Patents by Inventor Masahiko Kakizawa

Masahiko Kakizawa has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 9845538
    Abstract: The object of the present invention is to provide: an etching agent for a titanium-based metal on a semiconductor substrate, which suppresses decomposition of hydrogen peroxide, has a long liquid service life, and has less need for controlling the concentration of hydrogen peroxide in the etching agent, even in the cases where the etching agent is used for a semiconductor substrate having the titanium-based metal and a metallic copper or a metal alloy; an etching method; and an etching agent preparation liquid for use by mixing with hydrogen peroxide.
    Type: Grant
    Filed: July 3, 2014
    Date of Patent: December 19, 2017
    Assignee: WAKO PURE CHEMICAL INDUSTRIES, LTD.
    Inventors: Takahiro Yokomizo, Hiroyuki Tsurumoto, Masahiko Kakizawa
  • Publication number: 20160177457
    Abstract: The object of the present invention is to provide: an etching agent for a titanium-based metal on a semiconductor substrate, which suppresses decomposition of hydrogen peroxide, has a long liquid service life, and has less need for controlling the concentration of hydrogen peroxide in the etching agent, even in the cases where the etching agent is used for a semiconductor substrate having the titanium-based metal and a metallic copper or a metal alloy; an etching method; and an etching agent preparation liquid for use by mixing with hydrogen peroxide.
    Type: Application
    Filed: July 3, 2014
    Publication date: June 23, 2016
    Applicant: WAKO PURE CHEMICAL INDUSTRIES, LTD.
    Inventors: Takahiro YOKOMIZO, Hiroyuki TSURUMOTO, Masahiko KAKIZAWA
  • Publication number: 20150125985
    Abstract: It is the object of the present invention to provide an alkali etching solution for solar cell manufacturing, which is capable of forming uniformly a fine hubbly structure throughout a whole wafer on the surface of a wafer having a silicon as a main component, and still more is applicable to various wafers; and a method for manufacturing a silicon-based substrate for solar cell manufacturing, using the etching solution.
    Type: Application
    Filed: May 10, 2013
    Publication date: May 7, 2015
    Applicant: WAKO PURE CHEMICAL INDUSTRIES, LTD.
    Inventors: Naoko Ohuchi, Masahiko Kakizawa, Hiroyuki Tsurumoto, Terumi Watanabe, Shinshi Kawara
  • Patent number: 9006164
    Abstract: The present invention is directed to provide a resist remover composition for semiconductor substrate which enables to remove a resist simply and easily in the photolithography process in the semiconductor field, and a method for removing a resist comprising that the composition is used. The present invention relates to a resist remover composition for semiconductor substrate, comprising [I] a carbon radical generating agent, [II] an acid, [III] a reducing agent, and [IV] an organic solvent, and having pH of lower than 7, and a method for removing a resist, comprising that the composition is used.
    Type: Grant
    Filed: September 1, 2010
    Date of Patent: April 14, 2015
    Assignee: Wako Pure Chemical Industries, Ltd.
    Inventors: Hironori Mizuta, Masahiko Kakizawa
  • Patent number: 8900371
    Abstract: The present invention provides a cleaning agent for a substrate and a cleaning method thereof, which can effectively remove fine particles (particles) present on a surface of substrate or impurities derived from various kinds of metals (metallic impurities), without causing roughness surface of a substrate, in particular, a semiconductor substrate, and without causing corrosion or oxidation of metal wirings, in particular, copper wirings, provided on a surface of substrate, and can further remove at the same time a carbon defect present on a surface of substrate, without removing a metal corrosion inhibitor—Cu film, in particular, a Cu-BTA film.
    Type: Grant
    Filed: September 14, 2011
    Date of Patent: December 2, 2014
    Assignee: Wako Pure Chemical Industries, Ltd.
    Inventors: Hironori Mizuta, Masahiko Kakizawa, Ichiro Hayashida
  • Publication number: 20130261040
    Abstract: A cleaning agent for a substrate having a copper wiring consisting of an aqueous solution comprising [I] an amino acid represented by the following general formula [1], and [II] an alkylhydroxylamine; and a method for cleaning a semiconductor substrate having a copper wiring characterized by using the relevant cleaning agent for a substrate having a copper wiring; (wherein R1 represents a hydrogen atom, a carboxymethyl group or a carboxyethyl group; and R2 and R3 each independently represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, which may have a hydroxyl group, provided that those where R1 to R3 are all hydrogen atoms are excluded.).
    Type: Application
    Filed: November 28, 2011
    Publication date: October 3, 2013
    Applicant: WAKO PURE CHEMICAL INDUSTRIES, LTD.
    Inventors: Hiromi Kawada, Satoshi Shirahata, Hironori Mizuta, Masahiko Kakizawa, Kazuo Shiraki
  • Publication number: 20130171835
    Abstract: The purpose of the present invention to provide: a composition which can be used for water-repellent treating of the entire surface of a semiconductor substrate having a pattern formed by laminating a Si-containing insulating layer and a metal layer, at one time; and a method for water-repellent treatment of the semiconductor substrate surface using the composition. The present invention relates to: (1) a composition for water-repellent treatment of a semiconductor substrate surface comprising a) at least one kind of a compound selected from the group consisting of a long-chain alkyl tertiary amine and a long-chain alkyl ammonium salt, b) a base or an acid generating agent, having a condensed ring structure or forming a condensed ring structure by generating a base or an acid and c) a polar organic solvent, and (2) a method for water-repellent treatment of the semiconductor substrate surface having the pattern formed by laminating the Si-containing insulating layer and the metal layer, using the composition.
    Type: Application
    Filed: September 7, 2011
    Publication date: July 4, 2013
    Applicant: WAKO PURE CHEMICAL INDUSTRIES, LTD.
    Inventors: Hironori Mizuta, Yoji Urano, Masahiko Kakizawa
  • Publication number: 20120172274
    Abstract: The present invention is directed to provide a resist remover composition for semiconductor substrate which enables to remove a resist simply and easily in the photolithography process in the semiconductor field, and a method for removing a resist comprising that the composition is used. The present invention relates to a resist remover composition for semiconductor substrate, comprising [I] a carbon radical generating agent, [II] an acid, [III] a reducing agent, and [IV] an organic solvent, and having pH of lower than 7, and a method for removing a resist, comprising that the composition is used.
    Type: Application
    Filed: September 1, 2010
    Publication date: July 5, 2012
    Applicant: WAKO PURE CHEMICAL INDUSTRIES, LTD.
    Inventors: Hironori Mizuta, Masahiko Kakizawa
  • Publication number: 20120000485
    Abstract: The present invention provides a cleaning agent for a substrate and a cleaning method thereof, which can effectively remove fine particles (particles) present on a surface of substrate or impurities derived from various kinds of metals (metallic impurities), without causing roughness surface of a substrate, in particular, a semiconductor substrate, and without causing corrosion or oxidation of metal wirings, in particular, copper wirings, provided on a surface of substrate, and can further remove at the same time a carbon defect present on a surface of substrate, without removing a metal corrosion inhibitor—Cu film, in particular, a Cu-BTA film.
    Type: Application
    Filed: September 14, 2011
    Publication date: January 5, 2012
    Applicant: WAKO PURE CHEMICAL INDUSTRIES, LTD.
    Inventors: Hironori Mizuta, Masahiko Kakizawa, Ichiro Hayashida
  • Publication number: 20100269903
    Abstract: Provided are: a safe, low-cost method of producing a polycrystalline silicon substrate excellent in photoelectric conversion efficiency by which a uniform, fine uneven structure suited to a solar cell can be simply formed on the surface of the polycrystalline silicon substrate; and a polycrystalline silicon substrate having a uniform, fine, pyramid-shaped uneven structure so that its reflectance can be significantly reduced. The uneven structure is formed on the surface of the polycrystalline silicon substrate by etching the polycrystalline silicon substrate with an alkaline etching solution containing at least one kind selected from the group consisting of a carboxylic acid having 1 or more and 12 or less carbon atoms and each having at least one carboxyl group in one molecule, and salts of the acids.
    Type: Application
    Filed: November 28, 2008
    Publication date: October 28, 2010
    Applicants: MIMASU SEMICONDUCTOR INDUSTRY CO., LTD., WAKO PURE CHEMICAL INDUSTRIES, LTD.
    Inventors: Masato Tsuchiya, Ikuo Mashimo, Yoshimichi Kimura, Takehisa Kato, Masahiko Kakizawa
  • Publication number: 20090227115
    Abstract: Disclosed are an etching solution for a substrate and a substrate-etching method, which can prevent the contamination of a substrate, particularly a semiconductor substrate, with metal impurities. The etching solution comprises a dicarboxylic acid represented by the general formula (1) or a salt thereof and 20% (W/W) or more of an alkali metal hydroxide. The substrate-etching method comprises the step of etching a substrate with said etching solution.
    Type: Application
    Filed: May 22, 2007
    Publication date: September 10, 2009
    Applicant: WAKO PURE CHEMICAL INDUSTRIES, LTD.
    Inventors: Takehisa Kato, Masahiko Kakizawa, Ichiro Hayashida
  • Patent number: 7375066
    Abstract: A semiconductor surface cleaning agent containing a compound the molecule of which has a nitrogen atom having an unshared electron pair and used for cleaning the surface of a semiconductor on which copper wiring is provided, and a method for cleaning the surface of a semiconductor characterized by treating the surface of a semiconductor on which copper wiring is provided with such a cleaning agent. The cleaning agent does not corrode the copper wiring (copper thin film) on the semiconductor and SiO2 of the interlayer insulating film, does not impair the flatness of the surface, and is effective in removing CuO and particles adhering to the surface of the Cu-CMP step.
    Type: Grant
    Filed: March 19, 2001
    Date of Patent: May 20, 2008
    Assignee: Wako Pure Chemical Industries, Ltd.
    Inventors: Masahiko Kakizawa, Mayumi Kimura, Hironori Mizuta, Ichiro Hayashida
  • Publication number: 20070235061
    Abstract: The present invention provides a cleaning agent for a substrate and a cleaning method thereof, which can effectively remove fine particles (particles) present on a surface of substrate or impurities derived from various kinds of metals (metallic impurities), without causing roughness surface of a substrate, in particular, a semiconductor substrate, and without causing corrosion or oxidation of metal wirings, in particular, copper wirings, provided on a surface of substrate, and can further remove at the same time a carbon defect present on a surface of substrate, without removing a metal corrosion inhibitor—Cu film, in particular, a Cu-BTA film.
    Type: Application
    Filed: October 13, 2004
    Publication date: October 11, 2007
    Applicant: WAKO PURE CHEMICAL INDUSTRIES, LTD.
    Inventors: Hironori Mizuta, Masahiko Kakizawa, Ichiro Hayashida
  • Publication number: 20040077512
    Abstract: This invention relates to a cleaning agent for a semi-conductor substrate, particularly, one having copper wirings on its surface, comprising a nonionic surfactant and a method for cleaning the same.
    Type: Application
    Filed: October 14, 2003
    Publication date: April 22, 2004
    Applicant: WAKO PURE CHEMICAL INDUSTRIES, LTD.
    Inventors: Masahiko Kakizawa, Ken-Ichi Umekita, Ichiro Hayashida
  • Patent number: 6716803
    Abstract: This invention relates to a cleaning agent for a semi-conductor substrate, particularly, one having copper wirings on its surface, comprising a nonionic surfactant and a method for cleaning the same. The said cleaning agent and the method have made it possible to control a speed of etching on silicone oxide so as to remove impurities adsorbed on copper wirings and silicone oxide on a surface of a semi-conductor substrate having copper wirings on its surface, such as copper oxides and particles, without causing corrosion or oxidation of copper wirings nor causing roughness on the surface.
    Type: Grant
    Filed: August 8, 2001
    Date of Patent: April 6, 2004
    Assignee: Wako Pure Chemcial Industries, Ltd.
    Inventors: Masahiko Kakizawa, Ken-ichi Umekita, Ichiro Hayashida
  • Publication number: 20030083214
    Abstract: A semiconductor surface cleaning agent containing a compound the molecule of which has a nitrogen atom having an unshared electron pair and used for cleaning the surface of a semiconductor on which copper wiring is provided, and a method for cleaning the surface of a semiconductor characterized by treating the surface of a semiconductor on which copper wiring is provided with such a cleaning agent The cleaning agent does not corrode the copper wiring (copper thin film) on the semiconductor and SiO2 of the interlayer insulating film, does not impair the flatness of the surface, and is effective in removing CuO and particles adhering to the surface at the Cu-CMP step.
    Type: Application
    Filed: August 27, 2002
    Publication date: May 1, 2003
    Inventors: Masahiko Kakizawa, Mayumi Kimura, Hironori Mizuta, Ichiro Hayashida
  • Patent number: 6534458
    Abstract: This invention relates to a cleaning agent for a semi-conductor substrate, particularly, one having copper wirings on its surface, comprising a nonionic surfactant and a method for cleaning the same. The said cleaning agent and the method have made it possible to control a speed of etching on silicone oxide so as to remove impurities adsorbed on copper wirings and silicone oxide on a surface of a semi-conductor substrate having copper wirings on its surface, such as copper oxides and particles, without causing corrosion or oxidation of copper wirings nor causing roughness on the surface.
    Type: Grant
    Filed: November 16, 2000
    Date of Patent: March 18, 2003
    Assignee: Wako Pure Chemical Industries, Ltd.
    Inventors: Masahiko Kakizawa, Ken-ichi Umekita, Ichiro Hayashida
  • Patent number: 6514921
    Abstract: Removing particles and metallic contaminants without corrosing the metallized wirings and without giving adverse effect of planarization on the semiconductor substrate surface can be effectively achieved by use of a cleaning agent which comprises an organic acid having at least one carboxyl group and a complexing agent having chelating ability.
    Type: Grant
    Filed: September 11, 2000
    Date of Patent: February 4, 2003
    Assignee: Wako Pure Chemical Industries, Ltd.
    Inventors: Masahiko Kakizawa, Osamu Ichikawa, Ichiro Hayashida
  • Patent number: 6410494
    Abstract: Removing particles and metallic contaminants without corrosing the metallized wirings and without giving adverse effect of planarization on the semiconductor substrate surface can be effectively achieved by use of a cleaning agent which comprises an organic acid having at least one carboxyl group and a complexing agent having chelating ability.
    Type: Grant
    Filed: February 22, 2001
    Date of Patent: June 25, 2002
    Assignee: Wako Pure Chemical Industries, Ltd.
    Inventors: Masahiko Kakizawa, Osamu Ichikawa, Ichiro Hayashida
  • Publication number: 20020016272
    Abstract: This invention relates to a cleaning agent for a semi-conductor substrate, particularly, one having copper wirings on its surface, comprising a nonionic surfactant and a method for cleaning the same.
    Type: Application
    Filed: August 8, 2001
    Publication date: February 7, 2002
    Applicant: WAKO PURE CHEMICAL INDUSTRIES, LTD.
    Inventors: Masahiko Kakizawa, Ken-Ichi Umekita, Ichiro Hayashida