined to close internal clearance with said valve stem and close external clearance with the internal walls of said stuffing box.
    Type: Grant
    Filed: April 24, 1980
    Date of Patent: March 17, 1981
    Assignee: Union Carbide Corporation
    Inventors: Marvin R. Havens, Donald R. Fields, Douglas J. Miller