Patents by Inventor Masahiro Asami
Masahiro Asami has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 5434034Abstract: There is disclosed a silver halide color photographic material and a method for forming a color image using said color photographic material. The silver halide color photographic material comprises silver halide emulsion grains comprising silver chlorobromide having a high silver chloride content and being substantially free from silver iodide, and a cyan dye-forming coupler represented by formula (I) or (II), and said silver halide emulsion grains being formed by adding a water-soluble bromide at the grain formation step, and/or during the period from the completion of the formation of the grains to the coating of the cyan dye-forming layer onto the support: ##STR1## wherein Za and Zb each represent --N.dbd. or --C(R.sub.3).dbd., with one of Za and Zb being --N.dbd. and the other being --C(R.sub.3).dbd.; R.sub.1 and R.sub.2 each represent an electron-attracting group, whose Hammett substituent constant .sigma..sub.p value is 0.20 or more, with the sum of the .sigma..sub.p values of R.sub.1 and R.sub.Type: GrantFiled: April 15, 1993Date of Patent: July 18, 1995Assignee: Fuji Photo Film Co., Ltd.Inventor: Masahiro Asami
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Patent number: 5422232Abstract: Disclosed herein is a silver halide color photographic light-sensitive material comprising at least three silver halide emulsion layers having different color sensitivities and formed on a reflective support. The support comprises a substrate and a composition layer laminated on at least the surface of the substrate on which the emulsion layers are coated, and made of a thermoplastic resin containing polyester as a main component and a white pigment mixed and dispersed in the resin. The polyester is a polyester synthesized by the polycondensation of a dicarboxylic acid and a diol. The silver halide contained in the material is silver chlorobromide having silver chloride content of 95 mol % or more, or silver chloride. The ratio of the coated amount of all hydrophilic colloid used in the material to the coated amount of silver contained in all silver halide used in the material ranges from 5.0 to 30.Type: GrantFiled: November 30, 1993Date of Patent: June 6, 1995Assignee: Fuji Photo Film Co., Ltd.Inventors: Masahiro Asami, Naoto Ooshima
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Patent number: 5415978Abstract: An image is formed in a color photosensitive material through scanning exposure by using at least one semiconductor laser excited solid laser including a semiconductor laser, a non-linear optical element and means for controlling the temperature thereof as a light source for producing a laser beam. The laser beam is modulated by an external modulator in accordance with the image to be formed. Among the combinations of photosensitive layers and laser beams, at least two laser beam light sources are such that a laser beam has a wavelength falling within .+-.20 nm from the maximum wavelength in the spectral sensitivity distribution of the corresponding photosensitive layer. Each photosensitive layer has a spectral sensitivity distribution with a peak width of up to 40 nm.Type: GrantFiled: January 13, 1994Date of Patent: May 16, 1995Assignee: Fuji Photo Film Co., Ltd.Inventors: Masahiro Asami, Nobuharu Nozaki, Yoji Okazaki
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Patent number: 5399475Abstract: A silver halide photographic material having at least one light-sensitive silver halide emulsion layer coated on a support, wherein the silver halide emulsion layer contains silver chlorobromide grains comprising silver chlorobromide containing 90 mol % or more of silver chloride, having at least one region in which the silver bromide content is high at the vicinity of the corner of the grains, and with not more than 15 mol % of average silver bromide content at the surface of the grains. A method producing the silver halide photographic materials is also disclosed.Type: GrantFiled: December 11, 1992Date of Patent: March 21, 1995Assignee: Fuji Photo Film Co., Ltd.Inventors: Kazunori Hasebe, Osami Tanabe, Masahiro Asami, Naoto Ohshima, Keisuke Shiba, Toshihiro Nishikawa
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Patent number: 5368996Abstract: A color photographic material having photographic constituent layers including at least one light-sensitive silver halide emulsion layer on a reflective support, wherein the light-sensitive silver halide emulsion layer comprises silver chloride or silver chlorobromide containing 90 mol % or more of silver chloride is disclosed. The reflective support comprises at least one water-resistant resin layer, the water-resistant resin layer on the side of the support on which a silver halide emulsion layer is formed contains 14% by weight or more of a white pigment, and the total amount of calcium contained in the photographic constituent layers on the light-sensitive layer side of the photographic material is 10 mg/m.sup.2 or less, or the photographic material comprises at least one hydrophilic colloid layer on the support, the hydrophilic colloidal layer contains a white pigment at a coating amount of 2 g/m.sup.Type: GrantFiled: July 2, 1993Date of Patent: November 29, 1994Assignee: Fuji Photo Film Co., Ltd.Inventor: Masahiro Asami
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Patent number: 5284743Abstract: A silver halide photographic material comprising at least one photosensitive emulsion layer contains silver halide grains on a support. In the silver halide photographic material, (1) the silver halide grains are prepared in the presence of iridium compounds, (2) the silver halide grains consist of silver chlorobromide which is essentially free of silver iodide, (3) at least 90 mol% of all silver halide from which the silver halide grains are made is silver chloride, (4) the silver halide grains have localized phase in which the silver bromide content exceeds at least 20 mol%, (5) the localized phase is precipitated together with at least 50% of all the iridium which is added during the preparation of the silver halide grains, and (6) the surface of the silver halide grains is chemically sensitized to the extent that the grains are essentially of the surface latent image type.Type: GrantFiled: October 19, 1988Date of Patent: February 8, 1994Assignee: Fuji Photo Film Co., Ltd.Inventors: Naoto Ohshima, Masahiro Asami
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Patent number: 5273872Abstract: A silver halide photographic material having at least one light-sensitive emulsion layer on a support, wherein at least one light-sensitive emulsion layer has an emulsion containing silver halide grains of silver chlorobromide, silver chloroiodide, silver chloroiodobromide or silver chloride having a silver chloride content of 90 mol % or more, and incorporated with the silver halide grains are an iron compound of from 10.sup.-7 to 10.sup.-3 mol per mol of silver halide, and a tellurium compound of from 10.sup.-7 to 10.sup.-4 mol per mol of silver halide, before completion of physical ripening of the grains. The photographic material of the present invention is exposed for a short time period of 10.sup.-3 second or less and then color-developed to form a photographic image. The material has high sensitivity and high contrast and has excellent rapid processability.Type: GrantFiled: November 3, 1992Date of Patent: December 28, 1993Assignee: Fuji Photo Film Co. Ltd.Inventor: Masahiro Asami
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Patent number: 5244779Abstract: A silver halide color photographic material comprising on a reflective support at least three light-sensitive emulsion layers having different color sensitivities. At least one of the light-sensitive emulsion layers comprises a silver halide emulsion spectrally sensitized with at least one compound represented by the formula (I) in a red sensitive layer. At least one of the light-sensitive emulsion layers or light-insensitive layers comprises on the support at least one compound represented by the formula (II), (III) or (IV). The total amount of silver halide emulsion on the support is 0.65 g/m.sup.2 or less as calculated in terms of coated amount of silver. The formulas are shown and defined in the specification.Type: GrantFiled: January 13, 1992Date of Patent: September 14, 1993Assignee: Fuji Photo Film Co., Ltd.Inventor: Masahiro Asami
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Patent number: 5230995Abstract: In a method of manufacturing a silver halide emulsion which comprises a silver chlorobromide having a silver chloride content of 90 mol% or more or silver chloride and said silver halide containing substantially no silver iodide, the improvement which comprises the steps of,(i) adding to a reactor a compound capable of spectrally sensitizing the silver halide emulsion in a wavelength range between 590 nm and 720 nm, and(ii) then adding to the reactor a compound capable of spectrally sensitizing the silver halide emulsion in a wavelength range between 390 nm and 590 nm,prior to the completion of chemical sensitization of the silver halide emulsion, and color photographic material having the emulsion manufactured by the method.Type: GrantFiled: April 25, 1991Date of Patent: July 27, 1993Assignee: Fuji Photo Film Co., Ltd.Inventor: Masahiro Asami
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Silver halide photographic material which contains an iron dopant and substantially no silver iodide
Patent number: 5204234Abstract: There is disclosed a silver halide photographic material having at least one photosensitive emulsion layer containing silver halide emulsion of surface latent image type. The silver halide emulsion comprises high-silver-chloride emulsion grains that have a localized phase containing iron ions in a limited amount. According to the disclosure a silver halide photographic material can be attained that is excellent in rapid processability and high in sensitivity and contrast.Type: GrantFiled: October 10, 1990Date of Patent: April 20, 1993Assignee: Fuji Photo Film Co., Ltd.Inventor: Masahiro Asami -
Patent number: 5173395Abstract: A method for forming a color image which comprises developing an imagewise exposed silver halide color photographic material with a color developer containing at least one aromatic primary amine developing agent, wherein said silver halide color photographic material comprises a reflective support, whose transmission density in the red region ranges from 0.2 to 0.9, having thereon at least one light-sensitive emulsion layer containing at least one coupler capable of forming a dye on coupling with an oxidation product of the developing agent and silver chlorobromide grains comprising at least 80 mol % of silver chloride and containing substantially no silver iodide, said support having further provided thereon a dye represented by formula (A): ##STR1## wherein R.sub.101 and R.sub.102 each represents --OR.sub.105, --COOR.sub.105, ##STR2## --COR.sub.105, --CN or --R.sub.107, wherein R.sub.105 and R.sub.Type: GrantFiled: October 5, 1989Date of Patent: December 22, 1992Assignee: Fuji Photo Film Co., Ltd.Inventor: Masahiro Asami
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Patent number: 5166044Abstract: There are disclosed a silver halide emulsion and a silver halide photographic material using same. The silver halide emulsion comprises high-silver-chloride grains that have localized phases containing iron ions and iridium ions each in a limited amount. The disclosure as described provides a silver halide emulsion and a silver halide photographic material that are excellent in rapid processibility, high in sensitivity and contrast, less in the change of sensitivity due to a change of exposure illuminance.Type: GrantFiled: December 17, 1990Date of Patent: November 24, 1992Assignee: Fuji Photo Film Co., Ltd.Inventor: Masahiro Asami
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Patent number: 5108877Abstract: A method for forming a color image is described, using an image-wise exposed silver halide color photographic material comprising, a reflective support having thereon at least one silver halide emulsion layer containing at least one coupler that forms a dye by means of a coupling reaction with the oxidation product of an aromatic primary amine developing agent and silver halide grains comprising silver bromochloride containing not less than 90 mol % silver chloride and substantially not containing silver iodide, said silver halide grains having a localized silver bromide phase having a silver bromide content of not less than 20 mol % and being chemically sensitized at the surface thereof to provide substantially surface latent image type grains, comprising developing the light-sensitive material with a color developing solution containing from 3.5.times.10.sup.-2 to 1.5.times.10.sup.-1 mol/l of chloride ions and from 3.0.times.10.sup.-5 to 1.0.times.10.sup.-3 mol/l of bromide ions.Type: GrantFiled: April 9, 1991Date of Patent: April 28, 1992Assignee: Fuji Photo Film Co., Ltd.Inventor: Masahiro Asami
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Patent number: 5084374Abstract: There is disclosed a silver halide color photographic material having (A) a red-sensitive, (B) a green-sensitive, and (C) a blue sensitive silver halide emulsion layers, wherein the silver halide emulsion of each layer is a high-silver-chloride emulsion, and the silver halide emulsions of the red-sensitive and blue-sensitive layers is spectrally sensitized in the blue light region within a range satisfying specific relationships. Further two or more silver halide emulsions are mixed so that the gammas of the (A) red-sensitive and the (B) green-sensitive layers in the photosensitive region of the blue-sensitive layer may be in a limited range. The disclosure as described provides a silver halide color photographic material which can form a color image giving a stereoscopic feeling that can reproduce bright primary colors less in turbidity over the range from the low-density part to the high-density part, and which can produce fully the high-density region of primary colors with subtle shades.Type: GrantFiled: October 17, 1990Date of Patent: January 28, 1992Assignee: Fuji Photo Film Co., Ltd.Inventors: Kokichi Waki, Masahiro Asami
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Patent number: 5057402Abstract: A silver halide photographic material having at least one light-sensitive emulsion layer containing surface latent image type silver halide grains on a support, wherein the emulsion layer contains a silver halide emulsion, in an amount of 50% by weight or more, which is a substantially silver iodide-free silver chlorobromide comprising silver chloride in an amount of 70 mol % or more (as a mean value) of the total silver halide constituting the silver halide grains, which has a silver bromide-localized phase with a silver bromide content of less than 70 mol % in the inside or on the surface of the grains, and which further contains ions on in the grains.Type: GrantFiled: January 18, 1989Date of Patent: October 15, 1991Assignee: Fuji Photo Film Co., Ltd.Inventors: Keisuke Shiba, Kazunori Hasebe, Masahiro Asami
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Patent number: 4920042Abstract: A color image-forming process of developing a color photographic paper having on a support silver halide emulsion layer(s) containing a monodispersed silver chlorobromide emulsion having a deviation coefficient of not more than 20% and a color coupler, said emulsion being spectrally sensitized by at least one of the compounds represented by general formulae (I), (II), (III) and (IV) defined in this invention, using a color developer containing substantially no benzyl alcohol for a period of time of not more than 2 minutes and 30 seconds.In processing the aforesaid color photographic paper, even when the color paper is procesed using a color developer containing no benzyl alcohol, which caused pollution problems, in a short processing time of not more than 2 minutes and 30 seconds, stable color images having less formation of fog and high color density are obtained.Type: GrantFiled: August 10, 1989Date of Patent: April 24, 1990Assignee: Fuji Photo Film Co., Ltd.Inventors: Kokichi Waki, Masahiro Asami, Yoshinori Shibata
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Patent number: 4912029Abstract: Silver halide photographic materials of which the distinguishing features are that surface latent image type mono-disperse silver chlorobromide emulsions consisting of silver chlorobromide which is essentially silver iodide free, obtained by subjecting the surface of silver halide grains which have a plurality of layers which have different halogen compositions within the grains to halogen conversion, are included in at least one emulsion layer on a support.Type: GrantFiled: May 13, 1988Date of Patent: March 27, 1990Assignee: Fuji Photo Film Co., Ltd.Inventor: Masahiro Asami
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Patent number: 4892803Abstract: A color image-forming process which comprises developing, after imagewise exposure, a color photographic paper having at least one light-sensitive layer containing a core/shell surface latent image type monodispersed silver halide emulsion containing substantially no silver iodide, having a silver chloride content of up to 80 mol %, and having a silver bromide content in the shell portion lower than in the core portion with a color developer containing substantially no benzyl alcohol.When the color photographic paper described above is processed, color images having less fog can be obtained with high color density in a short time without using benzyl alcohol as a development accelerator, with the benzyl alcohol causing a pollution problem.Type: GrantFiled: September 23, 1987Date of Patent: January 9, 1990Assignee: Fuji Photo Film Co., Ltd.Inventors: Kokichi Waki, Kazunori Hasebe, Masahiro Asami
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Patent number: 4879206Abstract: A silver halide color photographic material which comprises a support having provided thereon at least one silver halide emulsion layer containing a cyan dye image-forming coupler represented by the following general formula (I), wherein the emulsion layer comprises silver bromide grains or silver chloro-bromide grains in which tabular grains having a mean aspect ratio of 5 or more amount to 50% or more based on the total projection area of the whole grains, and which are spectrally sensitized with a cyanine dye of the trimethine or pentamethine type or a merocyanine dye, which dye has a desensitization degree of 10 or more, thereby achieving high sensitivity and excellent fastness of photographic images and ensuring uniform quality in mass production: ##STR1## wherein R.sub.1 and R.sub.2 each represents a substituted or ubsubstituted aliphatic, aromatic or heterocyclic group; R.sub.Type: GrantFiled: December 27, 1988Date of Patent: November 7, 1989Assignee: Fuji Photo Film Co., Ltd.Inventor: Masahiro Asami
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Patent number: 4865962Abstract: A photographic light-sensitive material comprising a support having thereon at least one light-sensitive silver halide emulsion layer, characterized in that the emulsion layer contains silver chlorobromide prepared in such a manner that silver halide regular crystal grains, having no twinning crystal plane and containing 50 mol % or more of silver chloride, are used as host grains, an organic compound is adsorbed on a surface of each of the host grains, and sulfur-plus-gold sensitization is performed, either during or after halide conversion in the presence of a bromide.Type: GrantFiled: December 28, 1987Date of Patent: September 12, 1989Assignee: Fuji Photo Film Co., Ltd.Inventors: Kazunori Hasebe, Masahiro Asami, Naoto Ohshima, Keisuke Shiba, Toshihiro Nishikawa, Kei Sakanoue, Akira Abe