Patents by Inventor Masaji Hirota
Masaji Hirota has filed for patents to protect the following inventions. This listing includes patent applications that are pending as well as patents that have already been granted by the United States Patent and Trademark Office (USPTO).
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Patent number: 10457632Abstract: The present invention provides a process for producing an isocyanate compound such as 3-methyl-2-methoxymethyl-1-isocyanate benzene and the like. By reacting 3-Methyl-2-methoxymethyl aniline and the like with phosgene in the presence of a tertiary amine at 10° C. to 14° C. in one or more solvents selected from the group consisting of toluene and xylene, isocyanate compounds such as 3-methyl-2-methoxymethyl-1-isocyanate benzene and the like can be produced at high yield.Type: GrantFiled: December 14, 2016Date of Patent: October 29, 2019Assignee: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Takashi Miyamoto, Yuta Nagashima, Masaji Hirota
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Publication number: 20180354894Abstract: The present invention provides a process for producing an isocyanate compound such as 3-methyl-2-methoxymethyl-1-isocyanate benzene and the like. By reacting 3-Methyl-2-methoxymethyl aniline and the like with phosgene in the presence of a tertiary amine at 10° C. to 14° C. in one or more solvents selected from the group consisting of toluene and xylene, isocyanate compounds such as 3-methyl-2-methoxymethyl-1-isocyanate benzene and the like can be produced at high yield.Type: ApplicationFiled: December 14, 2016Publication date: December 13, 2018Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Takashi MIYAMOTO, Yuta NAGASHIMA, Masaji HIROTA
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Patent number: 10053419Abstract: By reacting 3-methyl-2-methoxymethylaniline, etc. with a phosgene compound in the presence of a tertiary amine at 10° C. to 14° C. in at least one kind of solvent selected from a group consisting of chlorobenzene and ortho-dichlorobenzene, an isocyanate compound such as 3-methyl-2-methoxymethyl-1-isocyanatobenzene can be manufactured with good yields.Type: GrantFiled: November 27, 2015Date of Patent: August 21, 2018Assignee: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Yuya Yoshimoto, Masaji Hirota
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Publication number: 20170342023Abstract: By reacting 3-methyl-2-methoxymethylaniline, etc. with a phosgene compound in the presence of a tertiary amine at 10° C. to 14° C. in at least one kind of solvent selected from a group consisting of chlorobenzene and ortho-dichlorobenzene, an isocyanate compound such as 3-methyl-2-methoxymethyl-1-isocyanatobenzene can be manufactured with good yields.Type: ApplicationFiled: November 27, 2015Publication date: November 30, 2017Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Yuya YOSHIMOTO, Masaji HIROTA
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Patent number: 8937200Abstract: A new process capable of producing a 2-(aryloxymethyl)benzaldehyde compound is provided. More particularly, a process for producing a 2-(aryloxymethyl)benzaldehyde compound represented by formula (2) comprising a step of hydrolyzing a compound represented by following formula (1); wherein X1 and X2 each represent independently a chlorine atom, a bromine atom or an iodine atom, Q1, Q2, Q3 and Q4 each represent independently a hydrogen atom or a halogen atom, and Ar represents a phenyl group optionally having a substituent.Type: GrantFiled: June 27, 2012Date of Patent: January 20, 2015Assignee: Sumitomo Chemical Company, LimitedInventors: Masaji Hirota, Masashi Takimoto, Tomonori Yamaoka, Yoshio Onogawa
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Publication number: 20140221695Abstract: A new process capable of producing a 2-(aryloxymethyl)benzaldehyde compound is provided. More particularly, a process for producing a 2-(aryloxymethyl)benzaldehyde compound represented by formula (2) comprising a step of hydrolyzing a compound represented by following formula (1); wherein X1 and X2 each represent independently a chlorine atom, a bromine atom or an iodine atom, Q1, Q2, Q3 and Q4 each represent independently a hydrogen atom or a halogen atom, and Ar represents a phenyl group optionally having a substituent.Type: ApplicationFiled: June 27, 2012Publication date: August 7, 2014Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Masaji Hirota, Masashi Takimoto, Tomonori Yamaoka, Yoshio Onogawa
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Patent number: 8624062Abstract: A method for producing a phenylacetamide compound represented by formula (1): wherein Q represents a hydrogen atom or a halogen atom, R2 represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, R4 represents an alkyl group having 1 to 4 carbon atoms, Ar represents an unsubstituted or substituted phenyl group, R5 represents R4 when R2 is a hydrogen atom, and R5 represents a hydrogen atom when R2 is an alkyl group having 1 to 4 carbon atoms; including reacting a phenylacetamide compound represented by formula (2): wherein Q, R2 and Ar have the same meanings as defined above; with a dialkyl sulfate represented by formula (3): wherein R4 has the same meaning as defined above; in the presence of a base.Type: GrantFiled: February 12, 2010Date of Patent: January 7, 2014Assignee: Sumitomo Chemical Company, LimitedInventors: Hajime Ishida, Masaji Hirota, Yoko Miyanaga, Yuya Mizushima
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Patent number: 8338625Abstract: A method of producing a corresponding acetal compound which comprises reacting a benzal halide compound represented by formula (1) (wherein, Q represents a hydrogen atom or a halogen atom, X represents a halogen atom, and Ar represents a phenyl group optionally substituted with at least one group selected from the group consisting of alkyl groups having 1 to 4 carbon atoms and halogen atoms.) and an alcohol compound in the presence of at least one alkaline earth metal compound selected from the group consisting of alkaline earth metal oxides, alkaline earth metal hydroxides and alkaline earth metal carbonates.Type: GrantFiled: June 9, 2009Date of Patent: December 25, 2012Assignee: Sumitomo Chemical Company, LimitedInventors: Yoshio Onogawa, Kazuyoshi Yamanaka, Masaji Hirota
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Publication number: 20120310003Abstract: A method for producing a salt of an amine with a cyanoalkenylcyclopropanecarboxylic acid, the method comprising a first step of mixing a carboxylic acid compound represented by formula (2C) and at least one amine selected from the group consisting of primary amines and secondary amines in an organic solvent; a second step of depositing a salt of the amine with a cyanoalkenylcyclopropanecarboxylic acid represented by formula (2) from the mixture obtained in the first step; and a third step of recovering the salt deposited in the second step; wherein, R represents an alkyl group optionally having a substituent or a halogen atom.Type: ApplicationFiled: February 10, 2011Publication date: December 6, 2012Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Ichiro Komoto, Toshio Somyo, Masaji Hirota
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Patent number: 8309752Abstract: A method for producing a compound represented by the following formula (2) (wherein, X, R1 and m represent respectively the same meaning as described below) which comprises reacting a compound represented by the following formula (1) (wherein, X represents an optionally substituted alkyl group or the like. R1 represents an optionally substituted alkyl group or the like. m represents an integer of 0 to 4. When m represents an integer of 2 to 4, R1s may be the same or different from each other) with hydrogen cyanide in an amount of 1.2 to 5 mol with respect to 1 mol of the compound, in the presence of an organic base, in an organic solvent.Type: GrantFiled: June 24, 2009Date of Patent: November 13, 2012Assignee: Sumitomo Chemical Company, LimitedInventors: Hajime Ishida, Masaji Hirota
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Patent number: 8299288Abstract: Disclosed is a method for producing a compound represented by Formula (4), the method including Step I of adding a solution in which hydrogen chloride is dissolved in an alcohol, to a mixture containing an organic solvent and a compound represented by Formula (1), and Step II of mixing a compound obtained in Step I, represented by Formula (3), with water.Type: GrantFiled: August 24, 2009Date of Patent: October 30, 2012Assignee: Sumitomo Chemical Company, LimitedInventors: Hajime Ishida, Masaji Hirota
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Publication number: 20120101294Abstract: Disclosed is a process for producing a (fluoroalkylthio)acetic acid ester represented by the formula (3) wherein R, R1 and R2 have the same meanings as defined below, which comprises reacting a thioglycolic acid ester represented by the formula (1) wherein R represents a hydrogen atom or an alkyl group having 1 to 5 carbon atoms, and R1 represents an alkyl group having 1 to 4 carbon atoms, with fluoroolefin represented by the formula (2) wherein R2 represents a fluoroalkyl group having 1 to 5 carbon atoms, in the presence of a radical generator.Type: ApplicationFiled: August 6, 2010Publication date: April 26, 2012Inventors: Masaji Hirota, Hiroyuki Miyazaki, Tadayoshi Itoh
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Publication number: 20110295035Abstract: A method for producing a phenylacetamide compound represented by formula (1): wherein Q represents a hydrogen atom or a halogen atom, R2 represents a hydrogen atom or an alkyl group having 1 to 4 carbon atoms, R4 represents an alkyl group having 1 to 4 carbon atoms, Ar represents an unsubstituted or substituted phenyl group, R5 represents R4 when R2 is a hydrogen atom, and R5 represents a hydrogen atom when R2 is an alkyl group having 1 to 4 carbon atoms; including reacting a phenylacetamide compound represented by formula (2): wherein Q, R2 and Ar have the same meanings as defined above; with a dialkyl sulfate represented by formula (3): wherein R4 has the same meaning as defined above; in the presence of a base.Type: ApplicationFiled: February 12, 2010Publication date: December 1, 2011Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Hajime Ishida, Masaji Hirota, Yoko Miyanaga, Yuya Mizushima
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Publication number: 20110118498Abstract: A method for producing a compound represented by the following formula (2) (wherein, X, R1 and m represent respectively the same meaning as described below) which comprises reacting a compound represented by the following formula (1) (wherein, X represents an optionally substituted alkyl group or the like. R1 represents an optionally substituted alkyl group or the like. m represents an integer of 0 to 4. When m represents an integer of 2 to 4, R1s may be the same or different from each other) with hydrogen cyanide in an amount of 1.2 to 5 mol with respect to 1 mol of the compound, in the presence of an organic base, in an organic solvent.Type: ApplicationFiled: June 24, 2009Publication date: May 19, 2011Inventors: Hajime Ishida, Masaji Hirota
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Publication number: 20110098489Abstract: A method of producing a corresponding acetal compound which comprises reacting a benzal halide compound represented by formula (1) (wherein, Q represents a hydrogen atom or a halogen atom, X represents a halogen atom, and Ar represents a phenyl group optionally substituted with at least one group selected from the group consisting of alkyl groups having 1 to 4 carbon atoms and halogen atoms.) and an alcohol compound in the presence of at least one alkaline earth metal compound selected from the group consisting of alkaline earth metal oxides, alkaline earth metal hydroxides and alkaline earth metal carbonates.Type: ApplicationFiled: June 9, 2009Publication date: April 28, 2011Applicant: SUMITOMO CHEMICAL COMPANY, LIMITEDInventors: Yoshio Onogawa, Kazuyoshi Yamanaka, Masaji Hirota
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Patent number: 7880038Abstract: A metal catalyst obtained by contacting (A) at least one metal or metal compound selected from i) tungsten compounds composed of tungsten and an element of group IIIb, IVb, Vb, or VIb, ii) molybdenum compounds composed of molybdenum and an element of group IIIb, IVb, Vb, or VIb, and iii) tungsten metal and molybdenum metal; (B) at least one compound selected from tertiary amine compounds, tertiary amine oxide compounds, nitrogen-containing aromatic compounds and nitrogen-containing aromatic N-oxide compounds; (C) hydrogen peroxide; and (D) a phosphate compound, is provided.Type: GrantFiled: April 14, 2004Date of Patent: February 1, 2011Assignee: Sumitomo Chemical Company, LimitedInventors: Masaji Hirota, Koji Hagiya
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Patent number: 7491845Abstract: It is provided to a process for producing adipic acid which comprises making a wastewater containing hydroxycaproic acid and discharged from the step of oxidizing cyclohexane with molecular oxygen in a liquid phase react with hydrogen peroxide in the presence of a tungsten catalyst in the pH range of 0 to 6.Type: GrantFiled: May 18, 2004Date of Patent: February 17, 2009Assignee: Sumitomo Chemical Company, LimitedInventors: Masaji Hirota, Koji Hagiya
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Publication number: 20080039653Abstract: It is provided to a process for producing adipic acid which comprises making a wastewater containing hydroxycaproic acid and discharged from the step of oxidizing cyclohexane with molecular oxygen in a liquid phase react with hydrogen peroxide in the presence of a tungsten catalyst in the pH range of 0 to 6.Type: ApplicationFiled: May 18, 2004Publication date: February 14, 2008Inventors: Masaji Hirota, Koji Hagiya
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Publication number: 20070078273Abstract: A process for preparing 5-methyl-2-furfural in a high yield by reacting 2-methylfuran, phosgene and N,N-dimethylformamide in a reaction medium comprising a hydrocarbon at a temperature of at least 45° C. and hydrolyzing a reaction mixture.Type: ApplicationFiled: September 28, 2006Publication date: April 5, 2007Inventor: Masaji Hirota
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Publication number: 20060211891Abstract: A metal catalyst obtained by contacting (A) at least one metal or metal compound selected from i) tungsten compounds composed of tungsten and an element of group IIIb, IVb, Vb, or VIb, ii) molybdenum compounds composed of molybdenum and an element of group IIIb, IVb, Vb, or VIb, and iii) tungsten metal and molybdenum metal; (B) at least one compound selected from tertiary amine compounds, tertiary amine oxide compounds, nitrogen-containing aromatic compounds and nitrogen-containing aromatic N-oxide compounds; (C) hydrogen peroxide; and (D) a phosphate compound, is provided.Type: ApplicationFiled: April 14, 2004Publication date: September 21, 2006Inventors: Masaji Hirota, Koji Hagiya