Patents by Inventor Masahiko Okamoto

Masahiko Okamoto has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).

  • Patent number: 9023906
    Abstract: To provide a propylene-based copolymer and a propylene-based copolymer composition, each of which has a high melt tension because it has a long-chain branched structure, exhibits excellent molding processability during molding, such as inflation molding, extrusion molding, blow molding, injection molding or vacuum forming, and is capable of favorably providing a foamed product having an excellent expansion ratio and excellent cell uniformity in the foaming stage. The propylene-based copolymer (A) of the present invention comprises 50 to 95% by mol of constituent units [i] derived from propylene, 4.9 to 49.9% by mol of constituent units [ii] derived from an ?-olefin of 2 to 10 carbon atoms other than propylene and 0.1 to 10% by mol of constituent units [iii] derived from a non-conjugated polyene (with the proviso that the total amount of the constituent units [i], [ii] and [iii] is 100% by mol), and is characterized by satisfying specific requirements (a) and (c).
    Type: Grant
    Filed: May 17, 2012
    Date of Patent: May 5, 2015
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Masahiko Okamoto, Mayumi Yasuda, Tetsuji Kasai, Kazuyoshi Kaneko, Kyoko Kobayashi, Kotaro Ichino
  • Publication number: 20140342111
    Abstract: To provide a 4-methyl-1-pentene/olefin (co)polymer composition which is excellent in transparency and heat resistance and is excellent also in elongation and toughness and to provide a molded product composed of the composition, a film composed of the composition, which is excellent in transparency, heat resistance and dimensional stability and has been uniformly stretched, and a hollow molded product composed of the composition, which is excellent in transparency, heat resistance and toughness and is excellent also in dimensional stability. The 4-methyl-1-pentene (co)polymer composition of the present invention comprises a specific 4-methyl-1-pentene (co)polymer (A) and a specific 4-methyl-1-pentene/?-olefin copolymer (B) in a specific ratio.
    Type: Application
    Filed: December 25, 2012
    Publication date: November 20, 2014
    Inventors: Hirokazu Tanaka, Takayuki Uekusa, Masahiko Okamoto, Yoshisada Tamo
  • Patent number: 8802779
    Abstract: The propylene-based polymer composition of the present invention includes 41 to 95 parts by weight of a propylene-based polymer (A) having a Tm measured by DSC of not less than 120° C. and not more than 170° C., and 59 to 5 parts by weight (provided that the total of (A) and (B) is 100 parts by weight) of a propylene/ethylene/?-olefin copolymer (B) that contains 84.0 to 60.0 mol % of constitutional units derived from propylene, 15.0 to 30.0 mol % of constitutional units derived from ethylene, and 1.0 to 10.0 mol % of constitutional units derived from an ?-olefin having 4 to 20 carbon atoms and has a B-value of not less than 0.9 and not more than 1.5. This polymer composition is excellent in transparency, low-temperature impact resistance, and mechanical properties (flexibility or rigidity, etc.) and also excellent in heat resistance.
    Type: Grant
    Filed: December 22, 2006
    Date of Patent: August 12, 2014
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Masahiko Okamoto, Ryoji Mori, Takashi Nakagawa, Hiromasa Marubayashi, Shigenobu Ikenaga, Yasushi Tohi, Kouji Nagahashi
  • Publication number: 20140088214
    Abstract: To provide a propylene-based copolymer and a propylene-based copolymer composition, each of which has a high melt tension because it has a long-chain branched structure, exhibits excellent molding processability during molding, such as inflation molding, extrusion molding, blow molding, injection molding or vacuum forming, and is capable of favorably providing a foamed product having an excellent expansion ratio and excellent cell uniformity in the foaming stage. The propylene-based copolymer (A) of the present invention comprises 50 to 95% by mol of constituent units [i] derived from propylene, 4.9 to 49.9% by mol of constituent units [ii] derived from an ?-olefin of 2 to 10 carbon atoms other than propylene and 0.1 to 10% by mol of constituent units [iii] derived from a non-conjugated polyene (with the proviso that the total amount of the constituent units [i], [ii] and [iii] is 100% by mol), and is characterized by satisfying specific requirements (a) and (c).
    Type: Application
    Filed: May 17, 2012
    Publication date: March 27, 2014
    Inventors: Masahiko Okamoto, Mayumi Yasuda, Tetsuji Kasai, Kazuyoshi Kaneko, Kyoko Kobayashi, Kotaro Ichino
  • Patent number: 8329825
    Abstract: A material for vibration control of the invention includes a propylene polymer (A) containing a constitutional unit (a) derived from propylene in the proportion of 40 to 100 mol % and a constitutional unit (b) derived from ?-olefin having 2 to 20 carbon atoms excluding propylene in the proportion of 60 to 0 mol % [provided that the total of (a) and (b) is 100 mol %], and having a melting point measured by DSC of 90° C. or below or no observed melting point, and the material has excellent vibration controllability such as vibration damping property, vibration preventing property, sound insulating property, and sound absorbing property.
    Type: Grant
    Filed: November 14, 2006
    Date of Patent: December 11, 2012
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Ryoji Mori, Masahiko Okamoto, Takashi Nakagawa, Shigenobu Ikenaga
  • Publication number: 20120220728
    Abstract: The present invention provides a 4-methyl-1-pentene/?-olefin copolymer being excellent in lightness, stress absorption, stress relaxation, vibration damping properties, scratch resistance, abrasion resistance, toughness, mechanical properties and flexibility, having no stickiness during molding operation and being excellent in the balance among these properties; a composition comprising the polymer; and uses thereof. The 4-methyl-1-pentene/?-olefin copolymer (A) of the present invention satisfies specific requirements, and comprises 5 to 95 mol % of a structural unit (i) derived from 4-methyl-1-pentene, 5 to 95 mol % of a structural unit (ii) derived from at least one kind of ?-olefin selected from ?-olefins having 2 to 20 carbon atoms excluding 4-methyl-1-pentene and 0 to 10 mol % of a structural unit (iii) derived from a non-conjugated polyene, provided that the total of the structural units (i), (ii), and (iii) is 100 mol %.
    Type: Application
    Filed: November 5, 2010
    Publication date: August 30, 2012
    Inventors: Takayuki Uekusa, Masahiko Okamoto, Yoshisada Tamo
  • Patent number: 8129489
    Abstract: The present invention provides an ethylene polymer that has excellent fluidity and moldability as well as gives a molded product having excellent mechanical strength. The ethylene polymer of the present invention contains 0.02 to 1.50 mol % of a constitutional unit derived from ?-olefin having 6 to 10 carbon atoms, and has the density of 945 to 975 kg/m3, which satisfies both of the following requirements [1] and [2] simultaneously: [1] in CFC, all the components having a molecular weight of 100,000 or more are eluted at a temperature of 85° C. or higher; and [2] the components eluted at a temperature of 80° C. or lower account for up to 5% of all the components eluted in CFC.
    Type: Grant
    Filed: August 12, 2005
    Date of Patent: March 6, 2012
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Masahiko Okamoto, Tetsuji Kasai, Yasushi Tohi, Koji Endo, Shiro Otsuzuki, Takahiro Akashi, Kenji Iwamasa, Yoshiyuki Hirase, Keiko Fukushi, Shinichi Nagano
  • Patent number: 8008401
    Abstract: A polyolefin composition comprising an olefin-based thermoplastic elastomer which is superior to conventional olefin-based thermoplastic elastomers in scratch resistance and abrasion resistance and has excellent heat aging resistance is proposed. [Means for Solving the Problem] A polyolefin composition comprising a syndiotactic ?-olefin-based copolymer (A), a polyolefin resin (B) (other than polybutene (C)), polybutene (C), and if necessary, an ethylene-based copolymer rubber (D).
    Type: Grant
    Filed: September 10, 2007
    Date of Patent: August 30, 2011
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Yuichi Ito, Kazuki Mita, Ryoji Mori, Masahiko Okamoto, Toru Takehara, Masakazu Jitsukata, Hayato Kurita
  • Patent number: 7879960
    Abstract: A high molecular weight propylene polymer exhibiting high stereoregularity (isotactic) and high position selectivity can be effectively produced by polymerizing at least one monomer selected from propylene, ?-olefins and polyenes in the presence of a catalyst for olefin polymerization comprising: (A) a bridged metallocene compound represented by the General Formula [I] given in claims (diphenylmethylene(3-tert-butyl-5-ethyl-cyclopentadienyl)(fluorenyl)zirconium dichloride, etc.); and (B) one or more compound(s) selected from (b-1) an organoaluminumoxy compound (b-2) a compound which reacts with the bridged metallocene compound (A) to form an ion pair, and (b-3) an organoaluminum compound.
    Type: Grant
    Filed: August 29, 2005
    Date of Patent: February 1, 2011
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Munehito Funaya, Naritoshi Hirota, Mayumi Hiwara, Yasushi Tohi, Koji Kawai, Ryoji Mori, Masahiko Okamoto, Shigenobu Ikenaga, Hiromasa Marubayashi
  • Patent number: 7847040
    Abstract: A composition having excellent transparency, flexibility, rubber elasticity, thermal resistance, impact resistance, abrasion resistance and the like, a composition having excellent rigidity and impact resistance as well as excellently balanced in whitening resistance, abrasion resistance and heat sealability, and a composition having excellent rubbery properties, thermal resistance, abrasion resistance and flexibility are provided. A composition comprising a specific propylene•?-olefin copolymer for which, in a signal chart measured by 13C-NMR and predetermined such that the peak present at the highest magnetic field among the signals originating from CH (methine) of the constituent unit derived from an ?-olefin having 4 to 20 carbon atoms is to be at 34.4 ppm, an absorption intensity A at about 22.0 to 20.9 ppm and an absorption intensity B at about 19.0 to 20.6 ppm satisfy the following relational expressions (i) and (ii) with respect to an absorption intensity C at about 19.0 to 22.
    Type: Grant
    Filed: April 8, 2005
    Date of Patent: December 7, 2010
    Assignee: Mitsu Chemicals, Inc.
    Inventors: Ryoji Mori, Takashi Nakagawa, Shigenobu Ikenaga, Hiromasa Marubayashi, Masahiko Okamoto, Yasushi Tohi, Kouji Nagahashi
  • Publication number: 20100227098
    Abstract: An ethylene-based resin satisfying simultaneously the following requirements [a] to [c] is excellent in strength and moldability and is suitably used for a blow molded article (a hollow molded article). [a] The environmental stress cracking resistance (ESCR), T, at 50° C. is 500 hours or more in the case of a flexural modulus of 1000 MPa to 1500 MPa and is 100 hours or more in the case of a flexural modulus of 1500 MPa to 2000 MPa, as measured according to ASTM-D-1693, [b] the melt tension at 190° C. is 50 (mN) or more and [c] the melt breaking drawing rate is 90 (m/min) or less.
    Type: Application
    Filed: February 14, 2007
    Publication date: September 9, 2010
    Inventors: Keiko Fukushi, Kenji Iwamasa, Masahiko Okamoto
  • Patent number: 7700708
    Abstract: An ethylene polymer containing 0.01 to 1.20 mol % of a constitutional unit derived from ?-olefin having 6 to 10 carbon atoms, wherein with respect to cross fractionation chromatography (CFC), either (1) the weight average molecular weight (Mw) of the components eluted at 73 to 76° C. does not exceed 4,000, or (2) the ethylene polymer satisfies the following relationship (Eq-1), provides a molded product having excellent moldability and therefore excellent mechanical strength and appearance: Sx/Stotal?0.1??(Eq-1) wherein Sx is the sum of the total peak areas related to the components eluted at 70 to 85° C., and Stotal is the sum of the total peak areas related to the components eluted at 0 to 145° C.
    Type: Grant
    Filed: February 17, 2004
    Date of Patent: April 20, 2010
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Mamoru Takahashi, Masahiko Okamoto, Tetsuji Kasai, Yasushi Tohi, Shiro Otsuzuki, Shinichi Nagano, Yasuo Funabara, Takahiro Akashi
  • Publication number: 20100048820
    Abstract: Disclosed is a graft-modified syndiotactic propylene polymer having a high graft ratio. Also disclosed are a method for producing such a polymer, a resin composition containing such a polymer, and a laminate having at least one layer which contains the composition as an adhesive resin composition. Specifically disclosed is a graft-modified syndiotactic propylene polymer which is characterized by satisfying the following characteristics [1]-[3]. [1] The melt flow rate (MFR) measured at 230° C. under a load of 2.16 kg is 30-1000 (g/10 minutes). [2] The concentration of graft groups derived from a radically polymerizable unsaturated compound by 1H-NMR measurement is within the range of 0.7-7.0% by weight. [3] The syndiotactic pentad fraction determined by 13C-NMR measurement is not less than 0.80.
    Type: Application
    Filed: November 15, 2007
    Publication date: February 25, 2010
    Inventors: Yasuyuki Soeda, Takayuki Onogi, Akihide Mori, Masahiko Okamoto, Fumio Kageyama
  • Publication number: 20100004401
    Abstract: [Problem] A polyolefin composition comprising an olefin-based thermoplastic elastomer which is superior to conventional olefin-based thermoplastic elastomers in scratch resistance and abrasion resistance and has excellent heat aging resistance is proposed. [Means for Solving the Problem] A polyolefin composition comprising a syndiotactic ?-olefin-based copolymer (A), a polyolefin resin (B) (other than polybutene (C)), polybutene (C), and if necessary, an ethylene-based copolymer rubber (D).
    Type: Application
    Filed: September 10, 2007
    Publication date: January 7, 2010
    Applicant: MITSUI CHEMICALS, INC.
    Inventors: Yuichi Ito, Kazuki Mita, Ryoji Mori, Masahiko Okamoto, Toru Takehara, Masakazu Jitsukata, Hayato Kurita
  • Publication number: 20090162633
    Abstract: A material for vibration control of the invention includes a propylene polymer (A) containing a constitutional unit (a) derived from propylene in the proportion of 40 to 100 mol % and a constitutional unit (b) derived from ?-olefin having 2 to 20 carbon atoms excluding propylene in the proportion of 60 to 0 mol % [provided that the total of (a) and (b) is 100 mol %], and having a melting point measured by DSC of 90° C. or below or no observed melting point, and the material has excellent vibration controllability such as vibration damping property, vibration preventing property, sound insulating property, and sound absorbing property.
    Type: Application
    Filed: November 14, 2006
    Publication date: June 25, 2009
    Inventors: Ryoji Mori, Masahiko Okamoto, Takashi Nakagawa, Shigenobu Ikenaga
  • Publication number: 20090036584
    Abstract: Disclosed is an environmental stress cracking resistance improver that is composed of a compound that has in the molecule thereof a structure represented by the following general formula (I) and a molecular weight of from 200 to 2,000. Also disclosed are a method for improving environmental stress cracking resistance properties that uses the environmental stress cracking resistance improver, and a resin composition with improved environmental stress cracking resistance properties that contains the environmental stress cracking resistance improver. In the above general formula, R1 and R2 are each a hydrocarbon group having 1 to 6 carbon atoms, and may be the same or different from each other.
    Type: Application
    Filed: February 15, 2007
    Publication date: February 5, 2009
    Inventors: Keiko Fukushi, Kenji Iwamasa, Masahiko Okamoto
  • Publication number: 20090018299
    Abstract: An ethylene-?-olefin copolymer for a film or sheet satisfying the following requirements [1] to [5] simultaneously is excellent in transparency and moldability and is suitably used for a film or sheet excellent in mechanical strength. [1] The density (d) is in the range of 890 to 980 kg/m3. [2] The intrinsic viscosity ([?]) measured at 135° C. in decalin is in the range of 0.5 to 10 dl/g. [3] The ratio of weight average molecular weight (Mw) to number average molecular weight (Mn) (Mw/Mn) measured by GPC is in the range of 2.0 to 50. [4] In an elution temperature-elution amount curve given by cross fractionation chromatography (CFC), the difference between a temperature at which the integrated elution amount is 1% by mass and a temperature at which the integrated elution amount is 40% by mass is 12° C. or less, wherein the total elution amount is 100% by mass. [5] The amount of a component soluble in decane is 0.5% by mass or less.
    Type: Application
    Filed: February 14, 2007
    Publication date: January 15, 2009
    Inventors: Tsutomu Tasaki, Takahiro Akashi, Shinya Matsubara, Masahiko Okamoto
  • Publication number: 20080220193
    Abstract: A catalyst for olefin polymerization, comprising: (A-1) a bridged metallocene compound represented by the following Formula [1-1], and (b) at least one compound selected from: (b-1) an organoaluminum oxy compound, (b-2) a compound which forms an ion pair, and (b-3) an organoaluminum compound: wherein in Formula [1-1], R1, R2, R3, R4, R5, R8, R9, and R12 are each selected from a hydrogen, a hydrocarbon group and a silicon-containing group; the four groups of R6, R7, R10, and R11 are not hydrogen atoms, and are each selected from a hydrocarbon group or a silicon-containing group; R13 and R14 are each a hydrocarbon group or the like, excluding a hydrogen atom and a methyl group; M is Ti, Zr or the like; Y is carbon or the like; Q is a halogen or the like; and j is an integer from 1
    Type: Application
    Filed: November 16, 2007
    Publication date: September 11, 2008
    Inventors: Yasushi Tohi, Masahiko Okamoto, Ryoji Mori, Tatsuya Nakamura, Takashi Yukita, Takashi Nakagawa, Miyuki Konno, Yuichi Yamamura, Shigenobu Ikenaga, Mayumi Hiwara, Naritoshi Hirota, Hiromasa Marubayashi, Kouji Nagahashi, Shiro Otsuzuki, Tomohiro Yamaguchi, Masashi Higuchi, Yasuo Ichiki, Takayuki Kajihara
  • Publication number: 20080097055
    Abstract: A high molecular weight propylene polymer exhibiting high stereoregularity (isotactic) and high position selectivity can be effectively produced by polymerizing at least one monomer selected from propylene, ?-olefins and polyenes in the presence of a catalyst for olefin polymerization comprising: (A) a bridged metallocene compound represented by the General Formula [I] given in claims (diphenylmethylene(3-tert-butyl-5-ethyl-cyclopentadienyl)(fluorenyl)zirconium dichloride, etc.); and (B) one or more compound(s) selected from (b-1) an organoaluminumoxy compound (b-2) a compound which reacts with the bridged metallocene compound (A) to form an ion pair, and (b-3) an organoaluminum compound.
    Type: Application
    Filed: August 29, 2005
    Publication date: April 24, 2008
    Inventors: Munehito Funaya, Naritoshi Hirota, Mayumi Hiwara, Yasushi Tohi, Koji Kawai, Ryoji Mori, Masahiko Okamoto, Shigenobu Ikenaga, Hiromasa Marubayashi
  • Publication number: 20080085977
    Abstract: The propylene-based polymer composition of the present invention includes 41 to 95 parts by weight of a propylene-based polymer (A) having a Tm measured by DSC of not less than 120° C. and not more than 170° C., and 59 to 5 parts by weight (provided that the total of (A) and (B) is 100 parts by weight) of a propylene/ethylene/?-olefin copolymer (B) that contains 84.0 to 60.0 mol % of constitutional units derived from propylene, 15.0 to 30.0 mol % of constitutional units derived from ethylene, and 1.0 to 10.0 mol % of constitutional units derived from an ?-olefin having 4 to 20 carbon atoms and has a B-value of not less than 0.9 and not more than 1.5. This polymer composition is excellent in transparency, low-temperature impact resistance, and mechanical properties (flexibility or rigidity, etc.) and also excellent in heat resistance.
    Type: Application
    Filed: December 22, 2006
    Publication date: April 10, 2008
    Inventors: Masahiko Okamoto, Ryoji Mori, Takashi Nakagawa, Hiromasa Marubayashi, Shigenobu Ikenaga, Yasushi Tohi, Kouji Nagahashi